# Physical Sciences Grade 12 P2 Gauteng June 2024 QP (Eng)

> Grade 12 Physical Sciences Paper 2 question paper from the Gauteng June Exam 2024 (English), 21 pages. Read online or download the free PDF.

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- Updated: 2026-09-27
- Subject: Physical Sciences
- Grade: Grade 12
- Language: English
- Document type: Question paper
- Year: 2024
- Exam period: Gauteng June Exam
- Paper: 2
- Curriculum: CAPS
- Pages: 21

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Physical Sciences · Grade 12 · Gauteng June Exam · 2024 · English. Question paper, 21 pages. Read online or download the PDF.

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   JUNE EXAMINATION
       GRADE 12

            2024

 PHYSICAL SCIENCES: CHEMISTRY

          (PAPER 2)

                         TIME:     3 hours

                         MARKS: 150

                         17 pages + 4 data sheets

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                                            PHYSICAL SCIENCES: CHEMISTRY               2
                                            (PAPER 2)             GR12 0624

INSTRUCTIONS AND INFORMATION

1.    This question paper consists of EIGHT questions. Answer ALL the questions in
      the ANSWER BOOK.

2.    Start EACH question on a NEW page in the ANSWER BOOK.

3.    Number the answers correctly according to the numbering system used in this
      question paper.

4.    Leave ONE line open between two subquestions, e.g., between QUESTION 2.1
      and QUESTION 2.2.

5.    You may use a non-programmable calculator.

6.    You may use appropriate mathematical instruments.

7.    Show ALL formulae and substitutions in ALL calculations.

8.    Round-off your FINAL numerical answers to a minimum of TWO decimal places.

9.    Give brief discussions, et cetera where required.

10.   You are advised to use the attached DATA SHEETS.

11.   Write neatly and legibly.

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                                            PHYSICAL SCIENCES: CHEMISTRY              3
                                            (PAPER 2)            GR12 0624

QUESTION 1: MULTIPLE-CHOICE QUESTIONS

Various options are given as possible answers to the following questions. Each
question has only ONE correct answer. Choose the answer and write only the letter
(A – D) next to the question numbers (1.1 to 1.10) in the ANSWER BOOK, e.g. 1.11 E.

1.1 Consider the condensed structural formula below:

                                   CH3CH2CH2OH
     What is the name of the functional group?

     A    Hydroxyl group
     B    Carbonyl group
     C    Formyl group
     D    Carboxyl group                                                               (2)

1.2 Consider the compound below:

     Which of the following is the IUPAC name of this compound?

     A    2,2,4-trimethyl-5-ethylheptane
     B    4,6,6-trimethyl-3-ethylheptane
     C    5-ethyl-2,2,4-trimethylheptane
     D    3-ethyl-4,6,6-trimethylheptane                                               (2)

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                                                             PHYSICAL SCIENCES: CHEMISTRY       4
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1.3 Ethanal, ethanol, ethanoic acid, and ethane are compounds that are found in a
    laboratory.
     Arrange the compounds mentioned above in decreasing order of vapour
     pressure.

     A     Ethanoic acid, ethanol, ethanal, ethane
     B     Ethane, ethanal, ethanol, ethanoic acid
     C     Ethanoic acid, ethanal, ethanol, ethane
     D     Ethane, ethanol, ethanal, ethanoic acid                                               (2)

1.4 Which of the following reaction types will be used to prepare ethene and propane
    from pentane under high temperatures and pressures?

     A     Combustion
     B     Esterification
     C     Catalytic cracking
     D     Thermal cracking                                                                      (2)

1.5 The graph below represents the relationship between potential energy and
    course of reaction for a certain chemical reaction.

                             Potential energy (kJ)

                                                     Course of reaction
     The heat of reaction for the reverse reaction is:

     A     2 kJ
     B     4 kJ
     C     -2 kJ
     D     -5 kJ                                                                                 (2)
1.6 The equation below represents the decomposition of calcium carbonate.

                                        CaCO3(s) CaO(s) + CO2(g)

     Which of the following factors will NOT affect the initial rate of decomposition of
     calcium carbonate?
     A    Increase in temperature
     B    Using powdered calcium carbonate
     C    Adding a catalyst
     D    Increasing the mass of calcium carbonate                                               (2)
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                                              PHYSICAL SCIENCES: CHEMISTRY                 5
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1.7 The reaction represented by the equation below reaches equilibrium.

             Co(H2O)     (aq) + 4Cℓ − (aq) ⇌ CoC      (aq) + 6H2O(ℓ)   ΔH > 0
              pink                           blue

     Which of the following changes to the reaction mixture will change its colour from
     pink to blue?

     A     Add a catalyst.
     B     Place the reaction mixture in a container with cold water.
     C     Add a few drops of concentrated hydrochloric acid to the reaction mixture.
     D     Add water to the reaction mixture.                                               (2)

1.8 The following hypothetical reaction is at equilibrium at 500 K:

                                A2(g) + B(g) ⇌ A(g) + AB(g)

     The diagram below shows the molecules involved in this chemical equilibrium at
     500 K.

                                                Key:

                                                       =A     and            =B

     The temperature is decreased to 300 K.

     The diagram below represents the same equilibrium mixture at 300 K.

     Which of the following statements is CORRECT?

     A     The forward reaction is exothermic.
     B     The concentration of AB is lower at a lower temperature.
     C     The forward reaction is endothermic.
     D     The concentration of B is higher at a lower temperature.                         (2)

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                                             PHYSICAL SCIENCES: CHEMISTRY                 6
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1.9    Which of the following is the CORRECT description for a 10 mol∙dm-3
       hydrochloric acid solution?

       A    Dilute strong acid
       B    Dilute weak acid
       C    Concentrated weak acid
       D    Concentrated strong acid                                                       (2)

1.10   Consider the reaction represented by the following equation:

                           2Ag+(aq) + Cu(s) → 2Ag(s) + Cu2+(aq)

       Which of the following represents the oxidising agent in the above reaction?

       A    Ag+
       B    Cu
       C    Ag
       D    Cu2+                                                                           (2)
                                                                                          [20]

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                                             PHYSICAL SCIENCES: CHEMISTRY              7
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QUESTION 2 (Start on a new page.)

A to H in the table below represents eight organic compounds.

        A                                     B

                                                         2-methylbutan-2-ol

        C                                     D
                    Pentan-2-one                         CH3CH2COCH2CH3

        E                                     F
                      Butan-2-ol                         Methyl propanoate

        G                                     H

Use the table above to answer the following questions.

2.1   Define the term homologous series.                                                (2)

2.2   Consider the organic compound G.

      2.2.1   Write down the homologous series to which this compound belongs.          (1)

      2.2.2   Write down the CONDENSED STRUCTURAL FORMULA.                              (1)

      2.2.3   Write down the IUPAC name of the functional isomer of G.                  (2)

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2.3   Write down the:

      2.3.1   IUPAC name of compound H                                                      (3)

      2.3.2   GENERAL FORMULA of the homologous series to which compound A
              belongs                                                                       (1)

2.4   Write down the letter(s) of the compound(s) that represent(s):

      2.4.1   The positional isomers                                                        (2)

      2.4.2   An ester                                                                      (1)

2.5   Consider the organic compound B.

      2.5.1   Write down the STRUCTURAL FORMULA.                                            (2)

      2.5.2   Is compound B a PRIMARY, SECONDARY or TERTIARY alcohol?                       (1)

      2.5.3   Explain the answer to QUESTION 2.5.2.                                         (2)

2.6   Hydrocarbons are the principal constituents of petroleum and natural gas.
      A hydrocarbon consists of 81,82% carbon and 18,18% hydrogen.

      Calculate the empirical formula of this hydrocarbon.                                  (4)
                                                                                           [22]

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QUESTION 3 (Start on a new page.)

A group of learners decide to conduct an investigation to compare the boiling points of
the first three haloalkanes, namely chloromethane, chloroethane and 1-chloropropane.

The table below shows the results obtained from the investigation.

      COMPOUND            IUPAC NAME                  BOILING POINT (°C)
          A               chloromethane                     -24,2
          B                chloroethane                      12,3
          C              1-chloropropane                     46,6

3.1   Define the term boiling point.                                                      (2)

3.2   Identify the:

      3.2.1    Independent variable                                                       (1)

      3.2.2    Dependent variable                                                         (1)

      3.2.3    Controlled variable                                                        (1)

3.3   Write down a suitable investigative question.                                       (2)

3.4   Chloromethane is highly flammable.

      Write down ONE precaution that should be taken when working with this
      substance in the laboratory.                                                        (1)

3.5   Which ONE of these substances (A, B, or C) has the lowest vapour pressure?
      Give a reason for the answer.                                                       (2)

3.6   The learners find 1-chlorobutane in the laboratory.

      How would the boiling point of 1-chlorobutane compare to that of
      1-chloropropane?

      Write only HIGHER THAN, LOWER THAN or EQUAL TO.                                     (1)

3.7   Explain the answer to QUESTION 3.6 by referring to the type of intermolecular
      forces, strength, and energy.                                                       (3)

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3.8   The learners decide to do another investigation with compounds J and K.

        J                                     K               Butane

      Bromine water is used to distinguish between compounds J and K by adding it
      to each compound in two separate test tubes.

      The learners observe that one compound decolourises the bromine water
      immediately, while the other substance only reacts after placing the test tube in
      direct sunlight.

      Write down:

      3.8.1   The letter (J or K) of the compound that will immediately decolourise
              the bromine water                                                            (1)

      3.8.2   The reason that the other substance only reacts when placed in direct
              sunlight                                                                     (1)

      3.8.3   The MOLECULAR FORMULA of the organic product formed in the test
              tube containing compound J                                                   (2)

      3.8.4   A balanced chemical equation when compound K undergoes complete
              combustion                                                                   (3)
                                                                                          [21]

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QUESTION 4 (Start on a new page.)

The flow diagram below shows three organic reactions, namely Reactions I, II and III.
Various organic and inorganic products are formed as a result of these reactions.

                                             Pentane

                                              + HBr
 Compound C                                                          2-bromopentane

                         Compound B

                                                       + Product A

Use the flow diagram above to answer the following questions.

4.1   Define the term saturated compound.                                                    (2)

4.2   2-bromopentane undergoes hydrolysis.

      4.2.1   Name the type of reaction represented in Reaction I.                           (1)

      4.2.2   Name the inorganic product A that is formed in the reaction.                   (1)

      4.2.3   Give ONE reaction condition.                                                   (1)

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                                             PHYSICAL SCIENCES: CHEMISTRY                   12
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4.3   Consider compound B.

      4.3.1   Write down the IUPAC name.                                                         (2)

      4.3.2   Name the type of reaction represented in Reaction II.                              (1)

      4.3.3   Write down the STRUCTURAL FORMULA of the major product C.                          (2)

      4.3.4   Write down the CHEMICAL FORMULA of the inorganic product formed
              in Reaction II.                                                                    (1)

4.4   Consider Reaction III.

      4.4.1   Name the type of addition reaction.                                                (1)

      4.4.2   Give the CHEMICAL FORMULA of the catalyst needed for this reaction.                (1)

4.5   Esterification is one of the most important reactions in both organic synthesis and
      the chemical industry. When making an ester, 60 g of propan-1-ol reacts with
      excess ethanoic acid which produces 90,78 g of an ester and water.

      The balanced chemical equation below shows the reaction that takes place.

              C3H8OH () + CH3COOH (aq) → C5H10O2 () + H2O ()

      4.5.1   Write down the STRUCTURAL FORMULA for the ester produced.                          (3)

      4.5.2   Give the IUPAC name for the ester.                                                 (2)

      4.5.3   Give the chemical name of the catalyst used.                                       (1)

      4.5.4   Calculate the percentage purity of propan-1-ol.                                 (5)
                                                                                             [24]

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QUESTION 5 (Start on a new page.)

A group of learners use the reaction between excess hydrochloric acid and magnesium
ribbon to investigate one of the factors that influences the rate of a chemical reaction.
The reaction that takes place is:

                       Mg(s) + 2HC (aq) → MgC2 (aq) + H2(g)

The learners follow the method shown below to conduct the investigation at room
temperature. A diagram of the apparatus is given below.

Method – Experiment 1:
Step 1: Place a piece of magnesium ribbon in a conical flask and add 50 cm3 HC (aq)
        of known concentration.
Step 2: Simultaneously start the stopwatch and close the flask with the rubber
        stopper containing the delivery tube.
Step 3: Measure the volume of the H2(g) formed in time intervals of 20 seconds.

Method – Experiment 2:
Repeat steps 1 to 3 above, but use only 15 cm3 of the same HC (aq) diluted with
50 cm3 distilled water.

Apparatus:

                                          gas syringe

      magnesium ribbon
                                                   dilute hydrochloric
                                                   acid

5.1   Define the term reaction rate.                                                             (2)

5.2   Write down a conclusion for this investigation.                                            (2)

5.3   The concentration of the hydrochloric solution is 2 mol·dm-3.

      Calculate the concentration used in Experiment 2.                                          (3)

5.4   Name TWO conditions that learners had to keep the same to ensure that this is a
      fair test.                                                                                 (2)

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                                                                           PHYSICAL SCIENCES: CHEMISTRY              14
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After completing the investigation, the learners represented the results obtained during
each experiment on the graph below.
                                                Graph of volume of hydrogen gas versus time

                                60                          ●        ●        ●      ●
                                         Experiment 1                         ●

                                                    ●
                                50                                   ●

                                                                   Experiment 2
                                                            ●
                                40

 Volume of hydrogen gas (cm3)
                                            ●
                                30                  ●

                                20
                                            ●

                                10

                                 0
                                     0     20      40      60       80       100     120     140
                                                                Time (s)

5.5                              Give a reason why the same volume of hydrogen gas is formed in both
                                 experiments.                                                                             (1)

5.6                              Write down the volume of hydrogen gas formed during the first minute in:

                                 5.6.1    Experiment 1                                                                    (1)

                                 5.6.2    Experiment 2                                                                    (1)

5.7                              Which ONE of the experiments (Experiment 1 or Experiment 2) took place at a
                                 faster rate? Use the graph to explain the choice.                                        (3)

5.8                              Calculate the average reaction rate with respect to the magnesium, in g·s-1, in
                                 Experiment 1 if the molar volume at room temperature is 24 dm3.                       (5)
                                                                                                                      [20]

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QUESTION 6 (Start on a new page.)

The reaction between steam and chlorine gas reaches equilibrium in a closed container
according to the following balanced equation:

               2H2O(g) + 2Cℓ2(g) ⇌ 4HCℓ(g) + O2(g)                             ΔH = +113 kJ

6.1   Is this reaction EXOTHERMIC or ENDOTHERMIC? Give a reason for the
      answer.                                                                                               (2)

6.2   The graphs below, not drawn to scale, show how the amount of products present
      in the container change with time at a specific temperature. The volume of the
      container is 5 dm3.

                                              1,0

                    Amount of product (mol)   0,3

                                                                                    HCℓ(g)
                                              0,1                                   O2(g)

                                                    0   t1     t2             t3
                                                             Time (minutes)

      6.2.1   Which reaction is favoured? Choose from FORWARD or REVERSE?
              Give a reason for the answer.                                                                 (2)

      6.2.2   How do the rates of the forward and the reverse reactions compare at
              time t3?

              Write down only GREATER THAN, SMALLER THAN or EQUAL TO.                                       (1)

      6.2.3   Calculate the equilibrium constant (Kc) for this reaction at this
              temperature if there was initially 5 g of water and 5 g of chlorine.                          (9)

6.3   The pressure is NOW increased. How will this change affect the value of the
      equilibrium constant?

      Write down only INCREASE, DECREASE or REMAINS THE SAME. Give a
      reason for the answer                                                                                 (2)

6.4   The reaction is repeated with a catalyst. Draw a potential energy diagram of this
      reaction and indicate the non-catalysed reaction (B) and catalysed reaction (A)
      on the same graph.                                                                                 (4)
                                                                                                        [20]
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QUESTION 7 (Start on a new page.)

7.1   Sulphuric acid is a diprotic acid.

      7.1.1   Define the term ACID in terms of the Arrhenius theory.                              (2)

      7.1.2   Give a reason why sulphuric acid is referred to as a diprotic acid.                 (1)

7.2   The hydrogen carbonate ion can act as both an acid and a base. It reacts with
      water according to the following balanced equation:

                         HCO3- (aq) + H2O(ℓ) ⇌ H2CO3(aq) + OH-(aq)

      7.2.1   Write down ONE word for the underlined phrase above.                                (1)

      7.2.2   Copy the equation above and indicate the conjugate acid-base pairs.                 (2)

7.3   A laboratory assistant was asked to prepare a 2 500 cm3 solution of HC with a
      concentration of 0,25 mol·dm-3. The laboratory had a bottle of concentrated HC
      which had the following written on the label:

                  Chemical:                   HC
                  Density:                   1,20 g·cm-3
                  % HC by mass in solution: 36%

      7.3.1   Calculate the mass of HC contained in 2 500 cm3 of a
              0,25 mol·dm-3 solution.                                                             (4)

      7.3.2   50 cm3 of the 0,25 mol·dm-3 HC solution is used to neutralise
              20 cm3 of a sodium carbonate (Na2CO3) solution.

                               2HC + Na2CO3 → 2NaC + H2O + CO2

              Calculate the concentration of the carbonate solution.                              (4)

      7.3.3   Name a suitable indicator that can be used for this titration. Give a
              reason for the answer.                                                           (2)
                                                                                              [16]

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                                              PHYSICAL SCIENCES: CHEMISTRY                17
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QUESTION 8 (Start on a new page.)

8.1   A clean piece of copper (Cu) is placed in a solution of silver nitrate (AgNO3).
      The balanced net ionic equation is:

                          Cu (s) + 2 Ag+ (aq) → Cu2+ (aq) + 2 Ag (s)

      8.1.1   Define oxidation in terms of electron transfer.                                  (2)

      8.1.2   What type of reaction does copper (Cu) undergo in this equation?

              Choose from OXIDATION or REDUCTION.

              Explain the answer by referring to oxidation numbers.                            (3)

8.2   Sulphur dioxide gas (SO2) is bubbled into an acidified solution of potassium
      permanganate as shown in the diagram below.

                             SO2 gas

                                KMnO4 solution

      It is observed that the solution turns from purple to colourless due to the
      reduction of MnO ions to Mn2+ ions. During the reaction SO2 is oxidised to
      sulphate ions, SO .
      Determine the oxidation number of manganese, in the permanganate ion
      (MnO ).                                                                                  (2)
                                                                                               [7]

                                                                                 TOTAL:    150

                                                                                           END

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                                                                PHYSICAL SCIENCES: CHEMISTRY              18
                                                                (PAPER 2)            GR12 0624

                           DATA FOR PHYSICAL SCIENCES GRADE 12
                                   PAPER 2 (CHEMISTRY)

                     GEGEWENS VIR FISIESE WETENSKAPPE GRAAD 12
                                VRAESTEL 2 (CHEMIE)

TABLE 1: PHYSICAL CONSTANTS/TABEL 1: FISIESE KONSTANTES

NAME/NAAM                                   SYMBOL/SIMBOOL                     VALUE/WAARDE
Standard pressure
                                                           p                          1,013 x 105 Pa
Standaarddruk
Molar gas volume at STP
                                                          Vm                           22,4 dm3∙mol-1
Molêre gasvolume by STD
Standard temperature
                                                          T                                 273 K
Standaardtemperatuur
Charge on electron
                                                           e                            -1,6 x 10-19 C
Lading op elektron
Avogadro’s constant
                                                          NA                          6,02 x 1023 mol-1
Avogadro-konstante

TABLE 2: FORMULAE/TABEL 2: FORMULES

     m                                                               N
n                                                              n
     M                                                               NA

     n                           m                                   V
c          OR/OF           c                                  n
     V                           MV                                  VM
 c a Va na
                                                               pH = - log[H3O+]
 cb Vb nb
Kw = [H3O+][OH-] = 1 x 10-14 at/by 298 K

E θcell  E θcathode  E θanode / E sel  E katode
                                             
                                                     E anode

or/of
  
 Ecell  E θ reduction  E θ oxidation/ E sel  Ereduksie
                                                              
                                                            E oksidasie

or/of
                               
                 sin g agent  E reducing agent / Esel  Eoksideermiddel  Ereduseermiddel
                                                   θ      θ                 θ
E cell  E oxidi

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                                                                                                                                                          FISIESE WETENSKAPPE: CHEMIE                                             19
                                                                                                                                                          (VRAESTEL 2)       GR12 0624

                              TABLE 3: THE PERIODIC TABLE OF ELEMENTS/TABEL 3: DIE PERIODIEKE TABEL VAN ELEMENTE
       1                2            3              4              5           6           7           8            9           10          11           12           13            14          15            16           17           18
      (I)              (II)                                                                                                                                          (III)         (IV)         (V)          (VI)         (VII)        (VIII)
                                                                                               Atomic number/
                                                             KEY/SLEUTEL                         Atoomgetal
            1                                                                                                                                                                                                                             2
2,1         H                                                                                                                                                                                                                            He
            1                                                                                          29                                                                                                                                 4
                                                              Electro negativity/                                       Symbol/
            3              4                                                                     1,9   Cu                                                               5             6           7             8            9           10
            Li            Be                                 Elektronegatiwiteit                                        Simbool                                        B             C           N             O            F            Ne
1,0              1,5                                                                                   63,5                                                    2,0           2,5          3,0          3,5          4,0
            7              9                                                                                                                                           11            12          14            16           19           20
        11               12                                                                                                                                            13            14          15            16           17            18
        Na               Mg
                                                                          Approximate relative atomic mass/                                                            Aℓ            Si          P             S            Cℓ            Ar
0,9              1,2                                                                                                                                           1,5           1,8          2,1          2,5          3,0
        23               24                                               Benaderde relatiewe atoommassa                                                               27            28          31            32          35,5           40
        19                20             21             22         23          24          25          26           27           28          29          30            31           32           33           34            35            36
0,8     K        1,0      Ca   1,3       Sc   1,5       Ti   1,6   V     1,6   Cr    1,5   Mn    1,8   Fe     1,8   Co    1,8    Ni   1,9    Cu    1,6   Zn    1,6     Ga    1,8    Ge    2,0    As    2,4    Se    2,8     Br            Kr
        39                40             45             48         51          52          55          56           59           59         63,5         65            70           73           75           79            80            84
        37                38             39             40         41          42          43           44           45          46          47           48           49            50          51            52           53            54
0,8     Rb       1,0      Sr   1,2       Y    1,4       Zr         Nb    1,8   Mo    1,9   Tc    2,2   Ru     2,2   Rh    2,2   Pd    1,9   Ag     1,7   Cd    1,7     In    1,8    Sn    1,9   Sb     2,1    Te    2,5      I           Xe
        86                88             89             91         92          96                      101          103         106         108          112          115           119         122           128          127           131
        55                56          57             72             73          74          75          76           77          78          79           80           81            82          83           84            85           86
       Cs                Ba          La              Hf            Ta           W          Re          Os            Ir          Pt         Au           Hg            Tℓ           Pb           Bi           Po            At           Rn
0,7              0,9                          1,6                                                                                                              1,8           1,8          1,9          2,0          2,5
       133               137         139            179            181         184         186         190          192         195         197          201          204           207         209

        87                88             89
0,7     Fr       0,9     Ra              Ac
                         226
                                                                    58          59          60         61            62          63          64           65           66            67           68           69           70            71
                                                                   Ce           Pr         Nd          Pm           Sm          Eu          Gd           Tb           Dy            Ho            Er          Tm           Yb            Lu
                                                                   140         141         144                      150         152         157          159          163           165          167          169          173           175

                                                                    90         91           92         93           94          95          96           97            98            99          100          101          102           103
                                                                   Th          Pa           U          Np           Pu          Am          Cm           Bk            Cf            Es          Fm           Md           No             Lr
                                                                   232                     238

### Page 20

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                                                                                                  PHYSICAL SCIENCES: CHEMISTRY                                                           20
                                                                                                  (PAPER 2)           GR12 0624

                                                              TABLE 4A: STANDARD REDUCTION POTENTIALS
                                                              TABEL 4A: STANDAARD-REDUKSIEPOTENSIALE
                                                                       Half-reactions/Halfreaksies                 E θ (V)
                                                                          F2(g) + 2e         ⇌    2F             + 2,87
                                                                            Co3+ + e         ⇌    Co2+            + 1,81
                                                                     H2O2 + 2H+ +2e          ⇌    2H2O            + 1,77
                                                                       
                                                                  MnO 4 + 8H+ + 5e           ⇌    Mn2+ + 4H2O     + 1,51
                                                                                                                 + 1,36
                                                                            Cℓ2(g) + 2e       ⇌    2Cℓ
                                                                      2
                                                                 Cr2O 7 + 14H+ + 6e          ⇌    2Cr3+ + 7H2O    + 1,33
                                                                    O2(g) + 4H+ + 4e         ⇌    2H2O            + 1,23
                                                                    MnO2 + 4H+ + 2e          ⇌    Mn2+ + 2H2O     + 1,23
                                                                            Pt2+ + 2e        ⇌    Pt              + 1,20
                                                                          Br2(ℓ) + 2e        ⇌    2Br            + 1,07
                                                                       
                                                                    NO 3 + 4H+ + 3e          ⇌    NO(g) + 2H2O    + 0,96

                                                                                                                             Increasing reducing ability/Toenemende reduserende vermoë
                                                                                Hg2+ + 2e    ⇌    Hg(ℓ)           + 0,85
                                                                                  Ag+ + e    ⇌    Ag              + 0,80

Increasing oxidising ability/Toenemende oksiderende vermoë
                                                                            
                                                                     NO 3 + 2H+ + e          ⇌    NO2(g) + H2O    + 0,80
                                                                                 Fe3+ + e    ⇌    Fe2+            + 0,77
                                                                    O2(g) + 2H+ + 2e         ⇌    H2O2            + 0,68
                                                                              I2 + 2e        ⇌    2I             + 0,54
                                                                             Cu+ + e         ⇌    Cu              + 0,52
                                                                     SO2 + 4H+ + 4e          ⇌    S + 2H2O        + 0,45
                                                                     2H2O + O2 + 4e          ⇌    4OH            + 0,40
                                                                           Cu2+ + 2e         ⇌    Cu              + 0,34
                                                                       2
                                                                   SO 4 + 4H+ + 2e           ⇌    SO2(g) + 2H2O   + 0,17
                                                                                 Cu2+ + e    ⇌    Cu+             + 0,16
                                                                           Sn4+ + 2e         ⇌    Sn2+            + 0,15
                                                                        S + 2H+ + 2e         ⇌    H2S(g)          + 0,14
                                                                            2H+ + 2e         ⇌    H2(g)            0,00
                                                                           Fe3+ + 3e         ⇌    Fe               0,06
                                                                           Pb2+ + 2e         ⇌    Pb               0,13
                                                                           Sn2+ + 2e         ⇌    Sn               0,14
                                                                            Ni2+ + 2e        ⇌    Ni               0,27
                                                                           Co2+ + 2e         ⇌    Co               0,28
                                                                           Cd2+ + 2e         ⇌    Cd               0,40
                                                                             Cr3+ + e        ⇌    Cr2+             0,41
                                                                           Fe2+ + 2e         ⇌    Fe               0,44
                                                                           Cr3+ + 3e         ⇌    Cr               0,74
                                                                           Zn2+ + 2e         ⇌    Zn               0,76
                                                                          2H2O + 2e          ⇌    H2(g) + 2OH     0,83
                                                                           Cr2+ + 2e         ⇌    Cr               0,91
                                                                           Mn2+ + 2e         ⇌    Mn               1,18
                                                                            Aℓ3+ + 3e        ⇌    Aℓ               1,66
                                                                           Mg2+ + 2e         ⇌    Mg               2,36
                                                                             Na+ + e         ⇌    Na               2,71
                                                                           Ca2+ + 2e         ⇌    Ca               2,87
                                                                            Sr2+ + 2e        ⇌    Sr               2,89
                                                                           Ba2+ + 2e         ⇌    Ba               2,90
                                                                              Cs+ + e-        ⇌    Cs              – 2,92
                                                                               K+ + e        ⇌    K                2,93
                                                                              Li+ + e        ⇌    Li               3,05

### Page 21

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                                                                                             PHYSICAL SCIENCES: CHEMISTRY                                                           21
                                                                                             (PAPER 2)           GR12 0624

                                                              TABLE 4B: STANDARD REDUCTION POTENTIALS
                                                              TABEL 4B: STANDAARD-REDUKSIEPOTENSIALE
                                                                          Half-reactions/Halfreaksies         E θ (V)
                                                                       Li+ + e          ⇌          Li         3,05
                                                                       K+ + e           ⇌          K          2,93
                                                                      Cs+ + e           ⇌         Cs          2,92
                                                                     Ba2+ + 2e          ⇌         Ba          2,90
                                                                      Sr2+ + 2e         ⇌         Sr          2,89
                                                                     Ca2+ + 2e          ⇌         Ca          2,87

                                                                                                                        Increasing reducing ability/Toenemende reduserende vermoë
                                                                       Na+ + e          ⇌         Na          2,71
                                                                     Mg2+ + 2e          ⇌         Mg          2,36
                                                                      Aℓ3+ + 3e         ⇌         Aℓ          1,66

Increasing oxidising ability/Toenemende oksiderende vermoë
                                                                     Mn2+ + 2e          ⇌         Mn          1,18
                                                                      Cr2+ + 2e         ⇌         Cr          0,91
                                                                     2H2O + 2e          ⇌    H2(g) + 2OH     0,83
                                                                     Zn2+ + 2e          ⇌         Zn          0,76
                                                                      Cr3+ + 3e         ⇌         Cr          0,74
                                                                     Fe2+ + 2e          ⇌         Fe          0,44
                                                                      Cr3+ + e          ⇌        Cr2+         0,41
                                                                     Cd2+ + 2e          ⇌         Cd          0,40
                                                                     Co2+ + 2e          ⇌         Co          0,28
                                                                      Ni2+ + 2e         ⇌          Ni         0,27
                                                                     Sn2+ + 2e          ⇌         Sn          0,14
                                                                     Pb2+ + 2e          ⇌         Pb          0,13
                                                                     Fe3+ + 3e          ⇌         Fe          0,06
                                                                      2H+ + 2e          ⇌        H2(g)        0,00
                                                                    S + 2H+ + 2e        ⇌       H2S(g)       + 0,14
                                                                     Sn4+ + 2e          ⇌        Sn2+        + 0,15
                                                                      Cu2+ + e          ⇌        Cu+         + 0,16
                                                                     2
                                                                  SO 4 + 4H+ + 2e       ⇌    SO2(g) + 2H2O   + 0,17
                                                                     Cu2+ + 2e          ⇌         Cu         + 0,34
                                                                  2H2O + O2 + 4e        ⇌        4OH        + 0,40
                                                                  SO2 + 4H+ + 4e        ⇌      S + 2H2O      + 0,45
                                                                      Cu+ + e           ⇌         Cu         + 0,52
                                                                       I2 + 2e          ⇌         2I        + 0,54
                                                                  O2(g) + 2H+ + 2e      ⇌        H2O2        + 0,68
                                                                      Fe3+ + e          ⇌        Fe2+        + 0,77
                                                                      
                                                                   NO 3 + 2H+ + e       ⇌    NO2(g) + H2O    + 0,80
                                                                      Ag+ + e           ⇌         Ag         + 0,80
                                                                     Hg2+ + 2e          ⇌        Hg(ℓ)       + 0,85
                                                                      
                                                                  NO 3 + 4H+ + 3e       ⇌    NO(g) + 2H2O    + 0,96
                                                                                                            + 1,07
                                                                     Br2(ℓ) + 2e         ⇌        2Br
                                                                     Pt2+ + 2 e         ⇌          Pt        + 1,20
                                                                  MnO2 + 4H+ + 2e       ⇌     Mn2+ + 2H2O    + 1,23
                                                                  O2(g) + 4H+ + 4e      ⇌        2H2O        + 1,23
                                                                     2
                                                                 Cr2O 7 + 14H+ + 6e     ⇌    2Cr3+ + 7H2O    + 1,33
                                                                                                            + 1,36
                                                                     Cℓ2(g) + 2e         ⇌        2Cℓ
                                                                      
                                                                  MnO 4    + 8H+ + 5e   ⇌     Mn2+ + 4H2O    + 1,51
                                                                  H2O2    + 2H+ +2 e    ⇌        2H2O        + 1,77
                                                                     Co3+ + e           ⇌        Co2+        + 1,81
                                                                    F2(g) + 2e          ⇌         2F        + 2,87

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