# Physical Sciences Grade 12 Paper 2 KZN Mock 2025 Memo

> Grade 12 Physical Sciences Paper 2 memorandum from the KZN Mock Exam 2025, 11 pages. Read online or download the free PDF.

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- Updated: 2026-09-27
- Subject: Physical Sciences
- Grade: Grade 12
- Document type: Memorandum
- Year: 2025
- Exam period: KZN Mock Exam
- Paper: 2
- Curriculum: CAPS
- Pages: 11

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Physical Sciences · Grade 12 · KZN Mock Exam · 2025. Memorandum, 11 pages. Read online or download the PDF.

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### Page 1

} KWAZULU-NATAL PROVINCE

EDUCATION
REPUBLIC OF SOUTH AFRICA

GRADE 12

NATIONAL
SENIOR CERTIFICATE

PHYSICAL SCIENCES P2 (CHEMISTRY)

PREPARATORY EXAMINATION
SEPTEMBER 2025
MARKING GUIDELINES

MARKS: 150

This marking guideline consists of 11 pages.

Copyright reserved Please turn over

### Page 2

Physical Sciences/P2

QUESTION 1
1.1 Byv
1.2 Dvv
1.3 Cvv
1.4 Cvv
1:5 Cvv
1.6 Cvv
1.7 Dvv
1.8 Cvv
1.9 D vv DO NOT MARK
1.10 Byv
QUESTION 2
2.1.1 4 -bromo—5 — ethyl — 2 - methyiheptanev vv
Marking criteria:
e correct stem i.e. heptane
e substituents correctly identified i.e. bromo, ethyl, methylv
e IUPAC name completely correct including numbering, sequence and
hyphen ¥
2.1.2 3-methylbut-1-enevv
Marking criteria:
¢ correct stem and substituents i.e. dibromo, methyl and heptanev
e {UPAC name completely correct including numbering, sequence and
hyphen ~
22 CrH2nO2v
2.3.1 Ev
232 Cy

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September 2025 Preparatory Examination

(2)
(2)
(2)
(2)
(2)
(2)
(2)
(2)
(2)

(2)
[20]

(3)

(2)

(1)
(1)
(1)

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Physical Sciences/P2 September 2025 Preparatory Examination

2.4.1. Compounds with the same molecular formula, “ but different functional

groups/homologous series.”

Marking criteria:

If any one of the underlined key words/phrases in the correct context is omitted,
deduct 1 mark.

24.2  CsHisO2v“v
2.4.3. Pentanoic acid or methylbutanoic acidv v

Marking criteria:
e correct homologous series: carboxylic acid. ¥

e IUPAC name completely correct. v

QUESTION 3

3.1 The temperature at which the vapour pressure of a substance equals
atmospheric pressure. v”

Marking criteria:

If any one of the underlined key words/phrases in the correct context is omitted,
deduct 1 mark.
The underlined phrases must be in the correct context.

$24 Ensure a fair test/comparison. Vv
3.2.2 London forces/Dispersion forces. ¥
3.2.3. Hydrogen bonding “
3.4 Ye

Y has the lowest boiling point. ”

Or Y has the lowest intermolecular forces compared to W and X.

3.5

Marking criteria:

e Relate boiling point with length of carbon chain/branching/number of side
chains/surface area. VV

e Compare the strength of the intermolecular forces. V

e¢ Compare the energy required to overcome the intermolecular forces. ¥

X has the lowest boiling point Y and therefore has the shorter carbon chain/is

branched/more compact/more spherical/smaller surface area over which the
intermolecular forces act than W.v

\Wlaakear intarmolaciilar farcac/\/an dar \Alaale farcac/| andan farcac than \Vi 4%

(2)

(2)

(2)
[14]

(2)

(1)
(1)
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Physical Sciences/P2 September 2025 Preparatory Examination

W has the higher boiling point Vv and therefore has the longer carbon chain/no
branches/less_compact/less_spherical/largest_surface_area_over which the
intermolecular forces act than X.v

Stronger/more_ intermolecular _forces/Van_ der Waals forces/London_ forces
than Xv

More energy needed to overcome the intermolecular forces”

3.6
i
H— C — H
H | H
| |
H — f — Cc — i — O-—-H
i | 4
H — C —H
|
H
Marking criteria:
e Functional group on first carbonY
e 3 carbons in the longest chain “
e 2-—methyl groups on the second carbon ~
(3)
3.7
Marking criteria:
e LOWER THAN Y
¢ Correctly identify intermolecular forces in both compounds. ~
e¢ Compare the strength of the intermolecular forces. “
e¢ Compare the energy required to overcome the intermolecular forces. ¥
LOWER THANY
2,2 — dimethylpropane has only London/Dispersion forces between molecules
and Compound Y has hydrogen bonds” and dipole-dipole forces in addition
to London/Dispersion forces
Intermolecular forces between molecules of 2,2 — dimethylpropane are
weakerY
Require less energy to overcome. ” (4)
[18]

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### Page 5

Physical Sciences/P2 September 2025 Preparatory Examination

QUESTION 4
4.1 additiony (1)
4.2 The C-atom bonded to the hydroxyl/-OHY is bonded to three other carbon

4.3.1

4.3.2

4.4.1

4.4.2

4.5.1
4.5.2

4.5.3

atoms.v

Marking criteria:

If any one of the underlined key words/phrases in the correct context is omitted,
deduct 1 mark.
The underlined phrases must be in the correct context.

(2)
Water/H20v (1)
Sulphuric acid/H2SOs or Phosphoric acid/HsPO4” (1)
H
|
H — C — H
H H H H
| | | |
H—C—C —¢G—C€C— C —H
| | | | |
H H H 7 H
H
Marking criteria:
e Correct functional groupY
e substituent correctly identified i.e. methylv
e IUPAC name completely correct including numbering, sequence and
hyphen ¥
(3)
2 - methyl — 1 - bromopentaney vv
Marking criteria:
¢ correct stem i.e. pentane
« substituents correctly identified i.e. bromo, methyl”
« IUPAC name completely correct including numbering, sequence and
hyphen ¥
(3)
hydroxyl” (1)
substitution’ (1)
Dilute KOH/potassium hydroxide” (1)

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### Page 6

Physical Sciences/P2

September 2025 Preparatory Examination

4.5.4 CeHi3Br + KOH -—> CoH140 + KBr
Marking criteria:
e Both reactants correct. Vv
¢ Both products correctv
e Balancing Vv
(3)
[17]
QUESTION 5
5.1 The COz produced escapes from the container. v (1)
5.2 e Change in concentration V of products/reactants per (unit) time. W
e Change in amount/number of moles/volume/mass VY of products/reactants
per (unit) time. Vv
e Amount/number of moles/volume/mass of products formed/reactants used
per (unit) time. vv
Marking criteria:
If any one of the underlined key words/phrases in the correct context is omitted,
deduct 1 mark.
The underlined phrases must be in the correct context.
e Rate of change in concentration/amount/number of moles/volume/
mass. vv (2 or 0) (2)
5.3 e Reaction is complete/no more COz2 is produced/CaCOs is used upY ¥ (2)
5.4 e Crush the calcium carbonate chips to a powder.
e Add a catalyst. v (2)
5:5 Marking criteria:

e Correct substitution (= ) in the formula n =a to calculate n(CaCOs) v
e Ratio: n(CaCOs) used equals n(COz) produced v
e Usen =a to calculate m(COz) v

e Substitute for both n and M correctly i.e.: n = 0,6225 and M = 44v

e Rate formula: rate = = v
e Correct substitution of 1,37 for ratev
¢ Correct substitution for Am in the formula: rate = =v

e Final answer At = 19,99 minutesY

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### Page 7

Physical Sciences/P2 September 2025 Preparatory Examination

n(COz) lost = n(CaCOs) reacted Vv
= m 7
M
- 62,25 oy
100
= 0,6225 mols
m(CO>?) lost = nM
= (0,6225)(44) v
= 27,399
Am
= aoe v
rate “At
_ 27,39 V
1,37V = At
At = 19,99 minutesY
(8)
5.6.1. INCREASES.Y (1)
5.6.2 REMAINS THE SAMEY
CaCOs is the limiting reagent” (2)

5.7 e More reacting molecules per unit volume. V
More molecules correctly orientated. ¥
More effective collisions per unit time/second. ¥

OR
e Frequency of effective collisions increases. (3)
[21]
QUESTION 6
6.1 Add more reactants/increase the amount/mols/concentration of the reactants. v
OR

Remove some of the products/ decrease the amount/mols/concentration of the

products.

OR

Decrease in pressure (1)

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### Page 8

Physical Sciences/P2

6.2

6.3

6.4

Marking criteria:

e Correctly calculate 70,59% of 5 = 3,53v

« Using the correct mol ratiov

e Calculating the quantity(mol) at equilibrium of all three substances Vv

e Using the concentration of Q2 at equilibrium and the number of mols of
Az at equilibrium in the equation c = n/Vto calculate the volume of the
container. vv

* Calculating the equilibrium concentrations of the reactantsv
e Ke expression’
e Correct substitution of equilibrium concentrations into Ke expression v
e Kce= 5,09 v

 TRQT A @
Initial quantity (mol) 5 0 0
Change (mol) 3,53Y (3,53 1,765) | v
Quantity at equilibrium (mol) (1.47 | 3,83 | 1,765>] v
Equilibrium concentration (mol.dm-) 0,736 4,765) 0,8825 | v

°
"
<|5

0,8825

Ke = [Az][Q2
[A2Q?

(1,765)2(0,8825)
= (0,735)?

= 5,09 v

The rates of the forward and reverse reaction do not increase equally. v

Marking criteria:

If any one of the underlined key words/phrases in the correct context is omitted,
deduct 1 mark.
The underlined phrase must be in the correct context.

When the equilibrium in a closed system is disturbed, the system will

September 2025 Preparatory Examination

re-instate_a_ new equilibrium by favouring the reaction that will oppose the

disturbance. vv (2)

Copyright reserved

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### Page 9

Physical Sciences/P2 September 2025 Preparatory Examination

6.5 GREATER THAN v¥

6.6 The rate of the forward reaction decreases less than the rate of the reverse

reaction. ~
The forward reaction is favoured. ¥

Concentration of the products increases while the concentration of the

reactants decreases. V

QUESTION 7
7.1.1. CHsCOOVY

7.1.2 GREATER THAN 7Y

7.1.3. CH3sCOO- + HzO — CH3sCOOH + OH"
LHSvY
RHSY
Balancingv

2a It is a substance_that_ionises_ completely v in water to produce a high

concentration of hydronium ions. ~

e Calculate n(HCfyexcess ¥

e Substitute for c and V inn =cV v

e Ratio HCf : NazCOs = 2:1”

e Substitute for c and V v

e Calculate n(HCf)ota by adding above 2 valuesY

e Ratio of c(HC2) = c(Hs0*)”

e Substitute into c = n/V to calculate concentration of H30*V
e Equation: pH = - log[H30*]“

e Substitute into pH = - log[Hs0*)

e Final answer”

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(1)

(3)
[17]

(1)
(1)

(3)

(2)

### Page 10

Physical Sciences/P2

n(HC£)excess

n(HCé) reacted with NazCO3

n ( HC£)totai

c(H30*)

pH

wou od

September 2025 Preparatory Examination

cV v
(0,013)(0,075) v
0,000975 mols

2cV v
(2)(0,075)(0,025)
0,00375 mols

0,000975 + 0,00375v
0,004725 mols

(HC?) ¥

n

Vv

0,004725
0,05

0,0945 mol.dm*?

-log[H3O*]v
-log0,0945v
1,02”

2H* + 2e =He (%)

QUESTION 8
8.1 Pty
8.2 Remain the same. Vv
8.3.1 H2—>2H* + 2e vv
Notes
« Ignore phases
© Hee-2H? + 2e (9%)
H22H* + 2e (4)
Ignore if charge on electron omitted.
8.3.2  25°C/298 K v
8.3.3. 1 mol.dm? v
8.4 Cutt v

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[17]

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(1)

(2)
(1)

(1)
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### Page 11

Physical Sciences/P2 September 2025 Preparatory Examination

8.5 Pt(s) /H2(g)/H*(aq)(1 mol.dm-?) v // ¥ Cu2*(aq)(1_ mol.dm?)/Cu(s) ¥ (3)
Ignore the phases and concentrations
8.6
Notes
« Accept any other correct formula from the data sheet.
Any other formula using unconventional abbreviations, e.g. E° cei = E°oa- E°ra
followed by correct substitutions Max: y,
EX cei = E* reduction - E*oxidation ¥
0,75 v = 0,34v -  E*oxidation
E°oxidation = -0,41VVY
Yesv, Cr?* is not a solid. ¥
(6)
[16]
QUESTION 9
9.1 Electrolyticv
They both have a power supply”
Both cells converts electrical energy to chemical energy. (2)
9.2 An electrolyte is a substance of which the aqueous solution contains ions. vv
OR
A substance that dissofves in water to give a solution that conducts electricity. (2)
9.3 2H20 + 2e — H2 + 20H YY
Ignore phases
Notes
e 2H20+2e5H2+20H = (1/2)
e H2+2OH"< 2H20+2e (2/2)
e H2+20OH"S 2H20+2e (0/2)
e 2H20 + 2e°<H2+20H° (0/2)
(2)
9.4 Cu or CopperY (1)
9.5 DecreasesY
Cu** (or Copper(Il) ions) are reducedv to Cu v (or Copper). (3)
[10]
TOTAL: 150

NB: MARK SCRIPT OUT OF 148 AND THEREAFTER CONVERT TO TOTAL MARKS : 150

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