# Physical Sciences Grade 12 P2 Gauteng Mock 2016 QP

> Grade 12 Physical Sciences Paper 2 question paper from the Gauteng Mock Exam 2016, 21 pages. Read online or download the free PDF.

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- Updated: 2026-09-27
- Subject: Physical Sciences
- Grade: Grade 12
- Document type: Question paper
- Year: 2016
- Exam period: Gauteng Mock Exam
- Paper: 2
- Curriculum: CAPS
- Pages: 21

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               GAUTENG DEPARTMENT OF EDUCATION
                      PREPARATORY EXAMINATION
                                  2016
                                  10842
                        PHYSICAL SCIENCES: CHEMISTRY

                              SECOND PAPER

TIME:    3 hours

MARKS: 150

17 pages + 4 information sheets

                                                       P.T.O.

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                                       PHYSICAL SCIENCES: CHEMISTRY                2
                                       (Second Paper)            10842/16

                       GAUTENG DEPARTMENT OF EDUCATION
                         PREPARATORY EXAMINATION – 2016

                                               PHYSICAL SCIENCES
                                               (Second Paper)

                                               TIME: 3 hours

                                               MARKS: 150

INSTRUCTIONS AND INFORMATION:

1.    Write your name in the appropriate space on the ANSWER BOOK.

2.    This question paper consists of 11 questions. Answer ALL the questions in
      the ANSWER BOOK.

3.    Start the answer to each question on a NEW page.

4.    Number the answers correctly according to the numbering system used in
      this question paper.

5.    Leave ONE line open between sub-questions, for example, between
      QUESTION 2.1 and QUESTION 2.2.

6.    You may use a non-programmable calculator.

7.    You may use appropriate mathematical instruments.

8.    You are advised to use the attached DATA SHEETS.

9.    Show ALL formulae and substitutions in ALL calculations.

10.   Round off your final numerical answers to a minimum of TWO decimal
      places.

11.   Give brief discussions, et cetera where required.

12    Write neatly and legibly.

                                                                                  P.T.O.

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QUESTION 1: MULTIPLE-CHOICE QUESTIONS
Four options are given as possible answers to the following questions. Each question has only
ONE correct answer. Write only the letter (A–D) next to the question number (1.1–1.10) in the
ANSWER BOOK.

1.1 Which ONE of the following is the functional group of the carboxylic acids?

      A     C       C                    B        O    H

                                                 O
      C         C       C                D       C    O     H
                                                                                                (2)

1.2 Consider the reaction represented below:

                                  HCℓO 2 + H 2 O ⇌ H 3 O+ + CℓO −2

      Which ONE of the following is a conjugate acid-base pair in the above reaction?

      A    HCℓO 2 and CℓO −2
      B    HCℓO 2 and H 2 O
      C    CℓO −2 and H 3 O+
      D    HCℓO 2 and H 3 O+                                                                    (2)

1.3   Which ONE of the following compounds has the highest boiling point?

      A    CH3CH3

      B    CH3CH2CH3

      C    CH3CH2CH2CH3

      D    CH3CH2CH2CH2CH3                                                                      (2)

                                                                                         P.T.O.

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1.4 A learner leaves a coil of copper wire overnight in a clear solution of silver nitrate. The
    next morning the learner observes that the solution turned blue. Which ONE of the
    equations below represents the reaction that takes place?

      A    Cu + Ag+ → Cu+ + Ag

      B    2Ag + Cu2+ → Cu + 2Ag+

      C    2Ag+ + Cu+ → 2Ag + Cu2+

      D    Cu + 2Ag+ → Cu2+ + 2Ag
                                                                                                        (2)

1.5 The half-reactions below take place in an electrochemical cell.

                                            Pt2+ + 2e- → Pt
                                             Cs+ + e- → Cs

      Which ONE of the statements below is TRUE for this cell when it delivers current?

      A    The mass of the Cs electrode increases.
      B    Pt2+ undergoes oxidation more easily than Cs.
      C    Pt2+ undergoes reduction more easily than Cs+.
      D    Electrons will flow from the Pt electrode to the Cs electrode in the external circuit.
                                                                                                        (2)

1.6   Two reactions, X and Y, represented below reach equilibrium in two separate, sealed
      containers.

      Reaction X:         2HI(g) ⇌ H 2 (g) + I 2 (g)
      Reaction Y:         CaCO 3 (s) ⇌ CaO(s) + CO 2 (g)

      The pressure in both containers is increased by decreasing the volume of the
      container. How will the number of moles of the products in each container change?

                 X                   Y
      A       Increases                  Decreases
      B       Stays the same             Increases
      C       Stays the same             Decreases
      D       Increases                  Stays the same                                                 (2)

                                                                                               P.T.O.

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1.7   Carbon monoxide, CO(g), and hydrogen, H 2 (g), react in a closed container to form
      methanol, CH 3 OH(g), according to the following balanced equation:

                                    CO(g) + 2H 2 (g) ⇌ CH 3 OH(g)

      The graph below shows the change in concentration of methanol with time.

                                   Concentration

                                     (mol·dm-3)

                                                         t    Time (s)
      Which ONE of the following statements, best explains the horizontal section of the
      graph after time t?

      A    The forward reaction has stopped.
      B    The rates of the forward and reverse reactions are equal.
      C    There is no CO(g) left to react with the H 2 (g).
      D    All the reacting gases have been converted to methanol.                                 (2)

1.8   When base X is titrated against acid Y, the pH of the solution at the end point is 8.
      Which ONE of the following represents base X and acid Y?

                   X                   Y
       A        NaOH           CH 3 COOH

       B       Na 2 CO 3           HCℓ

       C        NaOH             H 2 SO 4

       D       Na 2 CO 3       CH 3 COOH                                                           (2)

                                                                                              P.T.O.

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1.9    Two of the half-reactions below take place in a standard electrochemical cell with an
       emf of 1,2 V.

       R+ + e- ⇌ R                                    E θred = - 1,5 V
       P2+ + 2e- ⇌ P                                  E θred = - 0,3 V
       Q+ + e- ⇌ Q                                    E θred = - 0,9 V
       S2+ + 2e- ⇌ S                                  E θred = + 1,5 V

       The cell notation of this cell is:

       A    S(s)∣S2+(aq)∣∣P2+(aq)∣P(s)

       B    P(s)∣P2+(aq)∣∣Q+(aq)∣Q(s)

       C    R(s)∣R+(aq)∣∣S2+(aq)∣S(s)

       D    R(s)∣R+(aq)∣∣P2+(aq) ∣ (s)
                                                                                                    (2)

1.10    The graph below shows the relationship between the amount of substance and time
        in a chemical reaction involving substances K, L and M.

                                             5                                   K

                       Amount of substance
                                             4                                   L

                                             3                                   M

                               (mol)
                                             2

                                             1

                                             0
                                                 0   10        20          30   40
                                                                Time (s)

        The equation for the reaction can be represented as:

       A    3M → 4K + 5L
       B    5M → 2K + L
       C    M → 2K + L
       D    M → K + 2L                                                                             (2)
                                                                                                 [20]

                                                                                               P.T.O.

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QUESTION 2
2.1   Consider the structural formula of an organic compound below.

                                              H
                                                       H
                                          H   C   H
                                      H           H    C   H

                               H      C       C        C       H

                                      H       H   H    C   H
                                                       H

      2.1.1    Is the above compound a SATURATED or an UNSATURATED
               hydrocarbon? Give a reason for the answer.
                                                                                               (2)
      2.1.2    Write down the IUPAC name of the above compound.                                (2)

2.2   Draw the structural formula of 4,4-dimethylhexan-2-one.                                  (3)

2.3   In industry ethene is used to synthesise a variety of organic compounds. The flow
      diagram below illustrates some of the reactions that ethene can undergo.

              Write down:

      2.3.1   The general formula of the homologous series to which ethene belongs.            (1)

      2.3.2   A balanced equation, using structural formulae, for reaction B.                  (3)

      2.3.3   The type of reaction represented by G.                                           (1)

      2.3.4   The FORMULA of the inorganic reactant needed for reaction F.                     (1)

      2.3.5   The letter that represents a dehydrohalogenation reaction.                       (1)
                                                                                          P.T.O.

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      2.3.6   How the base used in reaction E differs from the base used in reaction G.         (1)

      2.3.7   The NAME or FORMULA of the catalyst used in reaction C.                           (1)
                                                                                               [16]

QUESTION 3
3.1   Write down the name of the homologous series to which each of the following
      compounds belongs:

      3.1.1   CH 3 CHO                                                                          (1)

      3.1.2   CH 3 COCH 3                                                                       (1)

3.2   3.2.1   Define the term positional isomer.                                                (2)

      3.2.2   Write down the structural formula of an isomer of 1-chloropropane.                (2)

3.3   The compound responsible for a fruity scent, pentyl butanoate, is prepared in the
      laboratory.

      Write down the:

      3.3.1   IUPAC names of TWO compounds needed for this preparation.                         (2)

      3.3.2   Type of reaction that takes place.                                                (1)

3.4   Consider the structural formula of a polymer shown below.

                     H      H     H     H      H    H      H      H    H

                     C      C     C     C      C    C      C      C    C

                     H      H     H     H      H    H      H      H    H

      Write down the:

      3.4.1   IUPAC name of this polymer.                                                       (1)

      3.4.2   Structural formula of the monomer used to prepare this polymer.                   (1)

      3.4.3   Type of polymer of which it is an example.                                        (1)
                                                                                               [12]

                                                                                          P.T.O.

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QUESTION 4
 The table below shows data collected for four organic compounds during two practical
 investigations. The compounds are represented by the letters A, B, C and D. The boiling
 point of compound B is unknown and recorded as X.

  Investigation                                          Relative         Boiling point
                         Organic compound
                                                      molecular mass           (˚C)
                     A CH 3 CH 2 CH 2 CH 2 CH 3            72,15               36,1
          I
                     B   CH 3 CH(CH 3 )CH 2 CH 3           72,15                 X
                     C   CH 3 CH 2 CH 2 CH 2 OH            74,12                117
         II
                     D CH 3 CH 2 COOH                      74,08               141,2

4.1   For investigation II, write down the:

      4.1.1    Dependent variable.                                                                  (1)

      4.1.2    Independent variable.                                                                (1)

      4.1.3    Controlled variable                                                                  (1)

4.2   Will the boiling point of compound B, be HIGHER THAN, LOWER THAN or EQUAL
      TO the boiling point of compound A?                                                           (1)

4.3   Fully explain the answer to QUESTION 4.2.                                                     (3)

4.4   How will the vapour pressure of compound C compare to that of compound D?
      Choose from HIGHER THAN, LOWER THAN or EQUAL TO.                                              (1)

4.5   Fully explain the answer to QUESTION 4.4                                                      (3)

4.6   Write down the STRUCTURAL FORMULA and IUPAC NAME of a FUNCTIONAL
      isomer of compound D.                                                                       (4)
                                                                                                [15]

                                                                                           P.T.O.

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QUESTION 5
A group of learners use the reaction between magnesium and nitric acid to investigate one of
the factors that affects reaction rate. The reaction that takes place is represented by the
balanced equation below.

                       Mg(s) + 2HNO 3 (aq) → Mg(NO 3 ) 2 (aq) + H 2 (g)

They add magnesium ribbon to dilute nitric acid and measure the mass of magnesium used
per unit time. The experiment is repeated using concentrated nitric acid.

5.1   Write down an investigative question for this investigation.                                   (2)

      The results obtained for the reaction with dilute nitric acid are represented in the
      graph below:

                                              1,0

                        Amount of magnesium   0,8

                               (mol)

                                                0 30   Time (s)

5.2   Which substance, Mg or HNO 3 , is in excess? Use the information on the graph to
      give a reason for the answer.                                                                  (2)

5.3   Define the term reaction rate.                                                                 (2)

5.4   Calculate the average rate of the reaction (in gram per second) during the first 30 s.         (5)

5.5   Copy the above graph in your answer book. On the same set of axes use a DOTTED
      LINE to show the curve that will be obtained when concentrated nitric acid is used.
      No numerical values are required.                                                            (2)
                                                                                                  [13]

                                                                                               P.T.O.

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QUESTION 6
6.1   Curve L shown below, is the Maxwell-Boltzman distribution curve for a gas in a closed
      container at 250 °C.

         Fraction of molecules

                                                 Kinetic energy

      6.1.1                      Name the energy represented by N.                                                     (1)

      6.1.2                      Write down the change in reaction conditions that resulted in:

                                 (a)    Curve M.                                                                       (1)

                                 (b)    Curve K.

                                        Use the collision theory to explain how this change affects the rate of
                                        the reaction.                                                                  (4)

                                                                                                              P.T.O.

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6.2   A series of experiments are carried out to compare the reactions of zinc foil, zinc
      powder, copper powder and a mixture of zinc powder and copper pieces with dilute
      sulfuric acid of concentration 1 mol·dm-3. Hydrogen gas is produced in all test tubes
      where a reaction takes place. The diagram shows the test tubes some time after the
      metals have been added to the acid.
              A                   B                                C                     D

                   H2SO4(aq)                                            H2SO4(aq)

         Zn foil               Zn powder                        Cu powder         Zn powder
                                                                                       +
                                                                                  Cu pieces

      6.2.1       Refer to the relative strengths of oxidizing agents or reducing agents to
                  explain why no reaction takes place in test tube C.                       (3)

      6.2.2       How does the rate of the reaction in test tube B compare to that in:
                  (Choose from GREATER THAN, SMALLER THAN or EQUAL TO.)

                  (a) Test tube A?
                      Give a reason for your answer.
                                                                                                     (2)
                  (b) Test tube D?
                      Give a reason for your answer.                                                 (2)

                                                                                                    [13]

                                                                                              P.T.O.

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QUESTION 7
7.1   The reaction represented below reaches equilibrium in a closed container.

                                     4C(s) + 5H 2 (g) ⇌ C 4 H 10 (g)

      The equilibrium constants for this reaction at two different temperatures are given in
      the table below.

                  TEMPERATURE                 EQUILIBRIUM
                      (K)                    CONSTANT (K c )
                      400                      1,58 x 10-3
                      600                      1,58 x 10-9

      7.1.1 Is the forward reaction ENDOTHERMIC or EXOTHERMIC?                                        (1)

      7.1.2 Use Le Chatelier’s principle to explain your answer in QUESTION 7.1.1.                    (3)

      7.1.3 The pressure in the container is now decreased by increasing the volume of
            the container. What effect will this have on the value of the equilibrium
            constant?

             Choose from INCREASES, DECREASES or REMAINS THE SAME.                                    (1)

      7.1.4 Give a reason for the answer to QUESTION 7.1.3.                                           (1)

7.2   Exactly 24,0 mol SO 3 (g) is sealed in an empty 2,0 dm3 container. The reaction
      reaches equilibrium at 700 K after 8 minutes according to the following balanced
      equation.

                                    2SO 3 (g) ⇌ 2SO 2 (g) + O 2 (g)

      If the reaction mixture contains 10,0 mol O 2 (g) at equilibrium at 700 K, calculate the
      equilibrium constant (K c ) at 700 K.                                                            (7)
                                                                                                      [13]

                                                                                             P.T.O.

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QUESTION 8

An electrochemical cell is set up as shown in the diagram below.

                                           V

                                       Salt bridge
                                        NaCℓ(aq)

                          Fe                                  Pt

                            Fe2+(aq)                 MnO −4 (aq)

8.1   What is the function of the salt bridge?                                                   (1)

8.2   Briefly explain the main difference between the cell illustrated above and an
      electrolytic cell by referring to the energy transferred.                                  (2)

8.3   Which electrode, Fe or Pt, is the cathode? Give a reason for the answer.                   (2)

8.4   Write down the FORMULA of the reducing agent in this cell.                                 (1)

8.5   Write down the overall cell reaction that takes place in this cell.                        (3)

8.6   Calculate the initial reading on the voltmeter when this cell functions under standard
      conditions.                                                                                (4)
                                                                                               [13]

                                                                                        P.T.O.

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QUESTION 9
The diagram below shows a simplified cell used to electroplate an iron spoon with silver.

                         silver                            Iron spoon

9.1   Define the term electrolyte.
                                                                                                     (2)
9.2   Write down the:

      9.2.1   NAME of a substance that can be used as electrolyte in this cell.                      (1)

      9.2.2   NAME or FORMULA of the substance which is oxidised.                                    (1)

      9.2.3   Half-reaction that takes place at the cathode.                                         (2)

9.3   Calculate the number of electrons transferred if 2 gram of silver is plated on the spoon.     (4)
                                                                                                  [10]

                                                                                            P.T.O.

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QUESTION 10

10.1   A factory accidentally spills sulphuric acid into a nearby river. The fish species in the
       river CANNOT survive in water with a pH LOWER THAN 5,8.

       Analysis of water samples from the river shows that the hydrogen ion concentration is
       5,6 x 10-6 mol·dm-3. Show with the aid of a calculation that the fish will not survive in
       the river.                                                                                    (3)

10.2   A sample of seawater is treated with 500 cm3 of a 2,5 mol·dm-3 sodium hydroxide
       solution to remove the magnesium ions. The reaction that takes place is represented
       by the following balanced equation:

                     Mg(NO 3 ) 2 (aq)+ 2NaOH(aq) → Mg(OH) 2 (s) + 2NaNO 3 (aq)

       After removal of the precipitate, the excess NaOH(aq) is titrated with 95 cm3 of a
       0,2 mol·dm3 sulphuric acid solution. The balanced equation for the reaction is:

                         2NaOH(aq) + H 2 SO 4 (aq) → Na 2 SO 4 (aq) + 2H 2 O(ℓ)

                Calculate the:

       10.2.1   Number of moles sodium hydroxide added to the seawater.                              (3)

       10.2.2   Original mass of magnesium nitrate in the seawater.                                  (6)

                                                                                                    [12]

                                                                                              P.T.O.

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QUESTION 11
11.1   A fertilizer bag is labelled 1:4:2(30).

       Explain the meaning of the:

       11.1.1     Ratio, 1:4:2.                                                                      (2)

       11.1.2     Value in brackets (30).                                                            (1)

11.2   Consider the two nitrogen containing fertilisers:

                Ammonium nitrate:           NH 4 NO 3
                Urea:                       (NH 2 ) 2 CO
       Which of the above fertilisers will provide the greatest amount of nitrogen per kg of
       fertiliser used?                                                                              (4)

11.3   The flow diagram below shows two industrial processes, A and B, used in the
       production of fertilizers.

                                         Process A

                              Nitrogen                  Hydrogen

                                         Process B

                                                                   H2SO4
                                    Ammonia

                                                              Y
       Write down the:

       11.3.1    NAME of process A.                                                                  (1)

       11.3.2    Balanced equation for the reaction that takes place in the process B.               (3)

       11.3.3    FORMULA and the NAME of the fertilizer represented by Y.                            (2)
                                                                                                     [13]

                                                                                     TOTAL: 150

                                                                                               P.T.O.

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                                   DATA FOR PHYSICAL SCIENCES GRADE 12
                                           PAPER 2 (CHEMISTRY)

                            GEGEWENS VIR FISIESE WETENSKAPPE GRAAD 12
                                       VRAESTEL 2 (CHEMIE)

TABLE 1: PHYSICAL CONSTANTS/TABEL 1: FISIESE KONSTANTES

NAME/NAAM                                      SYMBOL/SIMBOOL                       VALUE/WAARDE
Standard pressure
                                                               pθ                           1,013 x 105 Pa
Standaarddruk
Molar gas volume at STP
                                                              Vm                             22,4 dm3∙mol-1
Molêre gasvolume by STD
Standard temperature
                                                              Tθ                                    273 K
Standaardtemperatuur
Charge on electron                                             e                                 -1,6 x 10-19 C
Avogadro’s’ number                                                                                6,02×1023

TABLE 2: FORMULAE/TABEL 2: FORMULES

   m                                                 N
n=                                              n=
   M                                                 NA
   n       m                                          V
c = or c =                                      n=
   V       MV                                        Vm
c a Va  n
       = a                                      pH = -log[H 3 O+]
cb Vb   nb
Eθcell = Eθcathode − Eθanode / E θsel = E katode
                                          θ
                                                 − E θanode

E θcell = E reduction
            θ
                      − E θoxidation / E θsel = E reduksie
                                                  θ
                                                           − E θoksidasie

E θcell = E θoxidising agent − E reducing
                                 θ                  θ       θ                   θ
                                          agent / E sel = E oksideermi ddel − E reduseermiddel

                                                                                                                  P.T.O.

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                                                       P.T.O.

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                                                             TABLE 4A: STANDARD REDUCTION POTENTIALS
                                                             TABEL 4A: STANDAARD REDUKSIEPOTENSIALE
                                                                                                 θ
                                                                     Half-reactions/Halfreaksies
                                                                                                                     E   (V)
                                                                                         −            −
                                                                            F 2 (g) + 2e     ⇌   2F                  + 2,87
                                                                              Co3+ + e−      ⇌   Co2+                + 1,81
                                                                   H 2 O 2 + 2H+ +2e−        ⇌   2H 2 O              +1,77
                                                                     −
                                                                 MnO 4 + 8H+ + 5e−           ⇌   Mn2+ + 4H 2 O       + 1,51
                                                                         Cℓ 2 (g) + 2e−      ⇌   2Cℓ−                + 1,36
                                                                      2−                                  3+
                                                               Cr 2 O 7 + 14H+ + 6e−         ⇌   2Cr + 7H 2 O        + 1,33
                                                                                         −
                                                                                             ⇌
                                                                                 +
                                                                   O 2 (g) + 4H + 4e             2H 2 O              + 1,23
                                                                   MnO 2 + 4H+ + 2e−         ⇌   Mn2+ + 2H 2 O       + 1,23
                                                                           Pt2+ + 2e−        ⇌   Pt                  + 1,20
                                                                            Br 2 (ℓ) + 2e−   ⇌   2Br−                + 1,07
                                                                     −
                                                                  NO 3 + 4H+ + 3e−           ⇌   NO(g) + 2H 2 O      + 0,96

                                                                                                                               Increasing reducing ability/Toenemende reduserende vermoë
                                                                                         −
                                                                                2+
                                                                             Hg + 2e         ⇌   Hg(ℓ)               + 0,85
                                                                                Ag+ + e−     ⇌   Ag                  + 0,80

Increasing oxidising ability/Toenemende oksiderende vermoë
                                                                        −
                                                                    NO 3 + 2H+ + e−          ⇌   NO 2 (g) + H 2 O    + 0,80
                                                                                         −            2+
                                                                                             ⇌
                                                                                  3+
                                                                               Fe + e            Fe                  + 0,77
                                                                   O 2 (g) + 2H+ + 2e−       ⇌   H2O2                + 0,68
                                                                                I 2 + 2e−    ⇌   2I−                 + 0,54
                                                                               Cu+ + e−      ⇌   Cu                  + 0,52
                                                                    SO 2 + 4H+ + 4e−         ⇌   S + 2H 2 O          + 0,45
                                                                   2H 2 O + O 2 + 4e−        ⇌   4OH−                + 0,40
                                                                             Cu2+ + 2e−      ⇌   Cu                  + 0,34
                                                                     2−
                                                                  SO 4 + 4H+ + 2e−           ⇌   SO 2 (g) + 2H 2 O   + 0,17
                                                                                         −            +
                                                                                             ⇌
                                                                                  2+
                                                                              Cu + e             Cu                  + 0,16
                                                                             Sn4+ + 2e−      ⇌   Sn2+                + 0,15
                                                                       S + 2H+ + 2e−         ⇌   H 2 S(g)            + 0,14
                                                                              2H+ + 2e−      ⇌   H 2 (g)             0,00
                                                                                         −
                                                                                3+
                                                                             Fe + 3e         ⇌   Fe                  − 0,06
                                                                             Pb2+ + 2e−      ⇌   Pb                  − 0,13
                                                                             Sn2+ + 2e−      ⇌   Sn                  − 0,14
                                                                              Ni2+ + 2e−     ⇌   Ni                  − 0,27
                                                                             Co2+ + 2e−      ⇌   Co                  − 0,28
                                                                             Cd2+ + 2e−      ⇌   Cd                  − 0,40
                                                                               Cr3+ + e−     ⇌   Cr2+                − 0,41
                                                                             Fe2+ + 2e−      ⇌   Fe                  − 0,44
                                                                             Cr3+ + 3e−      ⇌   Cr                  − 0,74
                                                                             Zn2+ + 2e−      ⇌   Zn                  − 0,76
                                                                         2H 2 O + 2e−        ⇌   H 2 (g) + 2OH−      − 0,83
                                                                             Cr2+ + 2e−      ⇌   Cr                  − 0,91
                                                                             Mn2+ + 2e−      ⇌   Mn                  − 1,18
                                                                              Aℓ3+ + 3e−     ⇌   Aℓ                  − 1,66
                                                                             Mg2+ + 2e−      ⇌   Mg                  − 2,36
                                                                                         −
                                                                               Na + e+
                                                                                             ⇌   Na                  − 2,71
                                                                             Ca2+ + 2e−      ⇌   Ca                  − 2,87
                                                                              Sr2+ + 2e−     ⇌   Sr                  − 2,89
                                                                             Ba2+ + 2e−      ⇌   Ba                  − 2,90
                                                                               Cs+ + e-      ⇌   Cs                  – 2,92
                                                                                 K+ + e−     ⇌   K                   − 2,93
                                                                                 Li+ + e−    ⇌   Li                  − 3,05

                                                                                                                                                                                           P.T.O.

### Page 21

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                                                                                          PHYSICAL SCIENCES: CHEMISTRY                                                                      21
                                                                                          (Second Paper)            10842/16

                                                             TABLE 4B: STANDARD REDUCTION POTENTIALS
                                                             TABEL 4B: STANDAARD REDUKSIEPOTENSIALE
                                                                                                                      θ
                                                                          Half-reactions/Halfreaksies
                                                                                                                      E   (V)
                                                                                 Li+ + e−     ⇌   Li                  − 3,05
                                                                                 K+ + e−      ⇌   K                   − 2,93
                                                                               Cs+ + e−       ⇌   Cs                  − 2,92
                                                                              Ba2+ + 2e−      ⇌   Ba                  − 2,90
                                                                               Sr2+ + 2e−     ⇌   Sr                  − 2,89
                                                                             Ca2+ + 2e−       ⇌   Ca                  − 2,87
                                                                                Na+ + e−      ⇌                       − 2,71

                                                                                                                                Increasing reducing ability/Toenemende reduserende vermoë
                                                                                                  Na

Increasing oxidising ability/Toenemende oksiderende vermoë
                                                                             Mg2+ + 2e−       ⇌   Mg                  − 2,36
                                                                              Aℓ3+ + 3e−      ⇌   Aℓ                  − 1,66
                                                                             Mn2+ + 2e−       ⇌   Mn                  − 1,18
                                                                              Cr2+ + 2e−      ⇌   Cr                  − 0,91
                                                                            2H 2 O + 2e−      ⇌   H 2 (g) + 2OH−      − 0,83
                                                                                          −
                                                                                 2+
                                                                              Zn + 2e         ⇌   Zn                  − 0,76
                                                                              Cr3+ + 3e−      ⇌   Cr                  − 0,74
                                                                              Fe2+ + 2e−      ⇌   Fe                  − 0,44
                                                                                Cr3+ + e−     ⇌   Cr2+                − 0,41
                                                                             Cd2+ + 2e−       ⇌   Cd                  − 0,40
                                                                             Co2+ + 2e−       ⇌   Co                  − 0,28
                                                                              Ni2+ + 2e−      ⇌   Ni                  − 0,27
                                                                              Sn2+ + 2e−      ⇌   Sn                  − 0,14
                                                                              Pb2+ + 2e−      ⇌   Pb                  − 0,13
                                                                              Fe3+ + 3e−      ⇌   Fe                  − 0,06
                                                                              2H+ + 2e−       ⇌   H 2 (g)              0,00
                                                                          S + 2H+ + 2e−       ⇌   H 2 S(g)            + 0,14
                                                                                          −
                                                                                 4+
                                                                              Sn + 2e         ⇌   Sn2+                + 0,15
                                                                                          −            +
                                                                                              ⇌
                                                                                     2+
                                                                               Cu + e             Cu                  + 0,16
                                                                        2−
                                                                     SO 4 + 4H+ + 2e−         ⇌   SO 2 (g) + 2H 2 O   + 0,17
                                                                             Cu2+ + 2e−       ⇌   Cu                  + 0,34
                                                                      2H 2 O + O 2 + 4e−      ⇌   4OH−                + 0,40
                                                                                          −
                                                                                              ⇌
                                                                                  +
                                                                       SO 2 + 4H + 4e             S + 2H 2 O          + 0,45
                                                                                          −
                                                                                              ⇌
                                                                                      +
                                                                                Cu + e            Cu                  + 0,52
                                                                                 I 2 + 2e−    ⇌   2I−                 + 0,54
                                                                      O 2 (g) + 2H+ + 2e−     ⇌   H2O2                + 0,68
                                                                               Fe3+ + e−      ⇌   Fe2+                + 0,77
                                                                          −
                                                                       NO 3 + 2H+ + e−        ⇌   NO 2 (g) + H 2 O    + 0,80
                                                                                          −
                                                                                              ⇌
                                                                                      +
                                                                                Ag + e            Ag                  + 0,80
                                                                             Hg2+ + 2e−       ⇌   Hg(ℓ)               + 0,85
                                                                        −
                                                                     NO 3 + 4H+ + 3e−         ⇌   NO(g) + 2H 2 O      + 0,96
                                                                            Br 2 (ℓ) + 2e−    ⇌   2Br−                + 1,07
                                                                                          −
                                                                                              ⇌
                                                                                2+
                                                                              Pt + 2 e            Pt                  + 1,20
                                                                                          −            2+
                                                                                              ⇌
                                                                                  +
                                                                      MnO 2 + 4H + 2e             Mn + 2H 2 O         + 1,23
                                                                      O 2 (g) + 4H+ + 4e−     ⇌   2H 2 O              + 1,23
                                                                         2−
                                                                  Cr 2 O 7 + 14H+ + 6e−       ⇌   2Cr3+ + 7H 2 O      + 1,33
                                                                            Cℓ 2 (g) + 2e−    ⇌   2Cℓ−                + 1,36
                                                                        −                              2+
                                                                    MnO 4 + 8H+ + 5e−         ⇌   Mn + 4H 2 O         + 1,51
                                                                                          −
                                                                                              ⇌
                                                                                  +
                                                                      H 2 O 2 + 2H +2 e           2H 2 O              +1,77
                                                                               Co3+ + e−      ⇌   Co2+                + 1,81
                                                                             F 2 (g) + 2e−    ⇌   2F−                 + 2,87

                                                                                              END

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