# Physical Sciences Grade 12 P2 Gauteng June 2025 QP (Eng)

> Grade 12 Physical Sciences Paper 2 question paper from the Gauteng June Exam 2025 (English), 18 pages. Read online or download the free PDF.

- Page: https://www.hlayiso.com/library/physical-sciences-p2-english-june-2025-question-paper/2296685e-bdb3-4af5-b33a-007a87f9b36e
- Updated: 2026-09-27
- Subject: Physical Sciences
- Grade: Grade 12
- Language: English
- Document type: Question paper
- Year: 2025
- Exam period: Gauteng June Exam
- Paper: 2
- Curriculum: CAPS
- Pages: 18

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## About this document

Physical Sciences · Grade 12 · Gauteng June Exam · 2025 · English. Question paper, 18 pages. Read online or download the PDF.

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### Page 1

JUNE EXAMINATION
      GRADE 12

           2025

PHYSICAL SCIENCES: CHEMISTRY

         (PAPER 2)

                       TIME:     3 hours

                       MARKS: 150

                       16 pages + 2 data sheets

                                   Please turn over

### Page 2

PHYSICAL SCIENCES: CHEMISTRY              2
                                            (PAPER 2)             GR12 0625

INSTRUCTIONS AND INFORMATION

1.    This question paper consists of SEVEN questions. Answer ALL the questions in
      the ANSWER BOOK.

2.    Start EACH question on a NEW page in the ANSWER BOOK.

3.    Number the answers correctly according to the numbering system used in the
      question paper.

4.    Leave ONE line open between two subquestions, e.g., between QUESTION 2.1
      and QUESTION 2.2.

5.    You may use a non-programmable calculator.

6.    You may use appropriate mathematical instruments.

7.    Show ALL formulae and substitutions in ALL calculations.

8.    Round-off your FINAL numerical answers to a minimum of TWO decimal places.

9.    Give brief discussions, et cetera where required.

10.   You are advised to use the attached DATA SHEETS.

11.   Write neatly and legibly.

                                                                             Please turn over

### Page 3

PHYSICAL SCIENCES: CHEMISTRY                   3
                                             (PAPER 2)            GR12 0625

QUESTION 1: MULTIPLE-CHOICE QUESTIONS

Various options are provided as possible answers to the following questions. Each question
has only ONE correct answer. Choose the answer and write only the letter (A – D) next to
the question numbers (1.1 to 1.10) in the ANSWER BOOK, e.g. 1.11 D.

1.1   Which of the following represents a SATURATED hydrocarbon?

      A     C2H4
      B     C3H6
      C     C3H8
      D     C4H8                                                                             (2)

1.2   Which of the following pairs of reactants can be used to prepare the ester
      called ethyl propanoate in the laboratory?

      A     Ethane and propanoic acid
      B     Propanol and ethanoic acid
      C     Ethanol and propanoic acid
      D     Ethene and propanol                                                              (2)

1.3   Consider the reaction represented by the equation below:

                   CH3CHCH2        +     HBr     →        CH3CHBrCH3
      What type of reaction is represented above?

      A     Halogenation
      B     Substitution
      C     Hydrogenation
      D     Hydrohalogenation                                                                (2)

1.4   Consider the following compound:

                   CH3CH(C)CH2C(CH3)3
      The IUPAC name of this compound is:

      A     2-chloro-4,4-dimethylpentane
      B     2,2-dimethyl-4-chloropentane
      C     4,4-dimethyl-2-chloropentane
      D     4-chloro-2,2-dimethylpentane                                                     (2)

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### Page 4

PHYSICAL SCIENCES: CHEMISTRY                  4
                                              (PAPER 2)            GR12 0625

1.5   Two learners want to investigate the factors affecting the rate of reaction between
      magnesium (Mg) and hydrochloric acid (HC). The concentration of the acid
      remains the same.

                                            gas syringe

                                        test tube containing magnesium

                                        excess dilute hydrochloric acid

      Which of the following changes to the experiment will produce the fastest rate of
      reaction?

      A    Powdered magnesium with hydrochloric acid at room temperature
      B    Powdered magnesium with hydrochloric acid at a higher temperature
      C    Magnesium ribbon with hydrochloric acid at a higher temperature
      D    Magnesium ribbon with hydrochloric acid at room temperature                       (2)

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### Page 5

PHYSICAL SCIENCES: CHEMISTRY            5
                                                                        (PAPER 2)            GR12 0625

1.6   Consider the energy profile graph for a REVERSIBLE REACTION shown
      below.

                           Potential energy (kJ·mol )
                          -1

                                                                                   products

                                                        reactants

                                                                    Course of reaction

      The following statements are given:

      (i) a – c represents the activation energy for the reverse reaction.
      (ii) ∆H for the reverse reaction is a – b.
      (iii) A catalyst lowers the activation energy for both forward and reverse
            reactions.

      Identify the CORRECT statement(s).

      A     (ii) and (iii) only
      B     (iii) only
      C     (i), (ii) and (iii)
      D     (i) only                                                                                             (2)

1.7   The reaction of an acid-base indicator (In-) represented as HIn(aq), with H2O()
      reaches equilibrium according to the following balanced equation:

                      HIn(aq) + H2O() ⇌ H3O+(aq) + In-(aq)                                   ΔH < 0
                       Red                         Yellow

      At equilibrium, the colour of the solution is red.

      Which of the following will change the colour of the solution from red to yellow?

      A     Increasing the concentration of H₃O⁺ ions
      B     Increasing the temperature of the solution
      C     Adding a base
      D     Adding an acid                                                                                       (2)

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### Page 6

PHYSICAL SCIENCES: CHEMISTRY                6
                                             (PAPER 2)            GR12 0625

1.8   The expression for the equilibrium constant (KC) of a hypothetical reaction is
      given as follows:
                                            [PQ3 ]2
                                       KC =
                                             [Q2 ]3

      Which of the following equations for a reaction at equilibrium matches the above
      expression?

      A    P2(g) + 3Q2(g) ⇌ 2PQ3(aq)

      B    2PQ3() ⇌ P2(g) + 3Q2(g)

      C    2PQ3(aq) ⇌ P2(g) + 3Q2(g)

      D    P2(s) + 3Q2(g) ⇌ 2PQ3(g)                                                       (2)

1.9   Which statement best describes the difference between the endpoint and the
      equivalence point in a titration?

      A    The endpoint occurs when the acid or base has completely reacted with
           each other, while the equivalence point is when the indicator changes
           colour.
      B    The equivalence point occurs when the acid or base has completely
           reacted with each other, while the endpoint is when the indicator changes
           colour.
      C    The endpoint and equivalence point occur at different times and have no
           connection in a titration.
      D    The equivalence point and endpoint are always exactly the same in every
           titration.                                                                     (2)

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### Page 7

PHYSICAL SCIENCES: CHEMISTRY                 7
                                              (PAPER 2)            GR12 0625

1.10   A titration experiment was conducted using a sodium hydroxide (NaOH)
       standard solution of concentration 0,1 mol.dm-3 and hydrochloric acid (HC) of
       unknown concentration.

       In each titration, a volume of 20 cm3 of NaOH was used.
       The readings from the burette are given in the table below.

                                                 Volume of HC
                                Titration
                                                    (in cm3)
                                    1                 26,66
                                    2                 26,50
                                    3                 26,60

       What is the concentration, in mol.dm-3, of the HC required to neutralise the
       NaOH?

       A    0,0752
       B    0,0750
       C    0,0754
       D    0,0755                                                                          (2)
                                                                                           [20]

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### Page 8

PHYSICAL SCIENCES: CHEMISTRY                         8
                                              (PAPER 2)            GR12 0625

QUESTION 2 (Start on a new page.)

The letters A to H in the table below represent organic compounds.

  A    C5H12                                     B    C4H8O2

  C    Ethyl butanoate                           D    CH3CHCHCH2CH3

                                                           H    H        H       H   H     O

  E    Butan-1-ol                                F    H    C    C        C       C   C     C   O       H

                                                           H    H        H       H   H

                                                            H        H       H       H

  G                                              H    H     C        C       C       C     H

                                                            H        OH H            H

2.1   Consider compound H. Is this a PRIMARY, SECONDARY or TERTIARY alcohol?
      Explain the answer.                                                                                  (3)

2.2   Write down the letter that represents each of the following:
      2.2.1     A ketone                                                                                   (1)

      2.2.2     A MOLECULAR FORMULA of a hydrocarbon                                                       (1)

      2.2.3     A reactant in the preparation of compound C                                                (1)

2.3   Write down the STRUCTURAL formula of:
      2.3.1    Compound D                                                                                  (2)

      2.3.2    The FUNCTIONAL group of compound F                                                          (2)

      2.3.3    The FUNCTIONAL isomer of compound G with a prefix of 4-methyl                               (2)

2.4   Write down the IUPAC name of:
      2.4.1    Compound D                                                                                  (2)

      2.4.2    Compound G                                                                                  (3)

2.5   Consider compounds E and H.
      2.5.1    Identify the type of isomer.                                                                (1)

      2.5.2    Define this type of isomer.                                                                 (2)

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### Page 9

PHYSICAL SCIENCES: CHEMISTRY                 9
                                          (PAPER 2)            GR12 0625

2.6   Consider compound C.
      2.6.1    To which homologous series does compound C belong?                            (1)

      2.6.2    Give the NAME of the catalyst required in the preparation of compound C.      (1)

      2.6.3    Draw the STRUCTURAL FORMULA of compound C.                                    (3)
                                                                                            [25]

QUESTION 3 (Start on a new page.)

The factors that affect the vapour pressure of different organic compounds are
investigated. The table below shows the vapour pressure of five organic compounds,
represented by the letters A – E.

                                          MOLECULAR                VAPOUR
                    ORGANIC
                                             MASS                 PRESSURE
                   COMPOUND
                                            (g.mol-1)            (kPa) at 25 °C
          A    Propane                         44                   953,25
          B    Butane                          58                   242,63
          C    Ethyl methanoate                74                    32,38
          D    Alcohol                         59                    2,80
          E    Propanoic acid                  74                    0,47

3.1   Define the term vapour pressure.                                                      (2)

3.2   Write down the homologous series to which compounds A and B belong.                   (1)

3.3   Explain the decrease in vapour pressure from compound A to compound B, as
      indicated in the table.                                                               (3)

3.4   Compounds C and E are functional isomers.

      3.4.1   Define molecular formula.                                                     (2)

      3.4.2   Which compound will have a higher boiling point?                              (1)

      3.4.3   Explain the answer to QUESTION 3.4.2.                                         (4)

3.5   The percentage composition of some of the elements in compound D is given as
      61% carbon and 11,86% hydrogen. Determine, with calculations, the empirical
      formula of compound D.                                                                (4)

3.6   Write a balanced equation using molecular formulae for a complete combustion
      of compound A.                                                                        (3)
                                                                                           [20]

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### Page 10

PHYSICAL SCIENCES: CHEMISTRY             10
                                               (PAPER 2)            GR12 0625

QUESTION 4 (Start on a new page.)

 The flow diagram below shows how an alkene can be used to prepare other organic
 compounds. The letters J to N represent various organic reactions.

                                      Compound Q

                   K                                               L
                                         HBr

                                                               N        alcohol
       butane
                                      CH2=CH-CH2-CH3                    (major product)
                        J

                              HCl                          M

                     Compound R                        Compound S
                    (major product)            +      (minor product)

 4.1   Is an alkene a SATURATED or UNSATURATED hydrocarbon?
       Explain the answer.                                                                   (3)

 4.2   Write down the type of reaction represented by:

       4.2.1   J                                                                             (1)

       4.2.2   K                                                                             (1)

       4.2.3   M                                                                             (1)

 4.3   Write down the STRUCTURAL FORMULA of compound R.                                      (2)

 4.4   For reaction N, write down:

       4.4.1   The type of addition reaction                                                 (1)

       4.4.2   Two reaction conditions                                                       (2)

       4.4.3   The IUPAC name of the alcohol that forms                                      (2)

 4.5   Write down the IUPAC name of an isomer of butane.                                     (2)

 4.6   Use STRUCTURAL formulae to write down a balanced equation for
       reaction L.                                                                         (5)
                                                                                          [20]

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### Page 11

PHYSICAL SCIENCES: CHEMISTRY                   11
                                              (PAPER 2)            GR12 0625

QUESTION 5 (Start on a new page.)

Three different experiments are performed using the reaction between magnesium
carbonate and hydrochloric acid:

                MgCO3(s) + 2HC(aq) → MgC2(aq) + H2O() + CO2(g)

EXPERIMENT I

In this experiment, magnesium carbonate reacts with EXCESS hydrochloric acid in a
closed container at 23 oC. The reaction is monitored by measuring the volume of carbon
dioxide gas produced over time. The molar gas volume at 23 oC is 24 dm3. The data
collected is shown in the table below.

                      TIME (s)         VOLUME OF CO2 (cm3)
                          0                        0
                          10                      180
                          20                      300
                          30                      410
                          40                      470
                          50                      500
                          60                      500

5.1   Define the term reaction rate.                                                          (2)

5.2   Use the collision theory to explain the effect on the reaction rate as time
      progresses.                                                                             (4)

5.3   Calculate the reaction rate for the production of CO2(g) during the first
      20 seconds, in dm3.s-1.                                                                 (3)

5.4   Calculate the mass of MgCO3 required for this experiment.                               (4)

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### Page 12

PHYSICAL SCIENCES: CHEMISTRY        12
                                                       (PAPER 2)            GR12 0625

EXPERIMENT II

5.5   Experiment I is repeated, but this time at 30 °C.

      The following Maxwell-Boltzmann distribution curve was produced.

                       Number of molecules

                                             Kinetic energy

      5.5.1   Which graph, A or B, best represents Experiment II?                          (1)

      5.5.2   Explain the answer to QUESTION 5.5.1.                                        (2)

      5.5.3   If a catalyst was added, would the line representing the activation energy
              (Ea) be drawn to the LEFT or the RIGHT of the current line?                  (1)

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### Page 13

PHYSICAL SCIENCES: CHEMISTRY                  13
                                             (PAPER 2)            GR12 0625

EXPERIMENT III

5.6   Experiment I is repeated, but a catalyst is added, and the following graph is
      obtained.

                        A CATALYSED CHEMICAL REACTION

                                 Progress of the reaction

      5.6.1   Is the reaction EXOTHERMIC or ENDOTHERMIC?                                        (1)

      5.6.2   Which letter represents the activated complex?                                    (1)

      5.6.3   Give the value of the activation energy for the forward catalysed
              reaction.                                                                      (1)
                                                                                            [20]

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### Page 14

PHYSICAL SCIENCES: CHEMISTRY                  14
                                              (PAPER 2)            GR12 0625

QUESTION 6 (Start on a new page.)

The reaction between carbon disulfide CS2(g) and chlorine gas Cℓ2(g) reaches chemical
equilibrium in a closed container at constant temperature. The products that form are
carbon tetrachloride CCℓ4(g) and sulphur dichloride S2Cℓ2(g). The balanced equation for
this reaction is given below:

                  CS2(g) + 3Cℓ2(g) ⇌ CCℓ4(g) + S2Cℓ2(g)        ∆H < 0

Initially, an unknown quantity of CS2(g) and 5 moles of Cℓ2 are placed in a 2 dm3
container and allowed to reach equilibrium. The equilibrium mixture contains 0,8 mol of
CCℓ4. The equilibrium constant, Kc, for this reaction is 0,36.

6.1   State Le Chatelier's principle.                                                            (2)

6.2   Calculate the initial number of moles of CS2(g) required.                                  (8)

6.3   How will each of the following changes affect the yield of S2Cℓ2(g) at equilibrium?

      Write INCREASE, DECREASE, or REMAIN THE SAME and give a reason in
      terms of the reaction which is favoured.

      6.3.1   Carbon tetrachloride is removed from the system                                    (2)

      6.3.2   The volume of the container is increased                                           (2)

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### Page 15

PHYSICAL SCIENCES: CHEMISTRY                   15
                                                       (PAPER 2)            GR12 0625

6.4   The graph below shows the changes in the rate of the reaction after further
      changes were made to the equilibrium mixture above.

                                                                  Forward reaction:
                                                                  Reverse reaction:

         Rate (mol·s )
        -1

                                               Time (min)

      6.4.1              The equilibrium was disturbed at 5 minutes due to a change in the
                         concentration of CS2. Was this concentration INCREASED or
                         DECREASED?                                                                        (1)

      6.4.2              At 15 minutes the temperature was changed. Use Le Chatelier’s
                         principle to determine whether the temperature has INCREASED or
                         DECREASED. Explain the answer.                                                    (4)

      6.4.3              At what time does the system reach equilibrium after the temperature
                         change?                                                                        (1)
                                                                                                       [20]

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### Page 16

PHYSICAL SCIENCES: CHEMISTRY                   16
                                               (PAPER 2)            GR12 0625

QUESTION 7 (Start on a new page.)

Oxalic acid (H2C2O4) is an organic diprotic acid commonly found in plants such as
spinach. It is used in various industrial and laboratory applications, including cleaning,
bleaching, and as a standard solution in acid-base titrations.

When oxalic acid ionises in water, it follows the steps given below:

              STEP 1:        H2C2O4(aq) + H2O() → HC2O4-(aq) + H3O+(aq)
              STEP 2:        HC2O4⁻(aq) + H2O() → C2O4²⁻(aq) + H3O⁺(aq)

7.1   Define a weak acid.                                                                          (2)

7.2   Identify the acid-base conjugate pair in STEP 1.                                             (2)

7.3   Give a reason why oxalic acid is referred to as a diprotic acid.                             (1)

7.4   The oxalate ion (HC2O4⁻) can act as an ampholyte. Give a reason for this
      statement.                                                                                   (1)

7.5   In a volumetric flask 2,25 g of oxalic acid is added to water to make up a standard
      solution to 250 cm3.

      7.5.1    Calculate the concentration of the oxalic acid solution.                            (3)

      7.5.2    25 cm3 of the oxalic acid solution is titrated against sodium hydroxide. The
               average volume of NaOH required for neutralisation is 28,60 cm3.

                         H2C2O4(aq) + 2NaOH(aq) → Na2C2O4(aq) + 2H2O()

               Calculate the concentration of the sodium hydroxide.                                (4)

      7.5.3    Explain why phenolphthalein would be a suitable indicator for this reaction.        (2)

7.6   The reaction between EXCESS magnesium hydroxide (Mg(OH)₂), a slightly
      soluble base, and nitric acid (HNO3), occurs in aqueous solution, where it
      produces magnesium nitrate (Mg(NO3)2), a soluble salt and water, according to
      the following balanced equation below.

                    Mg(OH)₂(aq) + 2HNO₃(aq) → Mg(NO₃)₂(aq) + 2H₂O().

      0,05 dm3 of the Mg(OH)₂ solution has a concentration 0,115 mol.dm-3 and is added
      to 0,025 dm3 of a 0,095 mol.dm-3 HNO₃ solution.

      Calculate the pH of the FINAL solution.                                                  (10)
                                                                                               [25]

                                                                                  TOTAL:       150

                                                                                               END

### Page 17

PHYSICAL SCIENCES: CHEMISTRY                       1
                                                         (PAPER 2)            GR12 0624

                            DATA FOR PHYSICAL SCIENCES GRADE 12
                                    PAPER 2 (CHEMISTRY)

                      GEGEWENS VIR FISIESE WETENSKAPPE GRAAD 12
                                 VRAESTEL 2 (CHEMIE)

TABLE 1: PHYSICAL CONSTANTS/TABEL 1: FISIESE KONSTANTES

NAME/NAAM                                     SYMBOL/SIMBOOL                     VALUE/WAARDE
Standard pressure
                                                            p                            1,013 x 105 Pa
Standaarddruk
Molar gas volume at STP
                                                            Vm                            22,4 dm3∙mol-1
Molêre gasvolume by STD
Standard temperature
                                                            T                                  273 K
Standaardtemperatuur
Charge on electron
                                                             e                             -1,6 x 10-19 C
Lading op elektron
Avogadro’s constant
                                                            NA                          6,02 x 1023 mol-1
Avogadro-konstante

TABLE 2: FORMULAE/TABEL 2: FORMULES

     m                                                                 N
n                                                               n
     M                                                                 NA

     n                            m                                    V
c           OR/OF           c                                  n
     V                            MV                                   VM
 c a Va na
                                                                pH = - log[H3O+]
 cb Vb nb
Kw = [H3O+][OH-] = 1 x 10-14 at/by 298 K

E θcell  E θcathode  E θanode / E sel  Ekatode
                                                      
                                                    E anode

or/of
  
 Ecell  E θ reduction E θ oxidation/ Esel  Ereduksie
                                                           
                                                          Eoksidasie

or/of
                               
E cell  E oxidi sin g agent  E reducing agent / E sel  E oksideermiddel  E reduseermiddel
                                                    θ       θ                  θ

### Page 18

PHYSICAL SCIENCES: CHEMISTRY                                           2
                                                                                                                                                          (PAPER 2)             GR12 0625

                                TABLE 3: THE PERIODIC TABLE OF ELEMENTS/TABEL 3: DIE PERIODIEKE TABEL VAN ELEMENTE
       1                2            3              4              5           6           7           8            9           10          11           12           13            14          15           16           17      18
      (I)              (II)                                                                                                                                          (III)         (IV)         (V)         (VI)         (VII)   (VIII)
                                                                                               Atomic number/
                                                             KEY/SLEUTEL                         Atoomgetal
            1                                                                                                                                                                                                                         2
2,1         H                                                                                                                                                                                                                        He
            1                                                                                          29                                                                                                                             4
                                                             Electronegativity/                                         Symbol/
            3              4                                 Elektronegatiwiteit                 1,9   Cu               Simbool                                         5             6           7            8            9        10
1,0         Li   1,5      Be                                                                                                                                   2,0     B     2,5     C    3,0    N    3,5     O    4,0     F         Ne
                                                                                                       63,5
            7              9                                                                                                                                           11            12          14           16           19        20
        11               12                                                                                                                                            13            14          15           16           17        18
        Na               Mg
                                                                          Approximate relative atomic mass/                                                            Aℓ            Si          P            S            Cℓ        Ar
0,9              1,2                                                      Benaderde relatiewe atoommassa                                                       1,5           1,8          2,1         2,5          3,0
        23               24                                                                                                                                            27            28          31           32          35,5       40
        19                20             21             22         23          24          25          26           27           28          29          30            31           32           33          34            35        36
0,8     K        1,0      Ca   1,3       Sc   1,5       Ti   1,6   V     1,6   Cr    1,5   Mn    1,8   Fe     1,8   Co    1,8    Ni   1,9    Cu    1,6   Zn    1,6     Ga    1,8    Ge    2,0    As   2,4    Se    2,8     Br        Kr
        39                40             45             48         51          52          55          56           59           59         63,5         65            70           73           75          79            80        84
        37                38             39             40         41          42          43           44           45          46          47           48           49            50          51           52           53         54
0,8     Rb       1,0      Sr   1,2       Y    1,4       Zr         Nb    1,8   Mo    1,9   Tc    2,2   Ru     2,2   Rh    2,2   Pd    1,9   Ag     1,7   Cd    1,7     In    1,8    Sn    1,9   Sb    2,1    Te    2,5      I        Xe
        86                88             89             91         92          96                      101          103         106         108          112          115           119         122          128          127        131
        55                56          57             72             73          74          75          76           77          78          79           80           81            82          83          84            85        86
       Cs                Ba          La              Hf            Ta           W          Re          Os            Ir          Pt         Au           Hg            Tℓ           Pb           Bi          Po            At        Rn
0,7              0,9                          1,6                                                                                                              1,8           1,8          1,9         2,0          2,5
       133               137         139            179            181         184         186         190          192         195         197          201          204           207         209

        87                88             89
0,7     Fr       0,9     Ra              Ac
                         226
                                                                    58          59          60         61            62          63          64           65           66           67           68          69            70         71
                                                                   Ce           Pr         Nd          Pm           Sm          Eu          Gd           Tb           Dy           Ho            Er         Tm            Yb         Lu
                                                                   140         141         144                      150         152         157          159          163          165          167         169           173        175

                                                                    90         91           92         93           94          95          96           97            98           99          100         101           102        103
                                                                   Th          Pa           U          Np           Pu          Am          Cm           Bk            Cf           Es          Fm          Md            No          Lr
                                                                   232                     238

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