# Physical Sciences Grade 12 P2 NSC November 2015 QP (Eng)

> Grade 12 Physical Sciences Paper 2 question paper from the NSC November Exam 2015 (English), 19 pages. Read online or download the free PDF.

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- Updated: 2026-09-27
- Subject: Physical Sciences
- Grade: Grade 12
- Document type: Question paper
- Year: 2015
- Exam period: NSC November Exam
- Paper: 2
- Curriculum: CAPS
- Pages: 19

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Physical Sciences · Grade 12 · NSC November Exam · 2015. Question paper, 19 pages. Read online or download the PDF.

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                                 NATIONAL
                            SENIOR CERTIFICATE

                                    GRADE 12

                      PHYSICAL SCIENCES: CHEMISTRY (P2)

                                 NOVEMBER 2015

MARKS: 150

TIME: 3 hours

              This question paper consists of 15 pages and 4 data sheets.

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Physical Sciences/P2                         2                            DBE/November 2015
                                            NSC

INSTRUCTIONS AND INFORMATION

1.        Write your centre number and examination number in the appropriate spaces
          on the ANSWER BOOK.

2.        This question paper consists of TEN questions. Answer ALL the questions in
          the ANSWER BOOK.

3.        Start EACH question on a NEW page in the ANSWER BOOK.

4.        Number the answers correctly according to the numbering system used in this
          question paper.

5.        Leave ONE line between two subquestions, for example between
          QUESTION 2.1 and QUESTION 2.2.

6.        You may use a non-programmable calculator.

7.        You may use appropriate mathematical instruments.

8.        You are advised to use the attached DATA SHEETS.

9.        Show ALL formulae and substitutions in ALL calculations.

10.       Round off your final numerical answers to a minimum of TWO decimal places.

11.       Give brief motivations, discussions et cetera where required.

12.       Write neatly and legibly.

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Physical Sciences/P2                              3                                  DBE/November 2015
                                                 NSC

QUESTION 1: MULTIPLE-CHOICE QUESTIONS

Four options are provided as possible answers to the following questions. Each
question has only ONE correct answer. Choose the answer and write only the letter
(A–D) next to the question number (1.1–1.10) in the ANSWER BOOK, for example
1.11 E.

1.1       Which ONE of the following pairs of reactants is used in a reaction during the
          contact process?

          A     N 2 (g) and H 2 (g)

          B     SO 2 (g) and O 2 (g)

          C     NH 3 (g) and O 2 (g)

          D     H 2 SO 4 (ℓ) and NH 3 (g)                                                                  (2)

1.2       The rate of a chemical reaction is most correctly defined as the ...

          A     time taken for a reaction to occur.

          B     speed at which a reaction takes place.

          C     change in the amount of reactants or products.

          D     change in the concentration of reactants or products per unit time.                        (2)

1.3       Consider the reaction represented by the balanced equation below.

                            H 3 PO 4 (aq) + H 2 O(ℓ) ⇌ H 3 O+(aq) + H 2 PO −4 (aq)

          Which ONE of the following is a conjugate acid-base pair?

          A     H 3 O+(aq) and H 2 O(ℓ)

          B     H 3 PO 4 (aq) and H 2 O(ℓ)

          C     H 3 PO 4 (aq) and H 3 O+(aq)

          D     H 3 O+(aq) and H 2 PO −4 (aq)                                                              (2)

1.4       Which ONE of the following compounds has dipole-dipole forces between its
          molecules?

          A     Ethanal

          B     Ethane

          C     Ethene

          D     Ethyne                                                                                     (2)

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Physical Sciences/P2                                   4                         DBE/November 2015
                                                      NSC

1.5       The energy changes represented by P, Q and R on the potential energy
          graph below take place during a reversible chemical reaction.

                       Potential energy
                                                                           R
                                          P

                          (kJ∙mol-1)                            Q

                                                 Course of reaction

          Which ONE of the following changes will decrease both P and R, but leave Q
          unchanged?

          A     A decrease in volume

          B     The addition of a catalyst

          C     A decrease in temperature

          D     A decrease in concentration                                                            (2)

1.6       Which ONE of the following is a product formed during the hydrolysis of
          bromoethane?

          A     Water

          B     Ethene

          C     Ethanol

          D     Bromine                                                                                (2)

1.7       Which ONE of the                    following   is   the   EMPIRICAL   FORMULA     of
          1,2-dichloroethane?

          A     CHCℓ

          B     CH 2 Cℓ

          C     CHCℓ 2

          D     C 2 H 4 Cℓ 2                                                                           (2)

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Physical Sciences/P2                             5                              DBE/November 2015
                                                NSC

1.8       The reaction represented by the balanced equation below reaches equilibrium
          in a closed container.

                           Cℓ 2 (g) + H 2 O(ℓ) ⇌ Cℓ─(aq) + CℓO─(aq) + 2H+(aq)
          Which ONE of the following reagents will favour the forward reaction when
          added?

          A     Hydrogen

          B     Sodium chloride

          C     Hydrogen chloride

          D     Sodium hydroxide                                                                      (2)

1.9       The following half-reactions take place in a galvanic cell:

                                           Co3+ + e- ⇌ Co2+
                                            Aℓ3++ 3e- ⇌ Aℓ
          Which ONE of the following is the cell notation for this cell?

          A      Aℓ ∣ Aℓ3+ ∥ Co3+, Co2+

          B      Aℓ ∣ Aℓ3+ ∥ Co3+, Co2+ ∣ Pt

          C      Aℓ ∣ Aℓ3+ ∥ Co2+, Co3+ ∣ Pt

          D      Pt ∣ Co2+ , Co3+ ∥ Aℓ3+ ∣ Aℓ                                                         (2)

1.10      Chlorine gas (Cℓ 2 ) is bubbled through a potassium iodide solution (KI). The
          reducing agent in this reaction is:

          A      Potassium ions

          B      Chlorine gas

          C      Iodide ions

          D      Chloride ions                                                                        (2)
                                                                                                      [20]

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Physical Sciences/P2                           6                           DBE/November 2015
                                              NSC

QUESTION 2 (Start on a new page.)

The letters A to D in the table below represent four organic compounds.

           H      CH3 H                H                   H   H   O   H

A     H    C      C     C    C    C    C    H B     H      C   C   C   C   H

           CH3 H        CH2CH3         H                   H   H       H

C     CH 3 CH 2 CHO                             D   Butane

Use the information in the table to answer the questions that follow.

2.1       Write down the:

          2.1.1        Letter that represents a ketone                                               (1)

          2.1.2        Structural formula of the functional group of compound C                      (1)

          2.1.3        General formula of the homologous series to which compound A
                       belongs                                                                       (1)

          2.1.4        IUPAC name of compound A                                                      (3)

          2.1.5        IUPAC name of compound B                                                      (2)

2.2       Compound D is a gas used in cigarette lighters.

          2.2.1        To which homologous series does compound D belong?                            (1)

          2.2.2        Write down the STRUCTURAL FORMULA and IUPAC NAME of a
                       structural isomer of compound D.                                              (4)

          2.2.3        Is the isomer in QUESTION 2.2.2 a CHAIN, POSITIONAL or
                       FUNCTIONAL isomer?                                                            (1)

2.3       Compound D reacts with bromine (Br 2 ) to form 2-bromobutane.

          Write down the name of the:

          2.3.1        Homologous series to which 2-bromobutane belongs                              (1)

          2.3.2        Type of reaction that takes place                                             (1)
                                                                                                     [16]

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Physical Sciences/P2                             7                          DBE/November 2015
                                                NSC

QUESTION 3 (Start on a new page.)

3.1       The flow diagram below shows two organic reactions. The letter P represents
          an organic compound.

                                  +              Reaction 1    Ethyl propanoate
                       Alcohol          P

             Reaction 2

                       Alkene

          Use the information in the flow diagram to answer the questions that follow.

          Write down the:

          3.1.1        Type of reaction of which Reaction 1 is an example                         (1)

          3.1.2        STRUCTURAL FORMULA of the functional group of ethyl
                       propanoate                                                                 (1)

          3.1.3        IUPAC name of compound P                                                   (1)

          Reaction 2 takes place in the presence of an acid catalyst and heat.

          Write down the:

          3.1.4        Type of reaction of which Reaction 2 is an example                         (1)

          3.1.5        NAME or FORMULA of the acid catalyst                                       (1)

          3.1.6        STRUCTURAL FORMULA of the alkene                                           (2)

3.2       The condensed formula of a polymer is shown below.

                                            H     H

                                            C     C

                                            H     H
                                                       n

          Write down the:

          3.2.1        STRUCTURAL FORMULA of the monomer that is used to prepare
                       the above polymer                                                          (2)

          3.2.2        Type of polymerisation reaction (ADDITION or CONDENSATION)
                       that is used to prepare this polymer                                       (1)
                                                                                                  [10]

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Physical Sciences/P2                             8                                DBE/November 2015
                                                NSC

QUESTION 4 (Start on a new page.)

Four compounds of comparable molecular mass are used to investigate the effect of
functional groups on vapour pressure. The results obtained are shown in the table
below.

                                                   VAPOUR PRESSURE
                             COMPOUND
                                                      (kPa at 20 °C)
                         A    Butane                          204
                         B    Propan-2-one                   24,6
                         C    Propan-1-ol                      2
                         D    Ethanoic acid                   1,6

4.1       Define the term functional group of an organic compound.                                      (2)

4.2       Which ONE of the compounds (A, B, C or D) in the table has the:

          4.2.1        Highest boiling point
                       (Refer to the vapour pressures in the table to give a reason for the
                       answer.)                                                                         (2)

          4.2.2        Weakest intermolecular forces                                                    (1)

4.3       Refer to the type of intermolecular forces to explain the difference between
          the vapour pressure of compound A and compound B.                                             (3)

4.4       The vapour pressures of compounds C and D are much lower than those of
          compounds A and B. Name the type of intermolecular force in A and B that is
          responsible for this difference.                                                              (1)

4.5       Briefly explain the difference in vapour pressure between compound C and
          compound D.                                                                                   (2)

4.6       During a combustion reaction in a closed container of adjustable volume,
          8 cm3 of compound A (butane) reacts in excess oxygen according to the
          following balanced equation:

                             2C 4 H 10 (g) + 13O 2 (g) → 8CO 2 (g) + 10H 2 O(g)

          If the initial volume of the oxygen in the container was 60 cm3, calculate the
          TOTAL volume of the gases that are present in the container at the end of the
          reaction. All the gases in the container are at the same temperature and
          pressure.                                                                                     (5)
                                                                                                        [16]

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Physical Sciences/P2                                            9                          DBE/November 2015
                                                               NSC

QUESTION 5 (Start on a new page.)

Dilute acids, indicated in the table below, react with EXCESS zinc in each of the three
experiments to produce hydrogen gas. The zinc is completely covered with the acid in
each experiment.

                       EXPERIMENT                                DILUTE ACID
                                    1                   100 cm3 of 0,1 mol∙dm-3 H 2 SO 4
                                    2                   50 cm3 of 0,2 mol∙dm-3 H 2 SO 4
                                    3                    100 cm3 of 0,1 mol∙dm-3 HCℓ

The volume of hydrogen gas produced is measured in each experiment.

5.1       Name TWO essential apparatuses needed to determine the rate of hydrogen
          production.                                                                                            (2)

The graph below was obtained for Experiment 1.

                           Volume (cm3)
                                                                        Experiment 1

                                          0   t1   t2     t3         Time (s)

Use this graph and answer the questions that follow.

5.2       At which time (t 1 , t 2 or t 3 ) is the:

          5.2.1        Reaction rate the highest                                                                 (1)

          5.2.2        Mass of zinc present in the flask the smallest                                            (1)

5.3       In which time interval, between t 1 and t 2 OR between t 2 and t 3 , does the
          largest volume of hydrogen gas form per second?                                                        (1)

5.4       Redraw the graph for Experiment 1 in the ANSWER BOOK.

          On the same set of axes, sketch the graphs that will be obtained for
          Experiments 2 and 3. Clearly label the three graphs as EXPERIMENT 1,
          EXPERIMENT 2 and EXPERIMENT 3.                                                                         (4)

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Physical Sciences/P2                            10                                 DBE/November 2015
                                               NSC

5.5       The initial mass of zinc used in each experiment is 0,8 g. The balanced
          equation for the reaction in Experiment 3 is:

                               Zn(s) + 2HCℓ(aq) → ZnCℓ 2 (aq) + H 2 (g)

          5.5.1        Calculate the mass of zinc present in the flask after completion of
                       the reaction in Experiment 3.                                                     (5)

          5.5.2        How will the mass of zinc present in the flask after completion
                       of the reaction in Experiment 2 compare to the answer to
                       QUESTION 5.5.1? Write down only LARGER THAN, SMALLER
                       THAN or EQUAL TO.                                                                 (1)
                                                                                                         [15]

QUESTION 6 (Start on a new page.)

An unknown gas, X 2 (g), is sealed in a container and allowed to form X 3 (g) at 300 °C.
The reaction reaches equilibrium according to the following balanced equation:

                                      3X 2 (g) ⇌ 2X 3 (g)

6.1       How will the rate of formation of X 3 (g) compare to the rate of formation of
          X 2 (g) at equilibrium? Write down only HIGHER THAN, LOWER THAN or
          EQUAL TO.                                                                                      (1)

The reaction mixture is analysed at regular time intervals. The results obtained are
shown in the table below.

                              TIME        [ X2 ]              [ X3 ]
                               (s)      (mol∙dm-3)          (mol∙dm-3)
                                0           0,4                 0
                                2          0,22               0,120
                                4          0,08               0,213
                                6          0,06               0,226
                                8          0,06               0,226
                               10          0,06               0,226

6.2       Calculate the equilibrium constant, K c , for this reaction at 300 °C.                         (4)

6.3       More X 3 (g) is now added to the container.

          6.3.1        How will this change affect the amount of X 2 (g)? Write down
                       INCREASES, DECREASES or REMAINS THE SAME.                                         (1)

          6.3.2        Use Le Chatelier's       principle     to   explain   the     answer    to
                       QUESTION 6.3.1.                                                                   (2)

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Physical Sciences/P2                                            11                    DBE/November 2015
                                                               NSC

The curves on the set of axes below (not drawn to scale) was obtained from the results
in the table on page 10.

                             Concentration (mol∙dm-3)

                                                          t1               Time (s)
6.4       How does the rate of the forward reaction compare to that of the reverse
          reaction at t 1 ? Write down only HIGHER THAN, LOWER THAN or
          EQUAL TO.                                                                                          (1)

The reaction is now repeated at a temperature of 400 °C. The curves indicated by the
dotted lines below were obtained at this temperature.

                             Concentration (mol∙dm-3)
                                                                                      300 °C
                                                                                      400 °C

                                                                           Time (s)
6.5       Is the forward reaction EXOTHERMIC or ENDOTHERMIC? Fully explain how
          you arrived at the answer.                                                                         (4)
The Maxwell-Boltzmann distribution curve below represents the number of particles
against kinetic energy at 300 °C.

                                    Number of particles
                                                                     300 °C

                                                          Kinetic energy

6.6       Redraw this curve in the ANSWER BOOK. On the same set of axes, sketch
          the curve that will be obtained at 400 °C. Clearly label the curves as 300 °C
          and 400 °C respectively.                                                                           (2)
                                                                                                             [15]

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Physical Sciences/P2                            12                             DBE/November 2015
                                               NSC

QUESTION 7 (Start on a new page.)

7.1       Ammonium chloride crystals, NH 4 Cℓ(s), dissolve in water to form ammonium
          and chloride ions. The ammonium ions react with water according to the
          balanced equation below:

                              NH +4 (aq) + H 2 O(ℓ) ⇌ NH 3 (aq) + H 3 O+(aq)

          7.1.1        Write down the name of the process described by the underlined
                       sentence.                                                                     (1)

          7.1.2        Is ammonium chloride ACIDIC or BASIC in aqueous solution? Give
                       a reason for the answer.                                                      (2)

7.2       A certain fertiliser consists of 92% ammonium chloride. A sample of mass x g
          of this fertiliser is dissolved in 100 cm3 of a 0,10 mol∙dm-3 sodium hydroxide
          solution, NaOH(aq). The NaOH is in excess.

          The balanced equation for the reaction is:

                        NH 4 Cℓ(s) + NaOH(aq)  NH 3 (g) + H 2 O(ℓ) + NaCℓ(aq)

          7.2.1        Calculate the number of moles of sodium hydroxide in which the
                       sample is dissolved.                                                          (3)

          During a titration, 25 cm3 of the excess sodium hydroxide solution is titrated
          with a 0,11 mol∙dm-3 hydrochloric acid solution, HCℓ(aq). At the endpoint it is
          found that 14,55 cm3 of the hydrochloric acid was used to neutralise the
          sodium hydroxide solution according to the following balanced equation:

                              HCℓ(aq) + NaOH(aq)  NaCℓ(aq) + H 2 O(ℓ)

          7.2.2        Calculate the mass x (in grams) of the fertiliser sample used.                (8)

7.3       Calculate the pH of a 0,5 moldm-3 sodium hydroxide solution at 25 °C.                     (4)
                                                                                                     [18]

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                                                 NSC

QUESTION 8 (Start on a new page.)

Learners are given the following two unknown half-cells:

Half-cell 1: Q2+ (aq) | Q(s)

Half-cell 2: Pt | R 2 (g) | R-(aq)

During an investigation to identify the two half-cells, the learners connect each half-cell
alternately to a Cd2+(aq) | Cd(s) half-cell under standard conditions. For each
combination of two half-cells, they write down the net cell reaction and measure the
cell potential.

The results obtained for the two half-cell combinations are given in the table below.

       COMBINATION               NET CELL REACTION                  CELL POTENTIAL
            I                Q (aq) + Cd(s) → Cd2+(aq) + Q(s)
                               2+
                                                                         0,13 V
               II            R 2 (g) + Cd(s) → Cd2+(aq) + 2R-(aq)         1,76 V

8.1       Write down THREE conditions needed for these cells to function as standard
          cells.                                                                                   (3)

8.2       For Combination I, identify:

          8.2.1        The anode of the cell                                                       (1)

          8.2.2        Q by using a calculation                                                    (5)

8.3       For Combination II, write down the:

          8.3.1        Oxidation half-reaction                                                     (2)

          8.3.2        NAME or FORMULA of the metal used in the cathode
                       compartment                                                                 (1)

8.4       Arrange the following species in order of INCREASING oxidising ability:

          Q2+ ; R 2 ; Cd2+

          Explain fully how you arrived at the answer. A calculation is NOT required.              (4)
                                                                                                   [16]

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Physical Sciences/P2                         14                            DBE/November 2015
                                            NSC

QUESTION 9 (Start on a new page.)

The simplified diagram below represents an electrochemical cell used for the
purification of copper.
                                      DC source

               Electrode A
                                                           Electrode B
                                                           (impure copper)
               Electrolyte

9.1       Define the term electrolysis.                                                          (2)

9.2       Give a reason why a direct-current (DC) source is used in this experiment.             (1)

9.3       Write down the half-reaction which takes place at electrode A.                         (2)

9.4       Due to small amounts of zinc impurities in the impure copper, the electrolyte
          becomes contaminated with Zn2+ ions.

          Refer to the attached Table of Standard Reduction Potentials to explain why
          the Zn2+ ions will not influence the purity of the copper obtained during this
          process.                                                                               (3)

9.5       After the purification of the impure copper was completed, it was found that
          2,85 x 10-2 moles of copper were formed.

          The initial mass of electrode B was 2,0 g. Calculate the percentage of copper
          that was initially present in electrode B.                                             (4)
                                                                                                 [12]

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                                                     NSC

QUESTION 10 (Start on a new page.)

Ammonia is an important fertiliser. Large amounts are prepared from hydrogen and
nitrogen in industry.

10.1      For the industrial preparation of ammonia, write down:

          10.1.1            The name of the process used                                               (1)

          10.1.2            A balanced equation for the reaction that occurs                           (3)

          10.1.3            The source of nitrogen                                                     (1)

10.2      The yield of ammonia changes with temperature and pressure during its
          industrial preparation. The graphs below show how the percentage of
          ammonia in the reaction mixture that leaves the reaction vessel varies under
          different conditions.

                              GRAPHS OF THE PERCENTAGE OF AMMONIA IN
                               THE REACTION MIXTURE VERSUS PRESSURE

                                                                               300 °C

              Percentage
                                                                               400 °C
                                                                               500 °C

                                           Pressure (atmosphere)
          10.2.1            Use the appropriate graph to estimate the percentage of ammonia
                            present in the reaction mixture at 240 atmosphere and 400 °C.              (1)

          10.2.2            State TWO advantages of using high pressure in the preparation of
                            ammonia.                                                                   (2)

          10.2.3            The advantage of using a low temperature is the large percentage
                            of ammonia formed. What is the disadvantage of using a low
                            temperature?                                                               (1)

10.3      Ammonia is also used in the preparation of other fertilisers such as
          ammonium nitrate. Calculate the mass of nitrogen in a 50 kg bag of pure
          ammonium nitrate fertiliser.                                                                 (3)
                                                                                                       [12]

                                                                                        TOTAL:         150

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Physical Sciences/P2                                                                                     DBE/November 2015
                                                                  NSC

                                DATA FOR PHYSICAL SCIENCES GRADE 12
                                        PAPER 2 (CHEMISTRY)

                         GEGEWENS VIR FISIESE WETENSKAPPE GRAAD 12
                                    VRAESTEL 2 (CHEMIE)

TABLE 1: PHYSICAL CONSTANTS/TABEL 1: FISIESE KONSTANTES

NAME/NAAM                                      SYMBOL/SIMBOOL                          VALUE/WAARDE
Standard pressure
                                                               pθ                        1,013 x 105 Pa
Standaarddruk
Molar gas volume at STP
                                                               Vm                        22,4 dm3∙mol-1
Molêre gasvolume by STD
Standard temperature
                                                               Tθ                                273 K
Standaardtemperatuur
Charge on electron
                                                                e                         -1,6 x 10-19 C
Lading op elektron
Avogadro's constant
                                                               NA                       6,02 x 1023 mol-1
Avogadro-konstante

TABLE 2: FORMULAE/TABEL 2: FORMULES

       m                                                         N
  n=                                                        n=
       M                                                         NA
       n                                 m                        V
  c=         or/of                  c=                      n=
       V                                 MV                       Vm
  c a v a na
         =                                                  pH = -log[H 3 O+]
  c b v b nb

  K w = [H 3 O+][OH-] = 1 x 10-14 at/by 298 K

  Eθcell = Eθcathode − Eθanode / E θsel = E katode
                                            θ
                                                   − E θanode

  or/of
  E θcell = E reduction
              θ
                        − E θoxidation / E θsel = E reduksie
                                                    θ
                                                             − E θoksidasie

  or/of
  E θcell = E oxidising
              θ                   θ                  θ       θ                  θ
                        agent − E reducing agent / E sel = E oksideermiddel − E reduseermiddel

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Physical Sciences/P2
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                                                                                                  NSC
                                                                TABLE 3: THE PERIODIC TABLE OF ELEMENTS
                                                               TABEL 3: DIE PERIODIEKE TABEL VAN ELEMENTE

       1           2           3           4           5           6           7           8           9           10          11           12       13          14         15           16          17         18
      (I)         (II)                                                                                                                              (III)       (IV)        (V)         (VI)        (VII)      (VIII)
                                                                                   Atomic number
        1                                        KEY/SLEUTEL                         Atoomgetal                                                                                                                   2
2,1    H                                                                                                                                                                                                        He
        1                                                                                  29                                                                                                                    4
        3           4                             Electronegativity                                        Symbol                                        5           6           7           8           9       10
                                                                                     1,9   Cu
1,0    Li   1,5    Be                            Elektronegatiwiteit
                                                                                           63,5
                                                                                                           Simbool                                2,0    B    2,5    C    3,0    N    3,5   O     4,0    F      Ne
       7             9                                                                                                                                  11          12          14          16          19       20
       11           12                                                                                                                                  13          14          15          16          17       18
0,9   Na    1,2   Mg                                           Approximate relative atomic mass                                                   1,5   Aℓ    1,8   Si    2,1    P    2,5    S    3,0   Cℓ       Ar
       23           24                                         Benaderde relatiewe atoommassa                                                           27          28          31          32          35,5     40
       19           20         21          22          23          24          25          26          27          28          29           30          31          32          33          34           35      36
0,8    K    1,0    Ca    1,3   Sc    1,5   Ti    1,6    V    1,6   Cr    1,5   Mn    1,8   Fe    1,8   Co    1,8   Ni    1,9   Cu     1,6   Zn    1,6   Ga    1,8   Ge    2,0   As    2,4   Se    2,8   Br       Kr
       39           40         45          48          51          52          55          56          59          59          63,5         65          70          73          75          79          80       84
       37           38         39          40          41          42          43          44          45          46           47          48          49          50          51          52          53       54
0,8   Rb    1,0    Sr    1,2   Y     1,4   Zr          Nb    1,8   Mo    1,9   Tc    2,2   Ru    2,2   Rh    2,2   Pd    1,9   Ag     1,7   Cd    1,7   In    1,8   Sn    1,9   Sb    2,1   Te    2,5    I       Xe
       86           88         89          91          92          96                      101         103         106         108          112         115         119         122         128         127      131
       55           56         57          72          73          74          75           76          77          78         79           80          81          82           83         84           85      86
0,7   Cs    0,9    Ba          La    1,6   Hf          Ta          W           Re          Os           Ir         Pt          Au           Hg    1,8   Tℓ    1,8   Pb    1,9   Bi    2,0   Po    2,5   At      Rn
      133          137         139         179         181         184         186         190         192         195         197          201         204         207         209
       87           88          89
0,7    Fr   0,9    Ra          Ac                      58          59      60              61          62          63          64           65          66          67          68          69          70      71
                   226
                                                   Ce          Pr          Nd         Pm          Sm           Eu          Gd           Tb          Dy          Ho          Er          Tm          Yb         Lu
                                                   140         141         144                     150         152         157          159         163         165         167         169         173        175
                                                       90          91      92              93          94          95          96           97          98          99      100         101         102        103
                                                   Th          Pa              U       Np          Pu         Am          Cm            Bk          Cf          Es          Fm          Md          No          Lr
                                                   232                     238

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Physical Sciences/P2                                                                                                                                     DBE/November 2015
                                                                                                                  NSC
                                                                            TABLE 4A: STANDARD REDUCTION POTENTIALS
                                                                            TABEL 4A: STANDAARD-REDUKSIEPOTENSIALE
                                                                                                                                                θ
                                                                                  Half-reactions/Halfreaksies                                   E (V)
                                                                                                            −              −
                                                                                          F 2 (g) + 2e            ⇌   2F                        + 2,87
                                                                                                 3+         −                  2+
                                                                                            Co           +e       ⇌   Co                        + 1,81
                                                                                                 +
                                                                                  H 2 O 2 + 2H +2e−               ⇌   2H 2 O                    +1,77
                                                                                    −     +                                    2+
                                                                                MnO 4 + 8H + 5e−                  ⇌   Mn             + 4H 2 O   + 1,51
                                                                                                              −                −
                                                                                         Cℓ 2 (g) + 2e            ⇌   2Cℓ                       + 1,36
                                                                                     2−     +                                   3+
                                                                              Cr 2 O 7 + 14H + 6e−                ⇌   2Cr            + 7H 2 O   + 1,33
                                                                                                +           −
                                                                                 O 2 (g) + 4H + 4e                ⇌   2H 2 O                    + 1,23
                                                                                                 +            −                2+
                                                                                 MnO 2 + 4H + 2e                  ⇌   Mn             + 2H 2 O   + 1,23
                                                                                           2+
                                                                                         Pt + 2e−                 ⇌   Pt                        + 1,20
                                                                                         Br 2 (ℓ) + 2e−           ⇌   2Br−                      + 1,07
                                                                                    −     +
                                                                                 NO 3 + 4H + 3e−                  ⇌   NO(g) + 2H 2 O            + 0,96

                                                                                                                                                             Increasing reducing ability/Toenemende reduserende vermoë
                                                                                                2+            −
                                                                                          Hg         + 2e         ⇌   Hg(ℓ)                     + 0,85
                                                                                                     +
                                                                                             Ag + e−              ⇌   Ag                        + 0,80

              Increasing oxidising ability/Toenemende oksiderende vermoë
                                                                                     −     +
                                                                                  NO 3 + 2H + e−                  ⇌   NO 2 (g) + H 2 O          + 0,80
                                                                                                 3+                        2+
                                                                                            Fe           + e−     ⇌   Fe                        + 0,77
                                                                                                +
                                                                                 O 2 (g) + 2H + 2e−               ⇌   H2O2                      + 0,68
                                                                                                            −              −
                                                                                               I 2 + 2e           ⇌   2I                        + 0,54
                                                                                                     +      −
                                                                                             Cu + e               ⇌   Cu                        + 0,52
                                                                                                +
                                                                                  SO 2 + 4H + 4e−                 ⇌   S + 2H 2 O                + 0,45
                                                                                  2H 2 O + O 2 + 4e−              ⇌   4OH−                      + 0,40
                                                                                                2+            −
                                                                                          Cu         + 2e         ⇌   Cu                        + 0,34
                                                                                    2−           +
                                                                                 SO 4 + 4H + 2e−                  ⇌   SO 2 (g) + 2H 2 O         + 0,17
                                                                                                 2+         −                  +
                                                                                            Cu           +e       ⇌   Cu                        + 0,16
                                                                                                4+            −                2+
                                                                                           Sn        + 2e         ⇌   Sn                        + 0,15
                                                                                                +
                                                                                     S + 2H + 2e−                 ⇌   H 2 S(g)                  + 0,14
                                                                                                 +            −
                                                                                           2H + 2e                ⇌   H 2 (g)                    0,00
                                                                                                3+
                                                                                           Fe        + 3e−        ⇌   Fe                        − 0,06
                                                                                                2+
                                                                                           Pb        + 2e−        ⇌   Pb                        − 0,13
                                                                                                2+
                                                                                           Sn        + 2e−        ⇌   Sn                        − 0,14
                                                                                                2+
                                                                                           Ni        + 2e−        ⇌   Ni                        − 0,27
                                                                                                2+            −
                                                                                          Co         + 2e         ⇌   Co                        − 0,28
                                                                                                2+
                                                                                          Cd         + 2e−        ⇌   Cd                        − 0,40
                                                                                                 3+         −              2+
                                                                                            Cr           +e       ⇌   Cr                        − 0,41
                                                                                                2+
                                                                                           Fe        + 2e−        ⇌   Fe                        − 0,44
                                                                                                3+
                                                                                           Cr        + 3e−        ⇌   Cr                        − 0,74
                                                                                                2+
                                                                                           Zn        + 2e−        ⇌   Zn                        − 0,76
                                                                                                              −                             −
                                                                                         2H 2 O + 2e              ⇌   H 2 (g) + 2OH             − 0,83
                                                                                                2+
                                                                                           Cr        + 2e−        ⇌   Cr                        − 0,91
                                                                                               2+
                                                                                          Mn         + 2e−        ⇌   Mn                        − 1,18
                                                                                                3+
                                                                                           Aℓ        + 3e−        ⇌   Aℓ                        − 1,66
                                                                                               2+           −
                                                                                          Mg         + 2e         ⇌   Mg                        − 2,36
                                                                                                     +
                                                                                             Na + e−              ⇌   Na                        − 2,71
                                                                                                2+
                                                                                          Ca         + 2e−        ⇌   Ca                        − 2,87
                                                                                                2+            −
                                                                                           Sr + 2e                ⇌   Sr                        − 2,89
                                                                                                2+
                                                                                           Ba        + 2e−        ⇌   Ba                        − 2,90
                                                                                                     +        -
                                                                                             Cs + e               ⇌   Cs                        - 2,92
                                                                                                     +
                                                                                                K + e−            ⇌   K                         − 2,93
                                                                                                     +
                                                                                                Li + e−           ⇌   Li                        − 3,05
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