# Physical Sciences Grade 12 P2 Free State Mock 2025 QP

> Grade 12 Physical Sciences Paper 2 question paper from the Free State Mock Exam 2025, 18 pages. Read online or download the free PDF.

- Page: https://www.hlayiso.com/library/physics-grade-12-nsc-p2-qp-september-2025-free-state/58bf39e6-b0eb-476e-acab-a5701e3fe90c
- Updated: 2026-09-27
- Subject: Physical Sciences
- Grade: Grade 12
- Document type: Question paper
- Year: 2025
- Exam period: Free State Mock Exam
- Paper: 2
- Curriculum: CAPS
- Pages: 18

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## About this document

Physical Sciences · Grade 12 · Free State Mock Exam · 2025. Question paper, 18 pages. Read online or download the PDF.

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### Page 1

education

Department of
Education

FREE STATE PROVINCE

PREPARATORY EXAMINATION

GRADE 12

PHYSICAL SCIENCES P2

(CHEMISTRY)

SEPTEMBER 2025

MARKS: 150

TIME: 3 HOURS

This question paper consists of 14 pages and 4 data sheets.

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FS/September 2025

INSTRUCTIONS AND INFORMATION

1.

10.

Ts

12.

Write your name and other applicable information in the appropriate spaces
on the ANSWER BOOK.

The question paper consists of NINE questions. Answer ALL the questions in
the ANSWER BOOK.

Start EACH question on a NEW page in the ANSWER BOOK.

Number the answers correctly according to the numbering system used in this
question paper.

Leave ONE line between two subquestions, e.g. between QUESTION 3.1 and
QUESTION 3.2.

You may use a non-programmabie pocket calculator.
You may use appropriate mathematical instruments.
Show ALL formulae and substitutions in ALL calculations.

Round off your FINAL numerical answers to a minimum of TWO decimal places
where necessary.

Give brief motivations, discussions, etc. where required.
You are advised to use the attached DATA SHEETS.

Write neatly and legibly.

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QUESTION 1: MULTIPLE-CHOICE QUESTIONS
Various options are provided as possible answers to the following questions. Each
question has only ONE correct answer. Choose the answer and write only the letter
(A-D) next to the question numbers (1.1 to 1.10) in the ANSWER BOOK,
for example, 1.11 E.
1.1. Which ONE of the following is an unsaturated hydrocarbon?

A C4Hi0

B CH3(CH)2CH3

Cc CH3(CH2)2CH3

D CH3CH2CH2CH3 (2)

1.2 Consider the organic molecule below.

CaHsO2
Its correct IUPAC name is ...
A butan-2-ol.
B butanoic acid.
Cc methyl butanoate.
D ethyl butanoate. (2)

1.3. Consider the organic structure below.

ll
CH3—C—O—CH;

The IUPAC name of its FUNCTIONAL ISOMER is ...
A methyl ethanoate.
propanoic acid.

ethyl methanoate.

0 aO DB

ethanoic acid. (2)

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1.4 The reaction of copper(Il) carbonate with EXCESS dilute hydrochloric acid is
used to investigate the rate of reaction. The balanced equation for this reaction

iS!

CuCOs(s) + 2HC£(aq) > CuCta(aq) + H20(2) + CO2(g)

The rate of reaction can experimentally be measured by measuring the ...

A
B
Cc
D

hydrochloric acid used.
amount of water formed per time.
volume of COz2 produced per time.

temperature of the mixture. (2)

1.5 Which ONE of the following statements concerning equilibrium is NOT correct?

A

B

Equilibrium is reached in a closed system.
At equilibrium, the concentration of reactants and products is constant.

At equilibrium, the concentration of reactants and products is not
necessarily the same.

At equilibrium, the concentration of reactants is equal to the
concentration of products. (2)

1.6 Write down the conjugate base of the following acid:

HCl04

(2)

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1.7 The role of an indicator during a titration is to ...

A show the color of the base.

B standardise the solution.

Cc show the color of the acid.

D identify the endpoint. (2)

1.8 | Which statement is CORRECT for a Zn-Cu galvanic cell that operates under
standard conditions?

A The concentration of the Zn** ions in the zinc half-cell gradually
decreases.

B The concentration of the Cu?* ions in the copper half-cell gradually
increases.

[e} The intensity of the colour of the electrolyte in the copper half-cell
gradually decreases.

D Negative ions migrate from the zinc half-cell to the copper half-cell. (2)

1.9 What is the energy convertion in an electrolytic cell?

A Electrical to chemical

B Chemical to electrical

Cc Electrical to mechanical

D Chemical to mechanical (2)

1.10 During the purification of copper, the ...

A impure copper is the positive electrode.

B impure copper is connected to the cathode.
Cc pure copper is the positive electrode.
D

pure copper is connected to the anode. (2)
[20]

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QUESTION 2 (Start on a new page.)

The letters A to F in the table below represent organic compounds.

A CHsCOCH(CHs)2 B 3,3-dimethylhexane
H i"! H
oy on
H | H H—C—C—C=0O
ato-# i
ce | | i . H—¢C—H
H—C——C——C—H |
| | \ H—C—H
H H |
i i H
H
E C2H402 F Propan-1-ol
2.1. Write down the letter(s) representing:
2.1.1 An aldehyde (1)
2.1.2 Functional isomers (1)
2.1.3. Acarboxylic acid (1)
2.2 Write down the general formula of the homologous series to which
compound B belongs. (2)
2.3. For compound C, write down the:
2.3.1 Letter of the molecule that is its structural isomer (1)
2.3.2 Type of structural isomerism named in QUESTION 2.2.1 (1)
2.3.3 IUPAC name (3)
2.4 For compound A, write down the structural formula of its chain isomer. (3)
2.5 Compounds E and F react to form an organic molecule. For this reaction,

write down the:

2.5.1 Type of reaction (1)
2.5.2 NAME or FORMULA of the catalyst used (1)
2.5.3, IUPAC name of the ORGANIC product formed (2)

[17]

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QUESTION 3 (Start on a new page.)

The boiling points of four organic compounds are shown in the table below.

COMPOUND eon your ——~
A_ | CH3CH2COOH 141,1 74
B_ | CHs(CH2)30H tees 74
C | CHsCH(CH3)CH20H 108 74
D | CHsCOCH2CH3 79,6 72
3.1. Define the term boiling point. (2)

3.2 | Compounds C's boiling point is lower than that of compound B. Fully
explain. (3)

3.3. Consider compounds A, B and D.

3.3.1 Predict the value of the boiling point of compound B in °C.
Choose from:

145 141 117,7 (1)
3.3.2 Fully explain the answer to QUESTION 3.3.1. (6)
3.4. The vapour pressures of three straight-chained alkanes E, F and G are
shown below.
COMPOUND VAPOUR PRESSURE at 25 °C
(kPa)
E C2He 4 187
CsHs 1 050
G C4Hi0 250

3.4.1 Write the IUPAC NAME of the compound with the highest BOILING

POINT. (2)

3.4.2 Fully explain the trend in the vapour pressure from compound E to
compound G. (3)
[17]

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QUESTION 4 (Start on a new page.)

FS/September 2025

The flow diagram below shows a number of organic reactions. Reaction | is

CATALYTIC CRACKING.

Compound Q

Reaction |

CH3CH2CH3

Reaction Il] Oz

Compound R

Reaction III} HBr

Compound S Inorganic
Compound T

Compound R

Reaction V_ }H2SOz

Alcohol

Reaction IV

4.1. Define the term cracking.

4.2 Consider reaction Il.

NaOH

Compound U
CsH7Br

(2)

4.2.1. What type of reaction is it? Choose from ENDOTHERMIC or

EXOTHERMIC.

(1)

4.2.2 Using MOLECULAR FORMULAE, write down the balanced

chemical equation.

4.2.3. Write down the NAME of compound S.

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(3)
(1)

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4.3. In reaction Ill, compound R reacts with HBr to form compound U, which is
a major product with molecular formula C3H7Br.

For reaction Ill, write down:

4.3.1 The type of reaction (1)
4.3.2 ONE reaction condition (1)
4.3.3. The IUPAC name of compound U (2)

4.4 Forreaction IV, write down the:
4.4.1 Structural formula of the alcohol formed (2)
4.4.2 Type of reaction (1)

4.5 For reaction V, write down the:

4.5.1 Type of elimination reaction (1)
4.5.2 IUPAC name of compound R (2)
[17]

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QUESTION 5 (Start on a new page.)

A factor influencing the rate of a chemical reaction is investigated by conducting two
experiments, 1 and 2, in which the following reaction occurs:

Mg(s) + 2HCf(aq) > MgC£2(aq) + H2(g)

In both experiments, the same mass of magnesium(Mg) is added to an EXCESS
hydrochloric acid(HCé) solution with the same concentration in an open flask at STP.

The graph below shows the changes in the amount of gas collected during the reaction
in experiments 1 and 2.

A
no]
8 50
3
oO
aa
=~
i)
o
—E
3
$s
5.1. Write down the name of the apparatus used for collecting the gas. (1)
5.2 Define the term rate of reaction. (2)
5.3. Calculate the average rate (in dm°-s™) at which hydrogen is produced
in experiment 1. (3)
5.4 If 2 g of magnesium was used for this investigation, calculate the
percentage purity of the magnesium. (7)
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5.5 The Maxwell-Boltzmann distribution curves for the reaction in experiment 1
and 2 are given below.

Number of particles

Kinetic energy

5.5.1 Which factor affecting the reaction rate is being investigated? (1)
5.5.2 Which curve (A or B) represents the reaction in experiment 2? (1)
5.5.3 Explain the answer to QUESTION 5.5.2 by referring to the collision

theory. (2)
[17]

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### Page 12

FS/September 2025

QUESTION 6 (Start on a new page.)

Carbon, C, reacts with an unknown amount of carbon dioxide, COz, in a sealed 2 dm?
container, at a temperature T. The equilibrium constant, Ke, at this temperature is 0,2.
The balanced equation for the reaction is:

CO2(g) + C(s) = 2CO(g)

At equilibrium, the concentration of carbon monoxide, CO, is found to be

0,04 mol-dm*.
6.1. Can the above situation be referred to as a closed system?

Write down YES or NO. (1)
6.2 Explain the answer to QUESTION 6.1. (2)
6.3. Calculate the initial moles of CO2 used. (8)
6.4 Is the yield of carbon monoxide HIGH or LOW? (1)
6.5 Explain the answer to QUESTION 6.4. (2)
6.6 When the temperature is decreased, the yield of CO decreases.

6.6.1 Is the forward reaction EXOTHERMIC or ENDOTHERMIC? (1)

6.6.2 Use Le Chatelier's principle to explain the answer to

QUESTION 6.6.1. (2)

6.7. Drawa graph of potential energy (kJ-mol™') versus the reaction coordinate

for the reverse reaction.
Indicate the following on the graph:

e Activation energy
e Heat of reaction (AH)
e Energy of reactants and products

Write down the actual formulae of reactants and products (COz, C and CO)
on the graph as labels of these energies. (4)
[21]

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### Page 13

FS/September 2025

QUESTION 7 (Start on a new page.)

7.1

C2

Copyright reserved

Astandard solution of NaOH with a pH of 13,4 is used to neutralise 3,125 cm®
of a 0,4 mol-dm*® solution of H2SO4. The balanced chemical equation of the

reaction is:
H2SO4{aq) + 2NaOH{aq) — NazSOa(aq) + 2H20(£)
7.1.1 Define the term standard solution.
7.1.2 Is NaOH a strong or weak base?
7.1.3 Explain the answer to QUESTION 7.1.2.

7.1.4 Calculate the concentration of the NaOH solution.

7.1.5 Calculate the volume of the NaOH needed to neutralise the acid.

A laboratory technician neutralises an accidental spill by pouring 5 g of
baking soda (NaHCOs) on a 50 cm? hydrochloric acid solution of
concentration 1,6 mol-dms,

HCt(aq) + NaHCO3(s) + NaCt(aq) + CO2(g) + H20(£)

Calculate the pH of the final solution. Assume the volume remains
constant.

(2)
(1)
(2)
(5)
(5)

(7)
[22]

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### Page 14

FS/September 2025

QUESTION 8 (Start on a new page.)

A learner has the following reagents to construct an operational GALVANIC CELL
under standard conditions: Lead, Pb, lead nitrate, Pb(NOs)2, silver, Ag, silver nitrate,
AQgNOs, and iron(IIl) chloride, FeCf3

8.1

8.2

8.3

8.4

Define the term electrolyte. (2)

Using ONLY the reagents given above, write down the cell notation of the
operational galvanic cell. (3)

Write down the NAME or FORMULA of a substance that can be used in

the salt bridge. (2)
Calculate the EMF of the above cell. (4)
[11]

QUESTION 9 (Start on a new page.)

The simplified diagram below represents the electrolysis of a copper(II) chloride

solution.
Cle

9.1. Write down ONE safety measure which must be taken during the above
process. (1)
9.2 Explain why the safety measure in QUESTION 9.1 is necessary. (2)
9.3 In what direction are the electrons moving? Choose from P to Q or Qto P. (1)
9.4 | Write down the NAME of the substance that forms at electrode P. (1)
9.5 Write down the balanced net ionic equation for the reaction. (3)
[8]
TOTAL: 150

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### Page 15

FS/September 2025

DATA FOR PHYSICAL SCIENCES GRADE 12

PAPER 2 (CHEMISTRY)

GEGEWENS VIR FISIESE WETENSKAPPE GRAAD 12

VRAESTEL 2 (CHEMIE)

TABLE 1: PHYSICAL CONSTANTS / TABEL 1: FISIESE KONSTANTES

NAME / NAAM SYMBOL / SIMBOOL VALUE / WAARDE

TABLE 2: FORMULAE / TABEL 2: FORMULES

m N
ma nN,
n
oy
OR/OF ny
m
“MV
ae pH=-log(H,0"]

Ky=[H3O*][OH']=1*10"* atby 298 K

@ 8 8
Ecei=Ecathode"Eanode
OR

8 _-@ 8
Ece=Ereduction~Eoxidation
OR

8 6 8
Ecett=E oxidising agent"Eredusing agent

OF

OR

8 _-6 8
Ese1=Ekatode"Eanode

8 _ 6 8
Ese1=Ereduksie"Eoksidasie

8 8 8
Ese1=E oksideermiddel"Ereduseermiddel

Copyright reserved

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### Page 16

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gez zez
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SZ0z Jequiaydeg/s4

### Page 17

Increasing oxidising ability / Toenemende oksiderende vermoé

Copyright reserved

TABLE 4A: STANDARD REDUCTION POTENTIALS
TABEL 4A: STANDAARD-REDUKSIEPOTENSIALE

Half-reactions / Halfreaksies 59 (V)
F2(g) + 2e° 2F + 2,87
Co%*+e = Co* + 1,81
H202 + 2H*+2e° = 2H20 41,77
MnO, +8H*+S5e = Mn** +4H,O + 1,51
Ch(g)+2e = 2Ct + 1,36
Cr07 +14H*+6e = 2Cr*++7H20 + 1,33
O.(g)+4H*+4e = 2H20 + 1,23
MnO2+4H*+2e = Mn** +2H20 44,23)
Ptt+2e = Pt + 1,20
Br(t)+2e = 2Br +1,07
NO, +4H*+3e = NO(g)+2H,0 + 0,96
Hg**+2e = Hg(e) +0,85
Ag +e Ag + 0,80
NO, +2H*+e@ = NO2(g)+H0 + 0,80
Fe*+o = Fe* +0,77
Og) +2H*+2e = HO2 +0,68
k+2e = 2 + 0,54
Cutte = Cu + 0,52
SO.+4H'+4e = $+2H,0 +0,45
2H20+0O2+4e = 40H + 0,40
Cu%*+2e = Cu + 0,34
SO7 +4H'+2e = SOx(g)+2H20| +0,17
Cu%*+e = Cut +0,16
Sn#*+2e = Sn +0,15
S+2H*+2e = H2S(g) +0,14
2H*+2e- = Hag) 0,00
Fe*+3e = Fe — 0,06
Pb?* + 2e- Pb -0,13
Sn?*+2e = Sn — 0,14
Ni?*+2e = Ni - 0,27
Co*%*+2e = Co — 0,28
Cd**+2e = Cd —0,40
Cette = Crt — 0,41
Fe*+2e = Fe — 0,44
Cr++3e = Cr — 0,74
Zn*+2e = Zn — 0,76
2H20 + 2e = = H2(g) + 20H” — 0,83
Cr++2e = Cr —0,91
Mn’*+2e = Mn — 1,18
ABbt+3e = Al — 1,66
Mg**+2e = Mg — 2,36
Nat*+e = Na — 2,71
Ca**+2e = Ca — 2,87
Srt+2e = Sr — 2,89
Ba**+2e = Ba — 2,90
Cs*t+e = Cs - 2,92
Kt+e = K — 2,93
Litre Li —3,05

FS/September 2025

Increasing reducing ability / Toenemende reduserende vermoé

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### Page 18

Increasing oxidising ability / Toenemende oksiderende vermoé

FS/September 2025

TABLE 4B: STANDARD REDUCTION POTENTIALS
TABEL 4B: STANDAARD-REDUKSIEPOTENSIALE

Half-reactions / Halfreaksies E® (v)
litte = Li ~ 3,05
Kte = K — 2,93
Cs*+e = Cs — 2,92
Ba**+2e = Ba — 2,90
Srt+2e = Sr — 2,89
Ca*%*+2e = Ca — 2,87
Nat+e = Na - 2,71
Mg?*+2e = Mg — 2,36
AG++3e = AL ~ 1,66
Mn?*+2e- = Mn - 1,18
Cr++2e = Cr - 0,91
2H,0+2e = He{g)+20H | -0,83 *
Zn*+2e = Zn — 0,76 ®
crt+3e = Cr - 0,74 2
Fe +20 = Fe ~ 0,44 S
Cette = Crt - 0,41 ®
Cd*+2e = Cd - 0,40 2
Co*+2e = Co — 0,28 §
NP? +2e = Ni ~ 0,27 8
Sn +2e = Sn — 0,14 BS
Pb +2e = Pb -0,13 o
Fe +3e = Fe — 0,06 Hy
2H*+2e = Hag) 0,00 &
S+2H'+2e = HS(g) + 0,14 2
Sn*¥+2e = Sn? +0,15 e
Cu#+e = Cut +0,16 ~
$02 +4H'+2e = $0,(g)+2H.0| +0,17 2
Cu2++2e- = Cu + 0,34 2
2H20+O2+4e = 40H + 0,40 >
SO,+4H*+4e = S+2H,0 + 0,45 3
Cu’+e = Cu + 0,52 3
b+2e = 2b +0,54 £
O2(g)+2H*+2e = H2O2 + 0,68 2
Fet++e = Fe% +0,77 8
NO, +2H*+e = NOAg)+HO | +0,80 5
Ag'te = Ag + 0,80 =
Hg*+2e = Hg(t) + 0,85
NO3 +4H*+3e = NO(g)+2H,O | +0,96
Bro(t)+2e = 2Br + 1,07
Pt=+2e = Pt + 1,20
MnO2+4H*+2e = Mn? +2H20 + 1,23
O.(g)+4H*+4e = 2H20 + 1,23
CrO? +14H*+6e = 2Cr++7H,O | +1,33
Ch(g)+2e = 2Ct + 1,36
MnO, +8H*+5e = Mn? +4H,0 +1,51

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