# Physical Sciences Grade 12 P2 Free StateNovember 2016 QP

> Grade 12 Physical Sciences Paper 2 question paper from the Free StateNovember 2016, 18 pages. Read online or download the free PDF.

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- Updated: 2026-09-27
- Subject: Physical Sciences
- Grade: Grade 12
- Document type: Question paper
- Year: 2016
- Exam period: Free StateNovember
- Paper: 2
- Curriculum: CAPS
- Pages: 18

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Physical Sciences · Grade 12 · Free StateNovember · 2016. Question paper, 18 pages. Read online or download the PDF.

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### Page 1

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                 PREPARATORY EXAMINATION

                                   GRADE 12

                     PHYSICAL SCIENCES
                          PAPER 2
                        (CHEMISTRY)

                            SEPTEMBER 2016

                                 MARKS: 150

                              TIME: 3 HOURS

               This question paper consists of 14 pages and 4 data sheets.

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Physical Sciences P2                        2                           FS/September 2016
Grade 12 Prep. Exam.

INSTRUCTIONS AND INFORMATION

1.     Write your name and other applicable information in the appropriate spaces
       on the ANSWER BOOK.

2.     The question paper consists of TEN questions. Answer ALL the questions in
       the ANSWER BOOK.

3.     Start EACH question on a NEW page in the ANSWER BOOK.

4.     Number the answers correctly according to the numbering system used in this
       question paper.

5.     Leave one line between two sub-questions, for example between QUESTION
       3.1 and QUESTION 3.2.

6.     Non-programmable pocket calculators may be used.

7.     Appropriate mathematical instruments may be used.

8.     You are advised to use the attached DATA SHEETS.

9.     Show ALL formulae and substitutions in ALL calculations.

10.    Round off your final numerical answers to a minimum of TWO decimal places
       where necessary.

11.    Give brief motivations, discussions, et cetera where required.

12.    Write neatly and legibly.

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Physical Sciences P2                            3                    FS/September 2016
Grade 12 Prep. Exam.

QUESTION 1: MULTIPLE-CHOICE QUESTIONS

Four options are provided as possible answers to the following questions. Each
question has only ONE correct answer. Choose the answer and write only the letter
(A – D) next to the question number (1.1 – 1.10) in your ANSWER BOOK, for
example 1.11 E.

1.1    The most important mineral nutrient essential for the development of roots,
       is …

       A       nitrogen.
       B       phosphorus.
       C       potassium.
       D       calcium.                                                              (2)

1.2    The functional group of carboxylic acids is:

       A       ─ COO ─
       B       ─ COOH
       C       ─ OH
       D       ─ CHO                                                                 (2)

1.3    Consider the following structural formula of an organic compound.

                                    H

                                H   C   H

                                H   C H     H

                                H   C   C   C   H

                                            H
                                    H   C   H

                                        H

       The IUPAC name of this compound is:

       A       2-methyl-3-ethylprop-1-ene
       B       2-methyl-1-ethylprop-1-ene
       C       4-methylpent-3-ene
       D       2-methylpent-2-ene                                                    (2)

1.4    Which ONE of the following represents condensation polymerisation?

       A       Hydration
       B       Esterification
       C       Hydrolysis
       D       Dehydration                                                           (2)

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Physical Sciences P2                            4                     FS/September 2016
Grade 12 Prep. Exam.

1.5    50 cm3 of a 0,1 mol.dm-3 solution of hydrochloric acid is poured on to 5 g of
       granulated zinc which is inside a glass beaker at room temperature.
       Which one of the following factors will not increase the initial rate of the
       reaction?

       A       Grinding the granulated zinc into powder
       B       Using 30 cm3 of a 0,2 mol.dm-3 hydrochloric acid at room
               temperature
       C       Increasing the temperature of the acid solution to 50 °C
       D       Using 100 cm3 of a 0,1 mol.dm-3 solution of hydrochloric acid
               at room temperature                                                     (2)

1.6    The reaction represented below reaches equilibrium in a closed container.

       CH 4 (g) + H 2 O(g) ⇌ CO(g) + 3H 2 (g)       ∆H > 0

       Which ONE of the following changes will increase the yield of H 2 (g)?

       A       Add a catalyst
       B       Decrease pressure by increasing the volume
       C       Decrease the temperature
       D       Increase pressure by decreasing the volume                            (2)

1.7    Consider the reaction:

       2H 2 O(ℓ) ⇌ H 3 O+(aq) + OH-(aq)

       The equilibrium constant for this reaction at 25 °C is 10-14. At 60 °C the
       equilibrium constant for this reaction is 10-13. From the above information
       one can conclude that this reaction at 60 °C …

       A       is an exothermic reaction.
       B       has a high product yield.
       C       the concentration of H 3 O+ decreases.
       D       the concentration of products does not change.                          (2)

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Physical Sciences P2                          5                      FS/September 2016
Grade 12 Prep. Exam.

1.8    A saturated solution of NaCℓ in water is prepared at 50 °C. The equation
       for this equilibrium is:

       NaCℓ(s) ⇌ Na+(aq) + Cℓ-(aq)         H > 0

       Which ONE of the following changes will cause more NaCℓ(s) to form?

       A       Add dilute hydrochloric acid
       B       Add a catalyst at constant temperature
       C       Increase the pressure on the solution
       D       Decrease the temperature                                             (2)

1.9    The cell notation of a GALVANIC CELL is given as:

       Ni(s)|Ni2+(aq) (1mol.dm-3)||Ag+(aq) (1mol.dm-3)|Ag(s)

       A bulb connected across the two electrodes glows brightly. After some
       time the brightness of the bulb decreases. This is because …

       A       the silver electrode is used up.
       B       the nickel electrode is used up.
       C       the concentration of Ag+ decreases.
       D       the concentration of Ni2+ decreases.                                 (2)

1.10 During the electrolysis of a concentrated sodium chloride solution, water is
     reduced and not sodium ions because…

       A       Na+ is a stronger oxidising agent than H 2 O.
       B       H 2 O is a stronger reducing agent than Na+.
       C       H 2 O is a stronger oxidising agent than Na+.
       D       Na+ is a stronger reducing agent than H 2 O.                          (2)
                                                                                    [20]

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Physical Sciences P2                             6                      FS/September 2016
Grade 12 Prep. Exam.

QUESTION 2 (Start on a new page.)

The letters A to F in the table below represent six organic compounds.

 A    Butanal                        B   CH 3 CH 2 CCCH 3

            H       H        H
                                             H   Br H    H
 C    H     C       C    C   C   H   D   H   C   C   C   C   H
            H       H    O   H
                                             Br H    H   H

              H
            H CH
       H                H
 E    HC        C       CH           F   Ethyl ethanoate
       H                H
            HCH
             H

Use the information in the table to answer the questions that follow.

2.1       Write down the letter(s) representing:

          2.1.1 A compound with the general formula C n H 2n+2                         (1)

          2.1.2 A ketone                                                               (1)

          2.1.3 An aldehyde                                                            (1)

          2.1.4 An unsaturated hydrocarbon                                             (1)

2.2       For compound F, write down the:

          2.2.1 Structure of the functional group to which it belongs                  (2)

          2.2.2 IUPAC name of the acid and an alcohol needed to prepare F              (2)

2.3       Write down the IUPAC name of:

          2.3.1 Compound C                                                             (2)

          2.3.2 Compound D                                                             (2)

2.4       Write down the condensed structural formula for C.                           (2)

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Physical Sciences P2                           7                     FS/September 2016
Grade 12 Prep. Exam.

2.5    Write down the structural formula of:

       2.5.1 A chain isomer of compound E                                             (2)

       2.5.2 Compound F                                                               (2)
                                                                                     [18]

QUESTION 3 (Start on a new page.)

During a practical investigation the boiling points of five (5) organic compounds,
with known molar masses, were determined and the results were recorded in the
table below. The five organic compounds are represented by the letter A to E.

                                     MOLAR MASS               BOILING POINT
               COMPOUND
                                       (g.mol-1)                   (°C)
      A   CH 3 CH 2 CH 3                  44                       - 42
      B   CH 3 CH 2 CH 2 CH 3              58                        -1
          CH 3 CH 2 CH 2 CH 2 CH
      C                                    72                        36
          3
          CH 3 CH(CH 3 )CH 2 CH
      D                                    72                        28
          3

      E   CH 3 C(CH 3 ) 2 CH 3             72                        10

3.1    Consider only compounds A, B and C and write down:

       3.1.1 The independent variable                                                 (1)

       3.1.2 The dependent variable                                                   (1)

       3.1.3 An investigative question                                                (2)

3.2    What is the trend in boiling point from compound C to compound E? Write
       down INCREASES or DECREASES. Fully explain this trend.                  (4)

3.3    Consider compound E.

       3.3.1    Write down the NAME of the homologous series to which it
                belongs.                                                              (1)

       3.3.2    Write down the IUPAC name of this compound.                           (2)
                                                                                     [11]

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Physical Sciences P2                          8                     FS/September 2016
Grade 12 Prep. Exam.

QUESTION 4 (Start on a new page.)

The flow diagram below shows how alcohols can react to form other organic
compounds.

                                                                  Compound X
        Secondary              Reaction A                         CH3CHCℓCH3
        Alcohol

                                                                   +Concentrated
                                                                        KOH
                Reaction C
                                                            Reaction B

                                          Alkene

                             Reaction D      + H2

                                      Alkane

4.1    Write down the type of reaction represented by reaction:

       4.1.1 A                                                                       (1)

       4.1.2 B                                                                       (1)

       4.1.3 D                                                                       (1)

4.2    In reaction B, compound X is converted to an alkene. Write down the:

       4.2.1 IUPAC name of compound X                                                (2)

       4.2.2 Balanced equation for the reaction B, using structural formulae         (4)

4.3    Reaction C takes place in the presence of a strong acid.

       4.3.1 Explain the term secondary alcohol                                      (2)

       4.3.2 Write down the IUPAC name of the alcohol used                           (2)
                                                                                    [13]

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Physical Sciences P2                        9                       FS/September 2016
Grade 12 Prep. Exam.

QUESTION 5 (Start on a new page.)

In an investigation of the rate of reaction, excess magnesium powder is added to
dilute hydrochloric acid at room temperature. The following spontaneous reaction
takes place:

Mg(s) + 2HCℓ(aq) → MgCℓ 2 (aq) + H 2 (g)               ∆H < 0

5.1    Define the term spontaneous reaction.                                          (2)

5.2    Write down the limiting reagent for the above reaction.                        (1)

5.3    How will each of the following changes affect the rate of the reaction
       between magnesium and hydrochloric acid according to the above
       reaction? Choose from INCREASES, DECREASE or REMAINS THE SAME.

       5.3.1 The same mass of magnesium ribbon is used instead of powder.             (1)

       5.3.2 A more concentrated solution of hydrochloric acid is used.               (1)

       5.3.3 The diluted hydrochloric acid solution is heated before being added
             to the magnesium.                                                   (1)

5.4    Use the collision theory to explain your answer in QUESTION 5.3.3.             (3)
                                                                                      [9]

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Physical Sciences P2                        10                        FS/September 2016
Grade 12 Prep. Exam.

QUESTION 6 (Start on a new page.)

During the industrial preparation of ammonia, nitrogen gas and hydrogen gas react
in a closed container until the following equilibrium is established at a constant
temperature of 472 °C. Kc is 0,1 at this temperature of 472 °C. The volume of the
container is 0,5 dm3.

       N 2 (g) + 3H 2 (g) ⇌ 2NH 3 (g)       ∆H = - 92 kJmol-1

The equilibrium concentrations are:

       [NH 3 ] = 2,7 x 10-3 moldm-3
       [H 2 ] = 1,221 x 10-1 moldm-3

6.1    Write down the term for the underlined phrase.                                 (1)

6.2    Write down the NAME or FORMULA of the catalyst used in this reaction.          (1)

6.3    After equilibrium has been established, the temperature remained constant.
       Explain this observation.                                                 (2)

6.4    Calculate the initial mass of nitrogen gas.                                   (10)

6.5    Explain why such a high temperature is used although the yield is low.         (3)
                                                                                     [17]

QUESTION 7 (Start on a new page.)

7.1    Hydrochloric acid is a highly corrosive strong acid with many industrial
       uses. When 0,02 dm3 of sodium hydroxide is added to 0,15 dm3 of diluted
       hydrochloric acid of concentration 0,03 mol.dm-3, the pH of the mixture
       changes to 4.

       7.1.1 Give a reason why hydrochloric acid is classified as a strong acid.      (2)

       7.1.2 Write down a balanced chemical equation to show the dissociation
             of HCℓ in water.                                                 (3)

       7.1.3 Will the final mixture be acidic or basic? Give a reason for your
             answer by referring to the pH of the mixture.                            (2)

       7.1.4 Calculate the final concentration of the H+ ion in the mixture.          (3)

       7.1.5 Calculate the original concentration of the sodium hydroxide
             solution.                                                                (6)

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Physical Sciences P2                         11                        FS/September 2016
Grade 12 Prep. Exam.

7.2    Calcium carbonate solutions provide living organisms with the substance
       they need to grow their protective shells and skeletons. For example,
       eggshells are composed of calcium carbonate. Grade 12 learners decide
       to calculate the percentage calcium carbonate in eggshells at STP.

       They take 5 g of crushed eggshells and react it with excess hydrochloric
       acid according to the following equation:

       CaCO 3 (s) + 2 HCℓ(aq) → CaCℓ 2 (aq) + CO 2 (g) + H 2 O(ℓ)

       The carbon dioxide gas produced is collected and found to be 1,06 dm3
       after all the calcium carbonate has reacted. Calculate the percentage
       calcium carbonate in the 5 g eggshells. Show all the calculations.             (6)
                                                                                     [22]

QUESTION 8 (Start on a new page.)

An electrochemical cell is set up at standard conditions as shown below.
The electron flow is as indicated. The reading on the voltmeter is 1,07 V.

                                                            e-
                                                  V

                       X                   salt bridge                  Ni

                              X+(aq)                       Ni2+(aq)

8.1    Write down ONE function of the salt bridge.                                    (1)

8.2    Which electrode of the cell is the anode? Write only X or Ni.                  (1)

8.3    Using a calculation, identify the unknown metal X.                             (5)

8.4    Write down the balanced net (overall) equation for the above cell.             (3)

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Physical Sciences P2                          12                          FS/September 2016
Grade 12 Prep. Exam.

Metal X is now replaced by zinc.

8.5    For the new galvanic cell, write down:

       8.5.1 The NAME or FORMULA of the oxidising agent                                  (1)

       8.5.2 The half reaction for the ANODE                                             (2)

       8.5.3 The cell notation of the new cell                                           (3)
                                                                                        [16]
QUESTION 9 (Start on a new page.)

Electrolysis is an important industrial process used to decompose compounds,
extract metals from their ores and to purify metals like gold or copper.

ℓThe simplified diagram below represents an electrolytic cell used in the extraction
of aluminium.

                         (-)                                        (-)
                               (+)                 (+)                    Carbon electrode

                                  Aℓ2O3            Na3 AℓF6
                                                (molten cryolite)

                                     Molten aluminium

9.1    Write down the energy conversion that takes place in this cell.                   (1)

9.2    Write down the name of the mineral ore of aluminium.                              (1)

9.3    Write down the role played by cryolite in this cell.                              (1)

9.4    The carbon rods need to be replaced from time to time. Write down the
       balanced chemical equation that explains why they need to be replaced.            (2)

9.5    Write down the half-reaction at the cathode.                                      (1)

9.6    Write down TWO negative impacts of this cell on the environment.                  (2)

9.7    It is preferable to recycle aluminium products rather than extracting it
       from its mineral ore. Give a reason to substantiate the above statement.          (2)
                                                                                        [10]

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Physical Sciences P2                        13                         FS/September 2016
Grade 12 Prep. Exam.

QUESTION 10 (START ON A NEW PAGE)

Different processes used in the preparation of fertiliser E are represented in the flow
diagram below.

                            Sulphur                                 Oxygen

                                                 Gas A

                                                     Process X

                                                 Gas B

       Haber Process                          Oleum

        Compound D                         Compound C

                          Fertiliser E

10.1     Use the above information and write down the:

        10.1.1 NAME or FORMULA of gas A                                               (1)

        10.1.2 Name of process X                                                      (1)

        10.1.3 NAME or FORMULA of the catalyst used in process X                      (1)

        10.1.4 FORMULA of oleum                                                       (2)

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Physical Sciences P2                       14                         FS/September 2016
Grade 12 Prep. Exam.

       10.1.5 Balanced equation for the preparation of fertiliser E                  (4)

10.2 Describe ONE negative impact on humans when fertiliser runs off into
     dams and rivers as a result of rain.                                            (2)

10.3 Write down the NAME of the most important primary nutrient required to
     enhance:

       10.3.1 Leaf growth of spinach                                                 (1)

       10.3.2 Flower and fruit production of peach trees                             (1)

10.4 Which ONE of the three primary nutrients is absorbed by plants the
     least?                                                                          (1)
                                                                                    [14]

                                                                 GRAND TOTAL: 150

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Physical Sciences P2                                                 FS/September 2016
Grade 12 Prep. Exam.

                       DATA FOR PHYSICAL SCIENCES GRADE 12
                               PAPER 2 (CHEMISTRY)

                GEGEWENS VIR FISIESE WETENSKAPPE GRAAD 12
                           VRAESTEL 2 (CHEMIE)

TABLE 1: PHYSICAL CONSTANTS / TABEL 1: FISIESE KONSTANTES

NAME / NAAM                      SYMBOL / SIMBOOL    VALUE / WAARDE
Standard pressure
                                        pθ             1,013 x 105 Pa
Standaarddruk
Molar gas volume at STP
                                       Vm              22,4 dm3·molˉ1
Molêre gasvolume by STD
Standard temperature
Standaardtemperatuur                    Tθ                   273 K
Charge on electron
                                        e              -1,6 x 10ˉ19 C
Lading op elektron
Avogadro's constant
                                       NA             6,02 x 1023 mol-1

TABLE 2: FORMULAE / TABEL 2: FORMULES

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Physical Sciences P2
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Grade 12 Prep. Exam.

                             TABLE 3: THE PERIODIC OF ELEMENTS

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Physical Sciences P2                                                                                                                                                      FS/September 2016
Grade 12 Prep. Exam.

                                                                          TABLE 4A: STANDARD REDUCTION POTENTIALS
                                                                          TABEL 4A: STANDAARD-REDUKSIEPOTENSIALE
                                                                                                            θ
                                                                              Half-reactions / Halfreaksies E (V)
                                                                                     F2(g) + 2e−             ⇌   2F−                     + 2,87
                                                                                            3+           −                2+
                                                                                      Co            +e       ⇌   Co                      + 1,81
                                                                                            +            −
                                                                               H2O2 + 2H +2e                 ⇌   2H2O                    +1,77
                                                                                  −
                                                                              MnO 4 + 8H + 5e−
                                                                                        +                                 2+
                                                                                                             ⇌   Mn             + 4H2O   + 1,51
                                                                                                         −                −
                                                                                    Cℓ2(g) + 2e              ⇌   2Cℓ                     + 1,36
                                                                                 2−
                                                                            Cr2O 7 + 14H + 6e−
                                                                                        +                                  3+
                                                                                                             ⇌   2Cr            + 7H2O   + 1,33
                                                                               O2(g) + 4H + 4e−
                                                                                           +
                                                                                                             ⇌   2H2O                    + 1,23
                                                                                           +             −                2+
                                                                               MnO2 + 4H + 2e                ⇌   Mn             + 2H2O   + 1,23
                                                                                                + 2e−
                                                                                           2+
                                                                                      Pt                     ⇌   Pt                      + 1,20
                                                                                                         −                −
                                                                                    Br2(ℓ) + 2e              ⇌   2Br                     + 1,07
                                                                                  −
                                                                               NO 3 + 4H + 3e−               ⇌
                                                                                        +
                                                                                                                 NO(g) + 2H2O            + 0,96
                                                                                                         −
                                                                                     Hg
                                                                                           2+
                                                                                                + 2e         ⇌   Hg(ℓ)                   + 0,85
                                                                                                +        −
                                                                                       Ag + e                ⇌   Ag                      + 0,80
                                                                                   −
                                                                                NO 3 + 2H + e−               ⇌
                                                                                         +

          Increasing oxidising ability / Toenemende oksiderende vermoë                                                                            Increasing reducing ability / Toenemende reduserende vermoë
                                                                                                                 NO2(g) + H2O            + 0,80
                                                                                            3+           −            2+
                                                                                      Fe            +e       ⇌   Fe                      + 0,77
                                                                               O2(g) + 2H + 2e−
                                                                                           +
                                                                                                             ⇌   H2O2                    + 0,68
                                                                                                         −            −
                                                                                           I2 + 2e           ⇌   2I                      + 0,54
                                                                                       Cu + e−
                                                                                                +
                                                                                                             ⇌   Cu                      + 0,52
                                                                                           +             −
                                                                                SO2 + 4H + 4e                ⇌   S + 2H2O                + 0,45
                                                                                2H2O + O2 + 4e−              ⇌   4OH−                    + 0,40
                                                                                           2+            −
                                                                                     Cu         + 2e         ⇌   Cu                      + 0,34
                                                                                 2−
                                                                              SO 4 + 4H + 2e−
                                                                                       +
                                                                                                             ⇌   SO2(g) + 2H2O           + 0,17
                                                                                            2+           −                +
                                                                                      Cu            +e       ⇌   Cu                      + 0,16
                                                                                           4+            −                2+
                                                                                     Sn         + 2e         ⇌   Sn                      + 0,15
                                                                                  S + 2H + 2e−
                                                                                           +
                                                                                                             ⇌   H2S(g)                  + 0,14
                                                                                           +             −
                                                                                      2H + 2e                ⇌   H2(g)                   0,00
                                                                                                + 3e−                                    − 0,06
                                                                                           3+
                                                                                     Fe                      ⇌   Fe
                                                                                                + 2e−                                    − 0,13
                                                                                           2+
                                                                                     Pb                      ⇌   Pb
                                                                                                + 2e−                                    − 0,14
                                                                                           2+
                                                                                     Sn                      ⇌   Sn
                                                                                                         −
                                                                                                                                         − 0,27
                                                                                           2+
                                                                                      Ni        + 2e         ⇌   Ni
                                                                                                + 2e−                                    − 0,28
                                                                                           2+
                                                                                     Co                      ⇌   Co
                                                                                                         −
                                                                                                                                         − 0,40
                                                                                           2+
                                                                                     Cd         + 2e         ⇌   Cd
                                                                                                    + e−
                                                                                                                      2+
                                                                                                                                         − 0,41
                                                                                            3+
                                                                                       Cr                    ⇌   Cr
                                                                                                + 2e−                                    − 0,44
                                                                                           2+
                                                                                     Fe                      ⇌   Fe
                                                                                                + 3e−                                    − 0,74
                                                                                          3+
                                                                                     Cr                      ⇌   Cr
                                                                                                + 2e−                                    − 0,76
                                                                                           2+
                                                                                     Zn                      ⇌   Zn
                                                                                                         −                           −
                                                                                    2H2O + 2e                ⇌   H2(g) + 2OH             − 0,83
                                                                                                + 2e−                                    − 0,91
                                                                                          2+
                                                                                     Cr                      ⇌   Cr
                                                                                                       −
                                                                                                                                         − 1,18
                                                                                          2+
                                                                                     Mn         + 2e         ⇌   Mn
                                                                                      Aℓ        + 3e−            Aℓ                      − 1,66
                                                                                          3+
                                                                                                             ⇌
                                                                                                       −
                                                                                                                                         − 2,36
                                                                                          2+
                                                                                     Mg         + 2e         ⇌   Mg
                                                                                       Na + e−                                           − 2,71
                                                                                                +
                                                                                                             ⇌   Na
                                                                                                + 2e−                                    − 2,87
                                                                                           2+
                                                                                     Ca                      ⇌   Ca
                                                                                      Sr + 2e−                                           − 2,89
                                                                                           2+
                                                                                                             ⇌   Sr
                                                                                                + 2e−                                    − 2,90
                                                                                           2+
                                                                                     Ba                      ⇌   Ba
                                                                                                +        -
                                                                                       Cs + e                ⇌   Cs                      - 2,92
                                                                                           K + e−                                        − 2,93
                                                                                                +
                                                                                                             ⇌   K
                                                                                           Li + e−                                       − 3,05
                                                                                                +
                                                                                                             ⇌   Li
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