# Physical Sciences Grade 12 P2 KwaZulu Natal Mock 2022 Memo

> Grade 12 Physical Sciences Paper 2 memorandum from the KwaZulu Natal Mock Exam 2022, 31 pages. Read online or download the free PDF.

- Page: https://www.hlayiso.com/library/physical-science-grade-12-sept-2022-p2-and-memo/df994dba-4ca4-4b41-8144-c52022fa8e6a
- Updated: 2026-09-27
- Subject: Physical Sciences
- Grade: Grade 12
- Document type: Memorandum
- Year: 2022
- Exam period: KwaZulu Natal Mock Exam
- Paper: 2
- Curriculum: CAPS
- Pages: 31

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## About this document

Physical Sciences · Grade 12 · KwaZulu Natal Mock Exam · 2022. Memorandum, 31 pages. Read online or download the PDF.

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KWAZULU-NATAL PROVINCE s }

EDUCATION
REPUBLIC OF SOUTH AFRICA

NATIONAL
SENIOR CERTIFICATE

GRADE 12

MARKS: 150

This marking guideline consists of 13 pages.

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PhysicaLScience September 2022 Preparatory Examination

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QUESTION 1
1.4 Cvv (2)
1.2 Byv (2)
1.3 Dvv (2)
1.4 Avy (2)
15 Bvv (2)
1.6 Dvv (2)
1.7 Dvv (2)
1.8 A v¥ (accept C) (2)
1.9 Cvy (2)
1.10 Dvv (2)
[20]
QUESTION 2
2.1
2.1.1 CnHen-2 v (1)
2.1.2
H H
| |
_— — C — C — H
|
H
Marking criteria:
e functional groupY
e All the substituents( 2 methyl groups and 1 ethyl group) correct “
e Whole structure correct” oA (3)

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PhysicaLScience September 2022 Preparatory Examination

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oe
2.2.1. Organic compounds having the same molecular _formulay, but different
functional groupsY (underlined words must be in correct contexts) (2)
2.2.2 Pentanal/2-methylbutanal/3-methylbutanal/2,2-dimethylpropanal vv (2)
(functional group —anal Vv
Everything correct v’)
(If wrong functional group 0/2)
22a
2.3.1 hydroxylv (1)
232
H
|
H —cC—H
H H
| |
Ho oS ee
| |
H H
H —cC —H
H
Marking criteria:
e Only functional group correct: Max: Xx
2,
e Whole structure correct: 3,
(2)
2.4
2.4.1 — esterification v (1)
2.4.2 butylv propanoateY (2)
[14]

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Physic

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QUESTION 3

3.1

3.2

3.3

3.4

3.5

3.6

ag

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The temperature at which the vapour pressure equals atmospheric (external)
pressure. vv (2 or 0)

YES. v
P, Q and R are straight chain primary alcohols/only ONE independent
variable. v

Boiling point increases V with increase in chain length/molecular mass. ”

Intermolecular forces/Van der Waals forces/London forces/dispersion
forces increase (becomes stronger) with increase in chain lengthy
More energy needed to overcome/break intermolecular forces as chain
length increases. Vv

REMAINS UNCHANGEDY

Py

Any One

P has the lowest boiling point “ OR
P has the weakest intermolecular forcesv

LESS THANY

Intermolecular forces between molecules of alcohols are hydrogen
bonding (in addition to London forces/dispersion forces). v

Intermolecular forces between molecules of CeéHi4 are only London
forces/dispersion forces. v

London forces/dispersion forces are weaker than hydrogen bonding /
Intermolecular forces in CeH14 are weaker/ Intermolecular forces in Q are
stronger. “

Less energy needed to overcome/break intermolecular forces in CeH:4/
more energy needed to overcome Intermolecular forces in Q.”

September 2022 Preparatory Examination

(2)

(2)

(2)

(2)

(1)

(2)

(5)
[16]

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PhysicaLScience September 2022 Preparatory Examination

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QUESTION 4

41 Hydrogenation. ~ (1)
4.2 Hydrohalogenation/hydrobromination ~ (1)
4.3 Iv (1)
4.4.1 Strong basesY (1)

4.4.2 Reaction IV, base is dilutew

Reaction III base is concentrated (in ethanol). v (2)
45
¥ v
lbtlestecs aes ipaes
H-—C=C—C—H+H-—Br — H—C—C—C-—H
H H Br H
(3)
4.6 hydrolysis v (1)
4.7
(3)
48 dehydration” (1)
4.9 ethene vvv (3)
[17]

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QUESTION 5

521, Change in concentration of reactants/products per unit time.
Change in amount/number of moles/volume/mass” of reactants or products
per unit time. “
Amount/number of moles/volume/mass/ of products formed or reactants
used per unit time. “ (2)

a2 AV
average rate = —
At
_ (104-64) ¥
(60-30) v
=133 v ( cm*.s* ) (3)
5.3 lv
The gradient / m/ slope of graph | is less steep than Il. “ or
Took a longer time for rection to reach completion. ~ (2)
5.4 Catalystv (1)
5.5 e Acatalyst provides an alternate pathway of lower activation energy.”

e More particles will have sufficient energy for an effective collision/ more
molecules have kinetic energy equal to or greater than the activation
energy.”
e Number of effective collisions per unit time increases/frequency of
effective collisions increases.“ (3)

5.6 Marking criteria:

e Ratio: n(Mg) initial equals n(H2) final produced in reaction Il. v

Formula: n = ee
V,

m

e Correct substitution ( ) in the above formula

p

To calculate n(Mg) used(reacted) in reaction lin 150 sv
n(Mg)initial - n(Mg)used/reacted v

Formula: m = nMv

Correct substitution of 24 with n Mg in the above formula. ”
Final answer = 0,018 g. “

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Physic OuWhioa ‘eaFrom S tanmereaphysies.com 2022 Preparatory Examination

OPTION 1
n(Mg)initial = n(H2)produced in EXP Il
aM
Vie
0,12 ‘
= v v
24,04 Either
Either v
= 4,99 x 10? mol
n(Mg)used in‘EXP | = n(H2)produced in EXP |
V
= ve
_ 0,102
24,04
= 4,24 x 10° mol

n(Mg) remaining = 4,99x10° - 4,24 x 103v
= 0,75 x 10? mols

m(Mg) = nMv
= (0,75 x 10°°)(24) v
= 0,018 gv
OPTION 2

nHz still to be produced = nMg “

mY

_ 0,42-0,102 (4 mark for subtraction)
24,04

=7,49x10™ mol

m=nxMvY
= 7,49 x 10% x24 v
=0,018g “

(8)

[19]

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Physical-Science: September 2022 Preparatory Examination

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QUESTION 6
6.1 The rate of forward reaction equals the rate of reverse reaction. Vv“

Notes

IF: Forward reaction equals reverse reaction. Xx (2)
6.2 Reactants and products are ALL in the same phase. Vv (1)
6.3 Marking criteria:

e n(Cfe) equilibrium= 0,4”

e Using the correct mol ratiov’

e Calculating the quantity(mol) at equilibrium of all three substances v

e Divide number of moles at equilibrium by 5 dm3v

e Ke expression”

e Correct substitution of equilibrium concentrations into Ke expression ~

e Substitute n(Oz) initial and M(O2) into m = nMv

e Final answer 9,60 g v
OPTION 1

HCt O2 HzO Clo
Ratio 4 1: 2 2
Initial quantity (mol) 1 x 0 0 Seon
Change (mol) 0,8 —_0,2— 0,4 0,4
eames a4
Quantity at equilibrium (mol) 1-0,8 x-0,2 |0+0,4) 0,4v
, | x-02 | Ss
Equilibrium concentration (mol-dm-3) | 9:04 5 0,08 0,08 | Divide by 5
[HOPIC!.1°
= ; itution. 7,
c [HC¢]*[0,] No Ke expression, correct substitution. Ye
2 2
. 800 = 10:08)'(0.08)" G,oey v ;
0,04)*| == Wrong K- expression
(ooay(*2} %
x = 0,3 mols
n(Oz) = nM
= (0,3) (32) ¥
= 9,60 gv (range 9,595312 to 9,60) (8)

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PhysicaLScience

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September 2022 Preparatory Examination

OPTION 2
HCt O2 H20 Ck
Ratio 4 Z 2 2
Initial quantity (mol) 1 0,3 0 (e)
Change (mol) 08 | 02 | 04 0,4 Using ratio v
Quantity at equilibrium (mol) “4 , 0,8 0,1 0 +04) 0,4v
Equilibrium concentration (mol-dm?) | 9.04 [02] 0,08 0,08 | Divide by 5“

x. — HOF Ice)
*  [HC¢}*[0,]
(0,08)'(0,08)"

(0,04) [o,] Wrong K, expression A
[Oz] = 0,02 mol-dm?

v No K. expression, correct substitution. We

n(Oz) = nM
= (0,3) (32) v
= 9,60 gv (range 9,595312 to 9,60)
6.4 When the equilibrium in a closed system is disturbed, the system will

re-instate a new equilibrium by favouring the reaction that will oppose the
disturbance. vv
Note: Underlined phrases must be in correct context

6.5.1 Remains the same. “
6.5.2 Increases. Vv

6.6 An increase in pressure favours the reaction that produces a fewer number of
moles. ”
The forward reaction is favoured. ¥

6.7.1 Negative

6.7.2 Option 1

e When the temperature increases the reverse reaction is favoured. v
e An increase in temperature favours the endothermic reaction. ”
e Forward reaction is exothermic. ~

Option 2

e Kc decreases with an increase in temperature. v

e Reverse reaction is favoured/concentration of reactants
increases/concentration of products decreases/yield decreases. “

+ Increase in temperature favours the endothermic reaction. v

(2)
(1)
(1)

(2)
(1)

(3)
[21]

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September 2022 Preparatory Examination

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QUESTION 7
7.1.1 Asubstance that acts as an acid and as a base. vv (2)
7.1.2 HSO,/hydrogen sulphate ion” (1)
7.2.1. Marking quidelines:
> © Formula: pH = -log[HsO*] Vv
_e Substitution: 0,1”
“se Final answer: 1¥”
pH = - log [H3O*] “
= - log 0,1v
= 1v (3)
7.2.2 EQUALTO7Y (1)
7.2.3 | OPTION 1/OPSIE 1 Marking guidelines:
n(OH’) = n(H*) ” e Mol ratio: n(OH)) = n(H*)
=cVVv e n= cV (entire eq)
= (0,1)(0,03) v ¢ Substitution of 0,1
= 0,003 mol ¥ ¢ Substitution of 0,03.
e Final answer: 0,003 mol.
OPTION 2 Marking guidelines:
c.xV. n e Mol ratio
aay S = e Formula: n= cV
Spree: Mp Substitution of (0,15)(0,02)
O1x 30 1 v e Final answer: 0,03 mol
cbx 20 1
cb = 0,15 mol-dm*
n=cv ¥
= (0,15)(0,02) “ (4)
= 0,003 molsv

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Physic OuWhloa ‘eaFrom S tanmere. pliysies.com> °° Preparatory Examination

7.2.4 Marking criteria:

Calculate number of moles of hydroxide ions in 250 cm?.v
Calculate number of moles of hydroxide ions in Ba(OH)2. ¥
Calculate number of moles NaOH = 0,02 v

Mol ratio: number of moles of Ba(OH)2 : number of moles of OH.”
Formulae: n= cV ¥

Substitute in the above formula. “
Final answer: 0,175 mol.dm’.

eeeeeeu30e

OPTION 1
n(OH)in 250 cm? = oe) v
0,0375 mols

n(OH)in Ba(OH)2 n(OH’)totat - n(OH)NaOH

0,0375 0,02 v

0,0175 mols
n(Ba(OH)z) Y% n(OH)
Y (0,0175) ¥
0,00875 mols
c (Ba(OH)2) = a v
c (Ba(OH)2) = Oem v
0,05
= 0,175 mol.dm?. ¥
OPTION 2
, 4
V(NaOH) in 20 cm? = 5 x 20
= 16cm*
VBa(OH)2in 20cm? = 20- 16
= 4cm§
n(OH’) from NaOH = cV

(0,1)(46 x 10°)
1,6 x 10° mols ¥

n(OH) from Ba(OH)2 = 3.x 103 1,6 x 103v

1,4 x 10° mols

n(Ba(OH)2) = %n(OH)
= %(1,4 x 105)v
= 0,7 x 10° mols

c (Ba(OH)2) = y v
c (Ba(OH)2) = COON
0,004
= 0,175 mol.dm®. ¥ (7)

[18]

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Physical-Science: September 2022 Preparatory Examination

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QUESTION 8

1 Voltaic/galvanic cell.“ (1)

8.2 Temperature: 25 °C/298 K. v

Concentration of electrolytes: 1 mol.dm*. ” (2)
8.3 spontaneous. v No external energy is required

Accept: cell potential is positive / cell is a galvanic cell. ~ (2)
8.4.1 Pt(s)/ Fe**(aq)(1 mol.dm’s), Fe**(aq)(1 mol.dmr?) // X*(aq)(1 mol.dm’?)/Xx(s) (3)

Accept: Pt/Fe**, Fe?*//X*/x (MINUS 1 MARK FOR ANY ERROR)

84.2 X*(aq) +e — X(s) %¥v Ignore phases
Notes
© XaxXte (%) Xt+eex (Y)
=Xtte 0 4 Be 0,
X2xt+e (%) Xt eo X (%)
e Ignore if charge on electron omitted.
If a charge of an ion is omitted eg. X +e > X Max: (¥)
(2)
8.5 Ei = Er ecicaon = E  iicton v Notes
0,03v =EP suction —(0,77) e Accept any other correct formula from the
Fo -o80v data sheet.
reduction “"™* e Any other formula using unconventional
: abbreviations, e.g. E°cei = E°oa- E°ra
X is Agv followed by correct substitutions Max: 3/4 (4)
[14]

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Physic

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cience September 2022 Preparatory Examination

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QUESTION 9

9.1

9.2

9.3

9.4

9.5
9.5.1

9.5.2

A substance that forms free (positive and negative) ions when melted or
dissolved. Vv

OR
A solution that conducts electricity. vv
OR

A liquid/solution/dissolved substance that conducts electricity through the
movement of ions. v ” (2)
Electrode P ¥ (1)
Cu?*(aq) + 2e° — Cu(s) VY
Ignore phases

Notes

e Cue Cu + 2e (%) Cu** + 2e = Cu (¥)

Cu?* + 2e — Cu (%) Cu2*+ 2e = Cu (%)

e Ignore if charge on electron omitted.

e If acharge of anion is omitted eg. Cu+2e<Cu Max: (%) (2)
Increases. v
Reduction takes place at electrode P. v (2)
Zinc ions(Zn2*)V and Copper ions(Cu2*)” (2)
OPTION 1
Cu?* ions is a stronger oxidising agent than Zn?* ions” Cu?* will be reduced to
Cu.¥ ) ;
OPTION 2 _ :, (2)
Zn* ions are a weaker oxidising agent than Cu?* ions” Zn** will therefore not
be reduced to Zn. “

[11]

TOTAL: 150

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