# Physical Sciences Grade 12 Mpumalanga November 2020 QP

> Grade 12 Physical Sciences question paper from the Mpumalanga November 2020, 19 pages. Read online or get the free PDF download, memo linked when available.

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- Updated: 2026-09-27
- Subject: Physical Sciences
- Grade: Grade 12
- Document type: Question paper
- Year: 2020
- Exam period: Mpumalanga November
- Curriculum: CAPS
- Pages: 19

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Be Coucation

DEPARTMENT: EDUCATION
MPUMALANGA PROVINCE

NATIONAL
SENIOR CERTIFICATE

GRADE 12

PHYSICAL SCIENCES: CHEMISTRY P2

SEPTEMBER 2020

MARKS: 150

TIME: 3 hours

This question paper consists of 15 pages and 4 data sheets.
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Physical Sciences P2 2 MDE/September 2020

NCS

INSTRUCTIONS AND INFORMATION

10.
41s

12.

Write yourname in the appropriate space on the ANSWER BOOK.

This question paper consists of TEN questions. Answer ALL the questions in the
ANSWER BOOK.

Start EACH question ona NEW page in the ANSWER BOOK.

Number the answers correctly according to the numbering system usedin this
question paper.

Leave ONE line between two sub questions, for example between QUESTION 2.1
and QUESTION 2.2.

You may usea non-programmable calculator.

You may use appropriate mathematical instruments.

You are advised to use the attached DATA SHEETS.

Show ALL formulae and substitutions in ALL calculations.

Round off your final numerical answers to a MINIMUM of TWO decimal places.
Give brief motivations, discussions, etcetera where required.

Write neatly and legibly.

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Physical Sciences P2 3 MDE/September 2020
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QUESTION 1 : MULTIPLE-CHOICE QUESTIONS

Four options are provided as possible answers to the following questions. Each
question has only ONE correct answer. Choose the answer and write only the
letter (A — D) next to the question number (1.1 — 1.10) in the ANSWER BOOK ,
for example, 1.11 E.

14 Which ONE of the following organic compounds is an UNSATURATED
HYDROCARBON?

A C2He

B C3He

Cc CH3COOH

D CHa (2)
1.2 An organic compound was mistakenly named as 4,5-diethylpentan-3-ol.

Whatis the correct IUPAC name for this compound?

A 1 ,2-diethylpentan-3-ol

B 4-ethylheptan-5-ol

Cc 4-ethylheptan-3-ol

D 4-ethylhexan-5-ol (2)

1.3 The following reaction reaches equilibrium in a closed container
CHa(g) + H20(g) = CO(g) + 3H2(g) AH = +206 kJ-mol!

Which ONE of the following changes in temperature and pressure would
lead to the greatest yield in the products?

Pressure Temperature
A Decreases Increases
B Increases Decreases
Cc Increases Increases
D Decreases Decreases (2)

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14 Consider the equation fora hypothetical reaction below.
Aig) + Big) = ABQ)

At 70°C, the heat of reaction (AH) for this reaction is -30 kJ-mol™. At a
temperature of 90°C, the heat of reaction (AH), in kJ-mol", is:

A -30
B -10
c +50
D -50 (2)

1.5 Consider the reaction represented by the following equation:
Fe2Os(s) + 3CO(g) = 2Fe(s) + 3CO02(g)
The Kc expression for this reaction is:

A Ke = [Fe2Os][ COP

[Fe}2[CO2]
B kee |
[Fe2Os][CO}*
[FePIcoz)
Cc Kes ——*
[Fe2Os][CO}
[COz}*
D Ke =
[cop

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1.6 The reaction represented by the equation below reaches equilibrium in
a closed container at time to

2S02(g) + O2(g) @ 2803(g) AH = -198kJ

A changeis made to the equilibrium system at time t1, as shown in the

graph below.

- forward reaction
g Mego ul ., Tee reverse reaction
&

§
re
8
3
2
2 oie
a

lo hu time (t)

Which ONE of the following describes the change to the equilibrium atti
as indicated on the graph?

A Increase the concentration of O2(g)

B Increase the temperature.

Cc Increase in the pressure by decreasing the volume.

D Increase in the concentration of SO2(g) (2)

1.7 Which ONE of the following species CANNOT act as a Bransted-Lowy
acid anda Bronsted-Lowry base?

A H2PO4

B HzO

Cc HSOa

D CH3COOH (2)

1.8 The process used to deposit a metal onto a conductive object is called:
A Electrorefining
B Electroextraction
Cc Electroplating

D Neutralisation (2)

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Physical Sciences P2 6 MDE/September 2020
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1.9 Which ONE of the following pairs will react spontaneously?
A Mg?* (aq) + Zn (s)
B Mg?* (aq) + Cu (s)
Cc Cu?* (aq) + Ag (s) (2)
D

Ag* (aq) + Pb (s

440 Which ONE of the following is correct for the industrial preparation of

nitric acid?
PROCESS CATALYST
A Haber Platinum
B Ostwald Platinum
Cc Contact Iron
D Contact Vanadium pentoxide (2)
[20]

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Physical Sciences P2 7 MDE/September 2020
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QUESTION 2 (Start on anew page.)

Zl The structural formula of a functional group of a certain organic
compound is given below.

oO
II
—C—H
2.1.1 Define the term functional group. (2)
Write down the
2.1.2 Name of this functional group (1)
2.1.3. General formula of the homologous series to which this
functional group belongs. (1)
2.2 Consider the condensed structural formula of the organic compound

below.

CH3CH2COOCH2CH3

The above-mentioned organic compound has one functional isomer.
2.2.1 Define the term functional isomer. (2)

2.2.2 Draw the structural formula of the FUNCTIONAL ISOMER of
this compound (2)

The same compound can be prepared in a laboratory.

2.2.3 Write down the name for this type of reaction. (1)
2.2.4 Write down the IUPAC name of the alcohol needed to prepare

this compound. (1)
2.2.5 Write down two reaction conditions for this reaction. (2)

2.2.6 Howcan one easily identify whether this compoundis being
formed (1)

2.3 A sample of impure butane (C4H10) of mass 26 g burns in excess
oxygen, 34 g of COz forms. The balanced equation for this reaction is
given below:
2C4H10(g) + 1302 (g) + 8CO2(g) + 10H20(g)
Calculate the percentage purity of the sample of butane. (5)
[18]

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Physical Sciences P2

8
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QUESTION 3 (Start on a new page.)

Two separate experiments are conducted to determine the boiling points of

MDE/September 2020

organic compounds from different homologous series, under the same
conditions. The results obtained are shown in the table below.

Experiment Organic compound Boiling point
9}
A 2,2-dimeth ylpropane 9
I B 2-methylbutane 27
Cc Pentane 36
i P CH3CH2CH2CH20H 117,7
Q CH3sCH2COOH 141,2
3.1 Define the term homologous series.

82 Consider the boiling points of the compounds in Experiment I.

3.2.1. Write down the dependent variable for this investigation.

(2)

(1)

3.2.2 Fully explain why the boiling points increases from compound

A to compound C.

3:3 Use the data in Experiment Il to answer the following questions.

3.3.1. Formulate an investigative question for this experiment.

3.3.2 Explain why compound Qhasa higher boiling pointthan

compound P.

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(3)

(2)

(4)
[12]

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Physical Sciences P2 9 MDE/September 2020
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QUESTION 4 (Start on a new page.)

Consider the following series of organic reactions and answer the questions that
follow.

COMPOUND P
1 / Brand Y
UV light
CHsCH2CHBrCHs TT Alkene
Q (major product)
Ss
ll
oF IV
CaH100
R

4.1 Write down the TYPE of reaction represented by:

411 I (1)
41.2 I (1)
413 Vv (1)
4.2 During reaction II, compound Q reacts with a base to form compound S.

Write down:

4.2.1 Two reaction conditions for this reaction. (2)
4.2.2. The IUPAC name of compound Q. (2)
4.2.3. The STRUCTURAL FORMULA of the major product S formed. (2)

4.3. Consider reaction IV. Write down

4.3.1 The TYPE of addition reaction that take place. (1)
4.3.2 The NAME or FORMULA of the catalyst thatis used. (1)

4.4 Write down the FORMULA of the INORGANIC productthat is formed in
reaction II. (1)
[12]

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Physical Sciences P2 10 MDE/September 2020
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QUESTION 5 (Start on a new page.)

A series of experiments are conducted to investigate the effect of changing
temperature, concentration and surface area on the rate of reaction between
hydrochloric acid and calcium carbonate. The balanced chemical equation forthe

reaction taking place is:
CaCOx(s) + 2HC&aq) — CaCfe(aq) + H2O(t) + CO2(g)

Each experiment is carried out in a conical flask, which is placed on top of a
sensitive digital balance as shown in the diagram below.

Cotton wool

CaCOx(s) + HCf(aq)

—_4— _ Scale

The reading on the scale decreases over a period of time.
5.1. Whatis the reason for the decrease in the mass of the flask? (1)

5.2 Define the term rate of reaction. (2)

Four different experiments are carried out using the conditions indicated in the
table below.

Experiment | Temperature | Concentration State of CaCQz3
(°C) of HCe
(mol-dm*)
4 20 0,1 large pieces
2 15 0,1 large pieces
3 20 0,1 powder
4 20 0,2 large pieces

The results of EXPERIMENT 1 were used to sketch the graph shown below:

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2 45
To
Cc
oO
a4
O >
2
ge i
c
= 8 t
I
30 time (s)
5.3 Using the graph, calculate the rate of reaction for experiment 1. (3)
5.4 Redraw the graph in your answerbook. On the same set of axes draw

5.5

5.6

sketch graphs to represent the results of EXPERIMENT 2 and3. CLEARLY
LABEL EACH GRAPH USING 2 AND 3. (4)

Use the collition theory to explain the difference in rate of reactions between
EXPERIMENTS 1 and 4. (4)

The Maxwelt-Boltzrran curve below shows the distribution of molecular
energies of reacting molecules in the chemical reaction of experiment 1.

4

Ea (activation energy)

Number of molecules

Molecular (kinetic) energy (kJ)

Redraw the graph in your answerbook and draw a new curve that
represents experiment 2 (2)
; [16]

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QUESTION 6 (Start on a new page.)

6.1 In an experiment, ammonia gas and oxygen gas are introduced intoa
container at a certain temperature. The container is sealed and the
reaction taking place reaches equilibrium; according to the following
balanced chemical equation.

4NHa3(g) + 502(g) = 4NO(g) + 6GH20(g)

The graph below shows the change in consentration of NH3(g), O2(g),
NOV) and H2O0(g) with time.

¢ Me, | ayy | cueneeettennenteneres NH3. seeeeeneee
6 fet! NH3_ jee
re} Sees Li — Q2
— O2 aaneee
6 f \ Hi + —
2 Y ‘ 9 5 Re 8 ee
MW H20 Sgt No
= | ;
roy “| . ‘ca
2 a a aa
<
8 | no |
time(s)
t te ied ta

6.1.1 If numerical values were given for concentration on the y-axis,
would it be possible to calculate the equilibrium constant (Kc) for
this reaction at time t: ? Explain the answer. (2)

6.1.2 Identify the change (stress) which was introduced to the reaction
at time te and explain the subsequent changes in concentrations of
all substances immediately after time tz. (4)

6.1.3. At time ts the temperature of the container is decreased.
Is the forward reaction EXOTHERMIC or ENDOTHERMIC? (2)

6.2 Phosphorus pentachloride decomposes into phosphorous trichloride and
chlorine gas. When gaseous phosphorous pentachloride is sealed in a
closed container the following equilibriumis established.

PCts(g) = PCfa(g) + Cfa(g)

6.2.1. An unknown mass of phosphorous pentachloride is sealed in an
empty 2000 cm container. The system is allowed to reach
equilibrium at 250°C.

When the equilibrium mixture was analysed the concentrations of
PCfs and Cf2 were 0,7 mol-dm? and 0,5 mol-dm’ respectively.

Calculate the Kc value at 250°C. (5)

6.2.2 Calculate the mass of phosphorous pentchloride that was
originally placed in the container. (4)
[17]

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Physical Sciences P2 13 MDE/September 2020

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QUESTION 7 (Start on a new page)

7A

7.2

7.3

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Barium hydroxide (Ba(OH)z), is defined as.a strong base.
7.1.1 Define a strong base.

7.1.2 Calculate the pH of a solution of a barium hydroxide solution,
Ba(OH)z (aq), with a concentration of 0,1 mol-div3,

A standard solution of oxalic acid, (COOH)z (aq), with concentration
0,2 mol-dmvis prepared by dissolving a certain amount of oxalic acid
crystals, (COOH)2-2H20, in water. The flask is then filled with distilled
water up to the 250 cm? mark.

7.2.1 Define the term standard solution.

7.2.2 Calculate the mass of oxalic acid needed to prepare the
standard solution.

During atitration, 25 cm of the standard oxalic acid solution, (COCH)2

(aq), prepared in QUESTION 7.2, is neutralised by a sodium hydroxide
solution, NaOH(aq), from a burette.
The balanced equation for the reaction is given below.

(COOH)a(aq) + 2NaOH (aq) — (COO)2Naa(aq) + 2H20(2)

The diagrams below show the burette readings before the titration
commenced and at the endpoint respectively.

Before the titration At the endpoint

cm? em?

2 38
lx. Level of ~—_4+——._ Level of
3 NaOH(aq) 39 NaOH(aq)

|

7.3.1 Define the term endpoint.

7.3.2 What will the pH at the endpoint be? Choose from: GREATER
THAN 7, EQUAL TO 7 or LESS THAN 7.

7.3.3 Netermine the volume of NaOH(aq) that was added to the
(COOH)a(aq) to reach the endpoint of the titration from the
diagrams above..

73.4 Calculate the concentration of the sodium hydroxide solution,
NaOH (aq).

(2)

(5)

(2)

(4)

(2)

(1)

(1)

(5)
[22]

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QUESTION 8 (Start on a new page)
Consider the following galvanic cell at 25 °C.
Cu(s) | Cu2* (4 mol-dm) || C&2 (1 atm) | CL (1 mol-dm)

8.1. Write down the balanced chemical equation for the net cell reaction that

takes place. (3)
8.2 Calculate the initial cell potential at 25 °C. (4)
8.3 Write down the FORMULA of the cathode. (1)
8.4 Fully explain how the salt bridge functions to maintain electrical
neutrality by referring to the movement of the ions. (2)
[10] .

QUESTION 9 (Start on a new page)

Aluminium metal is extracted from pure aluminium oxide (Af2Os) in an electrolytic
cell represented in the diagram below.

Anode
Cathode
| Mixture of
alumina
> Molten aluminium
9.1. Whatis the NAME of the ore which contains aluminium oxide (Af2O3)? (1)
9.2 Define the term electrolytic cell. (2)
9.3. Write down the FORMULA of the ions present in the molten alumina
(Af2Os). (2)
9.4 Whatis the advantage of adding cryolite to the alumina? (1)
9.5 Write down the half reaction that takes place at the cathode. (2)
9.6 Explain why the carbon anode should be replaced regularly. Make use
of a chemical equation to support the answer. (3)
(11]

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QUESTION 10 (Start on a new page)

The fertiliser industry can be summarised as follows:

SubstanceA

Gas B

Oxygen Reaction 1

v
Gas C

N2 H2

v
L_ Processe _| Compound D

(H2S207)

NH3

H2S04
Fertiliser Z en

10.1 Write down the NAME or FORMULA for Substance A. (1)

10.2 Write down the NAME of the catalyst used in Reaction 1. (1)

10.3 Gas Cis diluted with a small amount of sulphuric acid to form
Compound D.

10.3.1 Write down the NAME for compound D. (1)
10.2.2 Whyis gas C notadded directly to water to form sulphuric acid? (2)
10.4 Write down a balanced equation for the formation of fertiliser Z. (3)

10.5 A farmer boughta 40 kg bag of fertiliser with a ratio of 3:2:1(22) for his
crops. Calculate the mass of the primary nutrient required for healthy
strong roots. (3)

[11]
TOTAL: 150

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DATA FOR PHYSICAL SCIENCES GRADE 12
PAPER 2 (CHEMISTRY)

GEGEWENS VIR FISIESE WETENSKAPPE GRAAD 12
VRAESTEL 2 (CHEMIE)

TABLE 1: PHYSICAL CONSTANTS/TABEL 1: FISIESE KONSTANTES

NAME/NAAM SYMBOL/S/IMBOOL — | VALUE/WAARDE
Motére gasvolumeby STD vn 22:4 demo
Avogadro's constant Na 6,023 x 1023 molt

TABLE 2: FORMULAE/TABEL 2: FORMULES

n= mM na
M Na
m Vv
n = — 1=—
c= ORIOF © = 7 Vv,
n, _ Cy Va pH = -log[H30*]
ny cy M

Kw= [H30*]]OH"] = 1 x 10-4 at’ by 298 K

Eon = Eaarees ~ Fa iote / ES = Eras ~ =

OR/OF

Ee = E luclin ~ Ee éaiin / a i Eeaaee ~ Shiddiade

OR/OF

Ean = Essidisneaom, ~ Ereducinosaent 1 Esa = Ebssdeamidet — Erdusacrnide

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Physical Sciences P2

Increasing oxidising ability/Toenemence oksiderende vermoé

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TABLE 4A: STANDARD REDUCTION POTENTIALS
TABEL 4A: STANDAARD-REDUKSIEPOTENSIALE

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Half-reactions/Halfreaksies po Wd)
F2(g) + 2e- 2F- +2,87

Co + e- Co* +1,81

H202+ 2H*+2e = 2H20 +1,77
“ = Mn*+4H2O +1,51

MnO 4 + RH*+ Se

Chg) +#2e- = 2Ct- + 1,36

2- = 2Cr*+7H20 41,33

Cro + 14H* + 6a-

dg) +4H" +4e- 2 2H20 +1,23

MnQ2+4H*+ 2e- = Mn +2H20 + 1,23

Pe +2e- = Pt + 1,20

Bro(t)+2e = 2Br +1,07

NO} +4H*43e~ = NO(g)+2H20 | +0,96

Hg**+2e- = Hg(e) + 0,85
Agite = Ag + 0,80

NO} + 2HtFe- NOdGY# HeO | ¥°0:80
Fe#+e- = Fe* +0,77

Og) +2H*+2e- = H202 + 0,68
k+2e = 2b +0,54

Cutt+e- = Cu +0,52

SQ2+4H*+4e- = S+2H20 +0,45
2H20+ O2+4e-° = 40H- + 0,40
Cu*+2e = Cu + 0,34
802" gaHte2—- = SOAS) *2H0) +0407

Cu*+e- = Cut +0,16

Sn#+2e = Sn* +015

S+2H*+2e = Ho2S(g) +0,14
2Ht+2e = Ha(g) 0,00

Fe +3e = Fe — 0,06

Pb?*+2e- = Pb -0,13
Sn*+2e = Sn -0,14

Nit +2e Ni —0,27

Co* + 2e- Co — 0,28

Cd*+2e = Cd — 0,40
Cette = Cre -0,41
Fe*+2e = Fe — 0,44
Crt+3e = Cr ~0,74
Zn*+2e = Zn —0,76

2H20 + 2e- = Hag) +2OH- — 0,83
Crt+2e = Cr 0,91
Mn*+2e = Mn -1,18

AGS +3e- = Al - 1,66

Mg?*+2e- = Mg — 2,36
Natte- = Na -2,71

Ca*+2e =. Ca — 2,87

Srt+2e- = Sr —2,89

Ba*+2e = Ba — 2,90
Cs*+e@e = Cs - 2,92

Ktte = K — 2,93

litte = Li — 3,05

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Increasing reducing ability/Toenemende reduserende vermoé

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Physical Sciences P2

Increasing oxidising ability/Toenemende oksiderende vermoé

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TABLE 4B: STANDARD REDUCTION POTENTIALS
TABEL 4B: STANDAARD-REDUKSIEPOTENSIALE

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Half-reactions/Halfreaksies 59 (v)
litte = Li —3,05

Kite = K — 2,93

Cstte = Cs — 2,92
Ba*+2e = Ba — 2,90

Sr++ 2e = Sr — 2,89
Ca*+2e = Ca — 2,87
Nat*te = Na =271
Mg*+2e = Mg — 2,36
AGS'+3e° = Al — 1,66

Mn? +2e- = Mn - 1,18
Crt+2e = Cr -0,91
2H20+2e- = Hag)+20H” | — 0,83
Zn**+2e = Zn -0,76

Cr+ +3e = Cr - 0,74
Fe*+2e = Fe -0,44
Crt+e- = Cre -0,41
Cd%*+2e = Cd - 0,40
Co*+2e = Co —0,28
Ni*+2e- = Ni - 0,27
Sn%+2e- = Sn 0,14
Pb*+2e = Pb -0,13

Fes + 3e7 Fe - 0,06

2H*+2e- = Hag) 0,00

S+2H*+2e = HeS(g) +0,14
Sn4*+2e- = Sn +0,15
Cu*+e- = Cut +0,16

so a eshte ze = SO2(g) + 2H20 | + 0,17
Cu*+2e = Cu + 0,34
2H20+O2+4e- = 40H™ + 0,40
SOQ2+4H*+4e = S+2H20 +0,45
Cu'+e- = Cu +0,52

It+2e = 2b + 0,54

Og) +2H*+2e = H202 + 0,68
Fe +e = Fe* +0,77
NO3+2H*te 7 NOAg) + H20 | +0,80
Agtte = Ag +0,80

Hg +2e- = Hg(t) +0,85

NO} +4Htege- = NO(g)+2H20 | +0,96
Bro(t)+2e° = 2Br +1,07
Pe+2e = Pt +1,20
MnO2+4H*+ 2e7 = Mn*+2H20 | +1,23
Og) +4H*+4e- = 2H20 +1,23
2- = 2Cr*+7H20 | +1,33

CrO7z +14H*+ be

Ctig)+2e- = 2Ch + 1,36

- = Mn*+4H20 +1,51

MnO, + 8H*+5e-

H202+ 2H*+#2e@ = 2H20 +1,77
Co*# +e = Cor +1,81

Fg) +2e- = 2F +287

MDE/September 2020

Increasing reducing ability/Toenemende reduserende vermoé

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Physical Sciences P2

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