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PREPARATORY EXAMINATION
VOORBEREIDENDE EKSAMEN
GRADE/GRAAD 12
PHYSICAL SCIENCES: CHEMISTRY (P2)
FISIESE WETENSKAPPE: CHEMIE (V2)
SEPTEMBER 2024
MARKS/PUNTE: 150
MARKING GUIDELINES/NASIENRIGLYNE
These marking guidelines consist of 14 pages.
Hierdie nasienriglyne bestaan uit 14 bladsye.
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Physical Sciences Grade 12 Free State Prelim 2024 QP
Grade 12 Physical Sciences question paper from the Free State Prelim Exam 2024, 14 pages. Read online or get the free PDF download, memo linked when available.
Physical Sciences · Grade 12 · Free State Prelim Exam · 2024. Question paper, 14 pages. Read online or download the PDF.
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Physical Sciences P2/Fisiese Wetenskappe V2 2 FS/VS/September 2024
Grade/Graad 12 Prep. Exam./Voorb. Eksam.
Marking Guidelines/Nasienriglyne
QUESTION 1/VRAAG 1
1.1 B ✓✓ (2)
1.2 B ✓✓ (2)
1.3 C ✓✓ (2)
1.4 D ✓✓ (2)
1.5 B ✓✓ (2)
1.6 C ✓✓ (2)
1.7 D ✓✓ (2)
1.8 C ✓✓ (2)
1.9 A ✓✓ (2)
1.10 A ✓✓ (2)
[20]
QUESTION 2/VRAAG 2
2.1.1 A ✓ (1)
2.1.2 E ✓ (1)
2.1.3 D ✓ (1)
2.2.1 Tertiary (alcohol) / Tersiêre (alkohol) ✓
The carbon atom bonded to the hydroxyl group is bonded to three other
carbon atoms. ✓
Die koolstofatoom wat aan die hidroksielgroep gebind is, is aan drie ander
koolstofatome gebind. (2)
2.2.2 3-methylheptan-3-ol / metielheptaan-3-ol
Marking criteria/Nasienkriteria:
• Correct stem of alcohol, i.e. heptanol.
• Substituent correctly identified, i.e. methyl.
• IUPAC name completely correct including
numbering and hyphens.
• Korrekte stam van alkohol, d.i. heptanol.
• Substituent korrek geïdentifiseer, d.i. metiel.
• IUPAC-naam heeltemal korrek, insluitend
nommering en koppeltekens.
(3)
2.2.3 Hydroxyl (group) / Hydroksiel (groep) ✓ (1)
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Physical Sciences P2/Fisiese Wetenskappe V2 3 FS/VS/September 2024
Grade/Graad 12 Prep. Exam./Voorb. Eksam.
Marking Guidelines/Nasienriglyne
2.3.1
Marking criteria/Nasienkriteria:
• Correct functional group of carboxylic acid.
• Whole structure of carboxylic acid correct.
• Correct functional group of alcohol.
• Whole structure of alcohol correct.
• Korrekte funksionele groep karboksielsuur.
• Hele struktuur van karboksielsuur korrek.
• Korrekte funksionele groep alkohol.
• Hele struktuur van alkohol korrek. (4)
2.3.2
✓
(1)
2.4
H H F H H Marking criteria/Nasienkriteria:
• Methyl substituent on second C atom.
H C C C C C H • Two fluorine atoms on third C atom.
• Whole structure correct.
H H F H
• Metielsubstituent op tweede C-atoom.
H C H • Twee fluooratome op derde C-atoom.
• Hele struktuur korrek.
H
(3)
m
2.5 n(CO2) = M (a) Marking criteria/Nasienkriteria:
m
(a) Formula/Formule n = M
2750
= 44 m
(b) Substitute/Vervanging M = 44 g·mol-1 in n = M
✓(b)
= 62,5 mol (c) Use mole ratio/Gebruik molverhouding:
n(CH4) = n(CO2)
m
n(CH4) = n(CO2) (c) (d) Substitute/Vervanging M = 16 g·mol-1 in n = M
= 62,5 mol (e) Correct final answer/Korrekte finale antwoord:
1 000 g OR 1 kg ✓
m(CH4) = n(CH4) x M (CH4)
= 62,5 x 16 (d)
=1000g/ 1kg (e)
(5)
[22]
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Physical Sciences P2/Fisiese Wetenskappe V2 4 FS/VS/September 2024
Grade/Graad 12 Prep. Exam./Voorb. Eksam.
Marking Guidelines/Nasienriglyne
QUESTION 3/VRAAG 3
3.1 Marking criteria/Nasienkriteria:
If any of the underlined key phrases in the correct context is omitted, deduct
1 mark.
Indien enige van die onderstreepte sleutelfrases in die korrekte konteks
weggelaat word, trek 1 punt af.
The temperature at which the vapour pressure of a liquid is equal to
the atmospheric pressure.
Die temperatuur waarby die dampdruk van 'n vloeistof gelyk is aan
die atmosferiese druk. (2)
3.2.1 FROM A TO C
• Increase branching/smaller surface area/more compact ✓
• Weaker intermolecular forces ✓
• Less energy needed to break the intermolecular forces ✓
• Boiling point decreases ✓
VANAF A TOT C
• Vergroot vertakking/kleiner oppervlakte/meer kompak
• Swakker intermolekulêre kragte
• Minder energie benodig om die intermolekulêre kragte te breek
• Kookpunt neem af (4)
3.2.2 C/2,2-dimethylpropane / dimetielpropaan ✓ (1)
3.2.3 Lowest boing point / Laagste kookpunt ✓ (1)
3.3 Greater than (103 °C) ✓
• Between compound D/pentanal molecules are dipole-dipole forces✓
(and London forces) and between compound E/butanoic acid are
hydrogen bonds✓ (dipole-dipole and London forces).
• Dipole-dipole forces are weaker than hydrogen bonds. ✓
OR
Intermolecular forces between compound D/pentanal molecules are
weaker than those between compound E/butanoic acid molecules.
OR
Less energy is needed to break the intermolecular forces between
pentanal molecules.
Groter as (103 °C)
• Tussen verbinding D/pentanale molekules is dipool-dipoolkragte (en
Londen-kragte) en tussen verbinding E/butaansuur is waterstofbindings
(dipool-dipool en Londen-kragte).
• Dipool-dipoolkragte is swakker as waterstofbindings.
OF
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Physical Sciences P2/Fisiese Wetenskappe V2 5 FS/VS/September 2024
Grade/Graad 12 Prep. Exam./Voorb. Eksam.
Marking Guidelines/Nasienriglyne
Intermolekulêre kragte tussen verbinding D/pentanale molekules is
swakker as dié tussen verbinding E/butaansuurmolekules.
OF
Minder energie benodig om die intermolekulêre kragte tussen pentanale
molekules te breek. (4)
3.4 Yes/Ja ✓ (1)
3.5 Comparable molecular masses AND only functional group (homologous
series) changed/only 1 independent variable ✓
Vergelykbare molekulêre massas EN enigste funksionele groep
(homoloë reeks) verander/slegs 1 onafhanklike veranderlike. (1)
[14]
QUESTION 4/VRAAG 4
4.1 A reaction of a halogen with a compound.
'n Reaksie van 'n halogeen met 'n verbinding. (2)
4.2.1 Heat/Sunlight/UV light / Hitte/Sonlig/UV-lig (1)
4.2.2 HBr (1)
4.3 CH3CH2Br ✓ + NaOH/ ✓ CH2CH2 ✓ + NaBr/ ✓ + H2O ✓
KOH/LiOH KBr/LiBr (5)
4.4 Addition/Hydration / Addisie/Hidrasie ✓ (1)
4.5 Methanoic acid / Metanoësuur ✓✓ (2)
4.6 Esterification/Condensation / Verestering/Kondensasie ✓ (1)
✓
4.7 ✓
✓ ✓
+
H2O ✓
(4)
[17]
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Physical Sciences P2/Fisiese Wetenskappe V2 6 FS/VS/September 2024
Grade/Graad 12 Prep. Exam./Voorb. Eksam.
Marking Guidelines/Nasienriglyne
QUESTION 5/VRAAG 5
5.1 Mass meter/Scale / Massameter/Skaal (1)
5.2 Calcium carbonate / Kalsiumkarbonaat (1)
5.3 • Change in concentration/mass/amount/volume ✓ of reactants/products
per unit time. ✓
• Concentration/amount/mass/volume of reactants used/products formed
per unit time.
• Rate of change in concentration/amount/mass/volume. (2 or 0)
• Verandering in konsentrasie/massa/hoeveelheid/volume van reaktante/
produkte per tydseenheid.
• Konsentrasie/hoeveelheid/massa/volume van reaktante gebruik/produkte
gevorm per tydseenheid.
• Tempo van verandering in konsentrasie/hoeveelheid/massa/volume. (2)
5.4 Marking criteria/Nasienriglyne:
• Mass of CO2 formed/Massa van CO2 gevorm: 270-268,4 or/of 1,6g
m
• Substituting/Vervanging 44 in n =
M
• Substitute number of moles of CO2 in the rate formula
Vervang die aantal mol CO2 in die tempoformule
• Substitute time in the rate formula / Vervang tyd in die tempoformule
• Correct final answer/Korrekte finale antwoord
• Range/Gebied: 0,001 to 0,0013 mol∙s-1
m
n(CO2) =
M
1,6 ✓ (a)
=
44 ✓ (b)
= 0,03636 mol
△n
Rate/Tempo = ( )
△t
0,03636-0
=( ) ✓ (c)
30-0 ✓ (d)
= 1,21 x 10-3 (mol·s-1) (e) (5)
5.5 Experiment 1 /Eksperiment 1 (1)
5.6 • High concentration results in more particles per unit volume
• More effective collisions per unit time/frequency of effective collisions
increases
• Higher rate of reaction ✓/Higher rate of formation of CO2.
•
•• Hoë konsentrasie lei tot meer deeltjies per eenheid volume
•• Meer effektiewe botsings per tydseenheid/frekwensie van effektiewe
botsings neem toe
• Hoër reaksietempo/Hoër tempo van vorming van CO 2. (3)
[13]
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Physical Sciences P2/Fisiese Wetenskappe V2 7 FS/VS/September 2024
Grade/Graad 12 Prep. Exam./Voorb. Eksam.
Marking Guidelines/Nasienriglyne
QUESTION 6/VRAAG 6
6.1.1 Rate of forward reaction is equal to rate of reverse reaction. ✓
Tempo van voorwaartse reaksie is gelyk aan tempo van terugwaartse
reaksie. (2)
6.1.2 Addition of a catalyst / Addisie van 'n katalisator (2)
6.1.3 (a) Decreased / Toeneem (1)
(b) Exothermic / Eksotermies (1)
(c) ● Decrease in temperature favours an exothermic reaction .
• The forward reaction is favoured /rate of forward reaction
decreased less than that of the reverse reaction.
• Verlaging in temperatuur bevoordeel 'n eksotermiese reaksie.
• Die voorwaartse reaksie word bevoordeel/tempo van
voorwaartse reaksie het minder afgeneem as dié van die
terugwaartse reaksie (2)
6.2.1 When the products can be converted back to reactants ✓
Wanneer die produkte terug na reaktante omgeskakel kan word (1)
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Physical Sciences P2/Fisiese Wetenskappe V2 8 FS/VS/September 2024
Grade/Graad 12 Prep. Exam./Voorb. Eksam.
Marking Guidelines/Nasienriglyne
6.2.2 CALCULATIONS USING NUMBER OF MOLES/
Mark allocation:
(a) USING ratio NOCℓ : NO : Cℓ2= 2:2:1
(b) Change in number of moles of NO = equilibrium moles of NO
Equilibrium number moles of Cℓ2 = change in moles of Cℓ2
(c) Equilibrium moles NOCℓ = initial moles NOCℓ – change moles of NOCℓ
(d) Dividing equilibrium moles NOCℓ and Cℓ2 by 2 AND mutiplying equilibrium
concentration NO by 2
(e) Correct Kc expression (formulae in square brackets) ✓
(f) Correct substitution of concentrations into Kc correct expression
(g) Final answer : 0,33
BEREKENINGE MET GEBRUIK VAN AANTAL MOL
Puntetoekenning:
(a) GEBRUIK verhouding NOCℓ : NO : Cℓ2= 2:2:1
(b) Verandering in aantal mol NO = ewewigsmol NO
Ekwilibriumgetal mol Cℓ2 = verandering in mol Cℓ2
(c) Ekwilibrium mol NOCℓ = aanvanklike mol NOCℓ – verander mol van NOCℓ
(d) Deel ewewigsmol NOCℓ en Cℓ2 deur 2 EN vermenigvuldig
ewewigkonsentrasie NO met 2
(e) Korrekte Kc-uitdrukking (formules tussen vierkantige hakies)
(f) Korrekte vervanging van konsentrasies in Kc korrekte uitdrukking
(g) Finale antwoord : 0,33
NOCℓ NO Cℓ2
Initial quantity (mol)
Aanvanklike hoeveelheid (mol) 4 0 0
Change
1,8 1,8 Ratio ✓ (a)
Verander (mol) 0,9
Verhouding
Quantity at equilibrium (mol) ✓ (c)
2,2 1,8 0,9 ✓(b)
Hoeveelheid by ewewig (mol)
Equilibrium concentration (mol∙dm-3)
✓(d)
Ekwilibriumkonsentrasie (mol∙dm-3) 1,1 0,9 0,45 ÷&x2
[NO]2 [Cl2]
Kc = ✓ (e)
[NOCl]2
(0,9)2 (0,45)
Kc = ✓(f)
1,1
Kc = 0,33 ✓(g)
Wrong Kc expression / Verkeerde Kc uitdrukking Max/Maks: 4⁄7
No Kc expression followed by correct substitutions / Geen Kc-uitdrukking gevolg
deur korrekte vervangings Max/Maks: 6⁄7
(7)
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Physical Sciences P2/Fisiese Wetenskappe V2 9 FS/VS/September 2024
Grade/Graad 12 Prep. Exam./Voorb. Eksam.
Marking Guidelines/Nasienriglyne
CALCULATIONS USING CONCENTRATIONS
Mark allocation:
(a) Initial concentration of NOCℓ = initial moles of NOCℓ 2
(b) USING ratio NOCℓ : NO: Cℓ2 = 2:2:1
(c) Change in concentration of NO = equilibrium concentration of NO
Equilibrium concentration of Cℓ2 = change in concentration of Cℓ2
(d) Equilibrium concentration of NOCℓ = initial concentration of NOCℓ –
change in concentration of NOCℓ
(e) Correct Kc expression (formulae in square brackets)
(f) Correct substitution of concentrations into Kc expression
(g) Final answer : 0,33
BEREKENINGE DEUR KONSENTRASIES
Puntetoekenning:
(a) Aanvanklike konsentrasie van NOCℓ = aanvanklike mol NOCℓ 2
(b) GEBRUIK verhouding NOCℓ : NO: Cℓ2 = 2:2:1
(c) Verandering in konsentrasie van NO = ewewigskonsentrasie van NO
Ekwilibriumkonsentrasie van Cℓ2 = verandering in konsentrasie van Cℓ2
(d) Ekwilibriumkonsentrasie van NOCℓ = aanvanklike konsentrasie NOC –
verandering in konsentrasie van NOCℓ
(e) Korrekte Kc-uitdrukking (formules tussen vierkantige hakies)
(f) Korrekte vervanging van konsentrasies in Kc uitdrukking
(g) Finale antwoord: 0,33
NOCℓ NO Cℓ2
Initial concentration (mol∙dm-3l)
Aanvanklike konsentrasie
2 0 0
(mol∙dm-3l) ✓ (a)
✓(c)
Change concentration (mol∙dm-3) Ratio ✓ (b)
0,9 0,9
Verander konsentrasie (mol∙dm-3) 0,45 Verhouding
Equilibrium concentration (mol∙dm-3)
Ekwilibriumkonsentrasie (mol∙dm-3) 1,1 ✓ (d) 0,9 0,45
2
[NO] [Cl2]
Kc = ✓ (e)
[NOCl]2
(0,9)2 (0,45) ✓(f)
Kc =
1,1
Kc = 0,33 ✓(g)
Wrong Kc expression / Verkeerde Kc uitdrukking Max/Maks: 4⁄7
No Kc expression followed by correct substitutions / Geen Kc-uitdrukking gevolg
deur korrekte vervangings Max/Maks: 6⁄7
(7)
[16]
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Physical Sciences P2/Fisiese Wetenskappe V2 10 FS/VS/September 2024
Grade/Graad 12 Prep. Exam./Voorb. Eksam.
Marking Guidelines/Nasienriglyne
QUESTION 7/VRAAG 7
7.1.1 The reaction of salt with water
Die reaksie van soutwater met water (2)
7.1.2 Acidic/Suur (1)
+
7.1.3 NH+4 (aq) + H2O(ℓ) → NH3 + H3 O (aq)
OR / OF
+ +
NH4 (aq) + 2H2O(ℓ) → NH4OH + H3 O (aq) (3)
7.2.1 Strong (acid) / Sterk (suur) (1)
7.2.2 Ionises/dissociate completely in waterto form a high concentration
of H3O+ ions.
Ioneer/dissosieer heeltemal in water om 'n hoë konsentrasie van
H3O+ ione te vorm. (2)
7.2.3 Methyl orange / Metiel oranje (1)
7.2.4 Titration of strong acid and weak base
Titrasie van sterk suur en swak basis (2)
7.2.5 Marking criteria/Nasienriglyne:
n
• Formula / Formule c =
V
• Substitute / Vervang 0,1 AND / EN 25 x 10-3 in n = cV
• Final answer/Finale antwoord: 0,0025 mol
n
c=
V
n = 0,1 x 25 x 10-3
n = 2,5 x 10-3 mol / 0,0025 mol (ACCEPT/AANVAAR: 0,003 mol) (3)
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Physical Sciences P2/Fisiese Wetenskappe V2 11 FS/VS/September 2024
Grade/Graad 12 Prep. Exam./Voorb. Eksam.
Marking Guidelines/Nasienriglyne
7.2.6 Marking criteria/Nasienriglyne:
(a) Ratio / Verhouding n(HCℓ) = n(NH3)
n
(b) Formula / Formule c = V / pH = -log[H3O+]
(c) Substituting n(NH3) and volume of 0,04dm3 / Vervang n(NH3) en
volume van 0,04dm3
(d) Subtraction / Aftrekking: c(HCℓ)initial – c(HCℓ)used
(e) c(H3O+) = c(HCℓ)
(f) Substituting / Vervanging c(H3O+) in pH = -log[H3O+]
(g) Final answer / Finale antwoord = 1,43
RANGE: 1,4 – 1,6
n(HCℓ) = n(NH3) (a)
= 2,5 x 10-3
n
c(HCℓ) =
V
2,5 x 10-3
= (c)
0,04
= 0,0625 mol·dm-3
ANY/ENIGE 1 (b)
c(HCℓ) excess/oormaat = 0,1 – 0,0625 (d)
= 0,0375 mol·dm-3
c(H3O+) = c(HCℓ) (e)
= 0,0375
pH = -log[H3O+]
= -log(0,0375) (f)
= 1,43 (g) (8)
[23]
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Physical Sciences P2/Fisiese Wetenskappe V2 12 FS/VS/September 2024
Grade/Graad 12 Prep. Exam./Voorb. Eksam.
Marking Guidelines/Nasienriglyne
QUESTION 8/VRAAG 8
8.1 Concentration / Konsentrasie = 1 mol·dm-3 ✓
Temperature / Temperatuur = 25 °C ✓ (2)
8.2.1 Potassium nitrate/KNO3/Any soluble salt ✓✓
Kaliumnitraat/KNO3/Enige oplosbare sout (2)
8.2.2 Cℓ- ✓ (1)
✓
8.2.3 Pt(s) | Cℓ-(aq)│Cℓ2(g) ✓|| Au3+(aq) | Au(s) ✓ (3)
8.3 OPTION/OPSIE 1 Notes/Aantekeninge:
Eθcell = Eθreduction - Eθoxidation Accept any other correct formula from the data
sheet.
0,14 = Eθreduction – 1,36 Aanvaar enige ander korrekte formule uit die
θ
Ereduction = 1,5 V datablad.
Any other formula using unconventional
Eθsel = Eθredukusie - Eθoksidasie
abbreviations, e.g. E =E
cell −E
OA RAfollowed
0,14 = Eθreduksie – 1,36 by correct substitutions: 3⁄4
Eθreduksie = 1,5 V Enige ander formule wat onkonvensionele
afkortings gebruik, bv. E =E
cell −E
OA gevolg
RA
3
deur korrekte vervangings: ⁄4
OPTION/OPSIE 2
Au3+ + 3e- → Au Eθ = 1,5 V
2Cℓ- → Cℓ2 + 2e- Eθ = -1,36 (V)
6 Cℓ- + 2Au3+ → 3Cℓ2 + 2Au Eθ = 0,14 (V) (4)
[12]
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Physical Sciences P2/Fisiese Wetenskappe V2 13 FS/VS/September 2024
Grade/Graad 12 Prep. Exam./Voorb. Eksam.
Marking Guidelines/Nasienriglyne
QUESTION 9/VRAAG 9
9.1 The chemical process in which electrical energy is converted to chemical
energy/ use of electrical energy to produce a chemical reaction.
Die chemiese proses waarin elektriese energie na chemiese energie
omgeskakel word/gebruik van elektriese energie om 'n chemiese
reaksie te produseer. (2)
9.2 X (1)
9.3.1 2Cℓ- → Cℓ2 + 2e-
Marking criteria/Nasienkriteria:
• 2Cℓ - ⇌ Cℓ2 + 2e- 12 Cℓ2 + 2e- ⇌ 2Cℓ - 0
2
- - - -
Cℓ2 + 2e → 2Cℓ 0
2
Cℓ2 + 2e ← 2Cℓ 2
2
• Ignore if charge omitted on electron/Ignoreer as lading op electron
weggelaat is
• If charge (-) omitted on Cℓ -/Indien lading (+) weggelaat is op Cℓ -:
Max./Maks: 1
2
Example/Voorbeeld: 2Cℓ → Cℓ2 + 2e-
(2)
9.3.2 2H2O + 2e- → H2 + 2OH-
Marking criteria/Nasienkriteria:
• 2H2O + 2e- ⇌ H2 + 2OH- 1 H2 + 2OH- ⇌ 2H2O + 2e- 0
2 2
H2 + 2OH ← 2H2O + 2e 2⁄2
- -
H2 + 2OH- → 2H2O + 2e- 0⁄2
• Ignore if charge omitted on electron / Ignoreer as lading op elektron
weggelaat is
• If charge (-) omitted on OH-
Indien lading (-) op OH- weggelaat is Max./Maks: 1
2
Example / Voorbeeld: 2H2O + 2e- → H2 + 2OH
(2)
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Physical Sciences P2/Fisiese Wetenskappe V2 14 FS/VS/September 2024
Grade/Graad 12 Prep. Exam./Voorb. Eksam.
Marking Guidelines/Nasienriglyne
9.4 Marking criteria/Nasienriglyne:
(a) Substitute / Vervang 0,5 x 18 000
(b) Dividing charge by / Deel lading deur 1,6 x 10-19
(c) Dividing number of electrons by Avogadro’s constant.
Deel die aantal elektrone deur Avogadro se konstante.
(d) Using ratio / Gebruik verhouding n(Cℓ) : n(e-) = 1:2
V
(e) Substituting / Vervanging n(Cℓ2) and / en 22,4 in n = V
m
(f) Final answer / Finale antwoord 1,04 dm3
Range / Gebied: 1,04 to 1,12 dm3
Q = I△t
= 0,5 x 18 000 (a)
= 9 000 C
Q
n=
qe
9 000
n = -19
✓ (b)
1,6 x 10
= 5,625 x 1022 electrons / elektrone
5,625 x 1022
n(electrons) =
6,02 x 1023 ✓ (c)
= 0,093 mol
1
n(Cℓ2) = 2n(e-)
= 0,093 2 (d)
= 0,0465 mol
V
n=
Vm
V = 0,0465 x 22,4 (e)
= 1,04 dm3 (f) (6)
[13]
TOTAL/TOTAAL: 150
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