# Physical Sciences Grade 12 P2 NSC Supplementary 2015 QP

> Grade 12 Physical Sciences Paper 2 question paper from the NSC Supplementary Exam 2015 (English), 21 pages. Read online or download the free PDF.

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- Updated: 2026-09-27
- Subject: Physical Sciences
- Grade: Grade 12
- Document type: Question paper
- Year: 2015
- Exam period: NSC Supplementary Exam
- Paper: 2
- Curriculum: CAPS
- Pages: 21

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Physical Sciences · Grade 12 · NSC Supplementary Exam · 2015. Question paper, 21 pages. Read online or download the PDF.

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### Page 1

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                                  NATIONAL
                             SENIOR CERTIFICATE

                                    GRADE 12

                      PHYSICAL SCIENCES: CHEMISTRY (P2)

                             FEBRUARY/MARCH 2015

MARKS: 150

TIME: 3 hours

              This question paper consists of 17 pages and 4 data sheets.

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Physical Sciences/P2                         2                             DBE/Feb.–Mar. 2015
                                            NSC

INSTRUCTIONS AND INFORMATION

1.        Write your examination number and centre number in the appropriate spaces
          on the ANSWER BOOK.

2.        This question paper consists of TEN questions. Answer ALL the questions in
          the ANSWER BOOK.

3.        Start EACH question on a NEW page in the ANSWER BOOK.

4.        Number the answers correctly according to the numbering system used in this
          question paper.

5.        Leave ONE line between two subquestions, for example between
          QUESTION 2.1 and QUESTION 2.2.

6.        You may use a non-programmable calculator.

7.        You may use appropriate mathematical instruments.

8.        You are advised to use the attached DATA SHEETS.

9.        Show ALL formulae and substitutions in ALL calculations.

10.       Round off your final numerical answers to a minimum of TWO decimal places.

11.       Give brief motivations, discussions, et cetera where required.

12.       Write neatly and legibly.

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Physical Sciences/P2                           3                        DBE/Feb.–Mar. 2015
                                              NSC

QUESTION 1: MULTIPLE-CHOICE QUESTIONS

Four options are provided as possible answers to the following questions. Each
question has only ONE correct answer. Write only the letter (A–D) next to the question
number (1.1–1.10) in the ANSWER BOOK, for example 1.11. D.

1.1       Which ONE of the following compounds is an aldehyde?

          A     Pentanal

          B     Pentan-2-ol

          C     Pentan-2-one

          D     Ethyl propanoate                                                               (2)

1.2       Consider the reaction represented by the equation below:

                                   CH 3 CHCH 2 + H 2 → CH 3 CH 2 CH 3

          This reaction is an example of …

          A     hydration.

          B     dehydration.

          C     substitution.

          D     hydrogenation.                                                                 (2)

1.3       Which ONE of the following is a CORRECT description for a 0,1 mol∙dm-3
          hydrochloric acid solution?

          A     Dilute strong acid

          B     Dilute weak acid

          C     Concentrated weak acid

          D     Concentrated strong acid                                                       (2)

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Physical Sciences/P2                           4                       DBE/Feb.–Mar. 2015
                                              NSC

1.4       Eutrophication involves the following stages:

          (i) Increase in growth of algae
          (ii) Increase in nitrate concentration
          (iii) Death of fish
          (iv) Decrease in oxygen concentration

          Which ONE of the following CORRECTLY represents the order in which these
          stages occur?

          A     (i) (ii) (iii) (iv)

          B     (i) (ii) (iv) (iii)

          C     (ii) (i) (iii) (iv)

          D     (ii) (i) (iv) (iii)                                                              (2)

1.5       Consider the reaction represented by the balanced equation below:

                                       A 2 (g) + B 2 (g) → 2AB(g)

          The activation energy for the forward reaction is 180 kJ and that for the
          reverse reaction is 200 kJ.

          The heat of reaction (∆H) is ...

          A     + 20 kJ.

          B     - 20 kJ.

          C     + 380 kJ.

          D     - 380 kJ.                                                                        (2)

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Physical Sciences/P2                            5                        DBE/Feb.–Mar. 2015
                                               NSC

1.6       Consider the structural formula of a compound below.

                                H     H    H         O    H

                           H    C     C    C    O    C    C      H

                                H     H    H              H

          Which ONE of the following pairs of reactants can be used to prepare this
          compound in the laboratory?

          A     Propanoic acid and ethanol

          B     Propanoic acid and methanol

          C     Ethanoic acid and propan-1-ol

          D     Methanoic acid and propan-1-ol                                                    (2)

1.7       The reaction of an acid-base indicator, represented as HIn(aq), with H 2 O(ℓ)
          reaches equilibrium according to the following balanced equation:

                       HIn(aq) + H 2 O(ℓ) ⇌ H 3 O+(aq) + In-(aq)      ∆H > 0
                       yellow                           purple

          At equilibrium the colour of the solution is purple.

          Which ONE of the following will change the colour of the solution from purple
          to yellow?

          A     Add NaOH(aq)

          B     Add HCℓ(aq)

          C     Add water

          D     Increase the temperature                                                          (2)

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Physical Sciences/P2                     6                           DBE/Feb.–Mar. 2015
                                        NSC

1.8       Which ONE of the following metals will NOT react spontaneously with
          sulphuric acid?

          A     Zn

          B     Mg

          C     Cu

          D     Fe                                                                          (2)

1.9       A learner wants to electroplate a copper ring with nickel. He uses the
          experimental set-up shown in the simplified diagram below.

                                       Power
                                       source

                                                        Nickel rod

                         Ring

                                     Electrolyte

          Which ONE of the following is CORRECT?

                       ANODE       CATHODE         ELECTROLYTE
         A           Copper ring   Nickel rod         CuSO 4
         B           Nickel rod    Copper ring        CuSO 4
         C           Copper ring   Nickel rod         NiSO 4
         D           Nickel rod    Copper ring        NiSO 4                                (2)

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                                         NSC

1.10      Consider the equilibrium constants for the same reaction at two different
          temperatures below.

          298 K:       K c = 0,03

          318 K:       K c = 0,005

          Which ONE of the following is CORRECT?

                      HEAT OF        YIELD OF PRODUCTS AS THE
                     REACTION         TEMPERATURE INCREASES
          A            ∆H > 0                 Increases
          B              ∆H < 0                Decreases
          C              ∆H > 0                Decreases

          D              ∆H < 0           Remains the same
                                                                                            (2)
                                                                                            [20]

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Physical Sciences/P2                                    8                         DBE/Feb.–Mar. 2015
                                                       NSC

QUESTION 2 (Start on a new page.)

The letters A to F in the table below represent six organic compounds.

                           H           H
                       H           C       H
          A   H        C           C       C       H           B   2-methylbutanoic acid

                       H                   H

                       H       H       O       H       H                H    CH3 H    CH2CH3

          C   H        C       C       C       C       C   H   D   H    C    C    C   C     H

                       H       CH2CH3          H       H                H    CH3 H    CH2CH3

                                                                       H     H

          E   But-2-ene                                        F       C     C

                                                                       H     H   n

2.1       Write down the:

          2.1.1        NAME of the functional group of compound B                                        (1)

          2.1.2        Homologous series to which compound C belongs                                     (1)

          2.1.3        Type of polymerisation reaction that produces compound F                          (1)

2.2       Write down the IUPAC name of:

          2.2.1        The monomer used to prepare compound F                                            (1)

          2.2.2        Compound C                                                                        (2)

          2.2.3        Compound D                                                                        (2)

2.3       Write down the NAME or FORMULA of each product formed during the
          complete combustion of compound D.                                                             (2)

2.4       Write down the structural formula of:

          2.4.1        Compound B                                                                        (2)

          2.4.2        A CHAIN ISOMER of compound A                                                      (2)

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                                             NSC

2.5       A laboratory assistant uses bromine water to distinguish between
          compounds D and E. She adds bromine water to a sample of each in two
          different test tubes. She observes that the one compound decolourises the
          bromine water immediately, whilst the other one only reacts after placing the
          test tube in direct sunlight.

          Write down the:

          2.5.1        Letter (D or E) of the compound that will immediately decolourise
                       the bromine water                                                         (1)

          2.5.2        Name of the type of reaction that takes place in the test tube
                       containing compound D                                                     (1)

          2.5.3        Structural formula of the organic product formed in the test tube
                       containing compound E                                                     (2)
                                                                                                 [18]

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                                                   NSC

QUESTION 3 (Start on a new page.)

Learners use compounds A to C, shown in the table below, to investigate a factor
which influences the boiling point of organic compounds.

           A         CH 3 CH 2 CH 2 CH 3
           B         CH 3 CH 2 CH 2 CH 2 CH 3
           C         CH 3 CH 2 CH 2 CH 2 CH 2 CH 3

3.1       Which ONE of the compounds (A, B or C) has the highest boiling point?               (1)

3.2       For this investigation, write down the:

          3.2.1        Independent variable                                                   (1)

          3.2.2        Dependent variable                                                     (1)

3.3       Write down the name of the type of Van der Waals force that occurs between
          the molecules of compound B.                                                        (1)

3.4       How will the vapour pressure of 2-methylpentane compare to that of
          compound C? Write down only HIGHER THAN, LOWER THAN or
          EQUAL TO.                                                                           (1)

The learners now compare the boiling points of compounds D and E, shown in the
table below.

          D          CH 3 CH 2 CH 2 CH 2 CH 2 OH
          E          CH 3 CH 2 CH 2 COOH

3.5       How does the boiling point of compound D compare to that of compound E?
          Write down HIGHER THAN, LOWER THAN or EQUAL TO. Fully explain the
          answer.                                                                             (4)
                                                                                              [9]

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Physical Sciences/P2                           11                         DBE/Feb.–Mar. 2015
                                              NSC

QUESTION 4 (Start on a new page.)

In the flow diagram below, but-1-ene is used as starting material in the preparation of
compound A.

                                                    reaction 1
            CH3 ― CH2 ― CH = CH2
                                                  H2O; H2SO4
             reaction 2      HCℓ                                     Compound A

                                                  reaction 3
                     Compound B

4.1       Is but-1-ene a SATURATED or UNSATURATED compound? Give a reason
          for the answer.                                                                        (2)

4.2       Compound A is the major product formed in reaction 1.

          Write down the:

          4.2.1        Structural formula of compound A                                          (2)

          4.2.2        Type of reaction that takes place                                         (1)

4.3       For compound B, write down the:

          4.3.1        IUPAC name                                                                (2)

          4.3.2        Structural formula of the positional isomer                               (2)

4.4       For reaction 3, write down:

          4.4.1        TWO reaction conditions needed                                            (2)

          4.4.2        The type of reaction that occurs                                          (1)

          4.4.3        A balanced equation, using molecular formulae                             (3)
                                                                                                 [15]

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Physical Sciences/P2                           12                          DBE/Feb.–Mar. 2015
                                              NSC

QUESTION 5 (Start on a new page.)

A group of learners uses the reaction of EXCESS hydrochloric acid (HCℓ) with zinc
(Zn) to investigate factors which influence reaction rate. The balanced equation for the
reaction is:

                           Zn(s) + 2HCℓ(aq) → ZnCℓ 2 (aq) + H 2 (g)

They use the same volume of hydrochloric acid and 1,2 g of zinc in each of five
experiments. The reaction conditions and temperature readings before and after
completion of the reaction in each experiment are summarised in the table below.

                                     REACTION CONDITIONS
                                        Temperature (°C) State of division          Time
      Experiment       Concentration of
                                        Before   After    of the 1,2 g of            (s)
                        HCℓ (mol·dm-3)
                                                                Zn
          1                  0,5          20       34        granules                50
          2                  0,5          20       35         powder                 10
          3                  0,8          20       36         powder                  6
          4                  0,5          35       50        granules                 8
          5                  0,5          20       34        granules                11

5.1       Is the reaction between hydrochloric acid and zinc EXOTHERMIC or
          ENDOTHERMIC? Give a reason for the answer by referring to the data in the
          table.                                                                                  (2)

5.2       Give a reason for the difference in reaction rate observed for Experiments 1
          and 2.                                                                                  (1)

5.3       The learners compare the results of Experiments 1 and 3 to draw a
          conclusion regarding the effect of concentration on reaction rate. Give a
          reason why this is not a fair comparison.                                               (1)

5.4       How does the rate of the reaction in Experiment 5 compare to that in
          Experiment 1? Write down FASTER THAN, SLOWER THAN or EQUAL TO.

          Write down the factor responsible for the difference in the rate of reaction and
          fully explain, by referring to the collision theory, how this factor affects
          reaction rate.                                                                          (5)

5.5       Calculate the rate at which the hydrochloric acid reacts in Experiment 4 in
          mol·s-1.                                                                                (6)
                                                                                                  [15]

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                                                    NSC

QUESTION 6 (Start on a new page.)

Pure hydrogen iodide, sealed in a 2 dm3 container at 721 K, decomposes according to
the following balanced equation:

                       2HI(g) ⇌ H 2 (g) + I 2 (g)         ∆H = + 26 kJ∙mol-1

The graph below shows how reaction rate changes with time for this reversible
reaction.

                         Reaction rate

                                    0       5             12   15    17   20
                                                    Time (minutes)

6.1       Write down the meaning of the term reversible reaction.                                     (1)

6.2       How does the concentration of the reactant change between the 12th and the
          15th minute? Write down only INCREASES, DECREASES or NO CHANGE.                             (1)

6.3       The rates of both the forward and the reverse reactions suddenly change at
          t = 15 minutes.

          6.3.1        Give a reason for the sudden change in reaction rate.                          (1)

          6.3.2        Fully explain how you arrived at the answer to QUESTION 6.3.1.                 (3)

The equilibrium constant (K c ) for the forward reaction is 0,02 at 721 K.

6.4       At equilibrium it is found that 0,04 mol HI(g) is present in the container.
          Calculate the concentration of H 2 (g) at equilibrium.                                      (6)

6.5       Calculate the equilibrium constant for the reverse reaction.                                (1)

6.6       The temperature is now increased to 800 K. How will the value of the
          equilibrium constant (K c ) for the forward reaction change? Write down only
          INCREASES, DECREASES or REMAINS THE SAME.                                                   (1)
                                                                                                      [14]

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Physical Sciences/P2                               14                             DBE/Feb.–Mar. 2015
                                                  NSC

QUESTION 7 (Start on a new page.)

7.1       Sulphuric acid is a diprotic acid.

          7.1.1         Define an acid in terms of the Lowry-Brønsted theory.                            (2)

          7.1.2         Give a reason why sulphuric acid is referred to as a diprotic acid.              (1)

7.2       The hydrogen carbonate ion can act as both an acid and a base. It reacts with
          water according to the following balanced equation:

                               HCO3− (aq) + H 2 O(ℓ) ⇌ H 2 CO 3 (aq) + OH-(aq)

          7.2.1         Write down ONE word for the underlined phrase.                                   (1)

          7.2.2          HCO3− (aq) acts as base in the above reaction. Write down the
                        formula of the conjugate acid of HCO3− (aq).                                     (1)

7.3       A learner accidentally spills some sulphuric acid of concentration 6 mol∙dm-3
          from a flask on the laboratory bench. Her teacher tells her to neutralise the
          spilled acid by sprinkling sodium hydrogen carbonate powder onto it. The
          reaction that takes place is: (Assume that the H 2 SO 4 ionises completely.)

                     H 2 SO 4 (aq) + 2NaHCO 3 (s) → Na 2 SO 4 (aq) + 2H 2 O(ℓ) + 2CO 2 (g)

          The fizzing, due to the formation of carbon dioxide, stops after the learner has
          added 27 g sodium hydrogen carbonate to the spilled acid.

          7.3.1         Calculate the volume of sulphuric acid that spilled. Assume that all
                        the sodium hydrogen carbonate reacts with all the acid.                          (6)

          The learner now dilutes some of the 6 mol∙dm-3 sulphuric acid solution in the
          flask to 0,1 mol∙dm-3.

          7.3.2         Calculate the volume of the 6 mol∙dm-3 sulphuric acid solution
                        needed to prepare 1 dm3 of the dilute acid.                                      (2)

          During a titration 25 cm3 of the 0,1 mol∙dm-3 sulphuric acid solution is added to
          an Erlenmeyer flask and titrated with a 0,1 mol∙dm-3 sodium hydroxide
          solution.

          7.3.3         The learner uses bromothymol blue as indicator. What is the
                        purpose of this indicator?                                                       (1)

          7.3.4         Calculate the pH of the solution in the flask after the addition of
                        30 cm3 of sodium hydroxide. The endpoint of the titration is not yet
                        reached at this point.                                                           (8)
                                                                                                         [22]

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                                              NSC

QUESTION 8 (Start on a new page.)

A learner conducts two experiments to investigate the reaction between copper (Cu)
and a silver nitrate solution, AgNO 3 (aq).

EXPERIMENT 1

The learner adds a small amount of copper (Cu) powder to a test tube containing silver
nitrate solution, AgNO 3 (aq). The solution changes from colourless to blue after a while.

          Before addition of Cu(s)                        After addition of Cu(s)

                       Colourless AgNO3(aq)                              Blue Cu(NO3)2(aq)

8.1       Define the term oxidising agent.                                                               (2)

8.2       Explain why the solution turns blue by referring to the relative strength of
          oxidising agents.                                                                              (4)

EXPERIMENT 2
The learner now sets up a galvanic cell as shown below. The cell functions under
standard conditions.
                                                  V

                                              A       B
                         Cu(s)                                            Ag(s)

                                 Cu2+(aq)                      Ag+(aq)

8.3       Write down the energy conversion that takes place in this cell.                                (1)

8.4       In which direction (A or B) will ANIONS move in the salt bridge?                               (1)

8.5       Calculate the emf of the above cell under standard conditions.                                 (4)

8.6       Write down the balanced equation for the net cell reaction that takes place in
          this cell.                                                                                     (3)

8.7       How will the addition of 100 cm3 of a 1 mol ⋅ dm-3 silver nitrate solution to the
          silver half-cell influence the initial emf of this cell? Write down only
          INCREASES, DECREASES or REMAINS THE SAME.                                                      (1)
                                                                                                         [16]

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Physical Sciences/P2                            16                            DBE/Feb.–Mar. 2015
                                               NSC

QUESTION 9 (Start on a new page.)

The apparatus below is used to demonstrate the electrolysis of a concentrated sodium
chloride solution. Both electrodes are made of carbon. A few drops of universal
indicator are added to the electrolyte. The equation for the net cell reaction is:

                     2NaCℓ(aq) + 2H 2 O(ℓ) → Cℓ 2 (g) + H 2 (g) + 2NaOH(aq)

                                            Power
                                            source

            Electrode Y                                        Electrode X

                                                                 NaCℓ(aq) and
                                                                 universal indicator

Initially the solution has a green colour. Universal indicator becomes red in acidic
solutions and purple in alkaline solutions.

9.1       Define the term electrolyte.                                                               (2)

When the power source is switched on, the colour of the electrolyte around electrode Y
changes from green to purple.

9.2       Write down the:

          9.2.1        Half-reaction that takes place at electrode Y                                 (2)

          9.2.2        NAME or FORMULA of the gas released at electrode X                            (1)

9.3       Refer to the Table of Standard Reduction Potentials to explain why hydrogen
          gas, and not sodium, is formed at the cathode of this cell.                                (2)
                                                                                                     [7]

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                                              NSC

QUESTION 10 (Start on a new page.)

Reactions A, B, C and D in the flow diagram below represent the manufacturing of
Fertiliser X.

       SO2(g)

                       A                B                   C                 D
                            SO3(g)           H2S2O7(ℓ)           H2SO4(ℓ)           Fertiliser X

        O2(g)

10.1      Write down the name of the industrial preparation of sulphuric acid.                     (1)

10.2      Write down the:

          10.2.1       NAME or FORMULA of the catalyst used in reaction A                          (1)

          10.2.2       Balanced equation for reaction C                                            (3)

10.3      Ammonia is one of the reactants used in reaction D to make Fertiliser X.

          Write down:

          10.3.1       A balanced equation for reaction D                                          (3)

          10.3.2       The NAME of Fertiliser X                                                    (1)

10.4      Two 50 kg bags, containing fertilisers P and Q respectively, are labelled as
          follows:

          Fertiliser P:    5 : 2 : 3 (25)
          Fertiliser Q:    1 : 3 : 4 (20)

          10.4.1       What do the numbers (25) and (20) on the labels represent?                  (1)

          10.4.2       Using calculations, determine which fertiliser (P or Q) contains the
                       greater mass of potassium.                                                  (4)
                                                                                                   [14]

                                                                                  TOTAL:           150

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                                                                  NSC

                               DATA FOR PHYSICAL SCIENCES GRADE 12
                                       PAPER 2 (CHEMISTRY)

                       GEGEWENS VIR FISIESE WETENSKAPPE GRAAD 12
                                  VRAESTEL 2 (CHEMIE)

TABLE 1: PHYSICAL CONSTANTS/TABEL 1: FISIESE KONSTANTES

NAME/NAAM                                      SYMBOL/SIMBOOL                          VALUE/WAARDE
Standard pressure
                                                               pθ                        1,013 x 105 Pa
Standaarddruk
Molar gas volume at STP
                                                               Vm                        22,4 dm3∙mol-1
Molêre gasvolume by STD
Standard temperature
                                                               Tθ                                273 K
Standaardtemperatuur
Charge on electron
                                                                e                         -1,6 x 10-19 C
Lading op elektron
Avogadro's constant
                                                               NA                       6,02 x 1023 mol-1
Avogadro-konstante

TABLE 2: FORMULAE/TABEL 2: FORMULES

       m                                                         N
  n=                                                        n=
       M                                                         NA
       n                                 m                        V
  c=         or/of                  c=                      n=
       V                                 MV                       Vm
  c a v a na
         =                                                  pH = -log[H 3 O+]
  c b v b nb

  K w = [H 3 O+][OH-] = 1 x 10-14 at/by 298 K

  Eθcell = Eθcathode − Eθanode / E θsel = E katode
                                            θ
                                                   − E θanode

  or/of
  E θcell = E reduction
              θ
                        − E θoxidation / E θsel = E reduksie
                                                    θ
                                                             − E θoksidasie

  or/of
  E θcell = E oxidising
              θ                   θ                  θ       θ                  θ
                        agent − E reducing agent / E sel = E oksideermiddel − E reduseermiddel

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Physical Sciences/P2
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                                                                                                            NSC
                                                                    TABLE 3: THE PERIODIC TABLE OF ELEMENTS
                                                                   TABEL 3: DIE PERIODIEKE TABEL VAN ELEMENTE

       1           2           3           4           5           6           7           8           9           10          11           12       13          14         15           16          17         18
      (I)         (II)                                                                                                                              (III)       (IV)        (V)         (VI)        (VII)      (VIII)
                                                                                   Atomic number
        1                                        KEY/SLEUTEL                         Atoomgetal                                                                                                                   2
2,1    H                                                                                                                                                                                                        He
        1                                                                                  29                                                                                                                    4
        3           4                             Electronegativity                                        Symbol                                        5           6           7           8           9       10
                                                                                     1,9   Cu
1,0    Li   1,5    Be                            Elektronegatiwiteit
                                                                                           63,5
                                                                                                           Simbool                                2,0    B    2,5    C    3,0    N    3,5   O     4,0    F      Ne
        7           9                                                                                                                                   11          12          14          16          19       20
       11           12                                                                                                                                  13          14          15          16          17       18
0,9   Na    1,2   Mg                                           Approximate relative atomic mass                                                   1,5   Aℓ    1,8   Si    2,1    P    2,5    S    3,0   Cℓ       Ar
       23           24                                         Benaderde relatiewe atoommassa                                                           27          28          31          32          35,5     40
       19           20         21          22          23          24          25          26          27          28          29           30          31          32          33          34           35      36
0,8    K    1,0    Ca    1,3   Sc    1,5   Ti    1,6    V    1,6   Cr    1,5   Mn    1,8   Fe    1,8   Co    1,8   Ni    1,9   Cu     1,6   Zn    1,6   Ga    1,8   Ge    2,0   As    2,4   Se    2,8   Br       Kr
       39           40         45          48          51          52          55          56          59          59          63,5         65          70          73          75          79          80       84
       37           38         39          40          41          42          43          44          45          46           47          48          49          50          51          52          53       54
0,8   Rb    1,0    Sr    1,2   Y     1,4   Zr          Nb    1,8   Mo    1,9   Tc    2,2   Ru    2,2   Rh    2,2   Pd    1,9   Ag     1,7   Cd    1,7   In    1,8   Sn    1,9   Sb    2,1   Te    2,5    I       Xe
       86           88         89          91          92          96                      101         103         106         108          112         115         119         122         128         127      131
       55           56         57          72          73          74          75          76          77          78          79            80          81          82          83          84          85       86
0,7   Cs    0,9    Ba          La    1,6   Hf          Ta          W           Re          Os           Ir         Pt          Au           Hg    1,8   Tℓ    1,8   Pb    1,9   Bi    2,0   Po    2,5   At      Rn
      133          137         139         179         181         184         186         190         192         195         197          201         204         207         209
       87           88         89
0,7    Fr   0,9    Ra          Ac                      58          59      60              61          62          63          64           65          66          67          68          69          70      71
                   226
                                                   Ce          Pr          Nd         Pm          Sm              Eu       Gd           Tb          Dy          Ho          Er          Tm          Yb         Lu
                                                   140         141         144                     150            152      157          159         163         165         167         169         173        175
                                                       90          91      92              93          94          95          96           97          98          99      100         101         102        103
                                                   Th          Pa              U       Np          Pu         Am          Cm            Bk          Cf          Es          Fm          Md          No          Lr
                                                   232                     238

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Physical Sciences/P2                                                                                                  3                                  DBE/Feb.–Mar. 2015
                                                                                                                     NSC
                                                                           TABLE 4A: STANDARD REDUCTION POTENTIALS
                                                                           TABEL 4A: STANDAARD-REDUKSIEPOTENSIALE
                                                                                                                                                θ
                                                                                 Half-reactions/Halfreaksies                                    E (V)
                                                                                                           −               −
                                                                                         F 2 (g) + 2e            ⇌    2F                        + 2,87
                                                                                                3+         −                   2+
                                                                                           Co           +e       ⇌    Co                        + 1,81
                                                                                                +
                                                                                 H 2 O 2 + 2H +2e−               ⇌    2H 2 O                    +1,77
                                                                                   −     +                                     2+
                                                                               MnO 4 + 8H + 5e−                  ⇌    Mn             + 4H 2 O   + 1,51
                                                                                                             −                 −
                                                                                        Cℓ 2 (g) + 2e            ⇌    2Cℓ                       + 1,36
                                                                                    2−     +                                    3+
                                                                             Cr 2 O 7 + 14H + 6e−                ⇌    2Cr            + 7H 2 O   + 1,33
                                                                                               +           −
                                                                                O 2 (g) + 4H + 4e                ⇌    2H 2 O                    + 1,23
                                                                                                +            −                 2+
                                                                                MnO 2 + 4H + 2e                  ⇌    Mn             + 2H 2 O   + 1,23
                                                                                          2+
                                                                                        Pt + 2e−                 ⇌    Pt                        + 1,20
                                                                                                             −                 −
                                                                                        Br 2 (ℓ) + 2e            ⇌    2Br                       + 1,07
                                                                                   −     +
                                                                                NO 3 + 4H + 3e−                  ⇌    NO(g) + 2H 2 O            + 0,96
                                                                                               2+            −
                                                                                         Hg         + 2e         ⇌    Hg(ℓ)                     + 0,85

                                                                                                                                                            Increasing reducing ability/Toenemende reduserende vermoë
                                                                                                    +
                                                                                            Ag + e−              ⇌    Ag                        + 0,80

             Increasing oxidising ability/Toenemende oksiderende vermoë
                                                                                    −     +
                                                                                 NO 3 + 2H + e−                  ⇌    NO 2 (g) + H 2 O          + 0,80
                                                                                                3+                         2+
                                                                                           Fe           + e−     ⇌    Fe                        + 0,77
                                                                                               +
                                                                                O 2 (g) + 2H + 2e−               ⇌    H2O2                      + 0,68
                                                                                                           −               −
                                                                                              I 2 + 2e           ⇌    2I                        + 0,54
                                                                                                    +      −
                                                                                            Cu + e               ⇌    Cu                        + 0,52
                                                                                               +
                                                                                 SO 2 + 4H + 4e−                 ⇌    S + 2H 2 O                + 0,45
                                                                                 2H 2 O + O 2 + 4e−              ⇌    4OH−                      + 0,40
                                                                                               2+            −
                                                                                         Cu         + 2e         ⇌    Cu                        + 0,34
                                                                                   2−           +
                                                                                SO 4 + 4H + 2e−                  ⇌    SO 2 (g) + 2H 2 O         + 0,17
                                                                                                2+         −                   +
                                                                                           Cu           +e       ⇌    Cu                        + 0,16
                                                                                               4+            −                 2+
                                                                                          Sn        + 2e         ⇌    Sn                        + 0,15
                                                                                               +
                                                                                    S + 2H + 2e−                 ⇌    H 2 S(g)                  + 0,14
                                                                                                +            −
                                                                                          2H + 2e                ⇌    H 2 (g)                    0,00
                                                                                               3+
                                                                                          Fe        + 3e−        ⇌    Fe                        − 0,06
                                                                                               2+
                                                                                          Pb        + 2e−        ⇌    Pb                        − 0,13
                                                                                               2+
                                                                                          Sn        + 2e−        ⇌    Sn                        − 0,14
                                                                                               2+
                                                                                          Ni        + 2e−        ⇌    Ni                        − 0,27
                                                                                               2+            −
                                                                                         Co         + 2e         ⇌    Co                        − 0,28
                                                                                               2+
                                                                                         Cd         + 2e−        ⇌    Cd                        − 0,40
                                                                                                3+         −               2+
                                                                                           Cr           +e       ⇌    Cr                        − 0,41
                                                                                               2+
                                                                                          Fe        + 2e−        ⇌    Fe                        − 0,44
                                                                                               3+
                                                                                          Cr        + 3e−        ⇌    Cr                        − 0,74
                                                                                               2+
                                                                                          Zn        + 2e−        ⇌    Zn                        − 0,76
                                                                                                             −                              −
                                                                                        2H 2 O + 2e              ⇌    H 2 (g) + 2OH             − 0,83
                                                                                               2+
                                                                                          Cr        + 2e−        ⇌    Cr                        − 0,91
                                                                                              2+
                                                                                         Mn         + 2e−        ⇌    Mn                        − 1,18
                                                                                               3+
                                                                                          Aℓ        + 3e−        ⇌    Aℓ                        − 1,66
                                                                                              2+           −
                                                                                         Mg         + 2e         ⇌    Mg                        − 2,36
                                                                                                    +
                                                                                            Na + e−              ⇌    Na                        − 2,71
                                                                                               2+
                                                                                         Ca         + 2e−        ⇌    Ca                        − 2,87
                                                                                               2+            −
                                                                                          Sr + 2e                ⇌    Sr                        − 2,89
                                                                                               2+
                                                                                          Ba        + 2e−        ⇌    Ba                        − 2,90
                                                                                                    +        -
                                                                                            Cs + e               ⇌    Cs                        - 2,92
                                                                                                    +
                                                                                               K + e−            ⇌    K                         − 2,93
                                                                                                    +
                                                                                               Li + e−           ⇌    Li                        − 3,05
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