# Physical Sciences Grade 12 Limpopo Prelim 2024 QP

> Grade 12 Physical Sciences question paper from the Limpopo Prelim Exam 2024, 18 pages. Read online or get the free PDF download, memo linked when available.

- Page: https://www.hlayiso.com/library/physicalsciencesp2limpopodoeseptember2024/d7db53dd-557d-4d15-9de7-205b38d1a566
- Updated: 2026-09-27
- Subject: Physical Sciences
- Grade: Grade 12
- Document type: Question paper
- Year: 2024
- Exam period: Limpopo Prelim Exam
- Curriculum: CAPS
- Pages: 18

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Physical Sciences · Grade 12 · Limpopo Prelim Exam · 2024. Question paper, 18 pages. Read online or download the PDF.

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———— pation -Thisis fi

LIMPOPO

PROVINCIAL GOVERNMENT I}
REPUBLIC OF SOUTH AFRICA

Vas

DEPARTMENT OF EDUCATION ]

SENIOR SERTIFICATE

| NATIONAL

| GRADE 12

ly
a" PHYSICAL SCIENCES: CHEMISTRY (P2) "

TF

" SEPTEMBER 2024 5

i "

"eam ewe see wi Se Sie i ee Be oe ee re eee eee ee
MARKS: 150
TIME: 3 HOURS

ATT

This paper consists of 14 pages and 4 data sheets

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Physical Sciences P2

1.
2.
3.

INSTRUCTIONS AND INFORMATION

10.

11.

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2 LimpopoDoE/September 2024

NSC

The question paper consists of nine questions. Answer ALL the questions.
Start EACH question on a NEW page.

Number your answers correctly according to the numbering system used in
this question Paper.

Leave ONE line between two sub-questions, e.g., between QUESTION 2.1
and QUESTION 2.2.

A non-programmable calculator may be used.
Appropriate mathematical instruments may be used.
Show ALL formulae and substitutions in ALL calculations.

Round off your FINAL numerical answers to a minimum of TWO decimal
places.

Give brief motivations, discussions, etc. where required.
You are advised to use the attached data sheets.

Write neatly and legibly.

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Physical Sciences P2 3 LimpopoDoE/September 2024

NSC
QUESTION 1: MULTIPLE-CHOICE QUESTIONS

Four options are provided as possible answers to the following questions.

Choose the answer and write only the letter (A-D) next to the question number
(1.1 — 1.10), for example 1.10 E

1.1 What is the IUPAC name for the compound CH3CH2CHFCH3?
A. 2-fluorobutane
B. 3-fluorobutane
C.  fluoro-3-butane
D. fluorobutane (2)
Base your answers to questions 1.2 and 1.3 on the graph below.

Boiling points of selected alcohols at 101,3 kPa

150 - - 7
| |
o LL mn 1@) |
4 ma I | | | | |
% 100
i oe 2 +
oa
2 T
—E se
®
fd HHH
it i il i
* Coco
= COPCCeerr
ie CO
50 ne [ J
6 ve)
%, % a, % Y
% % a % %,
% Y % : 2
Y 4 Y 4
yY Y
Alcohol

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i /September 2024
Physical Sciences P2 4 LimpopoDoE/Sep
NSC

1.2 What is represented by the number “1” in the IUPAC name for
three of these alcohols?

A. The number of isomers for each alcohol.

B. The number of —OH groups for each carbon atom in each
alcohol molecule.

C. The location of an OH group on one end of the carbon chain
in each alcohol molecule.

D. The location of an -OH group in the middle of the carbon chain
in each alcohol molecule. (2)

1.3 What can be concluded from this graph?

A. At 101,3 kPa, water has a higher boiling point than butan-1-ol.

B. At 101,3 kPa, water has a lower boiling point than ethanol.

C. The greater the number of carbon atoms per alcohol molecule,
the lower the boiling point of the alcohol.

D. The greater the number of carbon atoms per alcohol molecule,
the higher the boiling point of the alcohol

. (2)
1.4 Which formula represents the product of the addition reaction
between ethene and chlorine, Cl2?
A. B. |
Cl Cl Cl Cl
I I I I
Cl-C-C-Cl H-C-C-H
/ l
H H HH
Cc [D.C
Cl Cl Cl H
l I I I
H-C=C-H =C—n
4 I H ¢ C H
a HH
te |
(2)
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Physical Sciences P2 5 LimpopoDoE/September 2024
S & — ; NSC
1: reaction is most likely to occur when the reacting particles collide

1.6

1.7

1.8

with proper orientation and proper:

A. Charge

B. Energy

C. Mass

D. Volume (2)

Catalysts can increase the rate of a chemical reaction by
providing.......

A. an alternate reaction pathway with a higher activation energy.

B. the same reaction pathway with a higher activation energy.

C. analternate reaction pathway with a lower activation energy.

D. the same reaction pathway with a lower activation energy. (2)

Given the equation representing a system at equilibrium ina
sealed, rigid container:

2HI(g) S Ha(g) + la(g) + energy

Increasing the temperature of the system causes the concentration

A. HI to increase.

B. Hz to increase.

C. HI to remain constant.

D. Hz to remain constant. (2)

How will the pH change if there is a tenfold increase in the
hydronium ion concentration?

A. Adecrease of one unit of pH.
B. Adecrease of 10 units of pH.
C. An increase gions unit of pH.
D

. Anincrease of 10 units of pH. (2)

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Physical Sciences P2 6 LimpopoDoE/September 2024
1.9 Which positive ion must be present in an aqueous solution of an
Arrhenius acid?
A. Nat
B. NH,*
C. OH-

D. H30* (2)

1.10 Consider the reaction below.
2Al(s) + 6H*(aq)  2Al*(aq) + 3H2(g)
In this reaction, electrons are transferred from:

A. Alto H*
B. HtoH*
C. Alto Al*
D

H to Al (2)

[20]

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Physical Sciences P2 7 LimpopoDoE/September 2024

NSC
QUESTION 2 (Start on a new page.)

Carbon is the basic building block of organic compounds that recycles
through the earth’s air, water, soil, and living organisms including human
beings.

2.1 Discuss ONE special property of carbon that makes it possible to (2)
form a variety of bonds.

2.2 The IUPAC name of an organic compound is:
1-chloro-2,3-dimethylpentane

2.2.1. Write down the GENERAL FORMULA of the homologous

series to which this compound belongs. (1)
2.2.2 Draw the condensed STRUCTURAL formula of this (3)
compound.
2.2.3 |s this compound SATURATED or UNSATURATED? (1)

2.3 The organic compound below (CH3COCH2CH2CHs) has one
POSITIONAL isomer and one FUNCTIONAL isomer.

2.3.1 Define the term positional isomer. (2)

For this compound, write down the:

2.3.2 Name of the functional group present in this compound. (1)
2.3.3 IUPAC name of its POSITIONAL isomer. (2)
2.3.4 Structural formula of its FUNCTIONAL isomer. (2)

2.4 Consider this condensed structural formula of an alcohol.

(CHs)3C - OH
2.4.1 Is this a PRIMARY, SECONDARY or TERTIARY alcohol?
Give a reason for the answer. (2)
2.4.2 Write down the IUPAC name of the above compound. (2)
[18]

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NSC
QUESTION 3 (Start on a new page.)

The table below shows data collected for three organic compounds, ;
represented by the letters A, B and C, during a practical investigation:

Organic compound Mr (g.mol') | Boiling Point (ec) |

CHsCH2CH2CH3

A 58 -0,5
CH3sCH2CH20H

S 60 97

CHsCOOH
© 60 118
3.1 Which variable was controlled during this investigation? (1)

3.2 Identify the:
3.2.1 Dependent variable. (1)
3.2.2 Independent variable. (1)
3.3 Consider compound A:
3.3.1 2-methylpropane is an isomer of compound A.

Predict whether the boiling point of 2-methylpropane will be
HIGHER THAN, LOWER THAN or THE SAME as the

boiling point of compound A. (1)
3.3.2 Explain your prediction in QUESTION 3.3.1. (3)
3.4 Define the term vapor pressure. (2)
3.5 Refer to intermolecular forces and energy to explain why
compound B will have a higher vapour pressure than compound C
at 20 °C. (3)
[12]

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NSC

QUESTION 4 (Start on a new page.)

Various organic reactions are shown in the flow diagram.

LimpopoDoE/September 2024

()
xX sae + + energy |
A Bra
UV light
C3H7OH B | CsHrBr C | CsH7OH ie 2

== -1- 2: 4

propan-1-ol 4-bromopropane | propan-1-ol Seer Zz
KOH con.)
D Heat reflux
Y

41 Name the type of reaction illustrated by:

4.1.1 A (1)

41.2 B (1)

41.3 C (1)

41.4 D (1)
4.2 Use condensed structural formulas and write a balanced equation

for reaction C. (4)
4.3 Write down the structural formula for compound X. (2)
44 Compound X undergoes combustion in the presence of oxygen.

Write down the molecular formulas of the two products that form. (2)
4.5 Use structural formulas to write a balanced equation for the

reaction to produce product Y. (3)

Instead of heating concentrated potassium hydroxide under reflux

during the formation of Y, dilute sodium hydroxide is used.
46 Write the IUPAC name of the organic compound that will form. (2)
47 To which homologous series does product Z belong? (1)

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Physical Sciences P2 10 LimpopoDoE/September 2024
NSC
4.8 Write down the IUPAC name of product Z if ethanoic acid was
used during the reaction. (2)
[20]

QUESTION 5 (Start on a new page.)

Graph B represents the Maxwell-Boltzmann energy distribution curve for a
reaction mixture at 300°C. Area X represents the number of molecules in the
mixture that have enough kinetic energy for the reaction to take place.

fc ; ~ Area X

Number of molecules

Kinetic energy YA

5.1 Give a term for the “minimum energy needed for a reaction to take
place”, as indicated by Y. (1)

5.2 The temperature of the mixture is now increased to 500 °C.

5.2.1 Which ONE of graph A or C represents the distribution curve
of the mixture at this higher temperature? (1)

5.2.2 Give a reason for the answer. (1)

5.2.3 Use the collision theory to explain how this increase in
temperature will influence the rate of the reaction. (4)

5.3 A catalyst is added to the mixture.

2
5.3.1 Write down the definition of a catalyst. (2)
5.3.2 How will the above-mentioned action affect the size of area X
(area to the rightiof vertical line Y)? Write down only
INCREASES, DECREASES or REMAINS THE SAME. (1)
5.3.3 Explain your answer to QUESTION 5.3.2. ’ (2)
[12]

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3 NSC
QUESTION 6 (Start on a new page.)

2,0 g of CaCOs is sealed in an evacuated 1,0 dm? metal flask and a pressure
gauge is connected to the flask, in order to determine the equilibrium
constant for the decomposition of calcium carbonate (CaCOs).
The flask is heated to a 800°C at which equilibrium was reached.

CaCOa(s) = CaO(s) + CO2(g) AH>0

The graph obtained for pressure versus time for the decomposition of
calcium carbonate is shown below.

Pressure

to t th ts Time
6.1 Define the term reaction rate. (2)
6.2 How does the rate of the reverse reaction change from toto t1? (2)
6.3 Whatis the reason for the horizontal line between tz.and ts? (1)
6.4 Draw a sketch graph to show how the mass of CaCO3 changes for (3)

the period toto ts.

6.5 During a power failure the temperature of the oven drops to 500°C.
What effect (only write INCREASES, DECREASES or STAYS THE
SAME) does this decrease in temperature have on the following:

6.5.1 The rate of the forward reaction. (1)
6.5.2 The concentration of COz (1)
6.5.3 The value of Kc. (1)
6.6 Give a reason for your answer to QUESTION 6.5.3. (4)

67 When equilibrium was established at 800°C, the concentration of
COz2 present in the flask was 1,4 x 10? mol-dm?.
Calculate the equilibrium constant (Kc) at 800°C for this reaction. (2)

[17]

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Physical Sciences P2 12 LimpopoDoE/September 2024
NSC

QUESTION 7 (Start on a new page.)

7A Sulphuric acid is a diprotic acid.
7.1.1 Define an acid in terms of the Lowry-Bransted theory. (2)
7.1.2 Give a reason why sulphuric acid is a diprotic acid. (1)

7.2 The hydrogen carbonate ion can act as both an acid anda base. It
reacts with water according to the following balanced equation:

HCOs (aq) + H20(I) $ H2CO3(aq) + OH(aq)
7.2.1 Write down ONE word for the underlined phrase. (1)

7.2.2 HCOs'(aq) acts as a base in the above reaction.
Write down the formula of the conjugate acid of HCOs(aq). (1)

7.3 A chemist spills sulphuric acid of concentration 6 mol-dm* from a
flask on a laboratory bench. She neutralises the spilled acid by
sprinkling sodium hydrogen carbonate powder onto it. The reaction
that takes place is: (Assume that the H2SOs ionises completely.)

HzSOx (aq) + 2NaHCOs (s) > Na2SOx (aq) + 2H20 (I) + 2C02(g)

The fizzing, due to the formation of carbon dioxide, stops after the
chemist has added 27 g sodium hydrogen carbonate to the spilled
acid.

7.3.1 Calculate the volume of sulphuric acid that spilled. Assume
that all the sodium hydrogen carbonate reacts with all the
acid. (6)

The chemist now dilutes some of the 6 mol-dm? sulphuric acid
solution in the flask to 0,1 mol-dm*.

7.3.2 Calculate the volume of the 6 mol-dm* sulphuric acid
solution needed to prepare 1 dm of the dilute acid. (2)

During a titration 25 cm* of the 0,1 mol-dm* sulphuric acid solution
is added to an Erlenmeyer flask and titrated with a 0,1 mol-dm3
sodium hydroxide solution.

7.3.3 The chemist uses bromothymol blue as indicator.
What is the purpose of this indicator? (1)

7.3.4 Calculate the pH of the solution in the flask after the addition
of 30 cm* of sodium hydroxide. The endpoint of the titration
is not yet reached at this point. (e)

[22]

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13 LimpopoDoE/September 2024
NSC

QUESTION 8 (Start on a new page.)

A learner wants to investigate the

effect of the area of the metal plates used

as electrodes in a galvanic cell on the emf of the cell
on the emf of the cell.

The learner.sets up the following cell under standard conditions and
measures the emf.

8.1

8.2
8.3

8.4

8.5

8.6

A
2n
QL
Which electrode will show an increase in mass when this cell is (1)
functioning?
Write the equation for the half-reaction occurring at the anode. (2)
Calculate the emf that the learner will read on the voltmeter. (4)

Name TWO variables that should be controlled during this
investigation. (2)

The learner now replaces the two metal plates with ones of larger
surface area and takes the voltmeter reading again.

8.5.1 How would you expect the new emf to compare with the one
calculated in QUESTION 8.3? (Only write SMALLER
THAN, LARGER THAN or EQUAL TO.) (1)

8.5.2 Explain your answer to QUESTION 8.5.1. (2)

The learner now connects a resistor of low resistance across
terminals A and B. The learner notes that the reading on the
voltmeter immediately drops.

8.6.1 Give a reason for this observation. (1)

8.6.2 After some time the learner observes a further gradual drop
in the reading on the voltmeter. Give a reason for this
observation. (1)
[14]

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Physical Sciences P2 14 LimpopoDoE/September 2094

NSC

QUESTION 9 (Start on a new page.)

9.1
9.2
9.3
9.4

9.5

Electroplating is an electrolytic process that can be used to coat
metal objects with a less reactive metal. The diagram below shows
an electroplating cell that includes a power source connected to a
Copper rod and a bracelet made from a different metal. The rod and
bracelet are in an aqueous copper (II) sulphate solution.

Power source
g Cu rod
electrolyte
bracelet
Define the term electrolyte. (2)
Is the electrolytic process endothermic or exothermic? (1)
Which electrode, the BRACELET or the Cu rod is the cathode? (1)

Initially the CuSO«(aq) has a blue colour.

9.4.1 How will the intensity of the blue colour change whilst the
cell is functioning? Write down INCREASES, DECREASES

or REMAINS THE SAME. (1)

9.4.2 Give a reason for the answer in QUESTION 9.4.1. (2)
9.4.3 Write down the half-reaction that takes place at the pure

copper electrode. (2)
During the process, the bracelet is plated with 0,86 g of copper.

Calculate the number of electrons transferred during the process. (6)

[15]

TOTAL: 150

PI
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Physical Sciences P2 45

NSC

GEGEWENS VIR FISIESE WETENSKAPPE GRAAD 12
VRAESTEL 2 (CHEMIE)
DATA FOR PHYSICAL SCIENCES GRADE 12
PAPER 2 (CHEMISTRY)

TABLE 1: PHYSICAL CONSTANTSITABEL 1: FISIESE KONSTANTES

LimpopoDoE/September 2024

NAME/NAAM SYMBOL/SIMBOOL VALUE/WAARDE
Avogadro's constant 23 anit
Avogadro-konstante Na 6,02 x 10° mol
Charge on electron .
Lading op elektron 2 “1,6 x 10°C
Electron mass ;
Elektronmassa Me 9,11 x 10°31 kg
Molar gas volume at STP 4
Molére gasvolume by STD Vim 22,4 dm*-mol
Standard pressure
Standaarddruk pe 1,013 x 10° Pa
Standard temperature
Standaardtemperatuur is 273K

TABLE 2: FORMULAE/TABEL 2: FORMULES
m N
n=— n=—
M Na
=f orlof c= Wu ¥ caVa _ na
oy ~ MV my CbVb nb

K, =[H,O° ][OH] =1x10™ at/by 298K

pH = -log[H30*]

0 _ 70 0 po _ pe
Een = E cathode ~ — Eonode | Eset = Enatode E node
or / of

—E°

6
Fea = =E reduction oxidation

or / of
Eo, =E?

cell oxidising agent redusing agent

6 _ 7e 0
| Eva =E, eduksie — Ecisidasie

6 E®
-ER / Ea E jisideermiddel

@
-£ reduseermiddel

-2 -2

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Physical Sciences P2

LimpopoDoE/September 2024

Increasing reducing ability/Toenemende reduserende vermoé

17
NSC
TABLE 4A: STANDARD REDUCTION POTENTIALS

Half-reactions E® (vy)
Fog)+2e = = 2F- +2,87

Co*+e = Co* +1,81

H202+2H*+2e = 2H20 41,77

MnO4 +8H*+5e =~ Mn*+4H20 +151
Ch(g)+2e = 2Ch + 1,36
CrO z +14H'+6e =  2Cr*+7H,0 + 1,33
O2(g)+4H*+4e° = = 2H20 +1,23
MnO2+ 4H*+2e- = = = Mn** + 2H20. + 1,23
Pe+2e = Pt +1,20
i Bro(t)+2e- = 9 2Br +1,07
NO3 +4Ht+3e = NO(g)+2H20 + 0,96
Hg’+2e- =  Hg(t) +0,85
Ey) Ag'te = Ag + 0,80
2 NO3 +2H*+e = NOx(g)+H20 +0,80
ry Fe*+e = Fe* +0,77
a Oo(g)+2H*+2e- == H202 + 0,68
2 h+2e = 2b + 0,54
Cu'+e = Cu +0,52
$ SO2 + 4H* + 4e- S+2H20 +0,45
3 2:0 +02+4e° = 40H +0,40
Z Cu** + 2e- Cu + 0,34
S so = +4H'+2e- =  SO2(g)+2H2O +0,17
zg Cu*+e = Cut +0,16
£ Sn +2e =  Sn* +0,15
o S+2H*+2e =  HeS(g) +0,14
5 2H*+2e = Hag) 0,00
2 Fe* + 3e- Fe - 0,06
— Pb%*+2e = Pb -0,13
= Sn*+2e = Sn -0,14
‘8 N?*+2e = Ni -0,27
a Co%+2e = Co -0,28
c Cd*+2e = Cd - 0,40
7) Cette = Cr -0,41
3 Fe*+2e = Fe - 0,44
3 Ceé+3e = Cr -0,74
to) Zn*+2e = Zn - 0,76
= 2H,0+2e- == —-He(g) ++ 20H- — 0,83
© Cret+2e = Cr -0,91
5 Mn%+2e- = Mn -1,18
£ ABt+3e = AL = 1,66
Mg*+2e = Mg - 2,36

Nat+e = Na -2,71
Ca*+2e = Ca — 2,87
SPt+2e = Sr — 2,89
Ba+2e = Ba —2,90
Cst+e = Cs - 2,92
Ktte = K - 2,93
lite = Li - 3,05
TABLE 4B: STANDARD REDUCTION POTENTIALS
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LimpopoDoE/September 2024

Increasing oxidising ability/Toenemende oksiderende vermoé

18
NSC
. ()

Half-reactions E*™)
lite = Li = 9,05
K+e = K - 2,93
Cs*+ @& = Cs ~ 2,92
Ba*+2e = Ba ~ 2,90
S+2e = Sr ~ 2,89
Ca** + 2e- = Ca ~ 2,87
Na* +e = Na -2,71
Mg*+2e = = Mg - 2,36
AG +3e = AL ~ 1,66
Mn?*+2e = Mn ~1,18
Crt+2e = Cr - 0,91
2H20+2e = = ~—-Ha(g) + 20H" — 0,83
Zn*+2e = Zn. - 0,76
Crt+3e = Cr -0,74
Fe** + 2e- Fe — 0,44
Cr+e = cr -0,41
Cd*+2e = Cd - 0,40
Co*+2e = Co - 0,28
Ni?* + 2e- Ni -0,27
Sn*+2e = Sn - 0,14
Pb*+2e = Pb - 0,13
Fe** + 3e- Fe - 0,06

2H*+2e = = Hg) 0,00
S + 2H* + 2e- HeS(g) +0,14
Sn** + 2e- = Sn?* +0,15
Cu*+e- = Cut +0,16
so ze + 4H? + 2e- $02(g) + 2H20 +0,17
Cu* + 2e- = Cu +0,34
2H20+O2+4e° = = 40H- + 0,40
SO2 + 4H* + 4e- = S+2H2O +0,45
Cu? +e = Cu +0,52
b+2e = 2b + 0,54
O2(g)+ 2H*+2e- = Han +0,68
Fe*+e = Fe +0,77
NO3 +2H'+e == —NOx(g)+H20 +0,80
Ag* +e = Ag +0,80
Hg?* + 2e- Hg(t) +0,85
NO3 +4H"+3e- = —NO(g)+2H20 +0,96
Br(t)+2e = 2Br +1,07
Ph+2e = Pt +4,20
MnO2+4H*+2e- == = Mn®*+2H0 +1,23
O2(g) + 4H* + 4e- = 2H20 +1,23
Cre0 z +14H*+6e = 2Cr*+7H20 +133
Cha(g) + 2e- = 2cte +1,36
MnO4 +8H*+5e == Mn**+ 4,0 +154
H202+2H*+2e = 2H2O +177
Co*¥+e = Cor +181
F2(g) + 2e- = 2F- +2,87

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