# Physical Sciences Grade 12 Limpopo Prelim 2024 Memo

> Grade 12 Physical Sciences memorandum from the Limpopo Prelim Exam 2024, 11 pages. Read online or download the free PDF.

- Page: https://www.hlayiso.com/library/pshcp2sept2024memo/ac6d9ab1-065b-4226-b03a-fcd362fa4424
- Updated: 2026-09-27
- Subject: Physical Sciences
- Grade: Grade 12
- Document type: Memorandum
- Year: 2024
- Exam period: Limpopo Prelim Exam
- Curriculum: CAPS
- Pages: 11

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Physical Sciences · Grade 12 · Limpopo Prelim Exam · 2024. Memorandum, 11 pages. Read online or download the PDF.

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                                   NATIONAL
                           SENIOR SERTIFICATE

                                  GRADE 12

                  PHYSICAL SCIENCES: CHEMISTRY (P2)

                           MARKING GUIDELINES

                              SEPTEMBER 2024

This marking guideline consists of a cover page and 10 pages.

TOTAL: 150

TIME: 3 HOURS

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              GRADE 12 TRIAL EXAMINATION – LIMPOPO
2024    SEPTEMBER       PAPER 2: CHEMISTRY                           MARKS: 150
                      MARKING GUIDELINES

QUESTION 1

1.1     A                                                                   (2)

1.2     C                                                                   (2)

1.3     D                                                                   (2)

1.4     B                                                                   (2)

1.5     B                                                                   (2)

1.6     C                                                                   (2)

1.7     A                                                                   (2)

1.8     A 

                                                                              (2)

1.9     D                                                                   (2)

1.10    A                                                                   (2)

                                                                             [20]

QUESTION 2

2.1     Carbon has four valence electrons, so it can achieve a full outer    (2)
        energy level by forming four covalent bonds (this property is
        known as tetravalency). Carbon can form single, double, or triple
        covalent bonds with other carbon atoms to produce long chain or
        ring structures.

2.2.1   CnH2n+2                                                              (1)

2.2.2                                                                         (3)
                                             Marking criteria
                                             • Two methyl substituents
                                             • Chlorine substituent
                                             • Whole structure correct
                                             •
                                             • Chloor substituent 
                                             • Whole structure correct:
                                                3⁄
                                         2        3

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2.2.3   SATURATED                                                                (1)

2.3.1   Compounds with the same molecular formula,  but different
        positions of the side chain/substituents/functional groups  on the
        parent chain.                                                             (2)

2.3.2   carbonyl                                                                 (1)

2.3.3   pentan-3-one / 3-pentanone                                                (2)

                             Marking criteria
                             • Functional group and correct position i.e., 3 
                             • Correct IUPAC name 
                             
                             Accept for ONE mark/Aanvaar vir EEN
2.3.4
                                              Marking criteria
                                              • Correct functional group
                                              • Whole structure correct

        OR: Any correct structure of an aldehyde with five carbon atoms.

                                         OR

                                         OR

                                         3

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                                                                                (2)

2.4.1   TERTIARY 
        The C atom bonded to the functional group/hydroxyl (group)/-OH is       (2)
        bonded to three other C atoms. /The C-atom bonded to the hydroxyl
        (group) has no hydrogen atoms. 

2.4.2   2-methylpropan-2-ol / 2-methyl-2-propanol                               (2)

         Marking criteria
         • 2-methyl 
         • propan-2-ol / 2-propanol 
         • Any errors e.g., hyphens omitted and/or incorrect sequence:
            Max: 1⁄2

                                                                               [18]

QUESTION 3

3.1     Relative molecular mass/molar mass/Mr                                  (1)

3.2.1   Boiling point                                                          (1)

3.2.2   Type of organic compound/homologous series/functional group            (1)
                                 (alkane,alcohol,carboxylic acid)
3.3.1   LOWER THAN                                                             (1)
                                                     –
3.3.2   Negative marking from question 3.3.1

           •   2-methylpropane is a spherical molecule, therefore smaller
               surface area  is presented to other molecules (sphere is 3D
               shape with lowest surface-to-volume ratio).
           •   Less surface area at which van der Waals interactions with
               other molecules can occur  /fewer van der Waals
               interactions/fewer cohesive interactions.
           •   Less energy required  to overcome cohesive forces as
               liquid hydrocarbon is vaporised.                                 (3)

3.4     The pressure exerted by a vapour at equilibrium with its liquid in a
        closed system. (2 or 0)                                               (2)

                                          4

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3.5     Ethanoic acid (C) – It is possible for 2 H-bonds (at C=O and O-H)
                           to form between adjacent carboxylic acid
                           molecules. Therefore H-bonds stronger  in
                           carboxylic acid. Therefore, more energy
                           required to overcome the stronger forces of
                           attraction/to overcome the IMF BETWEEN
                           molecules.

                                          OR

        propan-1-ol (B) – H-bonds weaker in alcohol  as it is only possible
                          for 1 H bond at O-H to form between adjacent
                         molecules of alcohol therefore less energy
                         required  to overcome the strong forces of
                         attraction/to overcome the IMF BETWEEN
                         molecules.                                              (3)

                                                                                [12]

QUESTION 4

4.1.1   Substitution  / halogenation                                            (1)

4.1.2   Substitution                                                            (1)

4.1.3   Substitution                                                            (1)

4.1.4   Substitution / dehydrohalogenation                                      (1)

4.2     CH3CH2CH2Br  + H2O  → CH3CH2CH2OH  + HBr                             (4)

4.3                                                                              (2)

                          3-C atoms in chain    Whole structure correct

4.4     H 2O 
        CO2                                                                     (2)

4.5          H H H                               H H                             (3)
                                                          H
         H   C C C Br + KOH(gek.) → H            C C C        + H2O + KBr
             H H H                               H       H

                         Marking criteria
                            • Correct structural formula of 1-bromopropane 
                            • Correct structural formula of prop-1-ene 
                            • H2O + KBr 

                                          5

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4.6   Propan-1-ol / 1-propanol
                    Marking criteria
                       • Functional group and correct position, ie.1. 
                       • Propanol 
                                                                             (2)

4.7   Esters                                                                (1)

4.8   propylethanoate                                                      (2)

                                                                            [20]

                                      6

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QUESTION 5

5.1     Activation energy                                                         (1)

5.2.1 C                                                                           (1)
                                    –
5.2.2 Negative marking                                                             (1)

        Total area under graphs A and C approximately the same, but
        more molecules with greater average Ek therefore area X of graph C
        greater – more molecules with greater average Ek.

5.2.3      •   Increased temperature therefore increased average kinetic
               energy of molecules.
           •   More of these molecules will have sufficient kinetic energy  to
               react./ Ek≥activation energy
           •   More effective collisions per second /unit time.
           •   Increased rate of reaction.                                        (4)

5.3.1 A catalyst will speed up a chemical reaction                                (2)
      without itself undergoing permanent change. 

5.3.2 INCREASES                                                                   (1)

5.3.3 A catalyst will create an alternative path of lower activation energy 
      “line Y” moves to the left  – therefore area X increases in size.           (2)

                                                                                  [12]

QUESTION 6

6.1     The change in concentration of reactants or products                      (2)
        per unit time.  or any other acceptable definition(see Guideline)

6.2     It starts at zero in t0  and increases to time t1                        (2)

6.3     Equilibrium  is reached.                                                  (1)

6.4

                 m

                                                              t
         Criteria for graph
         Axes labelled correctly. 
         Gradient of graph initially high and then decreases with time. 

                                            7

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       Graph ends parallel to x-axis to represent equilibrium.                   (3)
6.5.1 Decreases                                                                  (1)

6.5.2 Decreases                                                                  (1)

6.5.3 Decreases                                                                  (1)

6.6     At lower T, the exothermic (forward) reaction is favoured. 
        Therefore, the reverse reaction is favoured, 
        reducing the concentration of the gas (products). If concentration of
        products decrease then Kc will also decrease

                                                                                  (4)

6.7     𝐾𝑐 = [𝐶𝑂2 ] = 1,4 × 10−2                                                (2)

                                                                                 [17]

QUESTION 7

7.1.1 An acid is a proton (H+-ion) -donor.                                      (2)

7.1.2 It ionises to form 2 protons/2 mol H+-ions.                                (1)
      OR
      It donates 2H+-ions per H2SO4 -molecule.

7.2.1 Amphiprotic (substance)/Ampholyte                                          (1)

7.2.2 H2CO3 (aq)                                                                 (1)

7.3.1 𝑛(𝐻2 𝐶𝑂3 ) = 𝑚 
                   𝑀

                          27
                     = 84 

                     = 0,32 𝑚𝑜𝑙                (0,3214285714 𝑚𝑜𝑙)
                          1
        𝑛(𝐻2 𝑆𝑂4 ) = 2 𝑛(𝑁𝑎𝐻𝐶𝑂3 )
                          1
                     = 2 (0,32) 
                     = 0,16 𝑚𝑜𝑙                (0,1607142857 𝑚𝑜𝑙)
             𝑛
        𝑐=𝑉
             0,16
        6=                                   ( 6 and 0,16)
                 𝑉
                                                                                  (6)
        ∴ 𝑉 = 0,03 𝑑𝑚3                        (30 𝑐𝑚3 / 0,027 𝑑𝑚3 / 27 𝑐𝑚3 )

7.3.2          𝑛𝑎 (𝑖𝑛𝑖𝑡𝑖𝑎𝑙) = 𝑛𝑎 (𝑓𝑖𝑛𝑎𝑙)
             𝑐𝑎 𝑣𝑎 (𝑖𝑛𝑖𝑡𝑖𝑎𝑙) = 𝑐𝑎 𝑣𝑎 (𝑓𝑖𝑛𝑎𝑙)

                                               8

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                   ∴ (6)𝑣𝑎 = (0,1)(1)
                      ∴ 𝑣𝑎 = 0,02 𝑑𝑚3
                                            (20 𝑐𝑚3 / 0,0167 𝑑𝑚3 / 16,7 𝑐𝑚3 )    (2)

7.3.3 Shows end point (of titration).  /Shows when neutralisation occurs.       (1)

7.3.4
         Marking criteria:
         • Substitute initial [acid] and volume
         • Substitute initial [base] and volume
         • Use ratio 1 : 2
         • Initial mole acid – mole acid reacted
         • Substitute volume acid + volume base
         • pH formula
         • Substitute 2 x ca in pH formula
         • Final answer: 1,44

        𝑛𝑎 (𝑖𝑛𝑖𝑡𝑖𝑎𝑙) = 𝑐𝑎 𝑣𝑎
                     = (0,1)(25 × 10−3) 
                     = 2,5 × 10−3 𝑚𝑜𝑙

        𝑛𝑏 (𝑟𝑒𝑎𝑐𝑡𝑒𝑑) = 𝑐𝑏 𝑣𝑏
                     = (0,1)(30 × 10−3 ) 
                     = 3 × 10−3 𝑚𝑜𝑙

        𝑛𝑎 1
          =
        𝑛𝑏 2
                            1    1
        ∴ 𝑛𝑎 (𝑛𝑒𝑢𝑡𝑟𝑎𝑙𝑖𝑠𝑒𝑑) = 𝑛𝑏 = (3 × 10−3 ) = 1,5 × 10−3 𝑚𝑜𝑙
                            2    2

        𝑛𝑎 (𝑙𝑒𝑓𝑡) = 𝑛𝑎 (𝑖𝑛𝑖𝑡𝑖𝑎𝑙) − 𝑛𝑎 (𝑛𝑒𝑢𝑡𝑟𝑎𝑙𝑖𝑠𝑒𝑑)
                       = 2,5 × 10−3 − 1,5 × 10−3 
                       = 1 × 10−3 𝑚𝑜𝑙

               𝑛
        𝑐𝑎 =
               𝑉
                       1 × 10−3
           =
               (25 × 10−3 + 30 × 10−3 )

           = 0,018 𝑚𝑜𝑙. 𝑑𝑚−3

        𝑝𝐻 = −𝑙𝑜𝑔[𝐻3 𝑂 + ] 

           = −log [2(0,018)]
           = 1,44                                                               (8)

                                                                                [22]

                                            9

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QUESTION 8

8.1    Pb  (lead)                                                                (1)

8.2    Zn → Zn2+ + 2e-  (2 or 0)                                                (2)

8.3     𝜃       𝜃                  𝜃
       𝐸𝑐𝑒𝑙𝑙 = 𝐸𝑜𝑥𝑖𝑑𝑖𝑠𝑖𝑛𝑔 𝑎𝑔𝑒𝑛𝑡 − 𝐸𝑟𝑒𝑑𝑢𝑐𝑖𝑛𝑔 𝑎𝑔𝑒𝑛𝑡 
       = −0,13  − (−0,76) 
       = 0,63 (𝑉)                                                                (4)

8.4    • Temperature                                                             (2)
       • (initial) concentration of the electrolytes. 

8.5.1 EQUAL TO                                                                   (1)

8.5.2 Area/size of electrodes has no effect on the emf of a cell.  / It is      (2)
      still a standard cell.

8.6.1 The cell has internal resistance.                                          (1)

8.6.2 The emf decreases as the concentration of Pb2+(aq) decreases.  /
      The cell is running flat as the electrolyte concentration in the Pb cell
      decreases.                                                                  (1)

                                                                                 [14]

QUESTION 9

9.1    A substance of which the aqueous solution contains ions.  /              (2)
       A substance that dissolves in water to give a solution that conducts
       electricity.

9.2    Endothermic                                                               (1)

9.3    Bracelet                                                                  (1)

9.4.1 REMAINS THE SAME                –                                          (1)

9.4.2 The rate of oxidation of copper at the anode is equal                      (2)
      to the rate of reduction of copper (II) ions at the cathode. 

9.4.3 Cu → Cu2+ + 2e-                                                           (2)
                                           Notes:
                                           𝐶𝑢 ⇌ 𝐶𝑢 2+ + 2𝑒 −   (1⁄2)
                                           𝐶𝑢 2+ + 2𝑒 − → 𝐶𝑢   (0⁄2)
                                           𝐶𝑢 2+ + 2𝑒 − ← 𝐶𝑢   (2⁄2)
                                           𝐶𝑢 2+ + 2𝑒 − ⇋ 𝐶𝑢   (0⁄2)

                                            10

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9.5           𝑚
      𝑛(𝐶𝑢) =
              𝑀
              0,86
            =      
              63,5
            = 0,0135 𝑚𝑜𝑙 
                             (0,01354330709 𝑚𝑜𝑙)

      𝑛(𝑒𝑙𝑒𝑐𝑡𝑟𝑜𝑛𝑠) = 2𝑛(𝐶𝑢) = 2(0,0135) = 0,027 𝑚𝑜𝑙

           𝑁
      𝑛=      
           𝑁𝐴
                    𝑁                                   (6)
      0,027 =
              6,02 × 1023 
      ∴ 𝑁 = 1,63 × 1022  𝑒𝑙𝑒𝑐𝑡𝑟𝑜𝑛𝑠

                                                       [15]

                                 TOTAL: 150

                                      11

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