# Physical Sciences Grade 12 Paper 2 NSC November 2014 Memo

> Grade 12 Physical Sciences Paper 2 memorandum from the NSC November Exam 2014, 20 pages. Read online or download the free PDF.

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- Subject: Physical Sciences
- Grade: Grade 12
- Document type: Memorandum
- Year: 2014
- Exam period: NSC November Exam
- Paper: 2
- Curriculum: CAPS
- Pages: 20

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Physical Sciences · Grade 12 · NSC November Exam · 2014. Memorandum, 20 pages. Read online or download the PDF.

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                                       NATIONAL
                                  SENIOR CERTIFICATE
                                      NASIONALE
                                  SENIOR SERTIFIKAAT

                                        GRADE/GRAAD 12

                          PHYSICAL SCIENCES: CHEMISTRY (P2)
                           FISIESE WETENSKAPPE: CHEMIE (V2)

                                         NOVEMBER 2014

                                         MEMORANDUM

MARKS/PUNTE: 150

                        This memorandum consists of 20 pages.
                      Hierdie memorandum bestaan uit 20 bladsye.

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Physical Sciences P2/Fisiese Wetenskappe V2     2                                DBE/November 2014
                                      NSC/NSS – Memorandum

QUESTION 1 / VRAAG 1

1.1      C                                                                                              (2)

1.2      B                                                                                              (2)

1.3      D                                                                                              (2)

1.4      D                                                                                              (2)

1.5      A                                                                                              (2)

1.6      B                                                                                              (2)

1.7      B                                                                                              (2)

1.8      A                                                                                              (2)

1.9      D                                                                                              (2)

1.10     C                                                                                               (2)
                                                                                                          [20]

QUESTION 2 / VRAAG 2

2.1
2.1.1    B                                                                                               (1)

2.1.2    E                                                                                               (1)

2.1.3    F                                                                                               (1)

2.2
2.2.1    2-bromo-3-chloro-4-methylpentane
         2-bromo-3-chloro-4-metielpentaan / 2-broom-3-chloor-4-metielpentaan
         Marking criteria / Nasienriglyne:
         •   Correct stem i.e. pentane. / Korrekte stam d.i. pentaan. 
         •   All substituents correctly identified. / Alle substituente korrek geïdentifiseer. 
         •   Substituents correctly numbered, in alphabetical order, hyphens and commas
             correctly used. 
             Substituente korrek genommer, in alfabetiese volgorde, koppeltekens en
             kommas korrek gebruik.                                                                       (3)

2.2.2    Ethene / Eteen                                                                                  (1)

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Physical Sciences P2/Fisiese Wetenskappe V2        3                                   DBE/November 2014
                                      NSC/NSS - Memorandum

2.3                                           H              Marking criteria / Nasienriglyne:
2.3.1                                                        • Six saturated C atoms in
                                         H    C   H             longest chain i.e. hexane. 
                                                                Ses versadigde C-atome in
                H       H       H    H            H             langste ketting d.i. heksaan.
                                                           • Three methyl substituents on
                                                                second C and fourth C. 
         H      C       C       C    C        C   C      H      Drie metielsubstituente op
                                                                tweede C en vierde C.
                H       H            H            H

                        H       C   H H       C   H
                                H             H
         Notes / Aantekeninge:
         • If correct structure, but H atoms omitted / Indien korrekte struktuur, maar H-atome
           weggelaat:                                                         Max / Maks. 1
                                                                                            2
         • Condensed or semi-structural formula:
           Gekondenseerde of semistruktuurformule:                            Max./Maks. 1
                                                                                           2
         • Molecular formula / Molekulêre formule:                                       0
                                                                                                          (2)
                                                                                           2

2.3.2                       H       H                Marking criteria / Nasienriglyne:
              H     H           O                     • Whole structure correct / Hele struktuur
         H    C     C       C   C    C       H         korrek: 2
                                                                  2
              H     H       H        H                • Only functional group correct / Slegs
                                                        funksionele groep korrek: 1
                                                                                    2
         Notes / Aantekeninge:
         • If two or more functional groups/Indien twee of meer funksionele groepe:            0
                                                                                                   2
         •   Condensed or semi-structural formula:
             Gekondenseerde of semistruktuurformule:                              Max / Maks 1
                                                                                               2
         •   Molecular formula / Molekulêre formule:                                         0
                                                                                               2          (2)

2.4
2.4.1    (Compounds with) the same molecular formula  but different functional
         goups / different homologous series. 
         (Verbindings met) dieselfde molekulêre formule, maar verskillende
         funksionele groepe / verskillende homoloë reekse.                                                (2)

2.4.2    B&F                                                                                              (1)
                                                                                                          [14]

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Physical Sciences P2/Fisiese Wetenskappe V2        4                                 DBE/November 2014
                                      NSC/NSS - Memorandum

QUESTION 3 / VRAAG 3

3.1      ANY ONE / ENIGE EEN:
         • Alkanes have ONLY single bonds. 
           Alkane het SLEGS enkelbindings.
         • Alkanes have single bonds between C atoms.
           Alkane het enkelbindings tussen C-atome.
         •       Alkanes have no double OR triple bonds OR multiple bonds.
         •       Alkane het geen dubbel- OF trippelbindings OF meervoudige bindings nie.
         •       Alkanes contain the maximum number of H atoms bonded to C atoms.
                 Alkane bevat die maksimum getal H-atome gebind aan C-atome.                            (1)

3.2
3.2.1    ANY ONE / ENIGE EEN:

          ─C─O─H                       ─ C ─ OH           – OH                –O–H

         R ─ OH                         R─O─H
                                                                                                        (1)

3.2.2                  H                     Marking criteria / Nasienriglyne:
                                             • - OH group on second C atom of longest
                   H   C   H                     chain. 
                                                 - OH-groep op tweede C-atoom van langste
                   H       H                     ketting.
                                             • Tertiary group consisting of four C atoms
             H     C   C   C    H              with methyl group on 2nd C atom. 
                                                 Tersiêre groep bestaande uit vier C-atome
                   H       H
                                                 met metielgroep op 2de C-atoom.
                       O                     • If two or more functional groups / Indien
                       H                           twee of meer funksionele groepe: 0
                                                                                          2
         Notes / Aantekeninge:
         • Accept / Aanvaar – OH
         • If correct structure and number of bonds, but H atoms omitted / Indien korrekte
            struktuur en getal bindings, maar H-atome weggelaat:          Max / Maks. 1
                                                                                         2
         • Condensed or semi-structural formula / Gekondenseerde of
            semistruktuurformule:                                         Max / Maks. 1
                                                                                          2
         • Molecular formula / Molekulêre formule:                                      0
                                                                                                        (2)
                                                                                          2

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Physical Sciences P2/Fisiese Wetenskappe V2        5                              DBE/November 2014
                                      NSC/NSS - Memorandum

3.3
3.3.1
                Criteria for investigative question / Riglyne vir ondersoekende vraag:
                The dependent and independent variables are stated.
                                                                                                
                Die afhanklike en onafhanklike veranderlikes is genoem.
        -       Ask a question about the relationship between the independent and
                dependent variables.
                                                                                                
                Vra 'n vraag oor die verwantskap tussen die onafhanklike en afhanklike
                veranderlikes.

            Examples / Voorbeelde:
            •  How does an increase in chain length / molecular size / molecular
               structure / molecular mass / surface area influence boiling point?
               Hoe beïnvloed 'n toename in kettinglengte / molekulêre grootte /
               molekulêre struktuur / molekulêre massa / reaksieoppervlak die
               kookpunt?
            •  What is the relationship between chain length / molecular size / molecular
               structure / molecular mass / surface area and boiling point?
               Wat is die verwantskap tussen kettinglengte / molekulêre grootte /
               molekulêre struktuur / molekulêre massa / oppervlakte en kookpunt?                    (2)
3.3.2       •  Structure / Struktuur:
               The chain length / molecular size / molecular structure / molecular mass /
               surface area increases. 
               Die kettinglengte / molekulêre grootte / molekulêre struktuur / molekulêre
               massa / oppervlakte neem toe.
            • Intermolecular forces / Intermolekulêre kragte:
               Increase in strength of intermolecular forces / induced dipole / London /
               dispersion / Van der Waals forces. 
               Toename in sterkte van intermolekulêre kragte / geïnduseerde
               dipoolkragte / London-kragte / dispersiekragte / Van der Waalskragte.
            • Energy / Energie:
               More energy needed to overcome / break intermolecular forces. 
                Meer energie benodig om intermolekulêre kragte te oorkom / breek.
            OR / OF
            • Structure / Struktuur:
               From propane to methane the chain length / molecular size / molecular
               structure / molecular mass / surface area decreases. 
               Van propaan na metaan neem die kettinglengte / molekulêre grootte /
               molekulêre struktuur / molekulêre massa / oppervlakte af.
            • Intermolecular forces / Intermolekulêre kragte:
               Decrease in strength of intermolecular forces / induced dipole forces /
               London forces / dispersion forces. 
               Afname in sterkte van intermolekulêre kragte / geïnduseerde dipoolkragte
               / London-kragte / dispersiekragte.
            • Energy / Energie:
               Less energy needed to overcome / break intermolecular forces. 
               Minder energie benodig om intermolekulêre kragte te oorkom / breek.                   (3)

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Physical Sciences P2/Fisiese Wetenskappe V2        6                                DBE/November 2014
                                      NSC/NSS - Memorandum

3.4      •   Between propane molecules are London forces / dispersion forces /
             induced dipole forces. 
             Tussen propaanmolekule is Londonkragte / dispersiekragte /
             geïnduseerde dipoolkragte.
         •   Between propan-1-ol molecules are London forces / dispersion forces /
             induced dipole forces and hydrogen bonds. 
             Tussen propan-1-ol molekule is Londonkragte / dispersiekragte /
             geïnduseerde dipoolkragte en waterstofbindings.
         •   Hydrogen bonds / Forces between alcohol molecules are stronger or need
             more energy than London forces / dispersion forces / induced dipole
             forces. 
             Waterstofbindings / Kragte tussen alkoholmolekule is sterker of benodig
             meer energie om oorkom te word as Londonkragte / dispersiekragte /
             geïnduseerde dipoolkragte.

         OR/OF
         Between propane molecules are weak London forces / dispersion forces /
         induced dipole forces  and between propan-1-ol molecules are strong
         hydrogen bonds. 
         Tussen propaanmolekule is swak Londonkragte / dispersiekragte /
         geïnduseerde dipoolkragte       en tussen propan-1-olmolekule is sterk                         (3)
         waterstofbindings.                                                                            [12]
QUESTION 4 / VRAAG 4

4.1
4.1.1    Substitution / chlorination / halogenation 
         Substitusie / chlorering / halogenering / halogenasie                                         (1)
4.1.2    Substitution / hydrolysis 
         Substitusie / hidrolise                                                                       (1)

4.2
4.2.1    Hydrogenation / Hidrogenasie / Hidrogenering                                                 (1)

4.2.2         H              H                              H   H      H
                                                                             
                                        
         H    C     C     C       + H       H          H     C   C      C    H
              H     H         H                              H   H      H
         Notes / Aantekeninge:
         • Ignore/Ignoreer ⇌
         • Accept H 2 if condensed. / Aanvaar H 2 as gekondenseerd.
         • Any additional reactants and/or products
             Enige addisionele reaktanse en / of produkte:               Max./Maks. 2
                                                                                        3
         •   Accept coefficients that are multiples.
             Aanvaar koëffisiënte wat veelvoude is.
         •   Molecular / condensed formulae
             Molekulêre-/ gekondenseerde formule:                        Max./Maks. 2
                                                                                        3              (3)

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Physical Sciences P2/Fisiese Wetenskappe V2        7                                     DBE/November 2014
                                      NSC/NSS - Memorandum

4.3           Cℓ H      H                Marking criteria / Nasienriglyne:
                                         • Whole structure correct:/ Hele struktuur korrek: 2
         H    C    C    C    H                                                                     2
                                         • Only ONE Cℓ atom as functional group. / Slegs
              H    H    H                   EEN Cℓ-atoom as funksionele groep. 1
                                                                                         2
         Notes / Aantekeninge:.
         • Condensed or semi-structural formula
             Gekondenseerde of semistruktuurformule: Max./Maks. 1
                                                                        2
         • Molecular formula. / Molekulêre formule: 0
                                                          2
         • If functional group is incorrect. / Indien funksionele groep verkeerd is: 0                   (2)
                                                                                         2

4.4
4.4.1    Esterification / Condensation 
         Verestering / Esterifikasie / Kondensasie                                                       (1)

4.4.2    (Concentrated) H 2 SO 4 / (Concentrated) sulphuric acid 
         (Gekonsentreerde) H 2 SO 4 / (Gekonsentreerde) swawelsuur of swaelsuur                          (1)

4.4.3                                               Marking criteria / Nasienriglyne:
              H    H    H         O     H
                                                     • Whole structure correct / Hele struktuur
        H     C    C    C    O    C     C    H        korrek: 2
                                                                 2
                                                     • Only functional group correct / Slegs
              H    H    H               H
                                                       funksionele groep korrek: 1
                                                                                   2
         Notes / Aantekeninge:
         • If two or more functional groups/Indien twee of meer funksionele groepe:            0
                                                                                                   2
         •    Condensed or semi-structural formula:
              Gekondenseerde of semistruktuurformule:                          Max./Maks. 1
                                                                                           2
         •    Molecular formula / Molekulêre formule:                                    0
                                                                                           2
         •    If functional group is incorrect/Indien funksionele groep verkeerd is:     0
                                                                                                         (2)
                                                                                           2

4.4.4    Propyl  ethanoate 
         Propieletanoaat                                                                                 (2)

4.5      Sulphuric acid / H 2 SO 4 / Phosphoric acid / H 3 PO 4 
         Swawelsuur / Swaelsuur / H 2 SO 4 / Fosforsuur / H 3 PO 4                                        (1)
                                                                                                         [15]

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Physical Sciences P2/Fisiese Wetenskappe V2        8                               DBE/November 2014
                                      NSC/NSS - Memorandum

QUESTION 5 / VRAAG 5

5.1       ONLY ANY ONE OF/ SLEGS ENIGE EEN VAN:
          • Change in concentration of products / reactants  per (unit) time. 
            Verandering in konsentrasie van produkte / reaktanse per (eenheids)tyd.
          •   Rate of change in concentration. 
              Tempo van verandering in konsentrasie.
          •   Change in amount / number of moles / volume / mass of products or
              reactants per (unit) time.
              Verandering in hoeveelheid / getal mol/volume / massa van produkte of
              reaktanse per (eenheids)tyd.
          •   Amount / number of moles / volume / mass of products formed or
              reactants used per (unit) time.
              Hoeveelheid / getal mol / volume / massa van produkte gevorm of
              reaktanse gebruik per (eenheids)tyd.                                                    (2)

5.2
5.2.1     Temperature / Temperatuur                                                                  (1)

5.2.2     Rate of reaction / Volume of gas (formed) per (unit) time 
          Reaksietempo / Volume gas (gevorm) per (eenheids)tyd                                        (1)

5.3      •    Larger mass / amount / surface area. 
              Groter massa / hoeveelheid / reaksieoppervlak.
         •    More effective collisions per (unit) time. / Frequency of effective collisions
              increase./ More particles collide with sufficient kinetic energy & correct
              orientation per (unit) time. 
              Meer effektiewe botsings per (eenheids)tyd. / Frekwensie van effektiewe
              botsings verhoog./ Meer deeltjies bots met genoeg kinetiese energie &
              korrekte oriëntasie per tyd(seenheid).

         IF / INDIEN:
         •     Larger mass / amount / surface area. 
               Groter massa / hoeveelheid / reaksieoppervlak.
         •     More particles collide. / More collisions. 
               Meer deeltjies bots. / Meer botsings.                       Max./Maks. 2
                                                                                            3
         Notes / Aantekeninge:
         IF/INDIEN:
         No reference to mass / amount / surface area in answer:
         Geen verwysing na massa / hoeveelheid / reaksieoppervlak in antwoord:            0
                                                                                              3       (3)

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Physical Sciences P2/Fisiese Wetenskappe V2        9                                  DBE/November 2014
                                      NSC/NSS - Memorandum

5.4       Marking criteria / Nasienriglyne:
          Compare        The reaction in exp. 1 is faster in exp. 1 than in exp. 2 due to the
          Exp.1 with     higher acid concentration.
                                                                                                 
          Exp. 2:        Die reaksie in eksp. 1 is vinniger as dié in eksp. 2 as gevolg van
          Vergelyk       die hoër suurkonsentrasie.
          Eksp. 1 met    Therefore the gradient of the graph representing exp. 1 is
          Eksp. 2:       greater / steeper than that of exp. 2. / Graph of Exp. 1 reaches
                         constant volume in shorter time than exp. 2.
                                                                                                 
                         Dus is die gradiënt van die grafiek wat eksp. 1 voorstel,
                         groter/steiler as dié vir eksp. 2. / Grafiek van exp. 1 bereik
                         konstante volume in korter tyd as dié vir eksp. 2.
          Compare        The reaction in exp. 3 is faster than that in exp. 1 due to the
          Exp. 1 with    higher temperature.
                                                                                                 
          Exp 3 & 4:     Die reaksie in eks. 3 is vinniger as dié in eksp. 1 as gevolg van
          Vergelyk       die hoër temperatuur.
          Eksp. 1 met    The reaction in exp. 4 is faster than that in exp. 1 due to the
          Eksp. 3 & 4:   higher temperature / larger surface area.
                         Die reaksie in eks. 4 is vinniger as dié in eksp. 1 as gevolg van
                         die hoër temperatuur / groter reaksieoppervlak.
                         OR/OF                                                                   
                         Graph A represents exp. 4 due to the greater mass of CaCO 3 -
                         greater yield of CO 2 at a faster rate.
                         Grafiek A stel eksp. 4 voor as gevolg van die groter massa
                         CaCO 3 - groter opbrengs CO 2 teen vinniger tempo.
                         Therefore the gradient of the graphs of exp. 3 & 4 are
                         greater/steeper than that of exp. 1. / Graphs of Exp. 3 & 4
                         reaches constant volume in shorter time than exp. 1.
                                                                                                 
                         Dus is die gradiënte van die grafieke vir eksp. 3 & 4 is
                         groter/steiler as dié in eksp. 1./ Grafieke van exp. 3 & 4 bereik
                         konstante volume in korter tyd as dié vir eksp. 1.
          Final answer
          Finale         C                                                                      
          antwoord                                                                                       (6)

          Notes/Aantekeninge
          • Compare exp. 1 with exp. 2 / Vergelyk eksp. 1 met eksp. 2:
             o Factor & rate / Faktor & tempo.
             o Gradient / volume CO 2 per time / gradient / volume CO 2 per tyd.
          • Compare exp. 1 with exp. 3 / Vergelyk eksp. 1 met eksp. 3:
             o Factor & rate / Faktor & tempo.
          • Compare exp. 1 with exp. 4/ Vergelyk eksp. 1 met eksp. 4:
             o Factor & rate / Faktor & tempo.
          • Compare gradient / volume CO 2 per time of exp 1 with that of exp. 3 & 4
             Vergelyk gradient/volume CO 2 per tyd van eksp 1 met die van eksp. 3 & 4
          • Final answer / finale antwoord: C

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Physical Sciences P2/Fisiese Wetenskappe V2       10                             DBE/November 2014
                                      NSC/NSS - Memorandum

5.5     Marking criteria / Nasienriglyne:
        • Divide volume by / Deel volume deur: 25,7 
        • Use ratio / Gebruik verhouding: n(CO 2 ) = n(CaCO 3 ) = 1:1 
                                             m
        • Substitute / Vervang 100 in n =      .
                                             M
        • Subtraction / Aftrekking. 
        • Final answer / Finale antwoord: 7,00 g to/tot 7,5 g 

        OPTION 1 / OPSIE 1                     OPTION 2 / OPSIE 2
                   V                           Calculate mass of CO 2 :
        n(CO 2 ) =                             Bereken massa CO 2 :
                   Vm
                                                          V
                   4,5                         n(CO 2 ) =
                =                                        Vm
                  25,7
                                                          4,5 
                = 0,18 mol (0,175 mol)                 =
                                                         25,7
        n(CaCO 3 ) = n(CO 2 ) = 0,18 mol              = 0,18 mol (0,175 mol)
                     m
        n(CaCO 3 ) =                                     m
                     M                         n(CO 2 ) =
                                                         M
                      m
             0,18 =                                       m
                     100                         0,18 =
            ∴ m = 18 g (17,5 g)                          44
                                                                                   Ratio/
                                               ∴ m(CO 2 ) = 7,92 g (7,7043 g)      verhouding
        m(CaCO 3 ) not reacted/nie                                               
                                                                             7,92      
        gereageer nie):                        m(CaCO 3 needed / benodig ) =      × 100
        25 – 18  = 7,00 g  (7,49 g)                                         44
                                                                           = 18 g (17,5 g)
                                               m(CaCO 3 not reacted/nie gereageer nie):
        (Accept range: 7,00 g – 7,5 g)         25 – 18,00  = 7,00 g  (7,49 g)
        (Aanvaar gebied: 7.00 g – 7,5 g)
                                               (Accept range: 7,00 g – 7,5 g)
                                               (Aanvaar gebied: 7.00 g – 7,5 g)                     (5)
        OPTION 3 / OPSIE 3                     OPTION 4 / OPSIE 4
        25,7 dm3 : 1 mol                       100 g CaCO 3 → 25,7 dm3 CO 2 
        4,5 dm3 : 0,18 mol                    x g → 4,5 dm3 CO 2 
                                               ∴ x = 17,51 g
        100 g : 1 mol
        x       : 0,18 mol                    Mass not reacted/Massa nie gereageer nie
        x = 18 g                               = 25 – 17,51 
        m(CaCO 3 not reacted/nie                   = 7,49 g 
        gereageer nie):                        (Accept range: 7,00 g – 7,5 g)
        25 – 18  = 7,00 g                    (Aanvaar gebied: 7,00 g – 7,5 g)
        (Accept range: 7,00 g – 7,5 g)
        (Aanvaar gebied: 7,00 g – 7,5 g)                                                            (5)

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Physical Sciences P2/Fisiese Wetenskappe V2       11                                DBE/November 2014
                                      NSC/NSS - Memorandum

QUESTION 6 / VRAAG 6

6.1      The stage in a chemical reaction when the rate of forward reaction equals the
         rate of reverse reaction. 
         Die stadium in 'n chemiese reaksie wanneer die tempo van die voorwaartse
         reaksie gelyk is aan die tempo van die terugwaartse reaksie. 

         OR / OF
         The stage in a chemical reaction when the concentrations of reactants and
         products remain constant. 
         Die stadium in 'n chemiese reaksie wanneer die konsentrasies van reaktanse
         en produkte konstant bly.                                                                   (2)

6.2      CALCULATIONS USING NUMBER OF MOLES
         BEREKENINGE WAT GETAL MOL GEBRUIK
         Mark allocation / Puntetoekenning:
         • Correct K c expression (formulae in square brackets). 
            Korrekte K c uitdrukking (formules in vierkanthakies).
         •    Substitution of concentrations into K C expression. 
              Vervanging van konsentrasies in K C -uitdrukking.
         •    Substitution of K C value / Vervanging van K C -waarde. 
         •    Equilibrium concentration of both NO 2 & N 2 O 4 multiplied by 0,08 dm3. 
              Ewewigskonsentrasie van beide NO 2 & N 2 O 4 vermenigvuldig met 0,08 dm3
         •    Change in n(N 2 O 4 ) = equilibrium n(N 2 O 4 ) – initial n(N 2 O 4 ) 
              Verandering in n(N 2 O 4 ) = ewewig n(N 2 O 4 ) – aanvanklike n(N 2 O 4 )
         •    USING ratio / GEBRUIK verhouding: NO 2 : N 2 O 4 = 2 : 1 

         •    Initial n(NO 2 )= equilibrium n(NO 2 ) + change n(NO 2 ). 
              Aanvanklike n(NO 2 )= ewewig n(NO 2 ) + verandering n(NO 2 ).
         •    Final answer / Finale antwoord: 1,11 (mol) 
              Accept range/Aanvaar gebied: 1,11 – 1,12 (mol)

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Physical Sciences P2/Fisiese Wetenskappe V2       12                                 DBE/November 2014
                                      NSC/NSS - Memorandum

         OPTION 1 / OPSIE 1
              [N O ]
         K c = 2 42                    No KC expression, correct substitution / Geen Kc-
              [NO 2 ]                   uitdrukking, korrekte substitusie: Max./Maks. 7
                                                                                        8
                 [N O ]
         171  = 2 42 
                  (0,2)                 Wrong KC expression /Verkeerde Kc-uitdrukking:
                                        Max./Maks. 5
         ∴ [N 2 O 4 ] = 171 x (0,2)2                 8
                     = 6,84 mol∙dm-3                                                                    (8)

                                                               NO 2          N2O4
              Initial quantity (mol)
                                                              1,11            0
              Aanvangshoeveelheid (mol)
              Change (mol)
                                                               1,094        0,55       ratio 
              Verandering (mol)               
                                                                                        verhouding
              Quantity at equilibrium (mol)/
                                                               0,016         0,55
              Hoeveelheid by ewewig (mol)
              Equilibrium concentration (mol∙dm-3)                                      x 0,08 
                                                                0,2          6,84
              Ewewigskonsentrasie (mol∙dm-3)

         OPTION 2 / OPSIE 2
              [N O ]                    No KC expression, correct substitution /Geen Kc-
         K c = 2 42 
              [NO 2 ]                   uitdrukking, korrekte substitusie: Max./Maks. 7
                                                                                        8
                  [N2 O 4 ]
         171  =            
                   (0,2)2               Wrong KC expression /Verkeerde Kc-uitdrukking:
                                        Max./Maks. 5
         ∴ [N 2 O 4 ] = 171 x (0,2)2                 8
                     = 6,84 mol∙dm-3

         Equilibrium moles / Ewewigsmol:
         n(N 2 O 4 ) = (6,84)(0,080)
                     = 0,55 mol
         n(NO 2 ) = (0,2)(0,080)      x 0,08 dm3
                     = 0,016 mol

         n(N 2 O 4 formed/gevorm) = 0,55 – 0 = 0,55 mol 

         Ratio / Verhouding:
         n(NO 2 reacted / gereageer) = 2n(N 2 O 4 formed/gevorm) = 2(0,55) = 1,094 mol
         
         Initial / Aanvanklike n(NO 2 ) = 0,016 + 1,094  = 1,11 (mol)                                 (8)

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Physical Sciences P2/Fisiese Wetenskappe V2       13                                   DBE/November 2014
                                      NSC/NSS - Memorandum

         OPTION 3 / OPSIE 3
                                                             NO 2              N2O4
            Initial quantity (mol)
                                                          2x + 0,016               0
            Aanvangshoeveelheid (mol)
            Change (mol)                                                                  ratio 
            Verandering (mol)                                2x                x        verhouding
            Quantity at equilibrium (mol)/
                                                             0,016                 x
            Hoeveelheid by ewewig (mol)
            Equilibrium concentration (mol∙dm-3)                                 x       x 0,08 &
            Ewewigskonsentrasie (mol∙dm-3)                    0,2              0,08      ÷ 0,08 

              [N2 O 4 ]
         Kc =                             No KC expression, correct substitution/Geen Kc-
              [NO 2 ] 2
                       x                   uitdrukking, korrekte substitusie: Max./Maks. 7
                                                                                           8
                    0,08
         171  =                          Wrong KC expression/Verkeerde Kc-uitdrukking:
                   (0,2)2
                                           Max./Maks. 5
                                                        8
         ∴ x = 0,5472
         ∴ n(initial/aanvanklik) = 2(0,5472) + 0,016
                                 = 1,11 mol 
                                                                                                        (8)

         OPTION 4 / OPSIE 4
                                                             NO 2            N2O4
             Initial quantity (mol)
                                                              x                0
             Aanvangshoeveelheid (mol)
             Change (mol)                                                 x − 0,016
             Verandering (mol)                           x – 0,016                   ratio 
                                                                              2       verhouding
                                                  
             Quantity at equilibrium (mol)/                                x − 0,016
             Hoeveelheid by ewewig (mol)                   0,016
                                                                                2
             Equilibrium concentration (mol∙dm-3)                          x − 0,016
                                                                                      x 0,08 &
             Ewewigskonsentrasie (mol∙dm-3)                  0,2              0,16     ÷ 0,08 
              [N2 O 4 ]
         Kc =                          No KC expression, correct substitution/Geen Kc-
              [NO 2 ] 2
                                        uitdrukking, korrekte substitusie: Max./Maks. 7
                  x − 0,016                                                             8
                       0,16
         171  =                       Wrong KC expression/Verkeerde Kc-uitdrukking:
                     (0,2)2
                                        Max./Maks. 5
                                                     8
         ∴ x = 1,11 mol                                                                                (8)

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Physical Sciences P2/Fisiese Wetenskappe V2       14                                   DBE/November 2014
                                      NSC/NSS - Memorandum

         CALCULATIONS USING CONCENTRATION
         BEREKENINGE WAT KONSENTRASIE GEBRUIK

         Mark allocation / Puntetoekenning:
         • Correct K c expression (formulae in square brackets). 
            Korrekte K c uitdrukking (formules in vierkanthakies).

         •   Substitution of concentrations into K C expression. 
             Vervanging van konsentrasies in K C -uitdrukking.
        •    Substitution of K C value. / Vervanging van K C -waarde. 
         •   Change in [N 2 O 4 ] = equilibrium [N 2 O 4 ] – initial [N 2 O 4 ]. 
             Verandering in [N 2 O 4 ] = ewewig [N 2 O 4 ] – aanvanklike [N 2 O 4 ].
         •    USING ratio/GEBRUIK verhouding: NO 2 : N 2 O 4 = 2 : 1 

         •    Initial [NO 2 ] = equilibrium [NO 2 ] + change in [NO 2 ]. 
              Aanvanklike [NO 2 ] = ewewigs [NO 2 ] + verandering in [NO 2 ].
         •   Equilibrium concentration of [NO 2 ] multiplied by 0,08 dm3. 
             Ewewigskonsentrasie van [NO 2 ] vermenigvuldig met 0,08 dm3.
         •    Final answer/Finale antwoord: 1,11 (mol) 
              Accept range/Aanvaar gebied: 1,11 – 1,12 (mol)

         OPTION 5 / OPSIE 5
              [N O ]                       No KC expression, correct substitution/Geen Kc-
         K c = 2 42 
              [NO 2 ]                      uitdrukking, korrekte substitusie: Max./Maks. 7
                                                                                           8
                  [N2 O 4 ]
         171  =            
                   (0,2)2                  Wrong KC expression/Verkeerde Kc-uitdrukking:
                                           Max./Maks. 5
         ∴ [N 2 O 4 ] = 171 x (0,2)2                    8
                     = 6,84 mol∙dm-3

                                                              NO 2            N2O4
                                            -3
             Initial concentration (mol∙dm )
                                                             13,88               0
             Aanvangskonsentrasie (mol∙dm-3)
             Change (mol∙dm-3)                                                            ratio 
                                    -3                       13,68            6,84 
             Verandering (mol∙dm )                                                         verhouding
             Equilibrium concentration (mol∙dm-3)
                                                              0,2              6,84
             Ewewigskonsentrasie (mol∙dm-3)

         n(NO 2 ) = cV = (13,88)(0,08)  = 1,11 mol                                                      (8)

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Physical Sciences P2/Fisiese Wetenskappe V2       15                                DBE/November 2014
                                      NSC/NSS - Memorandum

         OPTION 6 / OPSIE 6
                                                              NO 2           N2O4
                                           -3
              Initial concentration (mol∙dm )
                                                               x               0
              Aanvangskonsentrasie (mol∙dm-3)
              Change (mol∙dm-3)                                           x − 0,2       ratio 
                                     -3                      x – 0,2               
              Verandering (mol∙dm )                                           2          verhouding
              Equilibrium concentration (mol∙dm-3)                         x − 0,2
              Ewewigskonsentrasie (mol∙dm-3)                  0,2             2

              [N2 O 4 ]
         Kc =                          No KC expression, correct substitution/Geen Kc-
              [NO 2 ] 2
                                        uitdrukking, korrekte substitusie: Max./Maks. 7
                   x − 0,2                                                              8
         171  =        2              Wrong KC expression/Verkeerde Kc-uitdrukking:
                   (0,2)2
                                        Max./Maks. 5
                                                     8
         ∴ x = 13,88 mol⋅dm-3

         n(NO 2 ) = cV = (13,88)(0,08)  = 1,11 mol                                                   (8)

6.3
6.3.1     Concentration (of the gases) increases. / Molecules become more condensed
          or move closer to each other. 
          Konsentrasie (van die gasse) verhoog. / Molekule word meer saamgepers of
          beweeg nader aan mekaar.                                                                     (1)
6.3.2     •   Increase in pressure favours the reaction that leads to smaller number of
              moles / volume of gas. 
              Toename in druk bevoordeel die reaksie wat tot die kleiner getal mol /
              volume gas lei.
          •   Forward reaction is favoured. / Voorwaartse reaksie word bevoordeel. 
          •   Number of moles/amount of N 2 O 4 / colourless gas increases.
              Aantal mol/hoeveelheid N 2 O 4 / kleurlose gas neem toe.

              OR / OF
              Number of moles/amount of NO 2 / brown gas decreases. 
              Aantal mol/hoeveelheid NO 2 / bruin gas neem af.                                         (3)
6.4
6.4.1    Darker / Donkerder                                                                           (1)
6.4.2    Decreases / Verlaag                                                                           (1)
                                                                                                       [16]

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Physical Sciences P2/Fisiese Wetenskappe V2       16                               DBE/November 2014
                                      NSC/NSS - Memorandum

QUESTION 7/ VRAAG 7

PENALISE ONCE FOR THE INCORRECT CONVERSION OF UNITS.
PENALISEER EENMALIG VIR VERKEERDE OMSKAKELING VAN EENHEDE.

7.1
7.1.1     Ionises / dissociates completely (in water) 
          Ioniseer / dissosieer volledig (in water).                                                  (1)

7.1.2     NO 3 - / Nitrate ion / Nitraatioon                                                         (1)

7.1.3     pH = -log[H 3 O+] / -log[H+]     Notes/Aantekeninge:
                                          • If no/incorrect formula/Indien geen/foutiewe
             = -log(0,3)                    formule: Max./Maks: 2
             = 0,52                                                 3
                                           • If no substitution step: 2 marks for correct
                                             answer./Indien geen substitusie stap: 2 punte
                                             vir korrekte antwoord.                                   (3)

7.2
7.2.1         n
          c=    
             V
              n
          2=     
             0,1
          ∴ n(HCℓ) = 0,2 mol                                                                         (3)

7.2.2     Burette / Buret                                                                            (1)

7.2.3     B
        - Titration of strong acid and strong base. 
          Titrasie van sterk suur en sterk basis.

          OR/OF
          The endpoint will be approximately at pH = 7 which is in the range of the
          indicator.
          Die eindpunt sal ongeveer by pH = 7 wees wat in die gebied van die indikator
          is.                                                                                         (3)

7.2.4     The number of moles of acid in the flask remains constant. 
          Die getal mol van die suur in die fles bly konstant.                                        (1)

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Physical Sciences P2/Fisiese Wetenskappe V2       17                             DBE/November 2014
                                      NSC/NSS - Memorandum

7.2.5           n
              c=   
                V
                  n
          0,2 =        
                0,021
            n = 4,2 x 10-3 mol 

         n(HCℓ in excess/in oormaat):
         n(HCℓ) = n(NaOH)
                = 4,2 x 10-3 mol                                                                    (3)

7.2.6    POSITIVE MARKING FROM QUESTION 7.2.1 AND 7.2.5.
         POSITIEWE NASIEN VAN VRAAG 7.2.1 EN 7.2.5.
         Marking criteria / Nasienriglyne:
         • n(HCℓ reacted) = initial (from Q7.2.1) – excess (from Q7.2.5).
           n(HCℓ reageer) = begin (van Q7.2.1) – oormaat (van Q7.2.5).
          • Use mol ratio of acid: base = 2 : 1. 
            Gebruik molverhouding suur : basis = 2 : 1.
                                                     m
          • Substitute / Vervang 40 into / in n =      
                                                     M
               m(MgO reacted / reageer )
          •                              × 100 . 
                        4,5
          • Final answer / Finale antwoord: 87,11 % 
         OPTION 1 / OPSIE 1                   OPTION 2 / OPSIE 2
         n(HCℓ reacted/gereageer):            n(HCℓ reacted/gereageer):
         0,2 – 4,2 x 10-3  = 0,196 mol       0,2 – 4,2 x 10-3  = 0,196 mol

         n(MgO reacted/gereageer):                                              m
         ½n(HCℓ) = ½(0,196)                     n(HCℓ reacted/gereageer) =
                                                                                M
                = 9,8 x 10-2 mol                        m
                                                0,196 =
                                                       36,5
                                        m
         n(MgO reacted/gereageer) =             ∴ m(HCℓ reacted/gereageer) = 7,154 g
                                        M
                    m                           40 g MgO  .............. 73 g HCℓ 
         ∴ 0,098 =
                    40                         x g MgO ................... 7,154 g
         ∴ m = 3,92 g                           ∴ x = 3,92 g

                                  3,92                               3,92
         % purity/ suiwerheid =        × 100  % purity/suiwerheid =      × 100 
                                   4,5                                4,5
                                = 87,11%                          = 87,11% 

         (Accept range: 87 - 87,11 %.)          (Accept range: 87 - 87,11 %.)
         (Aanvaar gebied: 87 – 87,11 %)         (Aanvaar gebied: 87 – 87,11 %)                       (5)
                                                                                                    [21]

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Physical Sciences P2/Fisiese Wetenskappe V2       18                                  DBE/November 2014
                                      NSC/NSS - Memorandum

QUESTION 8 / VRAAG 8

8.1       •   Pressure: 1 atmosphere (atm) / 101,3 kPa / 1,013 x 105 Pa 
              Druk: 1 atmosfeer (atm) / 101,3 kPa / 1,013 x 105 Pa
          •   Temperature/Temperatuur: 25 °C / 298 K                                                    (2)

8.2       •   Platinum is inert / does not react with the H+ ions OR acid. 
              Platinum is onaktief / reageer nie met die H+-ione OF suur nie.
          •   Platinum is a conductor (of electricity). 
              Platinum is 'n geleier (van elektrisiteit).                                                (2)

8.3
8.3.1    Salt bridge / Soutbrug                                                                         (1)

8.3.2    -0,31 V                                                                                        (1)

8.3.3    2H+ + 2e- → H 2 
         Marking guidelines / Nasienriglyne:
         • 2H+ + 2e- ⇌ H 2     1                     H 2 ⇌ 2H+ + 2e-          0
                                2                                                 2
           H 2 ← 2H + 2e
                    +     -   2                      H 2 → 2H + 2e
                                                               +        -     0
                                2                                                 2                      (2)

8.4
8.4.1    POSITIVE MARKING FROM QUESTION 8.3.2.
         POSITIEWE NASIEN VAN VRAAG 8.3.2.
           θ        θ             θ
         E cell = E reduction − E oxidation  Notes / Aantekeninge:
                                                Accept any other correct formula from the
         2,05  = -0,31 – E Mθ / M2 +          data sheet.
         E Mθ / M2 + = -2,36 (V)               Aanvaar enige ander korrekte formule vanaf
                                                gegewensblad.
         M is magnesium/ Mg.                   Any other formula using unconventional
                                                                     θ       θ     θ
                                                abbreviations, e.g. Ecell = EOA − ERA followed
         Option 2/ Opsie 2
                    2+      -                   by correct substitutions: 4
           M→ M + 2e E° = 2,36 (V)                                           5
         X + 2e → X E° = -0,31 (V)            Enige ander formule wat onkonvensionele
             2+    -
                                                                        θ       θ      θ
                              E° = 2,05 V      afkortings gebruik bv. E sel = E OM − E RM
                     θ
         Thus/Dus: E reduction = - 2,36 (V)    gevolg deur korrekte vervangings: 4
                                                                                         5
         M is magnesium/ Mg. 
         Notes / Aantekeninge
         Give mark for Mg / magnesium ONLY if concluded from -2,36 V.
         Ken punt vir Mg / magnesium slegs toe indien afgelei uit -2,36 V                                (5)

8.4.2    Exothermic / Eksotermies                                                                       (1)

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Physical Sciences P2/Fisiese Wetenskappe V2       19                                 DBE/November 2014
                                      NSC/NSS - Memorandum

8.5      The cell reaction reaches equilibrium. 
         Die selreaksie bereik ewewig.

         Notes / Aantekeninge:
         Accept: One or more of reactants are used up. / The cell reaction has run to
         completion.
         Aanvaar: Een of meer van reaktanse word opgebruik. / Die selreaksie het volledig
         verloop.                                                                                        (1)
                                                                                                        [15]

QUESTION 9 / VRAAG 9
9.1      Electrolytic / Elektrolities                                                                  (1)
9.2      Q& T                           Notes / Aantekeninge:
                                          IF more than TWO electrodes, mark first two.
         Cu2+ + 2e → Cu 
                                          Indien meer as TWEE elektrodes, sien eerste twee na.
         Marking guidelines / Nasienriglyne
         Cu2+ + 2e ⇌ Cu       (1 )             Cu → Cu2+ + 2e-    (0 )
                                 2                                  2
         Cu ← Cu2+ + 2e      (2 )              Cu ⇌ Cu2+ + 2e-    (0 )
                               2                                     2                                  (4)
9.3
9.3.1    Cℓ 2 / chlorine (gas) / chloor(gas)                                                           (1)
9.3.2    Cu2+ (ions) / copper(II) ions / CuCℓ 2 / copper(II) chloride 
-        Cu2+ (ione) / koper(II)-ione / CuCℓ 2 / koper(II)chloried                                      (1)
9.4      Cu is a stronger reducing agent  than Cℓ- (ions)  and Cu will be oxidised 
         (to Cu2+).
         Cu is 'n sterker reduseermiddel as Cℓ-(-ione) en Cu sal geoksideer word
         (na Cu2+).

         OR/OF
         Cℓ- (ions) is a weaker reducing agent  than Cu  and Cu will be oxidised 
         (to Cu2+).
         Cℓ-(-ione) is 'n swakker reduseermiddel as Cu en Cu sal geoksideer word
         (na Cu2+).                                                                                      (3)
                                                                                                        [10]

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Physical Sciences P2/Fisiese Wetenskappe V2    20                        DBE/November 2014
                                      NSC/NSS – Memorandum

QUESTION 10 / VRAAG 10

10.1
10.1.1   Nitrogen / N 2 / Stikstof 
         Hydrogen / H 2 / Waterstof                                                           (2)

10.1.2   NH 3 + HNO 3  → NH 4 NO 3                  Bal. 

         Notes / Aantekeninge:
         • Reactants        Products        Balancing: 
             Reaktanse       Produkte         Balansering
         • Ignore double arrows. / Ignoreer dubbelpyle.
         • Marking rule 6.3.10. / Nasienreël 6.3.10.                                           (3)

10.2     Marking criteria / Nasienriglyne:
                                               3
         • Use ratio / gebruik verhouding:       
                                               9
         • x 20 kg 
         • x 36 / 36 % 
         • Final answer / Finale antwoord: 2,4 kg 

         OPTION 1 / OPSIE 1:        OPTION 2 / OPSIE 2:        OPTION 3 / OPSIE 3:
               3                    m(nutrients/voedingstowwe): m(N):
         % N =  (x 36)             36     
               9                         (x 20) = 7,2 kg
             = 12 %                 100                        3            36        
                                                                 × (× 20) (×     ) = 2,4 kg
                   12                                         9             100
         ∴ m(N) :     (× 20 kg)                3
                  100               ∴ m(N) =      x 7,2
                 = 2,4 kg                     9
                                             = 2,4 kg                                         (4)
                                                                                               [9]
                                                                        TOTAL/TOTAAL:         150

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- [Grade 12 past papers](https://www.hlayiso.com/grade-12/past-papers)

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