# Physical Sciences Grade 12 P2 North West November 2015 QP

> Grade 12 Physical Sciences Paper 2 question paper from the North West November 2015, 20 pages. Read online or download the free PDF.

- Page: https://www.hlayiso.com/library/nw-2015-sept-chemistry-p2/c296a04a-c823-4fe0-a197-90cd5c1aed43
- Updated: 2026-09-27
- Subject: Physical Sciences
- Grade: Grade 12
- Document type: Question paper
- Year: 2015
- Exam period: North West November
- Paper: 2
- Curriculum: CAPS
- Pages: 20

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Physical Sciences · Grade 12 · North West November · 2015. Question paper, 20 pages. Read online or download the PDF.

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### Page 1

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Education and Sport Development

Department of Education and Sport Development
Departement van Onderwys en Sportontwikkeling
Lefapha la Thuto ie Tihabololo ya Metshameko

NORTH WEST PROVINCE

NATIONAL
SENIOR CERTIFICATE

MARKS: 150

TIME: 3 hours

This question paper consists of 14 pages, 4 data sheets and 1 graph sheet.

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Physical Sciences/P2 2 NW/September 2015

NSC

INSTRUCTIONS AND INFORMATION

1.

2.

10.

11.

12.

Write your name in the appropriate space on your ANSWER BOOK.

This question paper consists of TEN questions. Answer ALL the questions in the
ANSWER BOOK, except for QUESTION 6.3 which should be answered on the
included GRAPH SHEET. Write your name on this sheet in the space provided and
insert it inside the back cover of your ANSWER BOOK.

Start EACH question on a NEW page in the ANSWER BOOK.

Number the answers correctly according to the numbering system used in this
question paper.

Leave ONE line between two subquestions, for example between
QUESTION 2.1 and QUESTION 2.2.

You may use a non-programmable calculator.
You may use appropriate mathematical instruments.
You are advised to use the attached DATA SHEETS.

Show ALL formulae and substitutions in ALL calculations.

Round off your final numerical answers to a minimum of TWO decimal places.

Give brief motivations, discussions, et cetera where required.

Write neatly and legibly.

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Physical Sciences/P2 3 NW/September 2015

NSC

QUESTION 1: MULTIPLE-CHOICE QUESTIONS

Four options are provided as possible answers to the following questions. Each question
has only ONE correct answer. Write only the letter (A-D) next to the question number
(1.1-1.10) in the ANSWER BOOK, for example 1.11 D.

1.1. Consider the organic compounds below:

(i)

CsHs (ii) CsHy2

Which ONE of the following statements does NOT apply to these
compounds? They ...

A

B
Cc
D

both burn in oxygen.

are both unsaturated.

are both alkanes.

are both hydrocarbons. (2)

1.2 TWO isomers of CsHi2 and their respective boiling points are shown below:

an dy

HoH HOH qa 4H
|

H—O—C——_H

Boiling point = 27,8 °C H I

Boiling point = 9,5 °C

Which ONE of the following statements is CORRECT about the structural
formula of compound Q above? it has:

A

B
Cc
D

Less side chains and weaker intermolecular forces
More side chains and weaker intermolecular forces
Less side chains and greater intermolecular forces
More side chains and greater intermolecular forces (2)

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4
NSC
1.3 Activation energy can best be described as the minimum energy required to ...
A make reactant molecules to collide.
cause effective collisions.

B
Cc change the orientation of reactant molecules.
D increase the kinetic energy of reactant molecules. (2)

1.4. Which ONE of the following reaction conditions is suitable for the
dehydrohalogenation of haloalkanes?

A No water should be present

B Presence of the catalyst H2SO,

Cc Strongly heated under reflux with ethanolic KOH/NaOH

D React with aqueous sodium hydroxide or potassium hydroxide (2)

1.5 The table below shows pH ranges of some indicators in acid and basic solutions.

INDICATORS pH RANGES
Methy! orange 3,1-4,4
Methyl red 4,2-6,2
Bromothymol blue 6,0—7,8
Phenolphthalein 8,3 - 10,0

The indicator best suited for the titration of ethanoic acid against a
solution of sodium hydroxide, is ...

A _ methyl orange.

B methyl red.
C _bromothymol blue.
D___ phenolphthalein. (2)

1.6 Which ONE of the following is the correct balanced equation for the
combustion of sulphur (IV) dioxide?
A  2802(g) + 202(g) — 2S0s(g)
B  2S02(g) + 202(g) — SOsa(g)
C S02(g) + 202(g) + 25802(g)
D 280,(g) + O2(g) ~ 250s(9) (2)

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Physical Sciences/P2 5 NW/September 2015
NSC

1.7. Consider the following redox reaction:
H2S(g) + 2FeCls(aq) —>  2FeClo(aq) + S(s) + 2HCl(aq)
The oxidation half-reaction for the above reaction is ...
HS — S+2H*+2e.
Fe*+e — Fe.

S$+2H*+2e -» HS.

50 0O DBD >

Cl + 2e — 2Cr. (2)

1.8  Astrip of magnesium metal is placed in a zinc sulphate (ZnSOxz) solution.

ZnSO, (aq)

The reaction that takes place is represented by the equation below:
Mg(s) + ZnSO.(aq) —> MgSO,(g) + Zn(s)
According to the above reaction ...

A Zn is the oxidising agent.

B Mg is the oxidising agent.

Cc Mg is reduced.

D —_Znis oxidised. (2)

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Physical Sciences/P2

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6 NW/September 2015
NSC

The following reversible reaction reaches equilibrium in a closed container:

Hog) + bg) =  2HI(g) AH <0

Equilibrium was first established after 5 minutes. (The broken line represents
the reverse reaction.)

Rate of reaction

>
Time (minutes)

0 5 10 15 20

What change in the conditions was made at t = 10 minutes to cause the rate
of both the forward and the reverse reactions to increase by the same
amount?

A Temperature was increased

B A catalyst was added

Cc Temperature was decreased

D

Pressure was increased

1.10 Which ONE of the following terms is TRUE about sulphuric acid?

A Dilute acid
B Weak acid
Cc Diprotic acid
D

Triprotic acid

[20]

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7
NSC
QUESTION 2 (Start on a new page.)

Study the following organic compounds, represented by the letters A to F in the table
below:

H O 48 H H A
~“ —~ Propanoic acid H—C— r | OH
H H \ H
A B c
ik I H 0 it OH H
| | | | |
H—C—C— HH) a—c—c— 0—C— Fa 1 r 1 H
H H H H H HA
D E F
2.1 Define the term functional isomers. (2)
2.2 Identify TWO FUNCTIONAL ISOMERS. Only write down the
corresponding LETTERS for the correct answers. (2)
2.3 Compound B and C react in the presence of an organic acid.
2.3.1 Write down the structural formula of the main organic product. (2)
2.3.2 Name the ORGANIC product. (1)

2.4 Compound C undergoes an ELIMINATION reaction in the presence of
concentrated sulphuric acid. Use structural formulae to write down a balanced
equation for the reaction. (3)

2.5 Name the:
2.5.1 Specific type of ELIMINATION reaction taking place in QUESTION 2.4 (1)
2.5.2 Organic PRODUCT formed (1)

2.6 Write down the following:

2.6.1 The IUPAC name of compound A (2)
2.6.2 The homologous series to which compound D belongs (1)
[15]

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Physical Sciences/P2 8 NW/September 2015

NSC

QUESTION 3 (Start on a new page.)

The table shows the data collected for three organic compounds A, B and C, with different
functional groups, during a practical investigation.

COMPOUND MELTING POINTS (°C)
B CHsCH2OH -114
Cc CH3COOH 16,6
3.1. Name the following in this investigation:
3.1.1. The independent variable
3.1.2 The dependent variable
3.1.3 The control variable
3.2 Write down the homologous series to which compound C belongs.
3.3. Write down the general formula for compound A.
3.4 Describe the trend in the melting points from A to C, as shown in the table.
3.5 Explain the trend in QUESTION 3.4 above. Make reference to

INTERMOLECULAR FORCES and ENERGY involved.

QUESTION 4 (Start on a new page.)

41

A sample of the compound 2-bromo-2-methylpropane is dissolved in ethanol
in the presence of diluted potassium hydroxide.

4.1.1. Write down the structural formula of 2-bromo-2-methylpropane.

4.1.2 Using structural formulae only, write a balanced equation for the
reaction in QUESTION 4.1.1.

4.1.3 Indicate TWO reaction conditions for this chemical reaction.

4.1.4 Name the type of reaction that occurs in QUESTION 4.1.2.

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(1)
(1)
(1)

(2)
(2)
(2)

(5)
[14]

(3)
(2)
(2)

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Physical Sciences/P2 9 NW/September 2015
NSC
4.2 Polymers are large molecules consisting of repeating monomer units.

4.3

4.4

4.2.1 What is a condensation polymer?

4.2.2 Write down the structural formula for the monomer from which
polyvinyl chloride is derived.

4.2.3 Give the name of the monomer.
Classify the following as addition or condensation polymers:

4.3.1 Polyester
4.3.2  Polyvinylchloride

State ONE use of polyvinyl chloride.

QUESTION 5 (Start on a new page.)

5.1

5.2

5.3

5.4

Define an acid in terms of the Bronsted-Lowry theory.
Consider the reaction below:
HF + Hs0 # HgO* + F
6.2.1 Identify the reactant which acts as a Bronsted-Lowry base.

5.2.2 Write down the formula of the conjugate acid of the base identified
in QUESTION 5.2.1.

Sulphuric acid (H2SOx) is a strong acid.

5.3.1 Explain why sulphuric acid is considered a strong acid.
5.3.2 Calculate the pH of a 0,025 mol.dm® sulphuric acid solution.
A certain solution X, has a pH of 12,8.

5.4.1. Which of the ions, OH’ or H* is in excess?

5.4.2 Acetic acid (CH3COOH) is added to solution X. Is the pH of the

(2)

(2)
(2)

(1)

(1)

(1)
[18]

(2)

(1)

(1)

(2)
(4)

(1)

solution going to INCREASE, DECREASE or REMAINS THE SAME?

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(1)

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Physical Sciences/P2 10 NW/September 2015
NSC

5.5 A learner accidentally spills 15 em? of 0,4 mol.dm® sulphuric acid

solution in the laboratory. He adds 25 em? of 0,2 mol.dm? of sodium
hydroxide to the spilled sulphuric acid in an attempt to neutralise it.

The equation for the reaction is given below:

H2SO4, + 2NaOQH — NaeSO4 + 2H20

Show by calculations that the addition of the sodium hydroxide

solution will not neutralise the sulphuric acid spill. (6)
[18]

QUESTION 6 (Start on a new page.)

The apparatus below is being used to investigate the effect of a certain factor on the rate of
reaction of calcium carbonate powder and calcium carbonate chunks with a diluted

hydrochloric acid solution.

A known mass of calcium carbonate powder was added to an excess of diluted hydrochloric
acid and the decrease in mass over a certain time interval was recorded. Readings were
taken at 30 second intervals.

The procedure was then repeated, this time using ‘chunks’ of the calcium carbonate.

<+——— Beaker
6
o Hydrochloric acid

CaCO;

Chemical balance

Experiment A: Reaction of calcium carbonate powder and hydrochloric acid

Time (s) 0 | 1,0 | 2,0 | 30 | 4,0 | 5,0 | 6,0 | 7,0
Mass of calcium carbonate
powder (g) 92 | 91,1 | 90,4 | 90,1 | 90 90 | 90 | 90
Decrease in mass (g) 0|09;}16/ 19 | 20 | 2,0 | 2,0 | 2,0

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Physical Sciences/P2 1 NW/September 2015

NSC

Experiment B: Reaction of calcium carbonate chunks and hydrochloric acid

Time (s) 0 | 1,0 | 2,0 | 3,0 | 4,0 | 5,0 | 6,0 | 7,0
Mass of calcium carbonate
chunks (g) 92 | 91,4} 91 | 90,6 | 90,3 | 90,1 | 90 | 90
Decrease in mass (g) 0105 /11,0; 1,4 | 1,7 | 1,9 | 20/20
6.1. Formulate an investigative question for this investigation. (2)
6.2 Write down a balanced chemical equation for the reaction between calcium
carbonate and diluted hydrochloric acid. (3)
6.3 Using the tables above, draw TWO graphs on the GRAPH SHEET comparing
the decrease in mass versus time for each of experiments A and B. Use the
same set of axes and label the graphs A and B respectively. (6)
6.4 Which reaction reaches completion first? (1)
6.5 How does the loss in mass compare after the completion of both
reactions? (1)
6.6 What conclusion can be drawn from this investigation? (2)
[15]
QUESTION 7 (Start on a new page.)

Study the reversible reaction represented by the balanced equation below:

Ho(g) + CO2(g) = H2O(g) + CO(g)

Initially X moles of H2(g) is mixed with 0,3 moles of CO2(g) in a sealed 10 dm?
container. When equilibrium was reached, the concentration of CO was

0,0:

7A
7.2
7.3

2 mol. dm and the equilibrium constant (K.) at that specific temperature was 4.
State Le Chatelier’s principle. (2)
Calculate the initial number of moles X of H2(g) that was in the container. (8)

The reaction is now carried out at a much higher temperature. It is found

that the value of K, decreases at this higher temperature. Is the forward

reaction EXOTHERMIC or ENDOTHERMIC? Explain your answer. (4)
[14]

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Physical Sciences/P2 12 NW/September 2015
NSC

QUESTION 8 (Start on a new page.)

The diagram represents a galvanic cell (A). A small light bulb connected in the external
circuit glows brightly.

Ni — [~~ Ag
Ne) — —As'en
porous plug
8.1. | State TWO conditions under which this cell will be a standard cell. (2)
8.2. Give the equation for the reaction which occurs at the Ag/Ag* half-cell. (2)
8.3. Which electrode is the anode? (1)
8.4. What happens to the emf of the cell as it continues to deliver current? (1)
8.5. Write down the overall reaction for this cell. (3)

8.6 If 0,4 moles of electrons flow to the cathode, what will be the decrease
in mass of the anode? (3)

8.7. ASECOND galvanic cell (B) is constructed using:
Mg(s) in Mg(NOs)2(aq) and Ag(s) in AgNO3(aq)

Without any calculations, determine which of the TWO galvanic cells

(A or B) will result in the highest potential difference. Explain your

answer by referring to the relative strengths of the two reducing agents

as well as the relative strengths of the two oxidising agents involved. (3)
[15]

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Physical Sciences/P2 13 NW/September 2015

NSC

QUESTION 9 (Start on a new page.)

Copper metal can be purified by electrolysis, using the cell shown below.

9.1
9.2
9.3
9.4

9.5

battery
P te}
CuS80,(aq)
Define the term electrolysis. (2)

Which electrode, P or Q, consists of the impure copper? Explain your answer. (3)

Write down the half-cell reaction that takes place at electrode Q. (2)

Explain why the concentration of the copper (II) sulphate solution remains

constant if the only impurities are silver and platinum. (2)

State TWO uses of copper. (2)
[11]

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Physical Sciences/P2 14 NW/September 2015

NSC

QUESTION 10 (Start on a new page.)

Study the diagram below, illustrating the industrial preparation of nitric acid.

NH3 A + H,0 Oz Oz; H20 Cc

Oo. ——

10.1. Write down a balanced equation for the formation of product A. (3)
10.2 Name the catalyst used during the reaction in QUESTION 10.1. (1)
10.3. What NAME is given to the reaction in QUESTION 10.1? (2)
10.4 Give the FORMULA of product C. (1)
10.5 Name the process used to produce product C. (1)
10.6 Fertilisers enable plants to grow better and faster, thus improving food

production. However, deficiency or excess of primary nutrients in plants can
be detrimental to the environment and humans.

State any TWO symptoms of a deficiency of Potassium as a primary nutrient in
plants. (2)
[10]

TOTAL: 150

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Physical Sciences/P2

15
NSC

NW/September 2015

DATA FOR PHYSICAL SCIENCES GRADE 12
PAPER 2 (CHEMISTRY)

GEGEWENS VIR FISIESE WETENSKAPPE GRAAD 12
VRAESTEL 2 (CHEMIE)

TABLE 1: PHYSICAL CONSTANTS/TABEL 1: FISIESE KONSTANTES

NAME/NAAM SYMBOL/SIMBOOL | VALUE/WAARDE

TABLE 2: FORMULAE/TABEL 2: FORMULES

m N

n=— n=—

M Na

n m Vv

-— /of = n=—

c Vv or/o c MV v,
Ca _ Ma =- *
CyVy Ny pH = -log[H30*]

Kw = [HgO*][OH]] = 1 x 10° at/by 298 K

cell ‘oxidising agent reducing agent

reduksie

=a = Eathode - Erode / Fea = Eatode
or/of

a = Feuction ~ Fe vdation / Eee = =
or/of

Ee, =E° — Ee

~ Ee

‘anode

)
~ E ocsidasie

6 _ fe
/ Ee 7 E oksideermiddel

— Ee

reduseermiddel

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Physical Sciences/P2

Increasing oxidising ability/ Toenemende oksiderende vermoé

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NW/September 2015

Increasing reducing ability/Toenemende reduserende vermoé

17
NSC
TABLE 4A: STANDARD REDUCTION POTENTIALS

Half-reactions/Halfreaksies E® (v)
Fpg)+2e = 2F + 2,87
Co*+e = Co* + 1,81
H202 + 2H*+2e = 2H2O +1,77
MnO] +8H*+5e7 = Mn™*+4H,O | +1,51
Ch(g)+2e = 2Cr + 1,36
cro” +14H*4+6e7 = 2Cr*+7H,0 + 1,33
O2(g)+4H*+4e7 = 2H20 + 1,23
MnO2+4H*+2e° = Mn*+2H20 + 1,23
PPt+2e Pt +1,20
Br(f)+2e = 2Br + 1,07
NO, +4H*+3e = NO(g)+2H20 | +0,96
Hg**+2e7 = Hg(2) + 0,85
Agi+e = Ag + 0,80
NO3 +2H*+e" = NO2(g)+H2O + 0,80
Fe*+e° = Fe +0,77
On(g) + 2H*+2e° = H2O2 + 0,68
lbt+2e = 2 + 0,54
Cutt+e° = Cu + 0,52
SO2+4H*+4e7° = S+2H20 + 0,45
2H20+O24+4e = 40H” + 0,40
Cu*+2e = Cu + 0,34
S04 +4H*+2e° = SO2(g)+2H20 | +0,17
Cu*+e = Cut + 0,16
Sn¥+2e° = Sn* +0,15
S+2H*+2e = H2S(g) + 0,14

2H*+2e" = H2(g) 0,00

Fe*+3e = Fe — 0,06
Pb**+2e° = Pb -0,13
Sn**+2e° = Sn ~ 0,14
Ni*+2e = Ni -0,27
Co*+2e° = Co ~ 0,28
Cd*+2e =. Cd ~0,40
Crt+e = Crt ~0,41
Fe+2e = Fe - 0,44
Crt+3e" = Cr ~0,74
Zn**42e = Zn - 0,76
2H20+2e7 = Ha(g) + 20H~ — 0,83
Cret+20 = Cr - 0,91
Mn**+2e = Mn —1,18
Abt+3e = At ~ 1,66
Mg*+2e = Mg ~ 2,36
Nat+e = Na -2,71
Ca*+2e = Ca — 2,87
SP*+2e = Sr - 2,89
Ba’t+2e = Ba - 2,90
Cs'+e = Cs + 2,92
Kr+e7 = K ~ 2,93
lite = Li — 3,05

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Physical Sciences/P2 1 Bo NW/September 2015
N
TABLE 4B: STANDARD REDUCTION POTENTIALS
Half-reactions/Halfreaksies E® (vy)
litte = Li ~ 3,05
KY+e = K ~2,93
Cs*+e@ = Cs - 2,92
Ba*+2e = Ba — 2,90
SP+2e = Sr — 2,89
Ca*+2e = Ca ~ 2,87
Nat+e> = Na 2,71
Mg’*+2e = Mg — 2,36
Aft 430 = AL ~1,66 4
Mn*+2e = Mn ~1,18
‘9 Crt+2e = Cr -0,91
= 2H20+2e = H2(g) +20H™ ~ 0,83
3 Zn*+2e = Zn 0,76 9
> Cr*+3e = Cr ~0,74 &
3 Fe4+2e" = Fe - 0,44 g
g ce+e = Cr ~0,41 g
3 Cd*+2e = Cd — 0,40 2
3 Co%*+2e = Co ~ 0,28 eo
$s Net42e = Ni ~0,27 8
8 Sn*+2e = Sn ~ 0,14 3
5 Pb 42e" 2 Pb -0,13 2
& Fe+3e = Fe ~ 0,06 3
2 2H*+2e = Hig) 0,00 §
8 S+2H'+2e = HAS(g) +0,14 £
Led Sn*+2e = Sn* + 0,15 2
£ Cut+e" = Cut + 0,16 e
s SOF +4H"+2e° = SO2(g)+2H.O| +0,17 >
> Cu%+2e = Cu +0,94 =
‘3 2H20+02+4e = 40H +0,40 o
3 SQ2+4H*+4e° = ~S+2H,0 + 0,45 >
3 Cuv+e = Cu + 0,52 ‘Oo
> b+2e = at +0,54 3
7 O2(g) + 2H*+2e == H2O2 + 0,68 =
$ Fe*+e = Fe* +0,77 >
g NO3 +2H*+e = NOx(g)+H20 | +0,80 9
~y Agit+e = Ag + 0,80 5
Hg*+2e = Hg(t) + 0,85 £
NO; +4H*+3e = NO(g)+2H20 | +0,96
Br(t)+2e° = 2Br + 1,07
Pht+2e = Pt +1,20
MnO2+ 4H? +2e° = Mn®*+2H2O +1,23
O2(g)+4H*+4e = 2H2O + 1,23
cro? +14H*+6e = 2Cr*+7H20 + 1,33
C(g)+2e = 200 + 1,36
MnO, +8H*+5e = Mn**+4H,0 +1,51
H2O2 + 2H*+2e = 2H20 +1,77
Co*+e = Co* +1,81
Fo(g)+2e = 2F + 2,87

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Physical Sciences/P2 19 NW/September 2015
NSC
GRAPH SHEET
NAME:
QUESTION 6.3
4

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