# Physical Sciences Grade 12 P2 Mpumalanga November 2014 QP

> Grade 12 Physical Sciences Paper 2 question paper from the Mpumalanga November 2014, 20 pages. Read online or download the free PDF.

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- Updated: 2026-09-27
- Subject: Physical Sciences
- Grade: Grade 12
- Document type: Question paper
- Year: 2014
- Exam period: Mpumalanga November
- Paper: 2
- Curriculum: CAPS
- Pages: 20

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### Page 1

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 NATIONAL SENIOR CERTIFICATE EXAM

             PHYSICAL SCIENCES P2

                SEPTEMBER 2014

                     GRADE 12

                                               MARKS: 150

                                           TIME: 3 HOURS

This paper consists of 17 pages and 4 data sheets

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Physical Science/P2                      2                           September 2014
                                        NSC

INSTRUCTIONS AND INFORMATION

1.   Write your name in the appropriate space on the ANSWER BOOK.

2.   This question paper consists of TEN questions. Answer ALL the questions in the
     ANSWER BOOK.

3.   Start EACH question on a NEW page in the ANSWER BOOK.

4.   Number the answers correctly according to the numbering system used in this
     question paper.

5.   Leave ONE line between two sub questions, for example between QUESTION 2.1
     and QUESTION 2.2.

6.   You may use a non-programmable calculator.

7.   You may use appropriate mathematical instruments.

8.   You are advised to use the attached DATA SHEETS.

9.   Show ALL formulae and substitutions in ALL calculations.

10. Round off your final numerical answers to a minimum of TWO decimal places.

11. Give brief motivations, discussions, et cetera where required.

12. Write neatly and legibly.

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Physical Science/P2                             3                        September 2014
                                               NSC
QUESTION 1 : MULTIPLE-CHOICE QUESTIONS

Four options are provided as possible answers to the following questions. Each question
has only ONE correct answer. Choose the answer and write only the letter (A – D) next
to the question number (1.1 – 1.10) in the ANSWER BOOK, for example 1.11 E.

1.1      Which ONE of the following compounds is an aldehyde?

         A      Butanol

         B      Butanoic acid

         C      Butane

         D      Butanal                                                                     (2)

1.2      Ethene can be converted into other carbon-containing compounds using
         the reactants shown in the following flow chart.
                       HBr                      NaOH
           ethene                 compound X                compound Y

                     reaction 1                reaction 2

         Compounds X and Y are, respectively:

                                  X                         Y

          A               bromoethane                  methanol

          B               bromoethane                   ethanol

          C               bromoethene                ethanoic acid

          D               bromoethene             ethane hydroxide
                                                                                            (2)

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Physical Science/P2                                        4                                 September 2014
                                                          NSC
1.3       A weak acid HA dissociates in aqueous solution as shown below

                              HA(aq)        H+(aq) + A–(aq)                          ΔH = +20 kJ·mol-1

          Which ONE of the following changes will result in an increase in the [H+] of the
          solution?

          A       Addition of a little aqueous sodium hydroxide solution

          B       Raising the temperature of the solution

          C       Dissolving a little of the sodium salt, NaA, in the solution

          D       Adding a catalyst to the solution
                                                                                                                (2)

1.4      Cobalt chloride crystals are dissolved in a water/alcohol mixture to form a blue
         solution as represented by the following equilibrium equation.

         CoCℓ42- (aq)         +       6H2O (ℓ)    ⇌ Co(H2O)62+ (aq)              +    4Cℓ – (aq)    ΔH<0
              (blue)                                            (pink)

         A few drops of concentrated sulphuric acid are added to the above solution.
         What colour change is observed and what is the reason for the colour change?

                       Colour                     Reason
          A            Blue                       H2O molecules are removed
          B            Pink                       Cℓ – ions are removed
          C            Blue                       Cℓ – ions are added
          D            No change                  H2O molecules are added
                                                                                                                (2)

1.5      In which ONE of the following equilibrium reactions is the yield of products
         favoured by increasing the pressure by decreasing the volume of the reaction
         mixture at constant temperature?

         A        2NO(g) + Cℓ2(g) ⇌ 2NOCℓ(g)

         B        CO(g)       +       H2O(g)      ⇌       CO2(g)    +    H2(g)

         C        2SO3(g)         ⇌     2SO2(g)       +     O2(g)

         D        PCℓ5(g)         ⇌     PCℓ3(g)       +    Cℓ2(g)
                                                                                                                (2)

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Physical Science/P2                         5                         September 2014
                                           NSC
1.6      Consider the reversible reaction represented below:

                CH3COOH(aq) + OH-(aq) ⇌ CH3COO-(aq) + H2O(ℓ)

         The correct conjugate acid-base pair is:

         A      CH3COOH and H2O

         B      CH3COOH and OH-

         C      CH3COO- and H2O

         D      CH3COOH and CH3COO-                                                       (2)

1.7      An aqueous solution that contains more hydronium ions than hydroxide ions is
         a(n)
         A      basic solution

         B      acidic solution

         C      neutral solution

         D      standardised solution                                                     (2)

1.8      According to the Brønsted-Lowry theory, a base ……..

         A      dissociates in aqueous solution

         B      raises the hydrogen ion concentration of an aqueous solution above
                1.0 x 10-7 mol.dm-3.

         C      tastes bitter and feels slippery

         D      accepts a proton during a collision with an acid
                                                                                          (2)

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Physical Science/P2                          6                                      September 2014
                                            NSC
1.9      Conductor Y is permanently fixed to an aluminium plate as shown in the
         diagram below. The plate is covered by a piece of filter paper soaked in a
         KNO3 solution. Point X is moveable and can be brought into contact with any
         of the clean metal squares arranged on the filter paper covering the aluminium
         plate.
                                X                                           V

                                    Zn     Mg         Ag     Fe

                                    KNO3 soaked filter paper

                                                                                Y
                                    Aluminium plate

         The voltmeter will give the highest reading when X is in contact with .............?

         A      Zn

         B      Mg

         C      Ag

         D      Fe                                                                                      (2)

1.10     What will happen at the negative electrode of a voltaic (galvanic) cell and at the
         negative electrode of an electrolytic cell ?

                       Voltaic (galvanic) cell                         Electrolytic cell

         A      Oxidation                                  Reduction

         B      Reduction                                  Oxidation

         C      Oxidation                                  Oxidation

         D      Reduction                                  Reduction                                    (2)

                                                                                                       [ 20]

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Physical Science/P2                        7                                                September 2014
                                          NSC
QUESTION 2 : (Start on a new page)

Organic chemistry is the chemistry of organic molecules divided into homologous series
which are identified by the functional groups.

2.1     Define the term homologous series.                                                                     (2)

2.2     Consider the organic molecules listed below.

                                                                H       H       H       H        O
                                                        H       C       C       C       C    C
                     A   hex-2-ene               B
                                                                H       H       H       H        H

                                                                    H       H       O
                     C   CH3CHCℓCHCH2            D          H       C       C       C O H
                                                                    H       H

        2.2.1   Draw the structural formulae of a positional isomer of A.                                      (2)

        2.2.2   Write down the structural formula of the functional group of B and next to
                it write down the name of the homologous series to which B belongs.                            (2)

        2.2.3   Write down the IUPAC name for compound C.                                                      (2)

        2.2.4   Write down the structural formula of ONE functional isomer of compound
                D                                                                                              (2)

                                                                                                               [10]

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Physical Science/P2                         8                                September 2014
                                           NSC

QUESTION 3 : (Start on a new page)

Damien and Luke carried out an investigation to determine the relationship between the
mass of a haloalkane and the boiling point, and obtained the results as shown in the
table below.

         Haloalkane                 Mass (g·mol-1)              Boiling point (K)
       Fluoromethane                      34                         194,7
       Chloromethane                     50,5                        248,9
       Bromomethane                       95                         276,7
        Iodomethane                       142                        315,5

3.1     Write the investigative question for their investigation.                               (2)

3.2     What was their dependent variable?                                                      (1)

3.3     What was their independent variable?                                                    (1)

3.4     What would need to be kept constant during this investigation?                          (1)

3.5     Why the variable, that you have named in 3.4 above, must be kept constant?              (1)

3.6     What trend in boiling points can be observed from the table?                            (2)

3.7     Give an explanation for the observed trend.                                             (3)

                                                                                                [11]

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Physical Science/P2                                9                            September 2014
                                                  NSC
QUESTION 4 : (Start on a new page)

4. 1     Organic reactions are often represented by reaction pathways as represented
         below. The reactions are labelled from I to VI.

                                 IV
            CH3– CH3                   CO2 + H2O

                        I

                                             II                          III
                                 CH2 = CH2              CH3– CH2 –Br            CH3– CH2 –OH
                                             V
                            VI

          – [CH2 –CH2]n –

         You are provided with a list of possible organic reactions that may be
         represented in the above pathway.

                      Addition               Elimination               Substitution
                     Esterification          Polymerisation            Combustion / Oxidation

         4.1.1       Match the process I to VI with the names of the organic reactions
                     provided above.                                                               (6)

         4.1.2       Write down the formula of the other reactant that has to be used in
                     reactions I and IV.                                              (2)

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Physical Science/P2                           10                           September 2014
                                             NSC
4.2      Propyl propanoate is an example of an ester with a chemically tinged pineapple
         flavour. The apparatus below represents the apparatus used in the laboratory to
         produce this ester.

         4.2.1       Write down the name of the type of reaction that takes place in the above
                     experiment.                                                                  (1)

         4.2.2       Explain why it is so important to add sulphuric acid to the reaction
                     mixture.                                                                     (2)

         4.2.3       State the safety precautions built into the design of the experiment when
                     using the above set-up.                                                      (2)

         4.2.4       Use structural formulae, to write down a balanced chemical equation for
                     the reaction taking place in the test tube.                                  (5)

4.3     Polymerisation is the formation of macromolecules by joining together a large
        number of small molecules (monomers).           One such process results in the
        formation of poly-ethene or polythene, first manufactured in 1933.

         4.3.1       Name the monomer of polythene.                                              (1)

         4.3.2       Identify the functional group of the monomer mentioned in 4.3.1 that        (1)
                     makes polymerisation possible.

         4.3.3       Write out and explain a practical method you could use to confirm the
                     presence of the functional group you identified in 4.3.2.                   (2)

         4.3.4       Draw a polymer consisting of three monomers of ethene.                      (2)

         4.3.5       Name the type of polymerisation that took place.                            (1)

                                                                                                 [25]

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Physical Science/P2                                         11                  September 2014
                                                           NSC
QUESTION 5 : (Start on a new page)

The mining of phosphate rock and its conversion to superphosphate is carried out in South
Africa at Phalaborwa, in the Limpopo province, represented by the reaction equation
below:

             Ca3(PO4)2 (s) + 2H2SO4 (aq) → Ca(H2PO4)2 (aq) + 2CaSO4 (s)

5.1      An increase in temperature will increase the rate of the above reaction. List
         any TWO other factors that will increase its rate.                                        (4)

5.2      The figure below shows the Maxwell-Boltzmann distribution curves for the
         above reaction at two different temperatures. The activation energy for
         this reaction is indicated on the graph by the vertical line and labelled as
         EA.

                                                  300 K

                            Number of particles
                                                           400 K

                                                                           EA

                                                          Kinetic energy   EA

         5.2.1       Define the term, activation energy.                                           (2)

         5.2.2 Write down the name of the theory used to explain how reactions occur
               at the molecular level.                                                             (1)

         5.2.3 Referring to the shaded areas in the distribution curves provided, use
               the theory named in QUESTION 5.2.2 to explain why an increase in
               temperature causes an increase in reaction rate.                                    (3)

                                                                                                   [10]

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Physical Science/P2                            12                          September 2014
                                              NSC
QUESTION 6 : (Start on a new page)

6.1     In a research laboratory, a mixture of SO2 gas and O2 gas was placed into a
        closed container at 30°C with a small amount of V2O5. This corresponds to the
        second step of the Contact Process and SO3 is formed. At certain times, various
        changes in the physical conditions applicable to the reaction or to the chemicals
        themselves, were made. A graph of reaction rate versus time was constructed:

         6.1.1       Explain what is meant by the term dynamic equilibrium.                      (2)

         6.1.2       Write down a balanced chemical equation for the reaction represented
                     by:
                                                                                                 (2)
                     (a)   The dotted line.                                                      (2)
                     (b)   The solid line.

         6.1.3       At t = 20 s, there was a change in pressure. State whether this change
                     was an INCREASE or a DECREASE in pressure. Give a reason for the
                     answer.                                                                     (3)

         6.1.4       What other change in reaction conditions occurred at t = 40 s?              (1)

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Physical Science/P2                           13                           September 2014
                                             NSC
6.2     0,5 mole hydrogen gas and 0,5 mole oxygen gas are sealed in a 200 cm3 container
        at temperature of 118 ºC. The following chemical equilibrium is established after a
        certain time.

                              2H2 (g) + O2 (g)  2H2O (g)         ΔH = -484 kJ

        Analysis of the equilibrium mixture shows that the mass of oxygen in the container
        is 9,6 g.

         Calculate the equilibrium constant for the reaction at this temperature.              (7)

                                                                                               [17]

QUESTION 7 : (Start on a new page)

7.1      A certain species of fish cannot survive in a river where the water has a pH of
         less than 5,5. The hydrogen ion concentration of the water in the river was
         measured to be 3,2 x 10-5 mol·dm-3.
         Will this species of fish survive in the river? Support your answer with a relevant
         calculation.                                                                          (4)

7.2      Write down the Brönsted- Lowry definition of an acid.                                 (2)

7.3      The following list of solutions is available in the laboratory:

                                      A   0,1 mol·dm-3 HCℓ
                                      B   0,2 mol·dm-3 NaOH
                                      C   0,5 mol·dm-3 Na2CO3
                                      D   0,5 mol·dm-3 CH3COOH

         From the above list choose …

         7.3.1       a weak base.                                                              (1)

         7.3.2       a strong acid.                                                            (1)

         7.3.3       an acid with the highest concentration.                                   (1)

                                                                                               [9]

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Physical Science/P2                              14                          September 2014
                                                NSC

QUESTION 8 : (Start on a new page)
8.1      Ethanoic acid (CH3COOH) is a monoprotic acid.

         8.1.1       What is meant by the term monoprotic acid?                                     (2)

         8.1.2       When ethanoic acid is mixed with water, ions form. Give the chemical
                     formulae of the ions formed.                                                   (2)

         8.1.3       A solution of CH3COOH of concentration 1 mol·dm-3 conducts electricity
                     but not as readily as a solution of HCℓ of the same concentration. Give a
                     brief explanation for this observation.                                        (2)

8.2      A standard solution of sodium hydroxide is prepared by dissolving exactly 2,5 g
         of NaOH in enough water to form a 500 cm3 solution.

         8.2.1       Calculate the concentration of the solution.                                   (3)

         8.2.2       20 cm3 of this solution of sodium hydroxide is titrated with ethanoic acid.
                     The volume of the acid required for the titration is 24,5 cm3. Calculate
                     the concentration of the acid. The chemical equation is:

                           NaOH + CH3COOH               CH3COONa + H2O                             (3)

         8.2.3       Which is the preferred reactant that should be placed in the burette?
                     Explain the answer.                                                            (2)

         8.2.4       The table below shows some indicators and their pH ranges.

                                    Indicator          pH range
                               bromothymol blue        6,0 - 7,6
                                phenolphthalein        8,3 - 10,0
                                 methyl orange         3,1 - 4,4

                     Select a suitable indicator for this titration and give a reason for the       (2)
                     answer.
                                                                                                   [16]

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Physical Science/P2                         15                            September 2014
                                           NSC
QUESTION 9 : (Start on a new page)

The sketch below represents an electro-chemical cell. A suitable light bulb in the external
circuit is glowing. The direction of electron flow is indicated.

                                                           soaked in NaCℓ solution
9.1      Which ONE of the electrodes (Ni or Ag) is the anode of the cell?                      (1)

9.2      Write down the equation of the reaction taking place in the Ag/Ag+ half-cell.         (2)

9.3      Calculate the initial EMF of the cell.                                                (4)

9.4      What does the cotton wool represent and explain its function.                         (3)

9.5      If 0,4 moles of electrons flow from the anode to the cathode, calculate the
         decrease in mass of the anode.                                                        (4)

                                                                                              [14]
QUESTION 10 : (Start on a new page)

The medal Natasha won for 3nd place in a dancing competition has badly tarnished, and
she wishes to coat it with copper.

10.1     Draw a fully annotated diagram indicating the apparatus and chemicals Natasha
         would use to coat the medal.                                                          (6)

10.2     Write down the reduction half reaction which takes place during the coating
         process.                                                                              (2)
10.3     Is the medal the anode or the cathode of the cell?                                    (1)

                                                                                               [9]

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Physical Science/P2                                         16                             September 2014
                                                           NSC
QUESTION 11 : (Start on a new page)

Nitrogen is a macronutrient which is essential for plant growth and is a vital component
of NPK commercial fertilisers.

11.1     A 50 kg bag of NPK fertiliser is labelled 3:2:5(26). Calculate the mass of
         nitrogen in this bag of fertiliser.                                                                  (3)

11.2     Give 1 advantage for a farmer of using commercial NPK fertilisers rather than
         using organic fertilisers such as compost or manure.                                                 (1)

11.3    These macronutrients are not available to plants in their elemental form and are
        manufactured in the form of soluble compounds. The following flow chart
        outlines the method used to produce ammonium nitrate. It includes the:

          The preparation of ammonia.
          The preparation of nitric acid.
          The reaction of ammonia with nitric acid to produce ammonium nitrate.
             Air

                   Fractional distillation of liquid air
             A                                                         Ammonia (NH3)
                                            C
                                                                  + oxygen (O2)
   Hydrogen (H2)
                                                                 Nitrogen monoxide (NO)
                 Electrolysis
                                                                  + oxygen (O2)                     E

             B                                                    Nitrogen dioxide (NO2)

                                                                   D

                                                                   Nitric acid (HNO3)

                                                                 Ammonium nitrate(NH4NO3)

         Study the above-mentioned flow chart for the manufacturing of ammonium
         nitrate, and write down the NAME of:

         11.3.1 reactant A                                                                                    (1)

         11.3.2 reactant B                                                                                    (1)

         11.3.3 the industrial process C                                                                      (1)

         11.3.4 reactant D                                                                                    (1)

         11.3.5 the industrial process E.                                                                     (1)

                                                                                                              [9]
                                                                                             GRAND TOTAL: 150
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Physical Sciences/P2                                     17                                      September 2014
                                                        NSC

                                   DATA FOR PHYSICAL SCIENCES GRADE 12
                                           PAPER 2 (CHEMISTRY)

                              GEGEWENS VIR FISIESE WETENSKAPPE GRAAD 12
                                         VRAESTEL 2 (CHEMIE)

TABLE 1: PHYSICAL CONSTANTS/TABEL 1: FISIESE KONSTANTES

            NAME/NAAM                          SYMBOL/SIMBOOL                        VALUE/WAARDE
Standard pressure
Standaarddruk
                                                          p                             1,013 x 105 Pa
Molar gas volume at STP
                                                         Vm                              22,4 dm3∙mol-1
Molêre gasvolume by STD
Standard temperature
                                                         T                                  273 K
Standaardtemperatuur
Charge on electron
                                                          e                               -1,6 x 10-19C
Lading op elektron

TABLE 2: FORMULAE/TABEL 2: FORMULES

     m                                                  N
n                                                 n
     M                                                  NA
     n             m                                    V
c     OR / OF c                                  n
     V             MV                                   Vm
caVa na
                                                 pH = -log[H3O+]
cbVb nb

Kw = [H3O+][OH-] = 1 x 10-14 at 298 K

Eθcell  Eθcathode  Eθanode / Eθsel  Ekatode
                                        θ
                                                Eθanode

Eθcell  Ereduction
          θ
                     Eθoxidation / Eθsel  Ereduksie
                                             θ
                                                       Eθoksidasie

                                              θ       θ                 θ
Eθcell  Eoxidising
          θ                 θ
                   agent  Ereducingagent / E sel  E oksideermiddel  Ereduseermiddel

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                                            Physical Sciences/P2                                                  18                                            September 2014
                                                                                                                 NSC
                                                                 TABLE 3: THE PERIODIC TABLE OF ELEMENTS
                                                                TABEL 3: DIE PERIODIEKE TABEL VAN ELEMENTE

       1            2           3           4            5            6           7            8             9           10           11           12         13          14               15       16           17          18
      (I)          (II)                                                                                                                                      (III)       (IV)             (V)      (VI)         (VII)      (VIII)

        1                                                                                                                                                                                                                     2
                                                                                        Atomic number
2,1    H                                          KEY/SLEUTEL                             Atoomgetal                                                                                                                         He
        1                                                                                                                                                                                                                     4
        3             4                                                                                                                                           5            6            7            8            9       10
1,0    Li    1,5    Be                                  Electronegativity
                                                                                              29
                                                                                                             Symbol
                                                                                                                                                          2,0    B     2,5    C     3,0    N     3,5    O     4,0    F       Ne
        7             9                                 Elektronegatiwiteit             1,9
                                                                                               Cu            Simbool                                             11           12           14           16           19       20
        11           12                                                                        63,5                                                              13           14           15           16           17       18
0,9   Na     1,2   Mg                                                                                                                                     1,5   Aℓ     1,8    Si    2,1    P     2,5    S     3,0   Cℓ       Ar
        23           24                                         Approximate relative atomic mass                                                                 27           28           31           32          35,5      40
                                                                Benaderde relatiewe atoommassa
        19           20         21          22            23       24        25        26      27                         28           29           30           31           32           33           34           35       36
0,8    K     1,0    Ca    1,3   Sc    1,5   Ti    1,6    V     1,6   Cr     1,5   Mn    1,8    Fe     1,8   Co     1,8    Ni    1,9   Cu     1,6   Zn     1,6   Ga     1,8   Ge     2,0   As     2,4    Se    2,8   Br       Kr
        39           40         45          48            51          52           55          56            59           59          63,5          65           70           73           75           79           80       84
        37           38         39          40            41          42           43          44            45           46           47           48           49           50           51           52           53       54
0,8   Rb     1,0    Sr    1,2   Y     1,4   Zr          Nb     1,8   Mo     1,9   Tc    2,2   Ru      2,2   Rh     2,2   Pd     1,9   Ag     1,7   Cd     1,7    In    1,8   Sn     1,9   Sb     2,1    Te    2,5     I      Xe
        86           88         89          91            92          96                       101           103          106          108          112          115          119          122          128          127     131
        55           56         57          72            73          74           75           76            77          78            79           80           81           82           83           84           85      86
0,7   Cs     0,9    Ba          La    1,6   Hf           Ta           W           Re           Os            Ir           Pt          Au           Hg     1,8    Tℓ    1,8   Pb     1,9    Bi    2,0   Po     2,5   At      Rn
       133          137         139         179          181          184         186          190           192          195          197          201          204          207          209
        87          88           89
0,7    Fr    0,9    Ra          Ac                      58           59           60          61            62           63           64           65           66           67           68           69           70      71
                    226
                                                    Ce            Pr          Nd          Pm            Sm             Eu         Gd           Tb            Dy          Ho           Er           Tm           Yb         Lu
                                                        140          141      144                           150          152          157          159          163          165          167          169          173     175
                                                        90           91           92          93            94           95           96           97           98           99           100          101          102     103
                                                    Th            Pa              U           Np        Pu             Am         Cm           Bk            Cf          Es           Fm           Md           No         Lr
                                                        232                   238

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                                                                           TABLE 4A: STANDARD REDUCTION POTENTIALS
                                                                           TABEL 4A: STANDAARD REDUKSIEPOTENSIALE
                                                                                  Half-reactions/Halfreaksies E θ (V)
                                                                                        F2(g) + 2e      ⇌   2F             + 2,87
                                                                                          Co3+ + e      ⇌   Co2+            + 1,81
                                                                                   H2O2 + 2H+ +2e       ⇌   2H2O            + 1,77
                                                                                    
                                                                                MnO 4 + 8H+ + 5e        ⇌   Mn2+ + 4H2O     + 1,51
                                                                                       Cℓ2(g) + 2e      ⇌   2Cℓ            + 1,36
                                                                                    2
                                                                               Cr2O 7 + 14H+ + 6e       ⇌   2Cr3+ + 7H2O    + 1,33
                                                                                  O2(g) + 4H+ + 4e      ⇌   2H2O            + 1,23
                                                                                  MnO2 + 4H+ + 2e       ⇌   Mn2+ + 2H2O     + 1,23
                                                                                         Pt2+ + 2e      ⇌   Pt              + 1,20
                                                                                       Br2(ℓ) + 2e      ⇌   2Br            + 1,07
                                                                                     
                                                                                  NO 3 + 4H+ + 3e       ⇌   NO(g) + 2H2O    + 0,96
                                                                                        Hg2+ + 2e       ⇌   Hg(ℓ)           + 0,85

                                                                                                                                       Increasing reducing ability/Toenemende reduserende vermoë
                                                                                          Ag+ + e       ⇌   Ag              + 0,80
                                                                                      
                                                                                   NO 3 + 2H+ + e           NO2(g) + H2O    + 0,80

             Increasing oxidising ability/Toenemende oksiderende vermoë
                                                                                                         ⇌
                                                                                          Fe3+ + e      ⇌   Fe2+            + 0,77
                                                                                  O2(g) + 2H+ + 2e      ⇌   H2O2            + 0,68
                                                                                           I2 + 2e      ⇌   2I             + 0,54
                                                                                           Cu+ + e      ⇌   Cu              + 0,52
                                                                                   SO2 + 4H+ + 4e       ⇌   S + 2H2O        + 0,45
                                                                                   2H2O + O2     + 4e   ⇌   4OH            + 0,40
                                                                                         Cu2+ + 2e      ⇌   Cu              + 0,34
                                                                                    2
                                                                                 SO 4 + 4H+ + 2e        ⇌   SO2(g) + 2H2O   + 0,17
                                                                                          Cu2+ + e      ⇌   Cu+             + 0,16
                                                                                         Sn4+ + 2e      ⇌   Sn2+            + 0,15
                                                                                      S + 2H+ + 2e      ⇌   H2S(g)          + 0,14
                                                                                         2H+ + 2e       ⇌   H2(g)           0,00
                                                                                         Fe3+ + 3e      ⇌   Fe               0,06
                                                                                         Pb2+ + 2e      ⇌   Pb               0,13
                                                                                         Sn2+ + 2e      ⇌   Sn               0,14
                                                                                         Ni2+ + 2e      ⇌   Ni               0,27
                                                                                         Co2+ + 2e      ⇌   Co               0,28
                                                                                         Cd2+ + 2e      ⇌   Cd               0,40
                                                                                          Cr3+ + e      ⇌   Cr2+             0,41
                                                                                         Fe2+ + 2e      ⇌   Fe               0,44
                                                                                         Cr3+ + 3e      ⇌   Cr               0,74
                                                                                         Zn2+ + 2e      ⇌   Zn               0,76
                                                                                        2H2O + 2e       ⇌   H2(g) + 2OH     0,83
                                                                                         Cr2+ + 2e      ⇌   Cr               0,91
                                                                                        Mn2+ + 2e       ⇌   Mn               1,18
                                                                                         Aℓ3+ + 3e      ⇌   Aℓ               1,66
                                                                                        Mg2+ + 2e       ⇌   Mg               2,36
                                                                                           Na+ + e      ⇌   Na               2,71
                                                                                         Ca2+ + 2e      ⇌   Ca               2,87
                                                                                         Sr + 2e
                                                                                            2+       
                                                                                                         ⇌   Sr               2,89
                                                                                         Ba2+ + 2e      ⇌   Ba               2,90
                                                                                           Cs+ + e-      ⇌   Cs              – 2,92
                                                                                            K+ + e      ⇌   K                2,93
                                                                                           Li+ + e      ⇌   Li               3,05

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### Page 20

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                                                                                                     NSC
                                                                       TABLE 4B: STANDARD REDUCTION POTENTIALS
                                                                       TABEL 4B: STANDAARD REDUKSIEPOTENSIALE

                                                                              Half-reactions/Halfreaksies                E θ (V)
                                                                                        Li+ + e     ⇌   Li               3,05
                                                                                         K+ + e     ⇌   K                2,93
                                                                                       Cs+ + e      ⇌   Cs               2,92
                                                                                     Ba2+ + 2e      ⇌   Ba               2,90
                                                                                      Sr2+ + 2e     ⇌   Sr               2,89

         Increasing oxidising ability/Toenemende oksiderende vermoë
                                                                                     Ca2+ + 2e      ⇌   Ca               2,87
                                                                                        Na+ + e         Na               2,71

                                                                                                                                     Increasing reducing ability/Toenemende reduserende vermoë
                                                                                                     ⇌
                                                                                     Mg2+ + 2e      ⇌   Mg               2,36
                                                                                     Aℓ3+ + 3e      ⇌   Aℓ               1,66
                                                                                     Mn2+ + 2e      ⇌   Mn               1,18
                                                                                      Cr2+ + 2e     ⇌   Cr               0,91
                                                                                    2H2O + 2e       ⇌   H2(g) + 2OH     0,83
                                                                                     Zn2+ + 2e      ⇌   Zn               0,76
                                                                                      Cr3+ + 3e     ⇌   Cr               0,74
                                                                                      Fe2+ + 2e     ⇌   Fe               0,44
                                                                                       Cr3+ + e     ⇌   Cr2+             0,41
                                                                                     Cd2+ + 2e      ⇌   Cd               0,40
                                                                                     Co2+ + 2e      ⇌   Co               0,28
                                                                                      Ni2+ + 2e     ⇌   Ni               0,27
                                                                                      Sn2+ + 2e     ⇌   Sn               0,14
                                                                                      Pb2+ + 2e     ⇌   Pb               0,13
                                                                                      Fe3+ + 3e     ⇌   Fe               0,06
                                                                                      2H+ + 2e      ⇌   H2(g)            0,00
                                                                                 S + 2H+ + 2e       ⇌   H2S(g)          + 0,14
                                                                                      Sn4+ + 2e     ⇌   Sn2+            + 0,15
                                                                                       Cu2+ + e     ⇌   Cu+             + 0,16
                                                                               2
                                                                            SO 4 + 4H+ + 2e         ⇌   SO2(g) + 2H2O   + 0,17
                                                                                     Cu2+ + 2e      ⇌   Cu              + 0,34
                                                                              2H2O + O2 + 4e        ⇌   4OH            + 0,40
                                                                              SO2   + 4H+ + 4e      ⇌   S + 2H2O        + 0,45
                                                                                        Cu+ + e     ⇌   Cu              + 0,52
                                                                                        I2   + 2e   ⇌   2I             + 0,54
                                                                             O2(g) + 2H+ + 2e       ⇌   H2O2            + 0,68
                                                                                       Fe3+ + e     ⇌   Fe2+            + 0,77
                                                                                 
                                                                              NO 3 + 2H+ + e        ⇌   NO2(g) + H2O    + 0,80
                                                                                       Ag+ + e      ⇌   Ag              + 0,80
                                                                                     Hg2+ + 2e      ⇌   Hg(ℓ)           + 0,85
                                                                                
                                                                             NO 3 + 4H+ + 3e        ⇌   NO(g) + 2H2O    + 0,96
                                                                                    Br2(ℓ) + 2e     ⇌   2Br            + 1,07
                                                                                      Pt2+ + 2 e    ⇌   Pt              + 1,20
                                                                             MnO2   + 4H+ + 2e      ⇌   Mn2+ + 2H2O     + 1,23
                                                                             O2(g) + 4H+ + 4e       ⇌   2H2O            + 1,23
                                                                               2
                                                                          Cr2O 7 + 14H+ + 6e        ⇌   2Cr3+ + 7H2O    + 1,33
                                                                                    Cℓ2(g) + 2e     ⇌   2Cℓ            + 1,36
                                                                                
                                                                            MnO 4 + 8H+ + 5e        ⇌   Mn2+ + 4H2O     + 1,51
                                                                             H2O2   + 2H+ +2 e      ⇌   2H2O            + 1,77
                                                                                       Co3+ + e     ⇌   Co2+            + 1,81
                                                                                     F2(g) + 2e     ⇌   2F             + 2,87
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