# Physical Sciences Grade 12 P2 KwaZulu Natal Mock 2019 Memo

> Grade 12 Physical Sciences Paper 2 memorandum from the KwaZulu Natal Mock Exam 2019, 8 pages. Read online or download the free PDF.

- Page: https://www.hlayiso.com/library/kzn-2019-paper-2-memo/d2707f57-f351-4407-87db-00f48d019c22
- Updated: 2026-09-27
- Subject: Physical Sciences
- Grade: Grade 12
- Document type: Memorandum
- Year: 2019
- Exam period: KwaZulu Natal Mock Exam
- Paper: 2
- Curriculum: CAPS
- Pages: 8

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Physical Sciences · Grade 12 · KwaZulu Natal Mock Exam · 2019. Memorandum, 8 pages. Read online or download the PDF.

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### Page 1

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Physical Sciences / P2                         1                                      19
                                         NSC-Memorandum

                         PHYSICAL SCIENCES P2 (CHEMISTRY)

                             PREPARATORY EXAMINATION

                                     SEPTEMBER 2019

                                     MEMORANDUM

                                      NATIONAL
                                 SENIOR CERTIFICATE

                                          GRADE 12

MARKS           : 150

                           This marking guideline consists of 8 pages.

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Physical Sciences / P2                      2            Preparatory Examination September 2019
                                      NSC-Memorandum

QUESTION 1

1.1     D                                                                           (2)

1.2     C                                                                           (2)

1.3     A                                                                           (2)

1.4     C                                                                           (2)

1.5     D                                                                           (2)

1.6     D                                                                           (2)

1.7     D                                                                           (2)

1.8     C                                                                           (2)

1.9     C                                                                           (2)

1.10    B                                                                           (2)
                                                                                      [20]

QUESTION 2

2.1.1 hexan-3-one                                                                   (2)
2.1.2 carboxyl (group)                                                               (1)
2.1.3
            H                       H       H
            │                       │       │                  Whole structure correct: 2/2
        H ― C ― C           ≡   C ― C     ― C   ― H            Only functional group
                                                                correct                 1/2
            │                               │
                                                               More than one functional
            H                               H
                                                                group                    0/2
                                H ―   C   ― H
                                      │
                                      H
                                                                                             (2)

2.1.4 addition polymerisation                                                               (1)
2.1.5
               H   H
               │   │                     Whole structure correct 
             ― C ― C ―                   Name 
               │   │
               H   H  n
        polyethene                                                                          (3)

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Physical Sciences / P2                            3             Preparatory Examination September 2019
                                            NSC-Memorandum

2.1.6 G                                                                                           (1)
2.2.1 esters/alkyl alkanoate                                                                      (1)
2.2.2 ethyl propanoate                                                                           (2)
2.2.3
                         H        H         O
                         │        │         ║
           H       ―     C   ―    C    ―    C       ―   O   ―   H
                         │        │
                         H        H

                    Whole structure correct: 2/2
                    Only functional group
                     correct                 1/2
                    More than one functional                                                      (2)
                     group                    0/2

2.2.4 acts as a catalyst/speeds up the reaction.  or
        acts as a dehydrating agent.                                                              (1)
2.3.1 Compounds that have the same molecular formula but different functional
      groups                                                                                     (2)

2.3.2 pentanoic acid                                                                              (2)
                                                                                                 [20]

QUESTION 3

3.1     the pressure exerted by a vapour at equilibrium with its liquid in a closed
        system.  (2 or 0)                                                                        (2)

3.2.1 length of carbon chain/surface area/branching                                               (1)

3.2.2 number of carbon atoms/molecular mass                                                       (1)

3.3.1 GREATER THAN                                                                                (1)

3.3.2 M has a longer carbon chain/greater surface area than N/ M has more sites for
      intermolecular forces
      Intermolecular forces between molecules of M are stronger than between molecules
      of N
      More energy is required to overcome the intermolecular forces between molecules
      of M                                                                                        (3)

3.4     N                                                                                         (1)
                                                                                                   [9]

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Physical Sciences / P2                           4              Preparatory Examination September 2019
                                           NSC-Memorandum

QUESTION 4
4.1.1 warm/mild heat dilute KOH/warm dilute strong base                                        (2)

4.1.2 hot KOH concentrated Base(KOH)                                                             (2)

4.2     substitution                                                                              (1)

4.3       H H H H                                    H H H H
          │ │ │ │                                    │ │ │ │
      H ─ C ─ C ─ C ─ C ─ H + KOH                H ─ C ─ C ═ C ─ C ─ H + KBr + H2O
          │ │ │ │                                    │           │
          H Br H H                                   H           H

                left hand side
                for organic product
                balancing                                                                        (4)

4.4     unsaturated
        contains a double bond/multiple bond between atoms of carbon                             (3)

4.5     hydration                                                                                (2)
                                                                                                  [14]
QUESTION 5
5.1     calcium carbonate there is some unreacted CaCO3 at the end of the reaction
        (time 60s)                                                                                (2)
5.2.1 ANY ONE
                The change in concentration of reactants/products per unit time. 
                Rate of change in concentration of reactants or products. 
                Change in amount/number of moles/volume/mass of reactants/products
                 per (unit) time.
                Amount/number of moles/volume/mass of products formed OR reactants used
                 per (unit) time.                                                        (2)

                     change in mass of CaCO3      Marking criteria
5.2.2 rate                                         Equation(accept if negative sign
                                t
                                                         is omitted)
                54  X                                Substitute 54 – X in equation 
        1,07 = -
                 30  0                                Substitute 30 – 0 in equation
                                                        Substitute 1,07for rate
                = 86,10 g 
                                                        Final answer: X = 86,10 g 
                 (if answer is negative minus
                 1 mark)                                                                           (5)

5.3     0 (cm3).                                                                                  (1)

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Physical Sciences / P2                                 5           Preparatory Examination September 2019
                                                 NSC-Memorandum

5.4     A decrease in concentration of reactants decreases the number of molecules per unit
        volume. 
        Fewer number of collisions per unit time
        A fewer number of effective collisions occur per unit time/lower frequency of
        effective collisions.                                                              (3)

5.5     REMAINS THE SAME                                                                                  (1)
                                                                                                          [14]
QUESTION 6
6.1     When the equilibrium in a closed system is disturbed, the system will
        re-instate a new equilibrium by favouring the reaction that will oppose the
        disturbance.  (2 or 0)                                                                           (2)

6.2     the reaction has reached a state of (dynamic) equilibrium/the rate of the forward
        reaction is equal to the rate of the reverse reaction. (2 or 0)                                  (2)
6.3      Marking criteria:
          Indicating that the number of mols of CO equilibrium is 0,6
          Correct mol ratio
          Calculating the quantity(mol) at equilibrium of all three substances 
                                        n
          Substitute V = 2 dm3 in c      to determine concentration at equilibrium of all the
                                        V
            substances.
          Kc expression
          Substitution of concentrations in Kc expression 
          Final answer: 0,456 

         No Kc expression, correct substitution: Max. 6
                                                            7

         Wrong Kc expression :      Max.     4
                                                 7

                                           CH4            H2O     CO          H2
         Initial quantity(mol)              2,2            1,8     0            0
         Change(mol)                       -0,6           -0,6    +0,6        + 1,8       Ratio 
         Quantity at                                                                  
                                           1,6            1,2      0,6        1,8
         equilibrium(mol)
         Equilibrium                       0,8            0,6      0,3         0,9        Divide by 2
         concentration(mol.dm-3)

                 Kc =
                          [CO] [H2 ]3
                                      =
                                           0,3 0,93      = 0,456                              (7)
                         [CH4 ] [H2O]       0,8 0,6

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Physical Sciences / P2                                             6            Preparatory Examination September 2019
                                                             NSC-Memorandum

6.4
                                                                                       Graph starts at 2,2

             Number of moles CH4
                                   2,2                                                  Decreases to 1,6
                                                                                       Correct shape
                                                                                       curve
                                                                          
                                   1,6                                                  horizontal
                                                                                        ignore labels on
                                                                                        axes

                                                             Time in minutes
                                                                                                                   (4)
6.5.1 INCREASES                                                                                                   (1)
6.5.2 REMAINS THE SAME                                                                                            (1)

6.6     An increase in the number of moles of CH4 increases the concentration of
        CH4(reactant).
        According to Le Chateliers Principle an increase in the concentration of the reactants 
        favours the reaction that decreases the concentration of the reactants
        In this case the forward reaction is favoured
                                                                                               (3)
                                                                                              [20]

QUESTION 7
7.1.1 An acid is a substance that produces hydrogen ions(H+)/hydronium ions(H3O+)
      when it dissolves in water.                                                                                 (2)

7.1.2 strong
      it ionises completely in water                             (ACCEPT: dissociates)                           (3)
7.2.1
                                   pH     = - log [H3O+] 
                                                                         Formula pH = - log [H3O+] 
                     0,65                = - log [H3O+]                 Substitute 0,65 for pH
           [H3O+]                        = 0,224 mol.dm-3               c((H2SO4)     = ½c(H3O+)
                                                                         c((H2SO4)     = 0,112 mol.dm-3
          c((H2SO4)                       = ½c(H3O+) 
                                          = ½(0,224)
                                          = 0,112 mol.dm-3
                                                                                                                   (4)

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Physical Sciences / P2                             7                Preparatory Examination September 2019
                                             NSC-Memorandum

7.2.2 POSITIVE MARKING FROM QUESTION 7.2.1: concentration of H2SO4
                         Marking guidelines/Nasienriglyne:
                              n
           Formulae: c        /n = cV/ 
                              V
             Calculate initial number of moles of H2SO4
             Calculate number of moles of H2SO4 that reacted
             Calculate number of moles of H2SO4 in excess
             Calculate number of moles of NaOH that reacted
             Ratio of NaOH to H2SO4
             Final answer cm3 or dm3

              n(H2SO4)initial       =   cV
                                    =   (0,25)(0,024) 
                                    =   6 x 10-3 mols

              n(H2SO4)excess        =   cV
                                    =   (0,112)(X + 24)
                                                             
                                                1000

                                                          (0,112)(X + 24)
              n(H2SO4)reacted       =    6 x 10-3    -                       
                                                                   1000

              n(NaOH)reacted        =    cV
                                        0,15(X)
                                                    
                                            1000

              n(NaOH)reacted        =   2   (n(H2SO4)reacted)

              0,15(X)                                      (0,112)(X + 24)
                                = 2(    (6 x 10-3    -                       )
                 1000                                              1000
                                X   =   17,71 cm3        0,01771 dm3
                                                                                                       (7)
                                                                                                      [16]
QUESTION 8
8.1     a solution/liquid/dissolved substance that conducts electricity through the
        movement of ions.                                                                             (2)

8.2     Zn(s) Zn 2+(aq) + 2e-

         Notes
          Zn2+ + 2e- ← Zn            (2 )                      Zn2+ + 2e- ⇌ Zn   (0 )
                                         2                                           2
                Zn ⇌ Zn2+ + 2e-       (1 )                      Zn2+ + 2e → Zn    ( 0   )
                                         2                                            2
               Ignore if charge on electron is omitted.
               If a charge of an ion is omitted e.g. Zn → Zn2 + 2e-                  Max.: 1
                                                                                             2
                                                                                                        (2)

8.3.1 Temperature of 25 ºC/298K
      Concentration of the electrolytes equals 1 mol.dm-3.                                             (2)

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Physical Sciences / P2                             8              Preparatory Examination September 2019
                                             NSC-Memorandum

8.3.2 EΘcell              = EΘcathode - EΘanode    Notes
                                                     Accept any other correct formula from the
        0,63             = EΘcathode - (-0,76)      data sheet.
        EΘcathode         = - 0,13 V                Any other formula using unconventional
               X is       lead(Pb)                   abbreviations, e.g. E°cell = E°OA - E°RA
                                                      followed by correct substitutions:
                                                      E°sel = E°OM - E°RM Max/: 4
                                                                                    5
                                                                                                       (5)
8.4     Zn(s)/Zn2+(aq) //Pb2+(aq)/Pb(s) 
        Zn(s)/Zn2+(1 mol.dm-3) //Pb2+(1 mol.dm-3)/Pb(s)
        Accept            Zn/Zn2+//Pb2+/Pb                                                             (3)
8.5     0(V)                                                                                          (1)
                                                                                                     [15]
QUESTION 9
9.1     from electrical energy to chemical energy                                                     (1)
9.2     P                                                                                             (1)
                      -
9.3     Cu2+ + 2 e         → Cu

         Notes
          Cu2+ + 2e- ← Cu            (0 )                    Cu2+ + 2e- ⇌ Cu    (1 )
                                         2                                          2
               Cu ⇌ Cu2+ + 2e-       (0 )                     Cu2+ + 2e → Cu     ( 2   )
                                        2                                            2
              Ignore if charge on electron is omitted.
              If a charge of an ion is omitted e.g. Cu → Cu2 + 2e-                  Max.: 1
                                                                                            2
                                                                                                      (2)
9.4.1 Q will break down/become eroded/surface becomes rough and eroded
      ACCEPT Q will be oxidised.                                                                    (2)
9.4.2 Cu/electrode Q is a stronger reducing agent than the Cℓ- ions.
      Cu/Q will be oxidised/loses electrons resulting in the electrode becoming eroded
                                             OR
      The Cℓ- ion is a weaker reducing agent than Cu(Q) and will therefore not
      be oxidised.                                                                                    (3)
9.4.3 P                                                                                                (1)
                                                                                                      [10]
QUESTION 10
10.1.1    Haber process                                                                               (1)
10.1.2    nitric oxide NO                                                                            (1)
10.1.3    platinum                                  Notes:                                            (1)
10.1.4    HNO3 + NH3 → (NH4)NO3                         Reactants  Products  Balancing 
                                                        Ignore double arrows.                        (3)
                                                        Marking rule 6.3.10.
10.2
               Mass P = 31/149 x11,95 = 2,486 kg
               2/8 x Z/100 x 20 = 2,486
               Z = 49,72%
                                                                                              (6)
                                                                                TOTAL MARKS: 150

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