# Physical Sciences Grade 12 P2 Eastern Cape Prelim 2024 QP

> Grade 12 Physical Sciences Paper 2 question paper from the Eastern Cape Prelim Exam 2024 (English), 19 pages. Read online or download the free PDF.

- Page: https://www.hlayiso.com/library/phys-sciences-p2-qp-sept2024-english/2d9cf105-7d25-4a79-95c4-911807c8301a
- Updated: 2026-09-27
- Subject: Physical Sciences
- Grade: Grade 12
- Language: English
- Document type: Question paper
- Year: 2024
- Exam period: Eastern Cape Prelim Exam
- Paper: 2
- Curriculum: CAPS
- Pages: 19

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Physical Sciences · Grade 12 · Eastern Cape Prelim Exam · 2024 · English. Question paper, 19 pages. Read online or download the PDF.

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                            NATIONAL
                       SENIOR CERTIFICATE

                                 GRADE 12

                        SEPTEMBER 2024

                   PHYSICAL SCIENCES P2
                       (CHEMISTRY)

MARKS:   150

TIME:    3 hours

          This question paper consists of 19 pages, including 4 data sheets.

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2                                 PHYSICAL SCIENCES P2                 (EC/SEPTEMBER 2024)

INSTRUCTIONS AND INFORMATION

1.    Write your full NAME and SURNAME in the appropriate spaces on the
      ANSWER BOOK.

2.    This question paper consists of NINE questions. Answer ALL the questions
      in the ANSWER BOOK.

3.    Start EACH question on a NEW page in the ANSWER BOOK.

4.    Number the answers correctly according to the numbering system used in
      this question paper.

5.    Leave ONE line between two subquestions, for example between
      QUESTION 2.1 and QUESTION 2.2.

6.    You may use a non-programmable calculator.

7.    You may use appropriate mathematical instruments.

8.    Show ALL formulae and substitutions in ALL calculations.

9.    Round off your FINAL numerical answers to a minimum of TWO decimal
      places.

10.   Give brief motivations, discussions, et cetera where required.

11.   You are advised to use the attached DATA SHEETS.

12.   Write neatly and legibly.

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(EC/SEPTEMBER 2024)              PHYSICAL SCIENCES P2                                      3

QUESTION 1: MULTIPLE-CHOICE QUESTIONS

Various options are provided as possible answers to the following questions. Choose
the answer and write only the letter (A–D) next to the question numbers (1.1 to 1.10)
in the ANSWER BOOK, for example 1.11 E.

1.1    Which ONE of the following homologous series contains a hydroxyl group that
       is bonded to a saturated carbon atom?

       A     Ketones

       B     Aldehydes

       C     Alcohols

       D     Esters                                                                       (2)

1.2    Consider the compound shown below:

                                        CH3   CH2CH3

                             H   C      C     C    H

                                 O      H     H

       The CORRECT IUPAC name of the above compound is:

       A     3-ethyl-2-methylpropanal

       B     2-methyl-3-ethylpropanal

       C     2-methylpentanal

       D     4-methylpentanal                                                             (2)

1.3    Consider the reaction:

                                     C3H6 + Cℓ2 → C3H6Cℓ2

       The name of the reaction is …

       A     hydration

       B     halogenation

       C     hydrogenation

       D     hydrolysis                                                                   (2)

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4                                                  PHYSICAL SCIENCES P2           (EC/SEPTEMBER 2024)

1.4    Consider the vapour pressure against temperature curves for THREE CHAIN
       ISOMERS under standard atmospheric pressure.
                                         VAPOUR PRESSURE VERSUS TEMPERATURE

                 Vapour pressure (kPa)
                                                         A           B
                                                                         C
                                         101

                                                  T1        T2         T3
                                                       Temperature (K)
       Consider the statements regarding the curves for the THREE CHAIN
       ISOMERS.

       I     Compound A has the shortest chain length.
       II    The boiling point of compound B is T2.
       III   Compound C is at a gaseous phase at T2.

       Which of the above statement(s) is/are true?

       A     I and II only

       B     III only

       C     II and III only

       D     I and III only                                                                        (2)

1.5    Consider the synthesis reaction of ammonia, NH3:

                                                  N2 (g) + 3 H2 (g) ⇌ 2 NH3 (g)

       The rate at which N2 (g) is consumed during the reaction is 𝒙 mol·dm-3·s-1.

       Which ONE of the following is the rate at which ammonia, NH3 (g) is produced
       in mol·dm-3·s-1 with respect to N2 (g)?

       A     𝒙

       B     2𝒙

             𝒙
       C
             2

       D     3𝒙                                                                                    (2)

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(EC/SEPTEMBER 2024)                  PHYSICAL SCIENCES P2                                       5

1.6    Consider the following reaction at equilibrium:

                      CoCℓ42– (aq) + 6 H2O (ℓ) ⇌ Co(H2O)62+ (aq) + 4 Cℓ – (aq)
                        Blue                        Pink

       The solution is currently pink.

       Concentrated hydrochloric acid (HCℓ) is added to the equilibrium mixture.

       Which ONE of the following combinations CORRECTLY describes the effect that
       the addition of concentrated hydrochloric acid (HCℓ) will have on the equilibrium
       constant, Kc and the colour change of the solution?

                                Kc                       COLOUR CHANGE
       A                     No Effect                   Solutions turns pinker
       B                     No Effect                    Solution turns blue
       C                     Increases                    Solution turns blue
       D                    Decreases                    Solution turns pinker
                                                                                                (2)

1.7    Which ONE of the following substances can be classified as a
       Lowry-Brønsted acid?

       A      Na2CO3

       B      KOH

       C      NH4+

       D      NaCℓ                                                                              (2)

1.8    Consider the salt, CH3COONa.

       Which ONE of the following combinations CORRECTLY identifies the
       hydrolysis reaction and the pH of the salt?

                              HYDROLYSIS                              pH
       A      CH3COO– + H2O ⇌ CH3COOH + OH –                    Greater than 7
       B       CH3COO– + H2O ⇌ CH3COOH + OH –                     Less than 7
       C               Na+ + H2O ⇌ NaOH + H2O                   Greater than 7
       D              CH3COO– + Na+ ⇌ CH3COONa                    Equal to 7
                                                                                                (2)

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6                                           PHYSICAL SCIENCES P2                     (EC/SEPTEMBER 2024)

1.9    Consider the cell notation of a galvanic cell below:

                                              Aℓ│Aℓ3+││MnO4– , Mn2+│Pt

       Which ONE of the following reactions occurs at the cathode?

       A       Mn2+ + 4 H2O → MnO4– + 8 H+ + 5 e–

       B       MnO4– + 8 H+ + 5 e– → Mn2+ + 4 H2O

       C       Aℓ → Aℓ3++ 3 e–

       D       Aℓ3++ 3 e– → Aℓ                                                                             (2)

1.10   A spoon is plated with silver (Ag) during the process of electrolysis.

                                       Ag
                                                                           spoon

                                                Ag+ (aq)

       Which ONE of the following graphs BEST represents the concentration of the
       silver ions (Ag+) in the electrolyte over time?

           A                                               B
                     Concentration
                                                               Concentration

                      (mol·dm-3)
                                                                (mol·dm-3)

                                            time                                   time
           C                                               D

                      Concentration
                                                               Concentration

                       (mol·dm-3)
                                                                (mol·dm-3)

                                              time                                 time
                                                                                                        (2)
                                                                                                       [20]

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(EC/SEPTEMBER 2024)                   PHYSICAL SCIENCES P2                               7

QUESTION 2 (Start on a new page.)

Consider the organic compounds A–E below.

      A                                B
            3-methylbutanone                                 C3H7Cℓ

      C                                D
         H  H                                   H           CH3
         │  │                                   │           │
      H —C —C —H                            H — C — C ≡ C — C — H
         │  │                                   │           │
         H  H                                   H           CH2CH3
      E
          H   H  O
          │   │
      H — C — C —C                   — O   — H
          │   │
          H   H

2.1       Define functional group.                                                      (2)

2.2       Write down the LETTER of a compound that:

          2.2.1   Contains a carboxyl group                                             (1)

          2.2.2   Has the general formula CnH2nO                                        (1)

          2.2.3   Has an empirical formula of CH2                                       (1)

2.3       How will the molecular mass of compound E compare to ethyl methanoate?

          Choose from GREATER THAN, SMALLER THAN or EQUAL TO.

          Give a reason for the answer.                                                 (3)

2.4       Write down the:

          2.4.1   STRUCTURAL FORMULA of compound A                                      (2)

          2.4.2   IUPAC name of compound E                                              (2)

          2.4.3   IUPAC name of compound D                                              (3)

2.5       Compound B is a secondary haloalkane.

          Draw the STRUCTURAL FORMULA of compound B.                                    (2)

2.6       Using the MOLECULAR FORMULAE, write down the balanced equation for the
          complete combustion of compound D.                                           (3)
                                                                                      [20]

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8                                                            PHYSICAL SCIENCES P2               (EC/SEPTEMBER 2024)

QUESTION 3 (Start on a new page.)

3.1                       The relationship between boiling point and the number of carbons in STRAIGHT
                          CHAIN PRIMARY ALCOHOLS is investigated. The following curve is obtained:

                              GRAPH OF BOILING POINT VERSUS NUMBER OF C ATOMS
                            500

      Boiling point (K)
                            400

                            300

                            200

                            100

                                   1        2       3      4      5     6            7   8
                                                         Number of carbons
                           3.1.1       Define boiling point.                                                          (2)

                           3.1.2       What is the structural similarity between the alcohols that make this a
                                       fair investigation?                                                            (1)

                           3.1.3       Which van der Waals force is responsible for the trend observed in
                                       this curve?                                                                    (1)

                           3.1.4       Write down the IUPAC name of the alcohol with a boiling point of
                                       approximately 410 K.                                                           (2)

3.2                        Another investigation is carried out to determine the effect of structural
                           differences on the boiling point. The table below shows the different compounds
                           and their respective molar mass that was used in this investigation.

                                                 COMPOUND                  MOLAR MASS
                                                                             (g·mol-1)
                                        A       Butanone                        72
                                        B       Butan-1-ol                      74
                                        C       Propanoic acid                  74

                           3.2.1       Which compound A, B or C will have the highest boiling point?                  (1)

                           3.2.2       Fully explain the answer to QUESTION 3.2.1.                                 (5)
                                                                                                                  [12]

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(EC/SEPTEMBER 2024)                 PHYSICAL SCIENCES P2                                         9

 QUESTION 4 (Start on a new page.)

 4.1    Consider the three organic reactions, I, II and III below:

        I        Pent-1-ene + HCℓ → Organic compound P
                                    (Major product)

        II       Organic compound P + NaOH → secondary alcohol Q + NaCℓ

        III      Organic compound P + NaOH → Organic compound R + NaCℓ + H2O
                                              (Major product)

        4.1.1 Is pent-1-ene SATURATED or UNSATURATED? Give a reason for the
              answer.                                                                            (2)

                 Write down the type of reaction represented by:

        4.1.2 Reaction II                                                                        (1)

        4.1.3 Reaction III                                                                       (1)

                 Write down the:

        4.1.4 STRUCTURAL FORMULA of compound P.                                                  (2)

        4.1.5 IUPAC name of compound Q.                                                          (2)

        4.1.6 Reactions II and III require the use of a strong base.

                 Write down the conditions that will prefer reaction II over reaction III.       (2)

        4.1.7 Pent-1-ene and organic compound R are isomers.

                 What type of isomer is pent-1-ene and organic compound R?

                 Choose from FUNCTIONAL, POSITIONAL or CHAIN.                                    (2)

 4.2    The flow diagram below shows the conversion of butan-1-ol to butane gas.

                               Step 1                             Step 2
                  Butan-1-ol            Organic compound X                   Butane

        The following chemicals are needed:

              Concentrated H2SO4                 Pt                         H2

        Using CONDENSED STRUCTURAL FORMULAE, write down the balanced
        equation and indicate the chemicals used in each step in the preparation of
        butane gas from butan-1-ol.                                                             (6)
                                                                                               [18]

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10                                  PHYSICAL SCIENCES P2                 (EC/SEPTEMBER 2024)

QUESTION 5 (Start on a new page.)

The reaction between EXCESS hydrochloric acid (HCℓ) with zinc (Zn) is used to
investigate factors that influences the reaction rate. The balanced equation for this
reaction is:

                   Zn (s) + 2 HCℓ (aq) → ZnCℓ2 (aq) + H2 (g)    ΔH < 0

Three experiments are carried out and one factor is changed in each experiment.
The same volume of hydrochloric acid and the same mass of zinc granules are used
in each experiment. The hydrochloric acid completely covers the zinc in each
experiment.

      The table below shows the reaction conditions.

       EXPERIMENT            CONCENTRATION OF HCℓ          Cu (s) PRESENT
                                  (mol·dm-3)
               1                     0,5                        No
               2                     0,8                        No
               3                     0,5                        Yes

5.1   Define reaction rate.                                                                    (2)

5.2   Write down an investigative question when comparing experiments 1 and 2.                 (2)

5.3   The curve, not drawn to scale, is obtained for the volume of hydrogen gas, H2
      (g) produced over time for experiment 1.

                        VOLUME OF HYDROGEN GAS VERSUS TIME

                        t1     t2    t3            time

      5.3.1     How does the rate at which hydrogen gas is produced between t1–t2
                compare to that at t2–t3?

                Write down only HIGHER THAN, LOWER THAN or EQUAL TO.                           (1)

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(EC/SEPTEMBER 2024)              PHYSICAL SCIENCES P2                                     11

      5.3.2     Redraw the graph in the ANSWER BOOK. Clearly label the curve as
                A.
                On the same set of axes, sketch the curve that will be obtained for
                experiment 3. Label this curve as B.                                       (2)

5.4   The reaction in experiment 1 takes 58 s to reach completion and the average
      reaction rate at which hydrogen gas, H2 is produced is 8,39 cm3·s-1.

      Calculate the initial mass of zinc used in each experiment.

      The molar volume for hydrogen gas (H2) at 25 °C is 24 000 cm3·mol-1.

      Experiment 4 is now conducted by increasing the temperature of the reaction
      mixture in experiment 1.                                                             (5)

5.5   How will this change affect the reaction rate?

      Choose from INCREASES, DECREASES or REMAINS THE SAME.                                (1)

5.6   Explain the answer to QUESTION 5.5 by referring to the collision theory.             (3)
                                                                                          [16]

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12                                 PHYSICAL SCIENCES P2                      (EC/SEPTEMBER 2024)

QUESTION 6 (Start on a new page.)

6.1     Consider the following hypothetical reaction at equilibrium:

                                         A (g) ⇌ 2 B (g)

        The data in the table below shows the equilibrium concentrations of A (g) and
        B (g) at different temperatures:

            Temperature (°C)              A (mol·dm-3)                 B (mol·dm-3)
                     200                      0,0125                      0,843
                     300                       0,171                      0,764

        6.1.1   State Le Chaterlier’s principle.                                                (2)

        6.1.2   Is the FORWARD or REVERSE reaction favoured at 200 °C?

                Give a reason for the answer.                                                   (2)

        How will the equilibrium concentration of A at 200 °C be affected by the
        following:

        Choose from INCREASES, DECREASES or NO EFFECT

        6.1.3   The pressure is increased.                                                      (1)

        6.1.4   Addition of a suitable catalyst.                                                (1)

        6.1.5   Is the forward reaction EXOTHERMIC or ENDOTHERMIC?                              (1)

        6.1.6   Use Le Chatelier’s principle and refer to the data in the table to explain
                the answer to QUESTION 6.1.5.                                                   (3)

6.2     Initially 1,05 moles of Bromine (Br2) are sealed in an empty container. The
        following reaction occurs at 1 600 °C.

                                        Br2 (g) ⇌ 2 Br (g)

        At equilibrium the concentration of Bromine (Br2) is 2,074 mol·dm-3. The
        equilibrium constant, Kc is 6,34 x 10-4 at 1 600 °C.

        Calculate the volume of the container.                                                 (7)
                                                                                              [17]

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(EC/SEPTEMBER 2024)                PHYSICAL SCIENCES P2                                     13

 QUESTION 7 (Start on a new page.)

 7.1    Sulphuric acid, H2SO4 is a strong acid that ionises in two steps as
        represented by the equations below:

         Step 1:             H2SO4 (aq) + H2O (ℓ) ⇌ HSO4 – (aq) + H3O+ (aq)

         Step 2:             HSO4 – (aq) + H2O (ℓ) ⇌ SO42 – (aq) + H3O+ (aq)

        7.1.1 Explain what is meant by strong acid.                                          (2)

        7.1.2 Give a reason why sulphuric acid is referred to as a diprotic acid.            (1)

        7.1.3 Write down the conjugate base of H3O+.                                         (1)

        7.1.4 Write down the FORMULA of the substance that acts as an ampholyte
              during the ionisation of sulphuric acid.                                       (2)

                Sulphuric acid has a concentration of 0,1 mol·dm-3.

        7.1.5 Calculate the pH value after complete ionisation.                              (4)

 7.2    1,2 g of anhydrous oxalic acid (H2C2O4) is dissolved in water to make a 50 cm3
        solution.

        7.2.1 Calculate the concentration of the oxalic acid, H2C2O4.                        (3)

        Learners dissolve x g of sodium hydroxide, NaOH to make a 2 dm3 solution of
        sodium hydroxide, NaOH (aq). They transfer 25 cm3 of the sodium hydroxide,
        NaOH solution to a volumetric flask and added distilled water to make a diluted
        100 cm3 solution.

                                                                        Distilled water

                                                 2 dm3                          100 cm3

       x g NaOH              2 dm3 NaOH                   25 cm3 NaOH

        They titrate 43,8 cm3 of the diluted sodium hydroxide, NaOH solution against
        25 cm3 oxalic acid, H2C2O4 prepared in QUESTION 7.2.1 to reach the endpoint.
        The balanced equation is:

                      H2C2O4 (aq) + 2 NaOH (aq) → Na2C2O4 (aq) + 2 H2O (ℓ)

        7.2.2 Calculate the mass, x g of sodium hydroxide that was used to make the
              2 dm3 solution.                                                               (7)
                                                                                           [20]

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14                                   PHYSICAL SCIENCES P2                (EC/SEPTEMBER 2024)

 QUESTION 8 (Start on a new page.)

 A standard electrochemical cell is set up as shown below.

                                                  V

            Pb                                                          Pt
                                                  Y

                         Pb2+ (aq)                    Fe2+, Fe3+ (aq)

 8.1    State the energy conversion that takes place in this cell.                             (2)

 8.2    Component Y ensures that the cell is complete.

        State ONE other function of component Y.                                               (1)

 8.3    Write down the reduction half reaction.                                                (2)

 8.4    Calculate the initial emf of this cell.                                                (4)

 8.5    How will the reading on the voltmeter be affected, if the:

        Choose from INCREASES, DECREASES or REMAINS THE SAME

        8.5.1 Initial concentration of Pb2+ is increased.                                      (1)

        8.5.2 Surface area of the Pt electrode is increased.                                   (1)

        8.5.3 The Pb│Pb2+ half-cell is replaced with Zn│Zn2+.                                  (1)

 8.6    Explain the answer to QUESTION 8.5.3 by referring to the relative strength of
        the reducing agents.                                                               (2)
                                                                                          [14]

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(EC/SEPTEMBER 2024)                PHYSICAL SCIENCES P2                                          15

 QUESTION 9 (Start on a new page.)

 A few drops of phenolphthalein are added to concentrated sodium chloride (NaCℓ)
 solution. The solution remains colourless. Carbon electrodes P and Q that are
 connected to a battery is dipped into the solution as shown below.

                     P                                                    Q

                                         NaCℓ (aq)

 9.1    Define electrolysis.                                                                      (2)

 9.2    Write down the name of the component that shows that the above cell is an
        electrolytic cell.                                                                        (1)

 9.3    Write down the NAME or FORMULA of the gas produced at electrode Q.                        (1)

 9.4    Write down the half reaction that occurs on electrode P.                                  (2)

 9.5    Phenolphthalein is COLOURLESS in an acidic solution and PINK in an
        alkaline solution.

        Write down the colour of the solution around electrode Q and formula of the
        substance responsible for the colour.                                                     (2)

 9.6    An electrolytic cell is set-up for the purification of copper (Cu) ore that contains
        zinc (Zn) and platinum (Pt) impurities. After the purification of the impure
        copper was completed, 1,38 x 10-2 mol of electrons were transferred. The
        initial mass of the cathode is 2 g.

        9.6.1   Which metal, besides copper, will be oxidised?

                Choose from zinc or platinum.                                                     (1)

        9.6.2   Calculate the mass of the cathode after the purification.                        (4)
                                                                                                [13]

                                                                                  TOTAL:         150

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16                                           PHYSICAL SCIENCES P2                              (EC/SEPTEMBER 2024)

                                     NATIONAL SENIOR CERTIFICATE
                                    NASIONALE SENIOR SERTIFIKAAT

                             DATA FOR PHYSICAL SCIENCES GRADE 12
                                     PAPER 2 (CHEMISTRY)

                        GEGEWENS VIR FISIESE WETENSKAPPE GRAAD 12
                                   VRAESTEL 2 (CHEMIE)

           TABLE 1: PHYSICAL CONSTANTS/TABEL 1: FISIESE KONSTANTES

      NAAM/NAME                                 SIMBOOL/SYMBOL               WAARDE/VALUE
      Standard pressure
                                                p                           1,013 × 105 Pa
      Standaarddruk
      Molar gas volume at STP
                                                Vm                           22,4 dm3∙mol-1
      Molêre gasvolume teen STD
      Standard temperature
                                                Tθ                           273 K
      Standaardtemperatuur
      Charge on electron
                                                e                            -1,6 × 10-19 C
      Lading op elektron
      Avogadro’s constant
                                                NA                           6,02 × 1023 mol-1
      Avogadro se konstante

TABLE 2: FORMULAE/TABEL 2: FORMULES

          m                           n                    m
     n = M or/of                 c = V or/of c = MV              pH= -log[H3O+]

          N                      ca Va   na                      Kw = [H3O+][OH-] = 1x10-14 at /by 298K
     n= N       or/of                  =
            A                    cb Vb nb
          V
     n= V
           m

     Eθcell = Eθcathode–Eθanode / Eθsel = Eθkatode–Eθanode

     Eθcell = Eθreduction–Eθoxidation / Eθsel = Eθreduksie–Eθoksidasie

     Eθcell = Eθoxidising agent–Eθreducing agent / Eθsel = Eθoksideermiddel–Eθreduseermiddel

                             Q                        Q
     q =IΔt             n=                or/of n =
                             e                        qe

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  (EC/SEPTEMBER 2024)                                                                            PHYSICAL SCIENCES P2                                                        17

TABLE 3: THE PERIODIC TABLE OF ELEMENTS/TABEL 3: DIE PERIODIEKE TABEL VAN ELEMENTE
1           2           3         4         5         6 7               8            9         10      11        12      13       14      15      16      17        18
(I)         (II)                                                          Atoomgetal                                     (III)    (IV)    (V)     (VI)    (VII)     (VIII)
                                             KEY/ SLEUTEL               Atomic number
      1                                                                                                                                                               2
      H                                                                                                                                                               He
2,1
      1                                                                             29                                                                                4
                                                  Elektronegatiwiteit                           Simbool
      3           4
                                                   Electronegativity          1,9   Cu          Symbol
                                                                                                                            5       6       7       8        9        10
      Li          Be                                                                63,5                                    B       C       N       O        F        Ne
1,0         1,5                                                                                                          2,0      2,5     3,0     3,5     4,0
      7           9                                                                                                         11      12      14      16       19       20
      11          12                                                                                                        13      14      15      16       17       18
      Na          Mg                                             Benaderde relatiewe atoommassa                             Aℓ      Si      P       S        Cℓ       Ar
0,9         1,2                                                  Approximate relative atomic mass                        1,5      1,8     2,1     2,5     3,0
      23          24                                                                                                        27      28      31      32       35,5     40
      19          20        21        22        23        24      25        26           27      28       29       30       31      32      33      34       35       36
      K           Ca        Sc        Ti        V         Cr      Mn        Fe           Co      Ni       Cu       Zn       Ga      Ge      As      Se       Br       Kr
0,8         1,0         1,3       1,5       1,6       1,6       1,5     1,8          1,8       1,8     1,9       1,6     1,6      1,8     2,0     2,4     2,8
      39          40        45        48        51        52      55        56           59      59       63,5     65       70      73      75      79       80       84
      37          38        39        40        41        42      43        44           45      46       47       48       49      50      51      52       53       54
      Rb          Sr        Y         Zr        Nb        Mo      Tc        Ru           Rh      Pd       Ag       Cd       In      Sn      Sb      Te       I        Xe
0,8         1,0         1,2       1,4                 1,8       1,9     2,2          2,2       2,2     1,9       1,7     1,7      1,8     1,9     2,1     2,5
      86          88        89        91        92        96                101          103     106      108      112      115     119     122     128      127      131
      55          56        57        72        73        74      75        76           77      78       79       80       81      82      83      84       85       86
      Cs          Ba        La        Hf        Ta        W       Re        Os           Ir      Pt       Au       Hg       Tℓ      Pb      Bi      Po       At       Rn
0,7   133   0,9   137       139   1,6 179       181       184     186       190          192     195      197      201   1,8204   1,8
                                                                                                                                    207   1,9
                                                                                                                                            209   2,0     2,5
      87          88        89
      Fr          Ra        Ac
0,7         0,9   226                        58        59        60      61              62     63      64        65      66       67      68      69      70        71
                                             Ce        Pr        Nd      Pm              Sm     Eu      Gd        Tb      Dy       Ho      Er      Tm      Yb        Lu
                                             140       141       144                     150    152     157       159     163      165     167     169     173       175
                                            90        91        92      93           94        95      96        97      98       99      100     101     102       103
                                            Th        Pa        U       Np           Pu        Am      Cm        Bk      Cf       Es      Fm      Md      No        Lr
                                            232                 238

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18                                                                                                     PHYSICAL SCIENCES P2                         (EC/SEPTEMBER 2024)

                                                                                  TABLE 4A: STANDARD REDUCTION POTENTIALS
                                                                                  TABEL 4A: STANDAARD REDUKSIEPOTENSIALE
                                                                                               Half-reactions/Halfreaksies                E θ (V)
                                                                        F2(g) + 2e−                               ⇌   2F−                 + 2,87
                                                                        Co   3+
                                                                                  +e       −                      ⇌   Co    2+
                                                                                                                                          + 1,81
                                                                        H2O2 + 2H+ +2e−                           ⇌   2H2O                +1,77
                                                                             −
                                                                        MnO 4 + 8H+ + 5e−                         ⇌   Mn2+ + 4H2O         + 1,51

                                                                        Cℓ2(g) + 2e−                              ⇌   2Cℓ−                + 1,36
                                                                             2−
                                                                        Cr2O 7 + 14H+ + 6e−                       ⇌   2Cr   3+
                                                                                                                                 + 7H2O   + 1,33

                                                                        O2(g) + 4H+ + 4e−                         ⇌   2H2O                + 1,23
                                                                        MnO2 + 4H + 2e             +       −      ⇌   Mn    2+
                                                                                                                                 + 2H2O   + 1,23
                                                                        Pt2+ + 2e−                                ⇌   Pt                  + 1,20
                                                                        Br2(ℓ) + 2e−                              ⇌   2Br−                + 1,07
                                                                           −
                                                                                                                  ⇌   NO(g) + 2H2O        + 0,96

                                                                                                                                                             Increasing reducing ability/Toenemende reduserende vermoë
                                                                        NO 3 + 4H+ + 3e−

         Increasing oxidising ability/Toenemende oksiderende vermoë
                                                                        Hg2+ + 2e−                                ⇌   Hg(ℓ)               + 0,85
                                                                        Ag+ + e−                                  ⇌   Ag                  + 0,80
                                                                           −
                                                                        NO 3 + 2H+ + e−                           ⇌   NO2(g) + H2O        + 0,80

                                                                        Fe3+ + e−                                 ⇌   Fe2+                + 0,77
                                                                        O2(g) + 2H + 2e            +       −      ⇌   H2O2                + 0,68
                                                                        I2 + 2e−                                  ⇌   2I−                 + 0,54
                                                                             +
                                                                        Cu + e         −                          ⇌   Cu                  + 0,52
                                                                        SO2 + 4H+ + 4e−                           ⇌   S + 2H2O            + 0,45
                                                                        2H2O + O2 + 4e−                           ⇌   4OH−                + 0,40
                                                                        Cu2+ + 2e−                                ⇌   Cu                  + 0,34
                                                                           2−
                                                                        SO 4 + 4H+ + 2e−                          ⇌   SO2(g) + 2H2O       + 0,17

                                                                        Cu2+ + e−                                 ⇌   Cu    +
                                                                                                                                          + 0,16
                                                                        Sn4+ + 2e−                                ⇌   Sn2+                + 0,15
                                                                        S + 2H + 2e +                  −          ⇌   H2S(g)              + 0,14
                                                                        2H+ + 2e−                                 ⇌   H2(g)               0,00
                                                                        Fe3+ + 3e−                                ⇌   Fe                  − 0,06
                                                                        Pb2+ + 2e−                                ⇌   Pb                  − 0,13
                                                                        Sn   2+
                                                                                  + 2e         −                  ⇌   Sn                  − 0,14
                                                                        Ni2+ + 2e−                                ⇌   Ni                  − 0,27
                                                                        Co2+ + 2e−                                ⇌   Co                  − 0,28
                                                                        Cd   2+
                                                                                  + 2e         −                  ⇌   Cd                  − 0,40
                                                                        Cr3+ + e−                                 ⇌   Cr2+                − 0,41
                                                                        Fe2+ + 2e−                                ⇌   Fe                  − 0,44
                                                                        Cr3+ + 3e−                                ⇌   Cr                  − 0,74
                                                                        Zn   2+
                                                                                  + 2e         −                  ⇌   Zn                  − 0,76
                                                                        2H2O + 2e−                                ⇌   H2(g) + 2OH−        − 0,83
                                                                        Cr2+ + 2e−                                ⇌   Cr                  − 0,91
                                                                        Mn2+ + 2e−                                ⇌   Mn                  − 1,18
                                                                        Aℓ   3+
                                                                                  + 3e     −                      ⇌   Aℓ                  − 1,66
                                                                        Mg2+ + 2e−                                ⇌   Mg                  − 2,36
                                                                        Na+ + e−                                  ⇌   Na                  − 2,71
                                                                        Ca2+ + 2e−                                ⇌   Ca                  − 2,87
                                                                             2+
                                                                        Sr + 2e            −                      ⇌   Sr                  − 2,89
                                                                        Ba2+ + 2e−                                ⇌   Ba                  − 2,90
                                                                        Cs+ + e-                                  ⇌   Cs                  - 2,92
                                                                        K+ + e−                                   ⇌   K                   − 2,93
                                                                         +
                                                                        Li + e     −                              ⇌   Li                  − 3,05

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(EC/SEPTEMBER 2024)                                                                               PHYSICAL SCIENCES P2                                                                              19

                                                                             TABLE 4B: STANDARD REDUCTION POTENTIALS
                                                                             TABEL 4B: STANDAARD REDUKSIEPOTENSIALE
                                                                           Half-reactions/Halfreaksies                        E θ (V)
                                                                           Li+ + e−                       ⇌   Li              − 3,05
                                                                           K+ + e−                        ⇌   K               − 2,93
                                                                           Cs+ + e−                       ⇌   Cs              − 2,92
                                                                           Ba2+ + 2e−                     ⇌   Ba              − 2,90
                                                                           Sr2+ + 2e−                     ⇌   Sr              − 2,89
                                                                           Ca2+ + 2e−                     ⇌   Ca              − 2,87
                                                                           Na+ + e−                       ⇌   Na              − 2,71
                                                                           Mg2+ + 2e−                     ⇌   Mg              − 2,36
                                                                             3+
                                                                           Aℓ + 3e        −               ⇌   Aℓ              − 1,66
                                                                            Mn2+ + 2e−                    ⇌   Mn              − 1,18
                                                                           Cr2+ + 2e−                     ⇌                   − 0,91

                                                                                                                                        Increasing reducing ability/Toenemende reduserende vermoë
                                                                                                              Cr
                                                                           2H2O + 2e−                     ⇌   H2(g) + 2OH−    − 0,83

            Increasing oxidising ability/Toenemende oksiderende vermoë
                                                                           Zn2+ + 2e−                     ⇌   Zn              − 0,76
                                                                           Cr3+ + 3e−                     ⇌   Cr              − 0,74
                                                                           Fe2+ + 2e−                     ⇌   Fe              − 0,44
                                                                           Cr3+ + e−                      ⇌   Cr2+            − 0,41
                                                                           Cd2+ + 2e−                     ⇌   Cd              − 0,40
                                                                           Co2+ + 2e−                     ⇌   Co              − 0,28
                                                                           Ni2+ + 2e−                     ⇌   Ni              − 0,27
                                                                              2+
                                                                           Sn + 2e        −               ⇌   Sn              − 0,14
                                                                           Pb2+ + 2e−                     ⇌   Pb              − 0,13
                                                                           Fe3+ + 3e−                     ⇌   Fe              − 0,06
                                                                           2H+ + 2e−                      ⇌   H2(g)           0,00
                                                                           S + 2H+ + 2e−                  ⇌   H2S(g)          + 0,14
                                                                           Sn4+ + 2e−                     ⇌   Sn2+            + 0,15
                                                                           Cu2+ + e−                      ⇌   Cu+             + 0,16
                                                                              2−
                                                                           SO 4 + 4H+ + 2e−               ⇌   SO2(g) + 2H2O   + 0,17

                                                                           Cu2+ + 2e−                     ⇌   Cu              + 0,34
                                                                           2H2O + O2 + 4e−                ⇌   4OH−            + 0,40
                                                                           SO2 + 4H+ + 4e−                ⇌   S + 2H2O        + 0,45
                                                                           Cu+ + e−                       ⇌   Cu              + 0,52
                                                                           I2 + 2e−                       ⇌   2I−             + 0,54
                                                                           O2(g) + 2H + 2e    +   −       ⇌   H2O2            + 0,68
                                                                           Fe3+ + e−                      ⇌   Fe2+            + 0,77
                                                                               −
                                                                           NO 3 + 2H+ + e−                ⇌   NO2(g) + H2O    + 0,80
                                                                              +
                                                                           Ag + e     −                   ⇌   Ag              + 0,80
                                                                           Hg2+ + 2e−                     ⇌   Hg(ℓ)           + 0,85
                                                                              −
                                                                           NO 3 + 4H+ + 3e−               ⇌   NO(g) + 2H2O    + 0,96

                                                                           Br2(ℓ) + 2e        −
                                                                                                          ⇌   2Br   −
                                                                                                                              + 1,07
                                                                           Pt2+ + 2 e−                    ⇌   Pt              + 1,20
                                                                           MnO2 + 4H+ + 2e−               ⇌   Mn2+ + 2H2O     + 1,23
                                                                           O2(g) + 4H+ + 4e−              ⇌   2H2O            + 1,23
                                                                                2−
                                                                           Cr2O 7 + 14H+ + 6e−            ⇌   2Cr3+ + 7H2O    + 1,33

                                                                           Cℓ2(g) + 2e−                   ⇌   2Cℓ−            + 1,36
                                                                                −
                                                                           MnO 4 + 8H+ + 5e−              ⇌         2+
                                                                                                              Mn + 4H2O       + 1,51

                                                                           H2O2 + 2H +2 e     +   −       ⇌   2H2O            +1,77
                                                                           Co3+ + e−                      ⇌   Co2+            + 1,81
                                                                           F2(g) + 2e−                    ⇌   2F−             + 2,87

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