# Physical Sciences Grade 12 P2 Eastern Cape June 2023 QP

> Grade 12 Physical Sciences Paper 2 question paper from the Eastern Cape June Exam 2023 (English), 21 pages. Read online or download the free PDF.

- Page: https://www.hlayiso.com/library/physc-sc-p2-gr12-qp-june-2023-english/239c2bb1-97ec-41cc-b926-778741de98c8
- Updated: 2026-09-27
- Subject: Physical Sciences
- Grade: Grade 12
- Language: English
- Document type: Question paper
- Year: 2023
- Exam period: Eastern Cape June Exam
- Paper: 2
- Curriculum: CAPS
- Pages: 21

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Physical Sciences · Grade 12 · Eastern Cape June Exam · 2023 · English. Question paper, 21 pages. Read online or download the PDF.

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                             NATIONAL
                        SENIOR CERTIFICATE

                                  GRADE 12

                                 JUNE 2023

         PHYSICAL SCIENCES: (CHEMISTRY) P2

MARKS:   150

TIME:    3 hours

         This question paper consists of 21 pages, including 4 data sheets.

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2                                  PHYSICAL SCIENCES P2                       (EC/JUNE 2023)

INSTRUCTIONS AND INFORMATION

1.     Write your name and surname in the appropriate space on the ANSWER
       BOOK.

2.     This question paper consists of SEVEN questions. Answer ALL the questions
       in the ANSWER BOOK.

3.     Start EACH question on a NEW page in the ANSWER BOOK.

4.     Number the answers correctly according to the numbering system used in this
       question paper.

5.     Leave ONE line between two sub-questions, for example between
       QUESTION 2.1 and QUESTION 2.2.

6.     You may use a non-programmable calculator.

7.     You may use appropriate mathematical instruments.

8.     You are advised to use the attached DATA SHEETS.

9.     Show ALL formulae and substitutions in ALL calculations.

10.    Round off your FINAL numerical answers to a minimum of TWO decimal
       places.

11.    Give brief motivations, discussions, et cetera where required.

12.    Write neatly and legibly.

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(EC/JUNE 2023)                                  PHYSICAL SCIENCES P2                       3

QUESTION 1: MULTIPLE-CHOICE QUESTIONS

Various options are provided as possible answers to the following questions. Choose
the answer and write only the correct letter (A–D) next to the question numbers
(1.1–1.10) in the ANSWER BOOK, for example 1.11 E.

1.1      Which ONE of the following homologous series has members that are
         SATURATED hydrocarbons?

         A       Alcohols

         B       Alkenes

         C       Alkanes

         D       Alkynes                                                                   (2)

1.2      When an ALKENE is converted to an ALKANE, the catalyst that is used is …

         A       Ni or Fe.

         B       Pt or Ni.

         C       H2SO4 or Ni.

         D       H2SO4 or Pt.                                                              (2)

1.3      The boiling point versus chain length graph below was obtained for straight
         chain molecules of aldehydes, alkanes, alcohols and carboxylic acids.

         The curve for EACH homologous series is labelled as A, B, C or D.

                                                           A
                                                               B

                 Boiling point (K)
                                                                   C

                                                                       D

                                            Chain length

         Which ONE of the curves above represents alcohols?

         A       Curve A

         B       Curve B

         C       Curve C

         D       Curve D                                                                  (2)
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4                                PHYSICAL SCIENCES P2                          (EC/JUNE 2023)

1.4     Consider the organic reaction below:

                                CH2CH2 + X              Alcohol

        Which ONE of the following is CORRECT about reactant X and the reaction
        condition?

                       X is …                     Reaction condition
        A       H2O                     Concentrated H2SO4 in excess

        B       H2O                     Small quantity of concentrated H2SO4

        C       dilute KOH              Mild heat

        D       concentrated KOH        Strong heat                                     (2)

1.5     Consider the reaction between an EXCESS hydrochloric acid (HCℓ) solution
        and magnesium powder:

                       Mg (s) + 2 HCℓ (aq)          MgCl2 (aq) + H2 (g)

        Which ONE of the following factors when INCREASED will cause an
        increase in both the REACTION RATE and the TOTAL VOLUME of H 2
        produced?

        A       Mass of Mg

        B       Volume of HCℓ

        C       Concentration of HCℓ

        D       Temperature of the reaction mixture                                     (2)

1.6     Which ONE of the following will affect BOTH the equilibrium position of a
        reversible reaction, and its Kc value?

        A       Mass

        B       Pressure

        C       Temperature

        D       Concentration                                                           (2)

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(EC/JUNE 2023)                                 PHYSICAL SCIENCES P2                         5

1.7       The graph below shows how the reaction rate changes with time for the
          reaction represented by the balanced equation below:

                              2 HI(g)          ⇌ H2(g) +   I2(g)   ΔH > 0

                               Reaction Rate

                                                     t1
                                                           Time (s)

          Consider the following changes made to the equilibrium mixture.

          I      More HI is added

          II     Temperature is increased

          III    Pressure is increased by decreasing the volume at constant
                 temperature

          Which ONE of the following changes will cause the change at t1?

          A      I only

          B      II only

          C      I and III

          D      III only                                                                  (2)

1.8       A substance that loses protons in some reactions and gains protons in other
          reactions is called a/an …

          A      base.

          B      acid.

          C      ampholyte.

          D      acid-base indicator.                                                      (2)

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6                               PHYSICAL SCIENCES P2                               (EC/JUNE 2023)

1.9     Four titrations are carried out using the pairs of substances shown below.

        For which pair of substances when titrated will phenolphthalein be the most
        suitable indicator?

        A       HNO3 and NaOH

        B       CH3COOH and NaOH

        C       Na2CO3 and HCℓ

        D       H2SO4 and NaOH                                                             (2)

1.10    The following equilibrium exists in pure water at 25 °C.

                           2 H2O(ℓ)    ⇌    H3O+(aq) + OH-(aq)

        How will the addition of NaOH to the pure water affect the concentration of
        the hydronium ion [ H3O+] and pH of water at constant temperature?

                               [ H3O+]                             pH of water
        A                    Increases                              Decreases

        B                    Decreases                              Increases

        C                    Increases                              Increases

        D                    Decreases                             Decreases               (2)
                                                                                          [20]

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(EC/JUNE 2023)                               PHYSICAL SCIENCES P2                             7

QUESTION 2 (Start on a new page.)

Consider the organic compounds A to F given in the table below.

      A           C5H12                 B       CH3                   CH2CH3

                                                CH2CH2        C       C   CH3

                                                              CH3

      C           Propan-1-ol           D       Methanal

      E           CH3CH(OH)CH3           F      CH3CH2CH2COOH

      G           Propanone             H       H     C   C       H

2.1       Write down the LETTER that represents the following compounds:

          2.1.1      An alkyne                                                                (1)

          2.1.2      An aldehyde                                                              (1)

          2.1.3      That has the general formula CnH2n+2                                     (1)

          2.1.4      That has a solution with pH < 7                                          (1)

          2.1.5      That has the same general formula as an ester                            (1)

2.2       Compounds C and E are structural isomers.

          2.2.1      Define the term structural isomer.                                       (2)

          2.2.2      What TYPE of structural isomers are compounds C and E?

                     Choose from CHAIN, POSITIONAL or FUNCTIONAL.                             (1)

          2.2.3      Is compound E a PRIMARY, SECONDARY or TERTIARY
                     ALCOHOL?

                     Give a reason for your answer.                                           (3)

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8                               PHYSICAL SCIENCES P2                       (EC/JUNE 2023)

2.3     Write down the:

        2.3.1    IUPAC name of compound B                                             (3)

        2.3.2    CONDENSED STRUCTURAL formula of a FUNCTIONAL isomer of
                 compound G                                                           (2)

2.4     For compound F write down the:

        2.4.1    Empirical formula                                                    (1)

        2.4.2    Name of its functional group                                         (1)

2.5     Compound F reacts with methanol in the presence of concentrated sulphuric
        acid to produce organic product X.

        For compound X write down the:

        2.5.1    Name of the homologous series to which it belongs                    (1)

        2.5.2    IUPAC name and STRUCTURAL formula                                    (4)
                                                                                     [23]

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(EC/JUNE 2023)                           PHYSICAL SCIENCES P2                                9

QUESTION 3 (Start on a new page.)

The table below shows a number of organic compounds and their respective melting
points.

Study the table below and answer the questions that follow.

                                 Compound            Melting point
                                                          (°C)
                      A        Propane                    -187

                      B        Butane                     -138

                      C        Pentane                    -129

                      D        2-methyl butane                X

                      E        Butanal                    -96,8

                      F        Butan-1-ol                 -89,8

3.1    Define the term melting point.                                                        (2)

3.2    Explain the trend in melting points from compound A to C.                             (3)

3.3    Which compound (A, B or C) will have the highest vapour pressure at a given
       temperature?

       Give a reason for the answer by referring to the data in the table above.             (2)

3.4    Consider compounds C and D. The melting point of compound D is indicated
       by X.

       3.4.1     Draw the structural formula of compound D.                                  (2)

       3.4.2     How does the value of X compare to the melting point of compound C?

                 Choose from GREATER THAN -129 °C or LESS THAN -129 °C.                      (1)

       3.4.3     Is the comparison between compounds C and D a fair comparison?

                 Write only YES or NO.

                 Give a reason for your answer.                                              (2)

3.5    Explain the difference in the melting points of compounds E and F by referring
       to intermolecular forces present and energy.                                          (4)
                                                                                            [16]

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10                               PHYSICAL SCIENCES P2                             (EC/JUNE 2023)

QUESTION 4 (Start on a new page.)

4.1     Consider the flow diagram showing organic reactions given below.

                                            Reaction 1
                         CH3CH(Br)CH3                            C3H8O
                                             hydrolysis
                     A                                       A
                           C4                                          C4Reaction 2

                                                Br2              ALKENE
                            Compound Q
                                                Reaction 3

        Consider REACTION 1.                                            C4
                        C4
        Write down:

        4.1.1    The name of the homologous series to which the compound C3H8O
                 belongs                                                                    (1)

        4.1.2    ONE reaction condition                                                     (1)

        4.1.3    The formula of the inorganic reactant                                      (1)

        Consider REACTION 2.

        4.1.4    Name the type of elimination reaction taking place.                        (1)

        4.1.5    Using structural formulae for the organic compounds, write down a
                 balanced equation for the reaction.                                       (6)

        Consider REACTIONS 3 and 4.

        Write down the:

        4.1.6    Name given to these types of reactions                                     (1)

        4.1.7    Formula of the inorganic reactant used in REACTION 4                       (1)

        4.1.8    IUPAC name and structural formula of compound Q                            (4)

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(EC/JUNE 2023)                         PHYSICAL SCIENCES P2                           11

4.2      Consider the incomplete equations for reactions I and II.

          I                 C15H32            ALKANE P + 2 Q + CxH6

          II                  CH3CH2Br + KOH            Q    + KBr + Z

         In reaction I, the compound C15H32 undergoes cracking. Q is an organic
         compound while compound Z is an inorganic compound.

         The compounds Q and CxH6 have the same FUNCTIONAL GROUP.

         4.2.1   Define cracking.                                                     (2)

         4.2.2   Write down a balanced equation for the complete combustion of
                 ALKANE P. (Show ALL workings.)                                       (6)
                                                                                    [24]

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12                                  PHYSICAL SCIENCES P2                             (EC/JUNE 2023)

QUESTION 5 (Start on a new page.)

A group of learners use the reaction between sodium thiosulphate (Na 2S2O3) and
EXCESS hydrochloric acid (HCℓ) to investigate one of the factors that affect reaction
rate. The balanced equation for the reaction is:

          Na2S2O3 (aq) + 2 HCℓ (aq)          2 NaCℓ (aq) + S (s) + H2O (ℓ) + SO2 (g)

The learners carry out five experiments under the same conditions changing only the
factor that is investigated in EACH experiment using the experimental set-up shown
below.

                                                             Na2S2O3 solution with HCℓ

                                                                White paper

They recorded the time taken for the cross to become invisible, when viewed from the
top.

The learners’ results are shown in the graph below.

                     GRAPH OF 1/TIME VERSUS INITIAL CONCENTRATION OF Na2S2O3

                    0,06

     1/time (s-1)
                    0,04

                    0,02

                                   0,05           0,1           0,15          0,20
                                      Initial Concentration of Na2S2O3
                                                (mol·dm-3)
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(EC/JUNE 2023)                            PHYSICAL SCIENCES P2                                 13

5.1      Define reaction rate.                                                                 (2)

5.2      Write down an investigative question for the above investigation.                     (2)

5.3      Name the substance responsible for the disappearance of the cross.                    (1)

5.4      Give a reason why the same cross must be used in ALL the experiments.                 (1)

5.5      Use the collision theory to explain the effect of concentration on reaction rate.     (3)

5.6      In one of the experiments 50 cm3 of Na2S2O3 is used and it takes 20 seconds
         for the cross to become invisible.

         Calculate the total mass of sulphur, S, formed in this experiment.                    (6)

5.7      The graph below represents Maxwell-Boltzmann distribution curve for SO2(g)
         at 30 °C.

                      Q

                                                Kinetic energy

         Q is a label on the vertical axis.

         5.7.1   What does Q in the graph represent?                                           (1)

         Redraw the graph in the ANSWER BOOK. Clearly label the curve as A.

         5.7.2   On the same set of axes, sketch the curve that will be obtained for
                 SO2(g) at 40 °C.

                 Label this curve as B.                                                       (2)
                                                                                             [18]

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14                                  PHYSICAL SCIENCES P2                              (EC/JUNE 2023)

QUESTION 6 (Start on a new page.)

The following reaction reaches equilibrium at a temperature of 200 °C.

                          PCℓ 5(g) ⇌ PCℓ 3(g) + Cℓ2 (g)       ∆H > 0

6.1     State Le Chatelier’s principle.                                                         (2)

6.2     Two conditions must be met for a chemical reaction to establish equilibrium.
        One of the conditions is represented by the double arrow “⇌”.

        State the other condition.                                                              (1)

6.3     The reaction is initiated by heating 83,4 grams PCℓ5(g) in a sealed 2 dm3
        container. At equilibrium it is found that the initial concentration of PCℓ 5 has
        changed by x mol·dm-3.

        6.3.1        Show that the equilibrium constant is, Kc = x2/ 0,2 – x.                   (6)

        6.3.2        The concentration of PCℓ5 at equilibrium is found to be
                     0,001 mol·dm-3.

                     Show by calculation that the value of Kc is equal to 39,601 at 200 °C.     (2)

        6.3.3        Is there a LOW or HIGH YIELD at 200 °C?

                     Give a reason for your answer.                                             (2)

6.4     What effect will the addition of a suitable catalyst have on the following:

        Choose from DECREASES, INCREASES or NO EFFECT.

        6.4.1        Percentage decomposition of PCℓ5 (g)?                                      (1)

        6.4.2        Time taken to reach equilibrium?                                           (1)

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(EC/JUNE 2023)                                            PHYSICAL SCIENCES P2                15

6.5      The graph below shows changes of concentration of reagents PCℓ5 and Cℓ2
         against time.

                                         PCℓ5

           Concentration   (mol·dm-3)
                                          Cℓ2

                                           0
                                                t1   t2          t3    t4
                                                              Time (min)

         6.5.1 What does the horizontal section of the graph between 0–t1 represent?          (1)

         At time t2 the temperature of the equilibrium mixture is changed.

         6.5.2 Was the container COOLED or HEATED at time t2?                                 (1)

         6.5.3 Use Le Chatelier’s principle to fully explain the answer to
               QUESTION 6.5.2.                                                               (3)
                                                                                            [20]

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16                                 PHYSICAL SCIENCES P2                              (EC/JUNE 2023)

QUESTION 7 (Start on a new page.)

7.1     An investigation is carried out to compare the strengths of TWO acids
        CH3COOH(aq) and H2CO3(aq).

        To determine the strength of EACH acid electrical conductivity of the acid is
        measured at 25 °C using the experimental set-up shown below.

        The concentration of the acids is the same.

                                           A

                                                                       Carbon electrodes

                               Acid

        7.1.1        Define an acid according to the Arrhenius theory.                        (2)

        7.1.2        State ONE property of the carbon electrodes that make them
                     suitable for this investigation.                                         (1)

                     The ammeter readings taken for each acid are given in the table
                     below.

                         FORMULA OF ACID                   AMMETER READING
                                                                (mA)

                              CH3COOH                                  500

                                 H2CO3                                 133

        7.1.3        Which ACID (CH3COOH or H2CO3) is stronger?

                     Explain the answer.                                                      (3)

        H2CO3 undergoes ionisation in a TWO step process as shown below:

                         I       H2CO3 +       H2O   ⇌     HCO3̄   + H3O+

                        II        HCO3̄ +      H2O ⇌      X        +     H3O+

        Write down the formula of the substance(s) that:

        7.1.4        Are bases in reaction I                                                  (2)

        7.1.5        Is represented by X in reaction II                                       (1)

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(EC/JUNE 2023)                             PHYSICAL SCIENCES P2                               17

7.2      Ammonium chloride (NH4Cℓ) undergoes hydrolysis.

         7.2.1     Define hydrolysis.                                                         (2)

         7.2.2     Is a solution of ammonium chloride ACIDIC, ALKALINE or
                   NEUTRAL?

                   Explain the answer with the aid of a balanced equation.                    (4)

7.3      A school laboratory has a hydrochloric acid (HCℓ) solution of concentration
         1 mol·dm-3.

         7.3.1     Calculate the pH of the HCℓ solution.                                      (3)

         250 cm3 of the HCℓ solution is used to dissolve an eggshell.

         7.3.2     Calculate the number of moles of HCℓ in 250 cm3 of solution                (3)

         The eggshell contains 99,3% calcium carbonate (CaCO3) by mass. The
         calcium carbonate (CaCO3) in the eggshell reacts with EXCESS HCℓ
         according to the balanced equation below:

                 CaCO3 (s) + 2 HCℓ (aq)            CaCℓ2 (aq) + H2O (ℓ) + CO2 (g)

         The unreacted HCℓ is neutralised by 103 cm3 of a solution of sodium
         hydroxide (NaOH) of concentration 0,5 mol·dm-3 according to the balanced
         equation:

                      NaOH (aq) +       HCℓ (aq)        NaCℓ (aq) + H2O (ℓ)

         7.3.3     Calculate the mass of the eggshell.                                       (8)
                                                                                            [29]

                                                                              TOTAL:         150

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18                               PHYSICAL SCIENCES P2                          (EC/JUNE 2023)

                              NATIONAL SENIOR CERTIFICATE
                             NASIONALE SENIOR SERTIFIKAAT

                         DATA FOR PHYSICAL SCIENCES GRADE 12
                                  PAPER 2 (CHEMISTRY)

                         GEGEWENS VIR FISIESE WETENSKAPPE GRAAD 12
                                 VRAESTEL 2 (CHEMIE)

 TABLE 1: PHYSICAL CONSTANTS/TABEL 1: FISIESE KONSTANTES

              NAME/NAAM                 SYMBOL/SIMBOOL         VALUE/WAARDE
     Standard pressure
     Standaarddruk                              p               1,013 x 105 Pa

     Molar gas volume at STP
     Molêre gasvolume teen STD                  Vm               22,4 dm3∙mol-1

     Standard temperature
     Standaardtemperatuur                       Tθ                     273 K

     Charge on electron
     Lading op elektron                             e             -1,6 x 10-19 C

     Avogadro’s constant
                                                NA              6,02 x 1023 mol-1
     Avogadro se konstante

 TABLE 2: FORMULAE/TABEL 2: FORMULES
         m                         n            m
     n= M       or/of           c = V or/of c = MV       pH= -log[H3O+]

         N                             ca Va   na        Kw = [H3O+][OH-] = 1x10-14
     n= N       or/of                        =
          A
                                       cb Vb nb          at/by 298 K
         V
     n= V
            o

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(EC/JUNE 2023)                                                                     PHYSICAL SCIENCES P2                                                                                                    19
TABLE 3: THE PERIODIC TABLE OF ELEMENTS/TABEL 3: DIE PERIODIEKE TABEL VAN ELEMENTE

   1               2           3           4         5             6           7           8             9     10         11         12       13          14         15           16         17          18
  (I)             (II)                                                                 Atoomgetal                                            (III)       (IV)        (V)         (VI)       (VII)       (VIII)
                                               KEY/ SLEUTEL
        1                                                                           Atomic number                                                                                                          2
2,1    H                                                                                                                                                                                                  He
        1                                                                                        29                                                                                                        4
        3            4                                   Elektronegatiwiteit                                  Simbool                              5          6           7           8           9        10
1,0    Li   1,5    Be                                                                      1,9                                             2,0    B    2,5    C    3,0    N    3,5    O    4,0    F       Ne
                                                         Electronegativity
                                                                                                 Cu           Symbol
        7            9                                                                                                                            11          12          14         16           19       20
       11           12                                                                           63,5                                             13          14          15         16           17       18
0,9   Na    1,2    Mg                                                                                                                      1,5   Aℓ    1,8    Si   2,1    P    2,5    S    3,0    Cℓ       Ar
                                                                               Benaderde relatiewe atoommassa
       23           24                                                                                                                            27          28          31         32          35,5      40
       19           20          21      22            23            24      25     26 relative
                                                                           Approximate     27 atomic
                                                                                                 28 mass29                            30          31          32          33         34           35       36
0,8    K    1,0    Ca    1,3   Sc    1,5Ti     1,6    V      1,6    Cr   1,5Mn     Fe1,8  Co     Ni1,8  Cu   1,8    1,9        1,6   Zn    1,6   Ga    1,8   Ge    2,0   As    2,4   Se    2,8    Br       Kr
       39           40          45      48            51            52      55     56      59    59    63,5                           65          70          73          75         79           80       84
       37           38          39      40            41            42      43     44      45    46     47                            48          49          50          51         52           53       54
0,8   Rb    1,0     Sr   1,2    Y    1,4Zr           Nb      1,8   Mo    1,9Tc     Ru2,2  Rh     Pd2,2  Ag   2,2    1,9        1,7   Cd    1,7    In   1,8   Sn    1,9   Sb    2,1   Te    2,5     I      Xe
       86           88          89      91            92            96             101 103 106         108                           112         115         119         122         128         127      131
       55           56          57      72            73            74      75     76      77    78     79                            80          81          82          83         84           85       86
0,7   Cs    0,9    Ba          La    1,6Hf           Ta             W       Re     Os       Ir   Pt     Au                           Hg    1,8    Tℓ   1,8   Pb    1,9    Bi   2,0   Po    2,5    At      Rn
      133          137         139     179           181           184     186     190 192 195         197                           201         204         207         209
       87           88          89
0,7    Fr   0,9    Ra          Ac
                   226                           58             59         60          61              62      63       64       65           66          67          68         69           70         71
                                                Ce              Pr        Nd           Pm             Sm      Eu       Gd        Tb          Dy          Ho           Er         Tm          Yb         Lu
                                                140            141        144                         150     152      157       159         163         165         167         169         173        175
                                                 90             91         92          93              94      95       96       97           98          99         100         101         102        103
                                                Th             Pa          U           Np             Pu      Am       Cm        Bk           Cf         Es          Fm          Md          No          Lr
                                                232                       238

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20                                                                                                             PHYSICAL SCIENCES P2                                                                                    (EC/JUNE 2023)

                                                                            TABLE 4A: STANDARD REDUCTION POTENTIALS
                                                                            TABEL 4A: STANDAARD REDUKSIEPOTENSIALE
                                                                                      Half-reactions/Halfreaksies                                E θ (V)
                                                                            F2(g) + 2e−                           ⇌   2F−                        + 2,87
                                                                            Co   3+
                                                                                      +e   −                      ⇌   Co2+                       + 1,81
                                                                            H2O2 + 2H+ +2e−                       ⇌   2H2O                       +1,77
                                                                                 −
                                                                            MnO 4 + 8H+ + 5e−                     ⇌   Mn2+ + 4H2O                + 1,51

                                                                            Cℓ2(g) + 2e−                          ⇌   2Cℓ       −                + 1,36
                                                                                 2−
                                                                            Cr2O 7 + 14H+ + 6e−                   ⇌   2Cr       3+
                                                                                                                                        + 7H2O   + 1,33

                                                                            O2(g) + 4H+ + 4e−                     ⇌   2H2O                       + 1,23
                                                                            MnO2 + 4H + 2e         +       −      ⇌   Mn       2+
                                                                                                                                     + 2H2O      + 1,23
                                                                            Pt2+ + 2e−                            ⇌   Pt                         + 1,20
                                                                            Br2(ℓ) + 2e−                          ⇌   2Br−                       + 1,07
                                                                               −
                                                                            NO 3 + 4H+ + 3e−                      ⇌

                                                                                                                                                           Increasing reducing ability/Toenemende reduserende vermoë
                                                                                                                      NO(g) + 2H2O               + 0,96

             Increasing oxidising ability/Toenemende oksiderende vermoë
                                                                            Hg2+ + 2e−                            ⇌   Hg(ℓ)                      + 0,85
                                                                            Ag+ + e−                              ⇌   Ag                         + 0,80
                                                                               −
                                                                            NO 3 + 2H+ + e−                       ⇌   NO2(g) + H2O               + 0,80
                                                                            Fe3+ + e−                             ⇌   Fe   2+
                                                                                                                                                 + 0,77
                                                                            O2(g) + 2H + 2e        +       −      ⇌   H2O2                       + 0,68
                                                                            I2 + 2e    −                          ⇌   2I   −
                                                                                                                                                 + 0,54
                                                                            Cu+ + e−                              ⇌   Cu                         + 0,52
                                                                            SO2 + 4H+ + 4e−                       ⇌   S + 2H2O                   + 0,45
                                                                            2H2O + O2 + 4e             −          ⇌   4OH           −            + 0,40
                                                                            Cu2+ + 2e−                            ⇌   Cu                         + 0,34
                                                                               2−
                                                                            SO 4 + 4H+ + 2e−                      ⇌   SO2(g) + 2H2O              + 0,17

                                                                            Cu2+ + e−                             ⇌   Cu+                        + 0,16
                                                                            Sn   4+
                                                                                      + 2e     −                  ⇌   Sn       2+
                                                                                                                                                 + 0,15
                                                                            S + 2H+ + 2e−                         ⇌   H2S(g)                     + 0,14
                                                                            2H+ + 2e−                             ⇌   H2(g)                      0,00
                                                                            Fe3+ + 3e−                            ⇌   Fe                         − 0,06
                                                                            Pb   2+
                                                                                      + 2e     −                  ⇌   Pb                         − 0,13
                                                                            Sn2+ + 2e−                            ⇌   Sn                         − 0,14
                                                                            Ni2+ + 2e−                            ⇌   Ni                         − 0,27
                                                                            Co   2+
                                                                                      + 2e     −                  ⇌   Co                         − 0,28
                                                                            Cd2+ + 2e−                            ⇌   Cd                         − 0,40
                                                                            Cr3+ + e−                             ⇌   Cr2+                       − 0,41
                                                                            Fe2+ + 2e−                            ⇌   Fe                         − 0,44
                                                                            Cr   3+
                                                                                      + 3e   −                    ⇌   Cr                         − 0,74
                                                                            Zn2+ + 2e−                            ⇌   Zn                         − 0,76
                                                                            2H2O + 2e−                            ⇌   H2(g) + 2OH−               − 0,83
                                                                            Cr2+ + 2e−                            ⇌   Cr                         − 0,91
                                                                            Mn   2+
                                                                                      + 2e     −                  ⇌   Mn                         − 1,18
                                                                            Aℓ3+ + 3e−                            ⇌   Aℓ                         − 1,66
                                                                            Mg2+ + 2e−                            ⇌   Mg                         − 2,36
                                                                            Na+ + e−                              ⇌   Na                         − 2,71
                                                                            Ca   2+
                                                                                      + 2e     −                  ⇌   Ca                         − 2,87
                                                                            Sr2+ + 2e−                            ⇌   Sr                         − 2,89
                                                                            Ba2+ + 2e−                            ⇌   Ba                         − 2,90
                                                                            Cs+ + e-                              ⇌   Cs                         - 2,92
                                                                             +
                                                                            K +e       −                          ⇌   K                          − 2,93
                                                                            Li+ + e−                              ⇌   Li                         − 3,05

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### Page 21

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(EC/JUNE 2023)                                                                                                     PHYSICAL SCIENCES P2                                                                          21

                                                                                 TABLE 4B: STANDARD REDUCTION POTENTIALS
                                                                                 TABEL 4B: STANDAARD REDUKSIEPOTENSIALE
                                                                                        Half-reactions/Halfreaksies                       E θ (V)
                                                                                Li+ + e−                             ⇌   Li              − 3,05
                                                                                K+ + e−                              ⇌   K               − 2,93
                                                                                Cs+ + e−                             ⇌   Cs              − 2,92
                                                                                Ba2+ + 2e−                           ⇌   Ba              − 2,90
                                                                                Sr2+ + 2e−                           ⇌   Sr              − 2,89
                                                                                Ca2+ + 2e−                           ⇌   Ca              − 2,87
                                                                                   +
                                                                                Na + e     −                         ⇌   Na              − 2,71
                                                                                Mg2+ + 2e−                           ⇌   Mg              − 2,36
                                                                                Aℓ3+ + 3e−                           ⇌   Aℓ              − 1,66
                                                                                Mn2+ + 2e−                           ⇌   Mn              − 1,18
                                                                                                                     ⇌

                                                                                                                                                     Increasing reducing ability/Toenemende reduserende vermoë
                                                                                Cr2+ + 2e−                               Cr              − 0,91
                                                                                2H2O + 2e−                           ⇌   H2(g) + 2OH−    − 0,83

                 Increasing oxidising ability/Toenemende oksiderende vermoë
                                                                                Zn2+ + 2e−                           ⇌   Zn              − 0,76
                                                                                Cr3+ + 3e−                           ⇌   Cr              − 0,74
                                                                                  2+
                                                                                Fe + 2e            −                 ⇌   Fe              − 0,44
                                                                                Cr3+ + e−                            ⇌   Cr2+            − 0,41
                                                                                Cd2+ + 2e−                           ⇌   Cd              − 0,40
                                                                                Co2+ + 2e−                           ⇌   Co              − 0,28
                                                                                Ni2+ + 2e−                           ⇌   Ni              − 0,27
                                                                                   2+
                                                                                Sn + 2e            −
                                                                                                                     ⇌   Sn              − 0,14
                                                                                Pb2+ + 2e−                           ⇌   Pb              − 0,13
                                                                                Fe3+ + 3e−                           ⇌   Fe              − 0,06
                                                                                2H+ + 2e−                            ⇌   H2(g)           0,00
                                                                                S + 2H+ + 2e−                        ⇌   H2S(g)          + 0,14
                                                                                   4+
                                                                                Sn + 2e            −
                                                                                                                     ⇌   Sn    2+
                                                                                                                                         + 0,15
                                                                                Cu2+ + e−                            ⇌   Cu+             + 0,16
                                                                                   2−
                                                                                SO 4 + 4H+ + 2e−                     ⇌   SO2(g) + 2H2O   + 0,17

                                                                                Cu2+ + 2e−                           ⇌   Cu              + 0,34
                                                                                2H2O + O2 + 4e−                      ⇌   4OH−            + 0,40
                                                                                SO2 + 4H + 4e      +       −         ⇌   S + 2H2O        + 0,45
                                                                                Cu+ + e−                             ⇌   Cu              + 0,52
                                                                                I2 + 2e−                             ⇌   2I−             + 0,54
                                                                                O2(g) + 2H+ + 2e−                    ⇌   H2O2            + 0,68
                                                                                Fe3+ + e−                            ⇌   Fe2+            + 0,77
                                                                                   −
                                                                                NO 3 + 2H+ + e−                      ⇌   NO2(g) + H2O    + 0,80
                                                                                   +
                                                                                Ag + e     −                         ⇌   Ag              + 0,80
                                                                                Hg2+ + 2e−                           ⇌   Hg(ℓ)           + 0,85
                                                                                   −
                                                                                NO 3 + 4H+ + 3e−                     ⇌   NO(g) + 2H2O    + 0,96

                                                                                Br2(ℓ) + 2e            −             ⇌   2Br   −
                                                                                                                                         + 1,07
                                                                                Pt2+ + 2 e−                          ⇌   Pt              + 1,20
                                                                                MnO2 + 4H + 2e         +       −     ⇌   Mn2+ + 2H2O     + 1,23
                                                                                O2(g) + 4H + 4e        +       −     ⇌   2H2O            + 1,23
                                                                                     2−
                                                                                Cr2O 7 + 14H+ + 6e−                  ⇌          3+
                                                                                                                         2Cr + 7H2O      + 1,33

                                                                                Cℓ2(g) + 2e−                         ⇌   2Cℓ    −
                                                                                                                                         + 1,36
                                                                                     −
                                                                                MnO 4 + 8H+ + 5e−                    ⇌   Mn2+ + 4H2O     + 1,51

                                                                                H2O2 + 2H+ +2 e−                     ⇌   2H2O            +1,77
                                                                                   3+
                                                                                Co + e         −
                                                                                                                     ⇌   Co2+            + 1,81
                                                                                F2(g) + 2e−                          ⇌   2F−             + 2,87

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