# Physical Sciences Grade 12 P2 Eastern Cape June 2022 QP

> Grade 12 Physical Sciences Paper 2 question paper from the Eastern Cape June 2022 (English), 20 pages. Read online or download the free PDF.

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- Updated: 2026-09-27
- Subject: Physical Sciences
- Grade: Grade 12
- Language: English
- Document type: Question paper
- Year: 2022
- Exam period: Eastern Cape June
- Paper: 2
- Curriculum: CAPS
- Pages: 20

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                              NATIONAL
                         SENIOR CERTIFICATE

                                   GRADE 12

                                  JUNE 2022

            PHYSICAL SCIENCES: CHEMISTRY P2

MARKS:   150

TIME:    3 hours

          This question paper consists of 20 pages, including 2 data sheets.

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2                                PHYSICAL SCIENCES P2                        (EC/JUNE 2022)

 INSTRUCTIONS AND INFORMATION

 1.    Write your name and surname in the appropriate spaces on the ANSWER
       BOOK.

 2.    This question paper consists of SEVEN questions. Answer ALL the questions
       in the ANSWER BOOK.

 3.    Start EACH question on a NEW page in the ANSWER BOOK.

 4.    Number the answers correctly according to the numbering system used in this
       question paper.

 5.    Leave ONE line between two sub questions, for example between
       QUESTION 2.1 and QUESTION 2.2.

 6.    You may use a non-programmable calculator.

 7.    You may use appropriate mathematical instruments.

 8.    You are advised to use the attached DATA SHEETS.

 9.    Show ALL formulae and substitutions in ALL calculations.

 10. Round off your FINAL numerical answers to a minimum of TWO decimal places.

 11. Give brief motivations, discussions, et cetera where required.

 12. Write neatly and legibly.

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(EC/JUNE 2022)                              PHYSICAL SCIENCES P2                           3

 QUESTION 1: MULTIPLE-QUESTIONS

 Various options are provided as possible answers to the following questions. Choose
 the answer and write only the letter (A–D) next to the question numbers (1.1 to 1.10)
 in the ANSWER BOOK, for example. 1.11 E.

 1.1 Which ONE of the following is the general formula of alkenes?

       A         CnH2n

       B         C2H2n+2

       C         CnH2n-2

       D         CnH2n+1                                                                  (2)

 1.2 When the carbonyl group is located at the end of an organic molecule, to which
     ONE of the given homologous series does the molecule belong?

       A         Alcohol

       B         Aldehyde

       C         Ketone

       D         Haloalkane                                                               (2)

 1.3 Which ONE of the following compounds has the HIGHEST boiling point?

       A         Octane

       B         2-methylheptane

       C         2,3-dimethylhexane

       D         2,2,3-trimethylpentane                                                   (2)

 1.4 Which ONE of the following changes will INCREASE the average kinetic energy
     of particles?

       A         Catalyst

       B         Decrease in temperature

       C         Increase in temperature

       D         Increase in surface area                                                 (2)

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4                                                            PHYSICAL SCIENCES P2                         (EC/JUNE 2022)

 1.5 Consider the organic reaction below in which compound P is the MAJOR
     organic product.

                                CH3CH(CH3)CH2CH = CH2 + H2O → compound P

       The correct IUPAC name of the major organic product P is …

       A      4-methylpentan-1-ol.

       B      4-methylpentan-2-ol.

       C      2-methylpentan-1-ol.

       D      2-methylpentan-2-ol.                                                                                  (2)

 1.6 Consider the potential energy diagram for the following hypothetical reversible
     reaction.

                                                             Q ⇌    P

                      Potential energy (kJ·mol-1)
                                                     Z

                                                     Y                      P

                                                     X
                                                         Q

                                                                          time

       Which ONE of the following is the CORRECT interpretation of the information
       displayed in the graph?

                                                    ∆H forward reaction             ∆H reverse reaction

       A                                                     Y–Z                           Z–Y

       B                                                     Z–Y                           Y–Z

       C                                                     X–Y                          Y–X

       D                                                     Y–X                          X–Y                       (2)

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(EC/JUNE 2022)                            PHYSICAL SCIENCES P2                                  5

 1.7 Consider the following reaction at equilibrium at temperature T.

                              NO2(g)      ⇌    N2O4(g)      ∆H < 0

       The temperature of the reaction mixture is increased.

       Which ONE of the following is CORRECT about the RATE OF THE FORWARD
       REACTION and the YIELD of N2O4 immediately after the temperature is
       increased?

                      Rate of the forward reaction               Yield of N2O4

       A                      Decreases                              Increases

       B                       Increases                             Decreases

       C                       Increases                             Increases

       D                      Decreases                              Decreases                 (2)

 1.8 Which ONE of the following graphs CORRECTLY describe the relationship
     between the [H3O+] and pH?

       A                                           B

                 pH                                    pH

                                [H3O+]                                 [H3O+]

       C                                          D
                 pH                                    pH

                                 [H3O+]                                  [H3O+]                (2)

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6                                        PHYSICAL SCIENCES P2                     (EC/JUNE 2022)

 1.9    Consider the acid-base reaction below.

              H2PO4       +     OH        ⇌   H2O    +   Q

        The correct formula for substance Q is …

        A       H3PO4.

        B       HPO42-.

        C       PO43-.

        D       H3O+.                                                                        (2)

 1.10   The following circuit is used to test the conductivity of acids, HA and HB, at
        25 °C. Both acids have a concentration of 1 mol·dm-3.

                                     A

        carbon rod                                           carbon rod

                 acid

        The learners’ results are shown in the table below.

                                ACID                AMMETER READING (A)

                                  HA                            0,8

                                  HB                            1,5

        Learners write the following statements as their conclusions down:

        I.       HA is a stronger acid than HB

        II.      pH of HB is lower than that of HA

        III.     Ka value of HB is higher than that of HA

        Which ONE of the above statements is/are CORRECT?

        A       I only

        B       II only

        C       I and II only

        D       II and III only                                                             (2)
                                                                                           [20]

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(EC/JUNE 2022)                           PHYSICAL SCIENCES P2                                7

 QUESTION 2 (Start on a new page.)

 Consider the organic compounds A to F given in the table below.

                                          CH2CH3

 A               CH3CHCH2      C     C    CH    CH2CH3      B   propan-2-one

                   CH3
 C          Bromomethane                                    D   C4H8O
 E          C7H15COOH                                       F   Hexane

 2.1     To which homologous series do the following compounds belong?

         2.1.1   Compound A                                                                 (1)

         2.1.2   Compound C                                                                 (1)

 2.2     Write down a LETTER for the compound that meets the following description:

         2.2.1   A carboxylic acid                                                          (1)

         2.2.2   A compound whose formula is the same as the empirical formula of
                 compound E                                                                 (1)

 2.3     Compound A is a hydrocarbon.

         2.3.1   Define the term hydrocarbon.                                               (2)

         2.3.2   Is compound A SATURATED or UNSATURATED?

                 Give a reason for the answer.                                              (2)

         2.3.3   Write down the IUPAC name of compound A.                                   (3)

 2.4     Write down the structural formula of compound B.                                   (2)

 2.5     Compound D, a straight chain molecule, has only ONE CHAIN ISOMER.

         For compound D write down the:

         2.5.1   IUPAC name                                                                 (2)

         2.5.2   STRUCTURAL formula of its CHAIN ISOMER                                     (2)

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8                              PHYSICAL SCIENCES P2                               (EC/JUNE 2022)

 2.6    A group of learners use compound F as a fuel by reacting it with excess
        oxygen.

        Write down the:

        2.6.1    Name of the reaction between compound F and oxygen                        (1)

        2.6.2    Write down a balanced equation for the reaction of compound F
                 with excess oxygen, by using the MOLECULAR FORMULAE                       (3)

        2.6.3    Give a reason why alkanes are used as fuel                               (1)
                                                                                         [22]

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(EC/JUNE 2022)                                            PHYSICAL SCIENCES P2                                    9

 QUESTION 3 (Start on a new page.)

 3.1 A group of learners compare the boiling points of THREE compounds A, B and
     C during an investigation. The compounds have comparable molecular mass.

       The data the learners obtained for the compounds is shown in the table below.

                                                    Compound                       Boiling point (°C)

                 A                                    Pentane                                36,1

                 B                                  Butan-2-one                          79,64

                 C                                   Butan-1-ol                          117,7

       3.1.1                     Define the term boiling point.                                                  (2)

       3.1.2                     Identify the independent variable for this investigation.                       (1)

       3.1.3                     Which intermolecular forces are comparable in this investigation?               (1)

       3.1.4                     Explain why the boiling point of compound C is HIGHER than that of
                                 compound B by referring to TYPE, RELATIVE STRENGTHS of
                                 intermolecular forces and ENERGY.                                               (4)

 3.2 The graphs below show how the vapour pressure of compounds A and B (shown
     in the table above) changes with temperature.

                                   GRAPH OF TEMPERATURE VERSUS VAPOUR PRESSURE

                                                        A                    B

                 Vapour pressure (kPa)
                                         p1

                                              36,1            79
                                               Temperature (°C)

       3.2.1                     Define the term vapour pressure.                                                (2)

       3.2.2                     Write down the value of p1 shown in the graph.                                  (1)

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10                              PHYSICAL SCIENCES P2                       (EC/JUNE 2022)

       3.2.3    In what phase is compound A at 50 °C?

                Explain the answer.                                                 (2)

       3.2.4    How would the vapour pressure of compound C compare, to that of
                compound A at 36,1 °C?

                Choose from HIGHER THAN, LOWER THAN or EQUAL TO.                    (1)

       3.2.5    Explain your answer to QUESTION 3.2.4.                              (2)
                                                                                   [16]

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(EC/JUNE 2022)                          PHYSICAL SCIENCES P2                         11

 QUESTION 4 (Start on a new page.)

 Consider the flow diagram given below. Compounds P, Q and R are organic products
 of reactions 1, 2 and 3 respectively.

 CH3CH2CH2CH2Br         Reaction1       Alcohol P     Reaction 2   Compound Q
                                                      CH3COOH
                                                                        C4
                                             Reaction 3
         C4                                 A
                                           C4
                                       Compound R
                                         (C4H8)

 For REACTION 1 write down the:
                                          C4
 4.1 Name of the type of reaction taking place                                       (1)

 4.2 Condensed structural formula of compound P                                      (2)

 4.3 Is alcohol P a primary, secondary, or tertiary alcohol?

       Give a reason for the answer.                                                 (2)

 For REACTION 2 write down the:

 4.4 Name of the reaction taking place                                               (1)

 4.5 IUPAC name and structural formula of the organic product Q                      (4)

 4.6 Type of elimination reaction represented by REACTION 3                          (1)

 4.7 ONE reaction condition other than heat for REACTION 3                           (1)

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12                             PHYSICAL SCIENCES P2                            (EC/JUNE 2022)

 Compound R, C4H8, produced in reaction 3 in the flow diagram above is converted
 to compound T in a TWO step process as shown below.

 Compounds R and T are unbranched POSITIONAL isomers.

                        STEP 1     Compound S      STEP 2      Compound T
            R: C4H8
                         HBr

 4.8    Define the term positional isomer.                                              (2)

 4.9    Write down a balanced equation using structural formulae for the reaction
        taking place in STEP 2.                                                         (6)
                                                                                       [20]

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(EC/JUNE 2022)                                                        PHYSICAL SCIENCES P2                          13

 QUESTION 5 (Start on a new page.)

 The decomposition of hydrogen peroxide represented by the balanced equation
 below is used to investigate the factors that influence reaction rate.

                                                      H2O2(aq)   →     H2(g) +   O2(g)      ∆H < 0

 5.1 Define reaction rate.                                                                                          (2)

 5.2 Besides temperature, write down TWO factors that affect the rate of this
     reaction.                                                                                                      (2)

 5.3 During an experiment (experiment 1),150 cm3 of H2O2 decomposes at 30 °C
     in a flask.

       The graph below shows the results of experiment 1.

                 Concentration of H2O2 (mol·dm-3)
                                                    1,0

                                                    0,2

                                                          0          2 000                     5 000
                                                                                 Time (s)

       5.3.1     Give a reason why the rate of reaction decreases between
                 t = 2 000 s and t = 5 000 s.                                                                       (2)

       5.3.2     How long (in seconds) did the reaction take to reach completion?                                   (1)

       Calculate the:

       5.3.3     Average rate of reaction                                                                           (3)

       5.3.4     Volume of oxygen produced during the interval t = 0 to t = 2 000 s.
                 Assume that the molar gas volume at 30 °C is 25 000 cm3·mol-1.

                 ASSUME THAT THE VOLUME OF THE SOLUTION REMAINS
                 CONSTANT.                                                                                          (5)

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14                                             PHYSICAL SCIENCES P2               (EC/JUNE 2022)

 5.4 How will the following be affected if the volume of hydrogen peroxide (H 2O2)
     used in experiment 1 is doubled?

       Choose from INCREASES, DECREASES or REMAINS THE SAME.

       5.4.1    Average rate of reaction                                                     (1)

       5.4.2    Total volume of oxygen produced                                              (1)

 5.5 In experiment 2 hydrogen peroxide decomposes under the same conditions
     as in experiment 1, but a small amount of manganese dioxide is added.

       The Maxwell-Boltzmann distribution curve for the reaction in experiment 1 and
       experiment 2 is shown below.

                     Number of particles

                                                    E2 E1
                                           Kinetic energy

       E1 and E2 represent activation energies for the reaction in experiments 1
       and 2.

       5.5.1    Define activation energy.                                                    (2)

       5.5.2    Describe what is represented by the shaded area in the graph.                (1)

       5.5.3    Which ONE of E1 or E2 would yield a higher reaction rate? Explain the
                answer by referring to the collision theory.                                (4)
                                                                                           [24]

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(EC/JUNE 2022)                                      PHYSICAL SCIENCES P2                         15

 QUESTION 6 (Start on a new page.)

 6.1     The following reaction reaches equilibrium at a temperature of 327 °C.

                                    N2(g) + 3 H2(g) ⇌ 2 NH3(g)             ∆H < 0

         6.1.1 What is the meaning of the double arrow “⇌”?                                      (1)

         How does the rate of the forward reaction compare to the rate of the reverse
         reaction during the following time intervals?

         Choose from HIGHER THAN, LOWER THAN or EQUAL TO.

         6.1.2 Before equilibrium is reached for the first time                                  (2)

         6.1.3 At equilibrium                                                                    (1)

         The reaction is started by placing 4,88 moles of N2 and 6,18 moles of H2 in a
         2 dm3 sealed container and allowed to react. When equilibrium is established
         at 327 °C it is found the 41,48 grams of NH3 is present.

 6.2     Calculate the equilibrium constant, Kc, at 327 °C.                                      (8)

 6.3     Write down the name of a factor that affects the value of Kc.                           (1)

 6.4     The graph below shows how the percentage yield of NH3 varies with pressure
         at different temperature values.

                                           A

                      % Yield NH3
                                           B

                                       C

                                               Temperature (°C)

         Which graph (A, B or C) represents percentage yield values obtained at the
         HIGHEST pressure?

         Explain the answer by referring to Le Chatelier’s principle.                            (4)

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16                                  PHYSICAL SCIENCES P2                           (EC/JUNE 2022)

 6.5    What effect will the following changes have on the yield of NH 3 at
        equilibrium?

        Choose from INCREASES, DECREASES or NO EFFECT.

        6.5.1        More N2 is pumped into the container.                                  (1)

        6.5.2        A suitable catalyst is added.                                          (1)

        6.5.3        The volume of the container is increased at constant temperature.      (1)
                                                                                           [20]

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(EC/JUNE 2022)                            PHYSICAL SCIENCES P2                                  17

 QUESTION 7 (Start on a new page.)

 7.1 Sulphuric acid, H2SO4 ionises according to the balanced equation below:

                             H2SO4 + H2O           →   H3O+    +   HSO4

       7.1.1       Define an acid according to the Lowry-Brønsted theory.                     (2)

       7.1.2       Write down the formulae of the TWO bases in the reaction above.            (2)

       7.1.3       Identify a substance in the reaction that can act as an ampholyte in
                   some reactions.                                                            (1)

 7.2 The table below gives information about solutions of two acids and a salt.

          NAME OF SUBSTANCE                 FORMULA                Ka value or pH

                   Ethanoic acid            CH3COOH            Ka = 1,8 x 10-4 at 25 °C

                  Sulphuric acid              H2SO4                     pH = 3

                 Sodium carbonate             Na2CO3                    pH = 7,8

       7.2.1       Is CH3COOH a STRONG or a WEAK acid?
                   Give a reason for the answer.                                              (2)

       7.2.2       Which acid, CH3COOH or H2SO4, would react faster with Na2CO3?
                   Assume the acids have the same concentration and are in excess.            (1)

       7.2.3       Calculate the concentration of the H2SO4 solution.                         (4)

       7.2.4       Explain by using a relevant equation, why the pH of Na2CO3 is greater
                   than 7.                                                                    (3)

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18                               PHYSICAL SCIENCES P2                             (EC/JUNE 2022)

7.3    A standard solution is prepared by dissolving 1,74 g of Mg(OH)2 in water to
       make 200 cm3 of the solution.

       7.3.1    Define the term standard solution.                                           (2)

       7.3.2    Show by calculation that the concentration of the Mg(OH)2 solution
                is 0,15 mol·dm-3.                                                            (2)

       A group of learners added 50 cm3 of a dilute hydrochloric acid solution to
       40 cm3 of the standard solution of Mg(OH)2.

       The balanced equation for the reaction is:

                        Mg(OH)2 + 2 HCℓ        →     MgCℓ2    + 2 H2O

       The diluted hydrochloric acid solution was obtained by adding 5 cm 3 of
       10 mol·dm-3 of concentrated hydrochloric acid to water to produce 100 cm 3 of
       the diluted acid solution. ONE of the ions (OH- or H3O+) is found to be in excess
       at the completion of the reaction.

       7.3.3    Calculate the concentration of the ions in excess.                          (9)
                                                                                           [28]

                                                                               TOTAL:      150

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(EC/JUNE 2022)                                 PHYSICAL SCIENCES P2                                           19

                                 NATIONAL SENIOR CERTIFICATE
                                NASIONALE SENIOR SERTIFIKAAT

                          DATA FOR PHYSICAL SCIENCES GRADE 12
                                   PAPER 2 (CHEMISTRY)

                        GEGEWENS VIR FISIESE WETENSKAPPE GRAAD 12
                                VRAESTEL 2 (CHEMIE)

 TABLE 1: PHYSICAL CONSTANTS/TABEL 1: FISIESE KONSTANTES

            NAME/NAAM                           SYMBOL/SIMBOOL                     VALUE/WAARDE
   Standard pressure
   Standaarddruk                                            p                       1,013 x 105 Pa

   Molar gas volume at STP
   Molêre gasvolume teen STD                               Vm                        22,4 dm3∙mol-1

   Standard temperature
   Standaardtemperatuur                                     Tθ                             273 K

   Charge on electron
   Lading op elektron                                       e                         -1,6 x 10-19 C

   Avogadro’s constant
                                                            NA                      6,02 x 1023 mol-1
   Avogadro se konstante

 TABLE 2: FORMULAE/TABEL 2: FORMULES
        m                                 n                m
   n= M       or/of                  c = V or/of c = MV                    pH= -log[H3O+]

         N                                      ca Va   na                 Kw = [H3O+][OH-] = 1x10-14
   n= N       or/of                                   =
          A
                                                cb Vb nb                   at/by 298 K
         V
   n= V
          o

   Eθcell = Eθcathode – Eθanode / Eθsel = Eθkatode – Eθanode

   Eθcell = Eθreduction – Eθoxidation / Eθsel = Eθreduksie – Eθoksidasie

   Eθcell = Eθoxidising agent – Eθreducing agent / Eθsel = Eθoksideermiddel – Eθreduseermiddel

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(EC/JUNE 2022)                                                                     PHYSICAL SCIENCES P2                                                                                                        20
TABLE 3: THE PERIODIC TABLE OF ELEMENTS/TABEL 3: DIE PERIODIEKE TABEL VAN ELEMENTE

   1               2           3           4         5             6           7           8             9      10          11           12       13          14         15           16         17          18
  (I)             (II)                                                                 Atoomgetal                                                (III)       (IV)        (V)         (VI)       (VII)       (VIII)
                                               KEY/ SLEUTEL                          Atomic number
        1                                                                                                                                                                                                      2
2,1    H                                                                                                                                                                                                      He
        1                                                                                        29                                                                                                            4
        3            4                                   Elektronegatiwiteit                                   Simbool                                 5          6           7           8           9        10
1,0    Li   1,5    Be                                                                      1,9                 Symbol                          2,0    B    2,5    C    3,0    N    3,5    O    4,0    F       Ne
                                                          Electronegativity                      Cu
        7            9                                                                                                                                11          12          14         16           19       20
       11           12                                                                           63,5                                                 13          14          15         16           17       18
0,9   Na    1,2    Mg                                                      Benaderde relatiewe atoommassa                                      1,5   Aℓ    1,8    Si   2,1    P    2,5    S    3,0    Cℓ       Ar
       23           24                                                     Approximate relative atomic mass                                           27          28          31         32          35,5      40
       19           20          21      22            23            24         25          26            27      28          29           30          31          32          33         34           35       36
0,8    K    1,0    Ca    1,3   Sc    1,5Ti     1,6    V      1,6    Cr   1,5   Mn    1,8   Fe      1,8  Co    1,8Ni   1,9    Cu    1,6   Zn    1,6   Ga    1,8   Ge    2,0   As    2,4   Se    2,8    Br       Kr
       39           40          45      48            51            52         55          56            59      59         63,5          65          70          73          75         79           80       84
       37           38          39      40            41            42         43          44            45      46          47           48          49          50          51         52           53       54
0,8   Rb    1,0     Sr   1,2    Y    1,4Zr           Nb      1,8   Mo    1,9   Tc    2,2   Ru      2,2  Rh    2,2
                                                                                                                Pd    1,9    Ag    1,7   Cd    1,7    In   1,8   Sn    1,9   Sb    2,1   Te    2,5     I      Xe
       86           88          89      91            92            96                     101          103     106         108          112         115         119         122         128         127      131
       55           56          57      72            73            74          75         76            77      78          79           80          81          82          83         84           85       86
0,7   Cs    0,9    Ba          La    1,6Hf           Ta             W          Re          Os            Ir      Pt          Au          Hg    1,8    Tℓ   1,8   Pb    1,9    Bi   2,0   Po    2,5    At      Rn
      133          137         139     179           181           184         186         190          192     195         197          201         204         207         209
       87           88          89
0,7    Fr   0,9    Ra          Ac
                   226                           58             59         60          61              62       63       64          65           66          67          68         69           70         71
                                                Ce              Pr        Nd           Pm             Sm       Eu       Gd           Tb          Dy          Ho           Er         Tm          Yb         Lu
                                                140            141        144                         150      152      157          159         163         165         167         169         173        175
                                                 90             91         92          93              94       95       96          97           98          99         100         101         102        103
                                                Th             Pa          U           Np             Pu       Am       Cm           Bk           Cf         Es          Fm          Md          No          Lr
                                                232                       238

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