# Physical Sciences Grade 12 Paper 2 NSC November 2021 Memo

> Grade 12 Physical Sciences Paper 2 memorandum from the NSC November Exam 2021, 21 pages. Read online or download the free PDF.

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- Updated: 2026-10-29
- Subject: Physical Sciences
- Grade: Grade 12
- Document type: Memorandum
- Year: 2021
- Exam period: NSC November Exam
- Paper: 2
- Curriculum: CAPS
- Pages: 21

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### Page 1

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                                      NATIONAL
                                 SENIOR CERTIFICATE
                                     NASIONALE
                                 SENIOR SERTIFIKAAT

                                    GRADE/GRAAD 12

                      PHYSICAL SCIENCES: CHEMISTRY (P2)
                       FISIESE WETENSKAPPE: CHEMIE (V2)

                                        NOVEMBER 2021

                      MARKING GUIDELINES/NASIENRIGLYNE

MARKS/PUNTE: 150

                      These marking guidelines consist of 21 pages.
                       Hierdie nasienriglyne bestaan uit 21 bladsye.

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Physical Sciences P2/Fisiese Wetenskappe V2     2                              DBE/November 2021
                             NSC/NSS – Marking Guidelines/Nasienriglyne

QUESTION 1/VRAAG 1

1.1      D                                                                                           (2)

1.2      D                                                                                           (2)

1.3      A                                                                                           (2)

1.4      B                                                                                           (2)

1.5      D                                                                                           (2)

1.6      D                                                                                           (2)

1.7      C                                                                                           (2)

1.8      B                                                                                           (2)

1.9      A                                                                                           (2)

1.10     B                                                                                            (2)
                                                                                                       [20]

QUESTION 2/VRAAG 2

2.1       A compound that contains a double bond/multiple bond/does NOT contain
          only single bonds (between C atoms).  (2 or 0)
          'n Verbinding wat dubbelbindings/meervoudige bindings/NIE net enkel-
          bindings (tussen C-atome) bevat NIE. (2 of 0)                                                (2)

2.2
2.2.1    B/E                                                                                          (1)

2.2.2     Carbonyl (group bonded to two C atoms)                         ACCEPT/AANVAAR
          Karboniel(groep gebind aan twee C-atome)                        Ketone/Ketoon                (1)

2.2.3     F                                                                                          (2)

2.2.4     2,5-dichloro-3-methylhexane/2,5-dichloro-3-metielheksaan
          Marking criteria:
             Correct stem i.e. hexane. 
             All substituents (dichloro and methyl) correctly identified. 
             IUPAC name completely correct including numbering, sequence, hyphens and
              commas. 
          Nasienkriteria:
             Korrekte stam d.i. heksaan. 
             Alle substituente (dichloro en metiel) korrek geïdentifiseer. 
             IUPAC-naam heeltemal korrek insluitende nommering, volgorde, koppeltekens
              en kommas.                                                                              (3)

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                             NSC/NSS – Marking Guidelines/Nasienriglyne

2.2.5     CnH2n                                                                                       (1)

2.3       Compounds with the same molecular formula,  but different functional
          groups/homologous series. 
          Verbindings met dieselfde molekulêre formule, maar verskillende funksionele
          groepe/homoloë reekse.                                                                       (2)

2.4
2.4.1     Carboxylic acids/Karboksielsure                                                             (1)

2.4.2                     H                     Marking criteria/Nasienkriteria:
               O                                  Whole structure correct/
                                                    Hele struktuur korrek:                  2
          H    C      O    C     H                                                             2
                                                  Only functional group correct/Slegs
                                                    funksionele groep korrek: Max/Maks.: 1
                           H                                                                    2
                                                 IF/INDIEN
                                                 More than one functional group:
                                                 Meer as een funksionele groep:              0
                                                                                                 2
          IF/INDIEN
             Molecular formula/Molekulêre formule 0
                                                       2
             Condensed structural formula /Gekondenseerde struktuurformule 1
                                                                                 2                     (2)

2.5
2.5.1     Ethanol/Etanol                                                                              (1)

2.5.2     E              ACCEPT/AANVAAR: C2H4                                                         (1)

2.5.3     (Concentrated) sulphuric acid/H2SO4/(concentrated) phosphoric acid/H3PO4 
          (Gekonsentreerde) swawelsuur/ H2SO4/(gekonsentreerde) fosforsuur/ H3PO4                       (1)
                                                                                                       [18]

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                             NSC/NSS – Marking Guidelines/Nasienriglyne

QUESTION 3/VRAAG 3

3.1       Marking criteria/Nasienkriteria:
          If any one of the underlined key phrases in the correct context is omitted, deduct 1
          mark./Indien enige van die onderstreepte frases in die korrekte konteks uitgelaat is,
          trek 1 punt af.
          The temperature at which solid and liquid phases are in equilibrium. 
          Die temperatuur waarby die vastestof- en vloeistoffases van 'n stof in ewewig
          is.                                                                                          (2)

3.2       Marking criteria
           Identification of independent variable. 
           Stating the relationship between dependent and independent variable. 
          Nasienkriteria
           Identifikasie van onafhanklike veranderlike. 
           Stel verwantskap tussen afhanklike en onafhanklike veranderlikes. 
           As the chain length/number of C atoms/molecular mass/surface
            area/strength of the intermolecular forces  increases, the melting points
            increase. 
            OR
           As the chain length/ number of C atoms/molecular mass/surface
            area/strength of the intermolecular forces  decreases, the melting points
            decrease. 

           Wanneer die kettinglengte/aantal C-atome/molekulêre massa/oppervlak-
            area/sterkte van intermolekulêre kragte  toeneem, neem die smeltpunte
            toe.
            OF
           Wanneer die kettinglengte/aantal C-atome/molekulêre massa/oppervlak-
            area/sterkte van intermolekulêre kragte afneem, neem die smeltpunte af.                    (2)

3.3       London forces                        ACCEPT/AANVAAR
          Londonkragte                          Dispersion forces/induced dipole forces
                                                Dispersiekragte/geïnduseerde dipoolkragte              (1)

3.4
3.4.1     Liquid/Vloeistof                                                                            (1)

3.4.2     Solid/Vaste stof                                                                            (1)

3.5
3.5.1     Equal to/Gelyk aan 

          Same molecular formula/Isomers/same number and types of atoms/same
          number of C and H atoms 
          Dieselfde molekulêre formule/Isomere/dieselfde aantal en soort atome/
          dieselfde aantal C- en H-atome                                                               (2)

3.5.2     Lower than/Laer as                                                                          (1)

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                             NSC/NSS – Marking Guidelines/Nasienriglyne

3.5.3     Marking criteria:
           Compare structures. 
           Compare the strength of intermolecular forces.
           Compare the energy required to overcome intermolecular forces. 
          2,2-dimethylbutane:
           Structure:
              More branched/more compact/more spherical/smaller surface area (over
              which intermolecular forces act).
           Intermolecular forces:
              Weaker/less intermolecular forces/Van der Waals forces/London
              forces/dispersion forces. 
           Energy:
              Lesser energy needed to overcome or break intermolecular forces/Van
              der Waals forces. 
          OR
          Hexane
           Structure:
              Longer chain length/unbranched/less compact/less spherical/larger
              surface area (over which intermolecular forces act). 
           Intermolecular forces:
              Stronger/more intermolecular forces/Van der Waals forces/London
              forces/dispersion forces. 
           Energy:
              More energy needed to overcome or break intermolecular forces/Van der
              Waals forces. 
          Nasienkriteria:
           Vergelyk strukture 
           Vergelyk die sterkte van intermolekulêre kragte. 
           Vergelyk die energie benodig om intermolekulêre kragte te oorkom. 
          2,2-dimetielbutaan:
           Struktuur:
              Meer vertak/meer kompak/meer sferies/kleiner oppervlak (waaroor
              intermolekulêre kragte werk). 
           Intermolekulêre kragte:
              Swakker/minder intermolekulêre kragte/Van der Waalskragte/London-
              kragte/dispersiekragte. 
           Energie:
              Minder energie benodig om intermolekulêre kragte/Van der Waalskragte/
              dispersiekragte/Londonkragte te oorkom/breek. 
          OF
          Heksaan
           Struktuur:
              Langer kettinglengte/onvertak/minder kompak/minder sferies/groter
              oppervlak (waaroor intermolekulêre kragte werk). 
           Intermolekulêre kragte:
              Sterker/meer intermolekulêre kragte/Van der Waalskragte/Londonkragte/
              dispersiekragte. 
           Energie:
              Meer energie benodig om intermolekulêre kragte/Van der Waalskragte/
              dispersiekragte/Londonkragte te oorkom/breek.                                            (3)
                                                                                                       [13]

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                             NSC/NSS – Marking Guidelines/Nasienriglyne

QUESTION 4/VRAAG 4

4.1
4.1.1    Substitution/Hydrolysis 
         Substitusie/Hidrolise                                                                         (1)

4.1.2     Primary (alcohol) 
          ANY ONE:
           The C atom of the functional group is the terminal C atom.
           The C-atom bonded to the hydroxyl/-OH is bonded to (only) one other C-
             atom. 
           The hydroxyl/-OH is bonded to a C-atom which is bonded to two hydrogen
             atoms.
           The hydroxyl/-OH is bonded to a primary C atom/terminal C atom/first C
             atom.

          Primêre (alkohol) 
          ENIGE EEN:
           Die C-atoom van die funksionele groep is die terminale C-atoom.
           Die C-atoom wat aan die hidroksiel/-OH gebind is, is aan (slegs) een
             ander C-atoom gebind. 
           Die hidroksiel/-OH is gebind aan 'n C-atoom wat aan twee waterstofatome
             gebind is.
           Die hidroksiel/-OH is aan 'n primêre C-atoom/terminale C-atoom/eerste C-
             atoom gebind.                                                                             (2)

4.1.3                    H                     Marking criteria:
                                               Four C atoms in longest chain. 
                   H     C     H                One methyl substituent on C2. 
                                                Bromo substituent on C1. 
              H    H          H                Nasienkriteria:
                                                Vier C-atome in langste ketting. 
         H    C    C     C    C     H          Een metielsubstituent op C2. 
                                                Broomsubstituent op C1. 
              H    H     H    Br 
                                               IF/INDIEN
                                               Any error e.g. omission of H atoms, condensed
                                               or semi structural formula/Enige fout bv.
                                               weglating van H-atome, gekondenseerde of
                                               semi-struktuurformule.          Max/Maks.: 2
                                                                                              3        (3)

4.1.4     Elimination/dehydrohalogenation/dehydrobromination 
          Eliminasie/dehidrohalogenering/dehidrohalogenasie/dehidrobrominasie/
          dehidrobromonering                                                                           (1)

4.1.5     Alkenes/Alkene                                                                              (1)

4.1.6     Addition/Addisie                                                                            (1)

4.1.7     2-bromo-2-methylbutane 
          2-bromo-2-metielbutaan                                                                     (2)
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                             NSC/NSS – Marking Guidelines/Nasienriglyne

4.2       NOTE/LET WEL:
           Penalise only once for the use of structural formulae or molecular formulae.
           Penaliseer slegs een keer vir die gebruik van struktuurformules of molekulêre
            formules.
4.2.1     Marking criteria:
              Correct condensed structure for but-2-ene. 
              React but-2-ene with H2/H — H. 
              Indicate the catalyst Pt/Ni/Pd on arrow/at the equation. 
              Correct condensed formula for butane as product. 
          IF: Any additional products or reactants - minus 1 mark
          Nasienkriteria:
             Korrekte gekondenseerde struktuur vir but-2-een. 
             Reageer but-2-een met H2/H — H. 
             Dui die katalisator Pt/Ni/Pd op die pyl/by die vergelyking aan. 
             Korrekte gekondenseerde formule vir butaan as produk. 
          INDIEN: Enige addisionele reaktanse of produkte – minus 1 punt
                                        Pt/Ni/Pd 
          CH3CHCHCH3  + H2                               CH3CH2CH2CH3 

          ACCEPT/AANVAAR
          As reactant/reaktans: CH3(CH)2CH3 / CH3CH ═ CHCH3 / CH3 — CH ═ CH — CH3
          As product/produk: CH3(CH2)2CH3 / CH3 — CH2 — CH2 — CH3 /CH3 — (CH2)2 —
          CH3                                                                                           (4)

4.2.2     Elimination/Cracking 
          Eliminasie/Kraking                                                                            (1)

4.2.3     Propene/1-propene/prop-1-ene 
          Propeen/1-propeen/prop-1-een                                                                  (2)

4.2.4     Marking criteria:
              Correct condensed formula for propene as reactant. 
              React (propene) with Br2/Br — Br 
              Correct condensed formula for 1,2-dibromopropane as product. 
          IF: Any additional products or reactants - minus 1 mark
          Nasienkriteria:
             Korrekte gekondenseerde formule vir propeen as reaktans. 
             Reageer (propeen) met Br2/Br — Br. 
             Korrekte gekondenseerde formule vir 1,2-dibromopropaan as produk. 
          INDIEN: Enige addisionele reaktanse of produkte – minus 1 punt

          CH3CHCH2  + Br2                             CH3CHBrCH2Br 

          ACCEPT/AANVAAR:
          As reactant/reaktans: CH3CH ═ CH2 / CH2 ═ CHCH3
          As product/produk: CH3CHBrCH2Br / CH3 — CH — CH2 /

                                                          Br     Br

                                BrCH2CHBrCH3 / CH2 — CH — CH3
                                                   Br      Br                                            (3)
                                                                                                        [21]
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                             NSC/NSS – Marking Guidelines/Nasienriglyne

QUESTION 5/VRAAG 5

5.1       NOTE/LET WEL
          Give the mark for per unit time only if in context of reaction rate.
          Gee die punt vir per eenheidtyd slegs indien in konteks van reaksietempo.

          ANY ONE
           Change in concentration  of products/reactants per (unit) time. 
             Change in amount/number of moles/volume/mass of products or reactants
              per (unit) time.
             Amount/number of moles/volume/mass of products formed/reactants used
              per (unit) time.
             Rate of change            in   concentration/amount     of   moles/number        of
              moles/volume/
              mass.  (2 or 0)

          ENIGE EEN
           Verandering in konsentrasie  van produkte/reaktanse per (eenheid) tyd.
           Verandering in hoeveelheid/getal mol/volume/massa van produkte of
            reaktanse per (eenheid) tyd.
           Hoeveelheid/getal mol/volume/massa van produkte gevorm/reaktanse
            gebruik per (eenheid) tyd.
           Tempo van verandering in konsentrasie/ hoeveelheid mol/getal mol/
            volume/ massa.  (2 of 0)                                                                 (2)

5.2       Reaction rate decreases./Concentration of HCℓ decreases./Concentration of
          reactant decreases./Reactants are used up/Mass of CaCO3 decreases or is
          used up. 
          Reaksietempo neem af./Konsentrasie van HCℓ neem af./Konsentrasie van
          reaktans neem af./Reaktanse word opgebruik./Massa van CaCO3 neem af of
          word opgebruik.                                                                             (1)
5.3
5.3.1     Exothermic/Eksotermies                                                                      (1)

5.3.2      Gradient increases/becomes steeper. / Curve becomes steeper. 
           Reaction rate increases/More (or larger volume) of CO2 is produced per
            unit time. 
           Temperature increases./Energy is released/Average kinetic energy of the
            molecules increases. 

           Gradiënt neem toe/word steiler. / Kurwe word steiler. 
           Reaksietempo neem toe./Meer (of groter volume) CO2 word produseer per
            eenheidtyd. 
           Temperatuur neem toe./Energie word vrygestel./Gemiddelde kinetiese
            energie van molekule neem toe.                                                            (3)

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5.4       Marking criteria
                                82,5                        82,5
           m(pure CaCO3) =             x 15  / V(CO2) =          x V(CO2) from/uit 15 g CaCO3
                                 100                   100
             Divide by 100 g∙mol-1. 
             Use mol ratio: n(CO2) = n(CaCO3). 
             Multiply n(CO2) by 24 000 cm3/24 dm3. 
             Final answer: 2 976 cm3 
             Range: 2880 to 2970 cm3 / 2,88 to 2,97 dm3

          Nasienkriteria
                                  82,5                       82,5
           m(suiwer CaCO3) =            x 15  / V(CO2) =          x V(CO2) uit 15 g CaCO3
                                   100                    100
                                 -1
              Deel deur 100 g∙mol . 
             Gebruik molverhouding: n(CO2) = n(CaCO3). 
             Vermenigvuldig n(CO2) met 24 000 cm3/24 dm3. 
             Finale antwoord: 2 976 cm3 
              Gebied: 2880 tot 2970 cm3 / 2,88 tot 2,97 dm3
          OPTION 1/OPSIE 1                             OPTION 2/OPSIE 2
                                      82,5             IF 15 g PURE CaCO3 reacts:
          m(pure/suiwer CaCO3) =           x 15       INDIEN 15 g SUIWER CaCO3 reageer:
                                      100
                                   = 12,375 g                           m
                                                       n(CaCO3) =
                                                                        M
                                     m                                   15
          n(pure/suiwer CaCO3) =                                      =
                                     M                                  100 
                                     12,375                           = 0,15 mol
                                   =
                                       100 
                                   = 0,124 mol         n(CO2) = n(CaCO3) 
                                                              = 0,15 mol
          n(CO2) = n(CaCO3)
                 = 0,124 mol                                     V
                                                       n(CO2) =
                                                                 VM
                                                                 V              V
          V(CO2) = 0,124 x 24 000                      0,15 =           / 0,15 =
                                                               24 000           24
                 = 2 976 cm3                                         3
                                                          V = 3 600 cm /     V = 3,6 dm3
          OR/OF
                                                      Actual CO2 formed:
          V(CO2) = 0,124 x 24
                                                       Werklike CO2 gevorm:
                 = 2,98 dm3 
                                                                 82,5
                                                       V(CO2) =       x 3 600 / 3,6 
                                                                 100
                                                              = 2 976 cm3 / 2,976 dm3                     (5)

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          OPTION 3/OPSIE 3
          IF 15 g PURE CaCO3 reacts:/INDIEN 15 g SUIWER CaCO3 reageer:
                          m
          n(CaCO3) =
                          M
                           15
                        =
                          100 
                        = 0,15 mol

          n(CO2) = n(CaCO3) 
                 = 0,15 mol

                   m
          n(CO2) =
                   M
          m(CO2) = 0,15 x 44
                 = 6,6 g

                    m actual/ werklik 
          82,5 =                      x 100
                          6,6
          m(actual/werklik) = 5,445 g

                      m
          n(CO2) =
                      M
                      5,445
                    =
                        44
                    = 0,12375 mol

                       V
          n(CO2) =
                       VM
                        V                 V
          0,12375 =           / 0,12375 =
                     24 000              24
                       3          3
          V = 2 976 cm / 2,976 dm                                                                     (5)

5.5       Increases/Toeneem                                                                           (1)

5.6        More (CaCO3) particles with correct orientation/exposed./ Greater
            (exposed) surface area. 
           More effective collisions per unit time./Higher frequency of effective
            collisions. 

           Meer (CaCO3)-deeltjies met korrekte oriëntasie/blootgestel./ Groter
            (blootgestelde) reaksieoppervlakte. 
           Meer effektiewe botsings per eenheid tyd./Hoër frekwensie van effektiewe
            botsings.
          NOTE/LET WEL
           If explanation in terms of CONCENTRATION: No mark for bullet 1.
            Indien verduideliking in terme van KONSENTRASIE: Geen punt vir kolpunt 1.
           Bullets are marked independently./Kolpunte word onafhanklik nagesien.                       (2)
                                                                                                       [15]

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Physical Sciences P2/Fisiese Wetenskappe V2    11                              DBE/November 2021
                             NSC/NSS – Marking Guidelines/Nasienriglyne

QUESTION 6/VRAAG 6

6.1      (The stage in a chemical reaction when the) rate of forward reaction equals
         the rate of reverse reaction.  (2 or 0)
         OR
         (The stage in a chemical reaction when the) concentrations of reactants and
         products remain constant. (2 or 0)

         (Die stadium in 'n chemiese reaksie wanneer die) tempo van die voorwaartse
         reaksie gelyk is aan die tempo van die terugwaartse reaksie. (2 of 0)
         OF
         (Die stadium in 'n chemiese reaksie wanneer die) konsentrasies van
         reaktanse en produkte konstant bly. (2 of 0)                                                  (2)

6.2
6.2.1     Negative/Negatief                                                                           (1)

6.2.2      Increase    in   temperature      favours an   endothermic reaction.
            Accept: Decrease in temperature favours an exothermic. 
           Reverse reaction is favoured./Concentration of reactants increases./
            Concentration of products decreases. 
           (Forward) reaction is exothermic.
            Accept: Reverse reaction is endothermic. 

           Toename in temperatuur bevoordeel 'n endotermiese reaksie. 
            Aanvaar: Afname in temperatuur bevoordeel die eksotermiese reaksie.
           Terugwaartse reaksie word bevoordeel./Konsentrasie van reaktanse neem
            toe./Konsentrasie van produkte neem af. 
           (Voorwaartse) reaksie is eksotermies.
            Aanvaar: Terugwaartse reaksie is endotermies.                                             (3)

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                             NSC/NSS – Marking Guidelines/Nasienriglyne

6.2.3    CALCULATIONS USING NUMBER OF MOLES
         BEREKENINGE WAT GETAL MOL GEBRUIK
         Marking criteria:
         a) Initial n(P) and n(Q2) and n(PQ) from table. 
         b) Change in n(P) = equilibrium n(P) – initial n(P).
         c) USING ratio: P : Q2 : PQ = 2 : 1 : 2 
         d) Equilibrium n(Q2) = initial n(Q2) + change in n(Q2)
                                                                    
            Equilibrium n(PQ) = initial n(PQ) - change in n(PQ)
         e) Divide equilibrium amounts of P and Q2 and PQ by 2 dm3. 
         f) Correct Kc expression (formulae in square brackets). 
         g) Substitution of equilibrium concentrations into Kc expression. 
         h) Final answer: 10,889 

         Nasienkriteria:
         a) Aanvanklike n(P) en n(Q2) en n(PQ) uit tabel.
         b) Verandering in n(P) = ewewigs n(P) – aanvanklike n(P).
         c) GEBRUIK verhouding: P : Q2 : PQ = 2 : 1 : 2 
         d) Ewewig n(Q2) = aanvanklike n(Q2) + verandering in n(Q2)
             Ewewig n(PQ) = aanvanklike n(PQ) - verandering in n(PQ) 
         e) Deel ewewigshoeveelhede van P en Q2 en PQ deur 2 dm3. 
         f)  Korrekte Kc-uitdrukking (formules in vierkanthakies). 
         g) Vervanging van ewewigskonsentrasies in Kc-uitdrukking. 
         h) Finale antwoord: 10,89 / 10,889 
                                                                                                       (3)
          OPTION 1/OPSIE 1

                                                          P          Q2        PQ
           Initial quantity (mol)
                                                         0,8        0,8        3,2     (a)
           Aanvangshoeveelheid (mol)
           Change (mol)
                                                       0,4 (b)     0,2        0,4    (c)
           Verandering (mol)
           Quantity at equilibrium (mol)/
           Hoeveelheid by ewewig (mol)
                                                         1,2        1,0        2,8        (d)
           Equilibrium concentration (mol∙dm-3)                                         (e)
                                                         0,6        0,5      1,4
           Ewewigskonsentrasie (mol∙dm-3)

                                          No Kc expression, correct substitution/Geen Kc-
                [PQ] 2
          Kc              (f)           uitdrukking, korrekte substitusie: Max./Maks.
               [Q 2 ][P] 2
                    1,4 2                 Wrong Kc expression/Verkeerde Kc-uitdrukking:
              =               (g)
                (0,5)(0,6) 2              Max./Maks.
              = 10,89  (h)

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Physical Sciences P2/Fisiese Wetenskappe V2    13                                DBE/November 2021
                             NSC/NSS – Marking Guidelines/Nasienriglyne

          OPTION 2/OPSIE 2

                                                        PQ          P            Q2
           Initial quantity (mol)
                                                        3,2        0,8           0,8   (a)
           Aanvangshoeveelheid (mol)
           Change (mol)
                                                        0,4      0,4 (b)        0,2 (c)
           Verandering (mol)
           Quantity at equilibrium (mol)/                                 (d)
                                                        2,8        1,2           1,0
           Hoeveelheid by ewewig (mol)
           Equilibrium concentration (mol∙dm-3)
                                                        1,4        0,6           0,5   (e)
           Ewewigskonsentrasie (mol∙dm-3)

          Reverse reaction
          Terugwaartse reaksie:
                   2
                        2                  No Kc expression, correct substitution/Geen Kc-
          Kc =         2    (f)
                                           uitdrukking, korrekte substitusie: Max./Maks.

                 (0 6 2 (0 5               Wrong Kc expression/Verkeerde Kc-uitdrukking:
             =                 (g)
                   (1 4 2                  Max./Maks.

          Kc = 0,09

          Forward reaction/Voorwaartse reaksie:
                1
          Kc =
               00
             = 10,89  (h)

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Physical Sciences P2/Fisiese Wetenskappe V2    14                                 DBE/November 2021
                             NSC/NSS – Marking Guidelines/Nasienriglyne

          CALCULATIONS USING NUMBER OF MOLES
          BEREKENINGE WAT GETAL MOL GEBRUIK

          Marking criteria:
          a) Initial n(P) = 4 mol and n(Q2) = 2,4 mol and n(PQ) = 0 
          b)   Change in n(P) = equilibrium n(P) – initial n(P) = 2,8 mol.
          c)   USING ratio: P : Q2 : PQ = 2 : 1 : 2 
          d)   Equilibrium n(Q2) = initial n(Q2) + change in n(Q2)
                                                                      
               Equilibrium n(PQ) = initial n(PQ) - change in n(PQ)
          e)   Divide equilibrium amounts of P and Q2 and PQ by 2 dm3. 
          f)   Correct Kc expression (formulae in square brackets). 
          g)   Substitution of equilibrium concentrations into Kc expression. 
          h)   Final answer: 10,89 / 10,889 

          Nasienkriteria:
          a)   Aanvanklike n(P) = 4 mol en n(Q2) = 2,4 mol en n(PQ) = 0.
          b)   Verandering in n(P) = ewewigs n(P) – aanvanklike n(P) = 2,8 mol.
          c)   GEBRUIK verhouding: P : Q2 : PQ = 2 : 1 : 2 
          d)   Ewewig n(Q2) = aanvanklike n(Q2) + verandering in n(Q2)
               Ewewig n(PQ) = aanvanklike n(PQ) - verandering in n(PQ) 
          e)   Deel ewewigshoeveelhede van P en Q2 en PQ deur 2 dm3. 
          f)   Korrekte Kc-uitdrukking (formules in vierkanthakies). 
          g)   Vervanging van ewewigskonsentrasies in Kc-uitdrukking. 
          h)   Finale antwoord: 10,89 / 10,889 
          OPTION 3/OPSIE 3

                                                          P          Q2           PQ
           Initial quantity (mol)
                                                          4         2,4            0     (a)
           Aanvangshoeveelheid (mol)
           Change (mol)
                                                       2,8 (b)     1,4           2,8   (c)
           Verandering (mol)
           Quantity at equilibrium (mol)/
                                                         1,2        1,0           2,8     (d)
           Hoeveelheid by ewewig (mol)
           Equilibrium concentration (mol∙dm-3)                                          (e)
                                                         0,6        0,5      1,4
           Ewewigskonsentrasie (mol∙dm-3)

                                          No Kc expression, correct substitution/Geen Kc-
                [PQ] 2
          Kc              (f)           uitdrukking, korrekte substitusie: Max./Maks.
               [Q 2 ][P] 2
                     1,4 2                Wrong Kc expression/Verkeerde Kc-uitdrukking:
                            2 (g)
               = (0,5)(0,6)               Max./Maks.
               = 10,89  (h)

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Physical Sciences P2/Fisiese Wetenskappe V2    15                                 DBE/November 2021
                             NSC/NSS – Marking Guidelines/Nasienriglyne

         CALCULATIONS USING CONCENTRATION
         BEREKENINGE WAT KONSENTRASIE GEBRUIK
         Marking criteria:
         a)  Initial c(P) and c(Q2) and c(PQ) from table. 
         b) Change in c(P) = equilibrium c(P) – initial c(P). 
         c) USING ratio: P : Q2 : PQ = 2 : 1 : 2 
         d) Equilibrium c(Q2) = initial c(Q2) + change in c(Q2)
                                                                   
             Equilibrium c(PQ) = initial c(PQ) - change in c(PQ)
         e) Divide initial amounts of P and Q2 and PQ by 2 dm3. 
         f)  Correct Kc expression (formulae in square brackets). 
         g) Substitution of equilibrium concentrations into Kc expression. 
         h) Final answer: 10,89 / 10,889 

         Nasienriglyne:
         a) Aanvanklike c(P) en c(Q2) en c(PQ) uit tabel.
         b) Verandering in c(P) = ewewigs c(P) – aanvanklike c(P).
         c) GEBRUIK verhouding: P : Q2 : PQ = 2 : 1 : 2 
         d) Ewewig c(Q2) = aanvanklike c(Q2) + verandering in c(Q2)
             Ewewig c(PQ) = aanvanklike c(PQ) - verandering in c(PQ) 
         e) Deel aanvangshoeveelhede van P en Q2 en PQ deur 2 dm3. 
         f)  Korrekte Kc-uitdrukking (formules in vierkanthakies). 
         g) Vervanging van ewewigskonsentrasies in Kc-uitdrukking. 
         h) Finale antwoord: 10,89 / 10,889 
         OPTION 4/OPSIE 4

                                                              P           Q2       PQ
          Initial concentration (mol∙dm-3)                                            (a)
                                                             0,4         0,4       1,6     (e)
          Aanvangskonsentrasie (mol∙dm-3)
          Change in concentration (mol∙dm-3)
                                                          0,2 (b)       0,1       0,2     (c)
          Verandering in konsentrasie (mol∙dm-3)
          Equilibrium concentration (mol∙dm-3)
                                                             0,6         0,5       1,4     (d)
          Ewewigskonsentrasie (mol∙dm-3)

                                        No Kc expression, correct substitution/Geen Kc-
               [PQ] 2
         Kc               (f)         uitdrukking, korrekte substitusie: Max./Maks.
              [Q 2 ][P] 2
                   1,4 2                Wrong Kc expression/Verkeerde Kc-uitdrukking:
             =               (g)
               (0,5)(0,6) 2             Max./Maks.
             = 10,89  (h)                                                                                (8)

6.2.4     Remains the same/Bly dieselfde 
          Only temperature can change Kc./Temperature remains constant. 
          Slegs temperatuur kan Kc verander./Temperatuur bly konstant.                                    (2)

6.3
6.3.1     Increases/Toeneem                                                                              (1)

6.3.2     Decreases/Afneem                                                                                (1)
                                                                                                          [18]

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Physical Sciences P2/Fisiese Wetenskappe V2    16                              DBE/November 2021
                             NSC/NSS – Marking Guidelines/Nasienriglyne

QUESTION 7/VRAAG 7

7.1
7.1.1       (It is a) proton/H3O+ (ion)/H+ (ion) donor. 
            (Dit is 'n) proton/H3O+-(ioon)/H+-(ioon)skenker.                                           (2)

7.1.2       HSO 4 /hydrogen sulphate ion/waterstofsulfaatioon 

            ANY ONE:
             It acts as base in reaction I and as acid in reaction II. 
             Acts as acid and base.
            ENIGE EEN:
             Dit reageer as basis in reaksie I en as suur in reaksie II.
             Reageer as suur en basis.                                                                (2)

7.1.3       HSO 4 /Reaction (solution) II/Reaksie (oplossing) II 
        -
            Smaller Ka value/weaker acid 
            Lower ion concentration/Incompletely ionised. 
            Kleiner Ka-waarde/swakker suur 
            Laer ioonkonsentrasie/Onvolledig geïoniseer.                                              (3)

7.2
7.2.1       OPTION 1/OPSIE 1                          OPTION 2/OPSIE 2
            pH = -log[H3O+]                          pH = -log[H3O+]
                                                                         Any one/Enige
            1,02 = -log[H3O+]                        [H3O+] = 10-pH
            [H3O+] = 0,0955 mol∙dm-3                        = 10-1,02 
                                                             = 0,0955 mol∙dm-3 
            Therefore/Dus                             Therefore/Dus
            [HCℓ = 0,0955 mol∙dm-3                    [HCℓ = 0,0955 mol∙dm-3
            (0 0 6/0 1 mol∙dm-3)                      (0 0 6/0 1 mol∙dm-3)                             (3)

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Physical Sciences P2/Fisiese Wetenskappe V2    17                                 DBE/November 2021
                             NSC/NSS – Marking Guidelines/Nasienriglyne

7.2.2     POSITIVE MARKING FROM 7.2.1/POSITIEWE NASIEN VAN VRAAG 7.2.1
          Marking citeria:
                             n c a Va n a
           Formula: c       /          
                             V c b Vb nb
           Calculate n(Na2CO3): 0,075 x 0,025 
           Calculate n(HCℓ): 0,0955 x 0,05 / 0,096 x 0,05 
           Use ratios: n(HCℓ) = 2n(Na2CO3) 
           n(HCℓ)excess = n(HCℓ)initial – n(HCℓ)used = 0,00475 – 0,0038 
                                            n
           Substitute 0,075 dm3 in c        
                                            V
           Final answer: 0,013 mol∙dm-3         (1,3 x 10-2 mol∙dm-3)
            Range: 0,01 to 0,02 mol∙dm-3
          Nasienkriteria:
                             n c a Va n a
           Formule: c       /          
                             V c b Vb nb
           Bereken n(Na2CO3): 0,075 x 0,025 
           Bereken n(HCℓ): 0,0955 x 0,05 / 0,096 x 0,05 
           Gebruik molverhouding: n(HCℓ = 2n(Na2CO3) 
           n(HCℓ oormaat = n(HCℓ aanvanklik – n(HCℓ gebruik = 0,00475 – 0,0038 
                                          n
           Vervang 0,075 dm3 in c         
                                          V
           Finale antwoord: 0 013 mol∙dm-3          (1,3 x 10-2 mol∙dm-3)
            Gebied: 0,01 tot 0,02 mol∙dm-3

          OPTION 1/OPSIE 1
          n(Na2CO3) = cV 
                         = 0,075 x 0,025 
                         = 0,001875 mol                       (1,875 x 10-3/0,002 mol)
          n(HCℓ initial/aanvanklik = cV
                                   = 0,096 x 0,05 
                                   = 0,00475 mol              (4,75 x 10-3/0,005 mol)
          n(HCℓ)used/gebruik = 2n(Na2CO3) 
                               = 2(0,001875)
                               = 0,0038 mol                   (3,75 x 10-3/0,004 mol)

          n(HCℓ)excess/oormaat = 0,00475 – 0,0038 
                              = 0,00095mol           (9,5 x 10-4/1 x 10-3 mol)
                    n
          c(HCℓ) =
                    V
                   0,00095
                 =
                     0,075
                 = 0,013 mol∙dm-3  (1,3 x 10-2 mol∙dm-3)

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Physical Sciences P2/Fisiese Wetenskappe V2    18                                    DBE/November 2021
                             NSC/NSS – Marking Guidelines/Nasienriglyne

          OPTION 2/OPSIE 2
           c a Va n a
                      
           c b Vb nb
              ca (50    2
                       = 
          (0 075 (25  1

          c(HCℓ rea = 0,075 mol∙dm-3

          c(HCℓ excess/oormaat = 0,0955 - 0,075 
                               = 0,0205 mol∙dm-3

                  c1V1 = c2V2
          (0,0205)(50) = c2(75) 
                    c2 = 0,014 mol∙dm-3                                                                      (8)
                                                                                                             [18]

QUESTION 8/VRAAG 8

8.1      Chemical (energy) to electrical (energy) 
         Chemiese (energie) na elektriese (energie)                                                          (1)

8.2      Marking criteria:
                                m          n          m
            Any formula: c        /c        /n 
                                                 
                              MV        V     M
           Substitute 1 mol∙dm-3.
           Substitute 170 g∙mol-1 [or 108 + 14 + 3(16)] and 0,15 dm3 in correct formulae. 
           Final answer: 25,50 g 
         Nasienkriteria:
                                    m          n          m
            Enige formule: c          /c       /n 
                               MV       V      M
           Vervang 1 mol∙dm-3.
           Vervang 170 g∙mol-1 [of 108 + 14 + 3(16)] en 0,15 dm3 in korrekte formules. 
           Finale antwoord: 25,50 g 

         OPTION 1/OPSIE 1                                 OPTION 2/OPSIE 2
             m                                            n = cV 
         c      
            MV                                              = 1  x 0,15
               m                                           = 0,15 mol           
         1=
             170  0,15 
                                                          m = nM
         m = 25,50 g                                       = (0,15)(170)
                                                            = 25,50 g                                       (4)

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Physical Sciences P2/Fisiese Wetenskappe V2    19                                     DBE/November 2021
                             NSC/NSS – Marking Guidelines/Nasienriglyne

8.3      ANY ONE:
          A substance that loses/donates electrons. 
          A substance that is oxidised.
          A substance whose oxidation number increases.
         ENIGE EEN:
          'n Stof wat elektrone verloor/skenk. 
          'n Stof wat geoksideer word.
          'n Stof wat waarvan die oksidasiegetal toeneem.                                                    (2)

8.4
8.4.1    Copper/Cu/Koper                                                                                     (1)

8.4.2     Marking criteria/Nasienkriteria:
           Reactants           Products          Balancing 
            Reaktanse            Produkte           Balansering
           Ignore double arrows./Ignoreer dubbelpyle.
           Ignore phases/Ignoreer fases.
           Marking rule 6.3.10./Nasienreël 6.3.10.

          Cu(s) + 2Ag+(aq)   Cu2+(aq) + 2Ag(s)  Bal 

          ACCEPT/AANVAAR:
          Cu(s) + 2AgNO3(aq)   Cu(NO3)2(aq) + 2Ag(s)  Bal 
          NOTE/LET WEL
           IF electrons are not cancelled – minus 1 mark
           INDIEN elektrone nie gekanselleer is nie – minus 1 punt                                           (3)

8.5       OPTION 1/OPSIE 1                      Notes/Aantekeninge
            
          E cell    
                  Ereduction     
                               E oxidation     Accept any other correct formula from the data
                                                  sheet./Aanvaar enige ander korrekte formule
                 = 0,80  – (0,34)               vanaf gegewensblad.
                 = 0,46 V                       Any other formula using unconventional
                                                  abbreviations, e.g. E°cell = E°OA - E°RA followed by
                                                  correct substitutions:/Enige ander formule wat
                                                  onkonvensionele afkortings gebruik bv. E°sel =
                                                  E°OM - E°RM gevolg deur korrekte vervangings: 3
                                                                                                     4
          OPTION 2/OPSIE 2
          2Ag+ + 2e-  2Ag                       E  = 0,80 V 
          Cu  Cu2+ + 2e-                         E  = - 0,34 V 
          2Ag+ + Cu 2Ag + Cu2+                  E  = +0,46 V                                               (4)

8.6      Decreases/Afneem                                                                                     (1)
                                                                                                              [16]

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                             NSC/NSS – Marking Guidelines/Nasienriglyne

QUESTION 9/VRAAG 9

9.1       ANY ONE: (2 or 0)
           A substance whose (aqueous) solution contains ions. 
           Substance that dissolves in water to give a solution that conducts
            electricity.
           A substance that forms ions in water / when melted.
           A solution that conducts electricity through the movement of ions.
          ENIGE EEN: (2 of 0)
           'n Stof waarvan die oplossing ione bevat. 
           'n Stof wat in water oplos om 'n oplossing te vorm wat elektrisiteit gelei.
           'n Stof wat ione in water vorm/ wanneer dit gesmelt word.
           'n Oplossing wat elektrisiteit gelei deur die beweging van ione.                           (2)

9.2       Anode 
      -
          Chromium is oxidised./Oxidation takes place (at the anode)./Chromium (it)
          loses electrons./Mass decreases./Cr  Cr3+ + 3e- 
          Chroom word geoksideer./Oksidasie vind (by die anode) plaas./Chroom (dit)
          verloor elektrone./Massa neem af./Cr  Cr3+ + 3e-
          NOTE/LET WEL:
          If half-reaction is used, it must be correct/Indien halfreaksie gebruik word, moet dit
          korrek wees: Cr  Cr3+ + 3e-                                                                 (2)

9.3       Cr3+(aq) + 3e-  Cr(s) 
          Ignore phases./Ignoreer fases.
          Marking guidelines/Nasienkriteria
           Cr3+ + 3e- ⇌ Cr        1             Cr ⇌ Cr3+ + 3e-        0
                                    2                                     2
                     3+
            Cr ← Cr + 3e   -      2                        3+
                                                 Cr → Cr + 3e    -      0
                                    2                                     2
           Ignore if charge omitted on electron./Ignoreer indien lading weggelaat op elektron.
           If charge (+) omitted on Cr3+/Indien lading (+) weggelaat op Cr3+: Max./Maks: 1
                                                                                            2
             Example/Voorbeeld: Cr3 + 3e- → Cr                                                        (2)

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### Page 21

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Physical Sciences P2/Fisiese Wetenskappe V2    21                               DBE/November 2021
                             NSC/NSS – Marking Guidelines/Nasienriglyne

9.4      Marking criteria:
                                            m
            Substitute 52 g∙mol-1 in n      /ratio 
                                            M
            Use mol ratio: n(electrons): n(Cr) = 3 : 1. 
            Number of electrons = n x 6,02 x 1023/No of Cr atoms = n x 6,02 x 1023/ratio. 
            Total charge = number of electrons x 1,6 x 10-19/ratio. 
            Final answer: 11 113,85 C 
             Range: 11 076,8 to 11 580 C
         Nasienkriteria:
                                         m
            Vervang 52 g∙mol-1 in n      /verhouding 
                                         M
            Gebruik molverhouding: n(elektrone) : n(Cr3+) = 3 : 1. 
            Aantal elektrone = n x 6,02 x 1023/Aantal Cr-atome = n x 6,02 x 1023/verhouding.
            Totale lading = aantal elektrone x 1,6 x 10-19/verhouding. 
            Finale antwoord: 11 113,85 C 
             Gebied: 11 076,8 tot 11 580 C
         OPTION 1/OPSIE 1                                OPTION 2/OPSIE 2
            m                                               m
         n                                              n
            M                                               M
             2                                               2
          =                                               =
            52                                             52
          = 0,038 mol    (0,04 mol)                       = 0,038 mol   (0,04 mol)

         n(e-) = 3n(Cr)                                 Number Cr atoms
               = 3(0,038)                                = 0,038 x 6,02 x 1023 
               = 0,115 mol     (0,12 mol)                = 2,315 x 1022
         Number (e-) = 0,115 x 6,02 x 1023              Number (e-) = 3N(Cr) 
                     = 6,946 x 1022                                  = 3(2,315 x 1022)
                                                                     = 6,946 x 1022
         Q = 6,95 x 1022 x 1,6 x 10-19 
           = 11 113,85 C                                Q = 6,95 x 1022 x 1,6 x 10-19 
                                                           = 11 113,85 C 
         OPTION 3/OPSIE 3
             m
         n
             M
            2
         =
           52
         = 0,038 mol

         n(e-) = 3n(Cr) 
               = 3(0,038)
               = 0,115 mol

         1 mol ……              6 500 C 
         0,115 mol           11 134,62 C                                                           (5)
                                                                                                    [11]
                                                                             TOTAL/TOTAAL:          150

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