Physical Sciences Grade 11 P2 Eastern Cape November 2016 QP (Eng)

Downloaded from hlayiso.com NATIONAL SENIOR CERTIFICATE GRADE 11 NOVEMBER 2016 PHYSICAL SCIENCES P2 MARKS: 150 TIME: 3 hours This question paper consists of 15 pages including 2 data sheets.

Downloaded from hlayiso.com 2 PHYSICAL SCIENCES P2 (EC/NOVEMBER 2016) INSTRUCTIONS AND INFORMATION 1. Write your full NAME and SURNAME in the appropriate spaces on the ANSWER BOOK. 2. This question paper consists of EIGHT questions. Answer ALL the questions in the ANSWER BOOK. 3. Start EACH question on a NEW page in the ANSWER BOOK. 4. Number your answers correctly according to the numbering system used in this question paper. 5. Leave ONE line between two sub questions, for example between QUESTION 2.1 and QUESTION 2.2. 6. You may use a non-programmable calculator. 7. You may use appropriate mathematical instruments. 8. You are advised to use the attached DATA SHEETS. 9. Show ALL formulae and substitutions in ALL calculations. 10. Round off your final numerical answers to a minimum of TWO decimal places. 11. Give brief motivations, discussions et cetera where required. 12. Write neatly and legibly. Copyright reserved Please turn over

Downloaded from hlayiso.com (EC/NOVEMBER 2016) PHYSICAL SCIENCES P2 3 QUESTION 1: MULTIPLE-CHOICE QUESTIONS Four possible options are provided as answers to the following questions. Each question has only ONE correct answer. Choose the answer and write only the correct letter (A–D) next to the question number (1.1–1.10) in the ANSWER BOOK, for example 1.11 E. 1.1 A Lowry-Bronsted base is a substance that … A donates a proton. B accepts a proton. C donates an electron. D accepts an electron. (2) 1.2 Nitrogen gas, N2(g), is cooled until it turns into liquid nitrogen, N2(ℓ). What type of intermolecular forces exist between nitrogen molecules in the liquid phase? A Ionic bonds B Ion-dipole forces C Dipole-dipole forces D Induced dipole forces or dispersion forces or London forces (2) 1.3 How many valence electrons are in one atom of lithium? A 1 B 2 C 3 D 4 (2) 1.4 Which ONE of the following equations represents a REDOX reaction? A S + O2 → SO2 B AgNO3 + KI → AgI + KNO3 C NaOH + HCℓ → NaCℓ + H2O D Na2CO3 + 2HCℓ → 2NaCℓ + CO2 + H2O (2) 1.5 Which ONE of the following correctly defines pressure exerted by a gas? A Average kinetic energy of gas particles B Number of particles filling the container C Collisions of gas particles with each other D Collisions of gas particles with the walls of the container (2) Copyright reserved Please turn over

Downloaded from hlayiso.com 4 PHYSICAL SCIENCES P2 (EC/NOVEMBER 2016) 1.6 𝑝𝑉 In the diagram below, R the solid line, represents graph of versus p for 𝑅𝑇 ONE mole of an ideal gas. The other graphs P, Q and S are for ONE mole of each of the gases CH4, He and NH3 in random order. Identify the gases whose behaviour is represented by graph P, Q and S. P Q S A He CH4 NH3 B NH3 He CH4 C NH3 CH4 He D CH4 NH3 He (2) 1.7 The chemical analysis of a compound with molecular formula, CxH2xO2 where x is the number of carbon atoms in one molecule of the compound shows that it contains 12,5% oxygen (O) by mass. The percentage by mass of carbon (C) in the compound is … A 75%. B 25%. C 12,5%. D 87,5%. (2) Copyright reserved Please turn over

Downloaded from hlayiso.com (EC/NOVEMBER 2016) PHYSICAL SCIENCES P2 5 1.8 Ozone(O3) decomposes to form oxygen gas(O2) according to the equation: 2O3(g) → 3O2(g) Which ONE of the following is NOT CORRECT about the equation for the reaction? According to the equation … A 2 moles of O3 decompose to produce 3 moles of O2. B 2 grams of O3 decompose to produce 3 grams of O2. C 96 grams of O3 decompose to produce 96 grams of O2. D 1,204x1024 molecules of O3 decompose to produce 1,806x1024 molecules of O2. (2) 1.9 Consider the reaction represented by the equation below: 2H2(g) + O2(g) → 2H2O(g) ∆H= - 469kJ/mol The total energy absorbed when bonds are broken in TWO moles of H 2 and ONE mole of O2 is 1 371 kJ/mol. What is the bond energy in kJ/mol for each O-H bond in the water molecule? A 920 B 499 C 460 D 1840 (2) 1.10 Which properties of gold make it useful for the electrical circuits of electrical and electronic devices? A Malleability and ductility B Good ductility and conductivity C Malleability and heat ray reflector D Shiny appearance and good ductility (2) [20] Copyright reserved Please turn over

Downloaded from hlayiso.com 6 PHYSICAL SCIENCES P2 (EC/NOVEMBER 2016) QUESTION 2 (Start on a new page.) Consider the TWO compounds BF3 and NH3. 2.1 Both BF3 and NH3 have the same type of intra-molecular forces (interatomic bonds). 2.1.1 Write down the NAME of these intra-molecular forces. (1) 2.1.2 Explain how these intra-molecular forces in QUESTION 2.1.1 are formed. (1) 2.2 Give the LEWIS diagrams for: 2.2.1 BF3 (2) 2.2.2 NH3 (2) 2.3 Compare the polarity of the BF3 and NH3 molecules by referring to the POLARITY OF THE BONDS and the EFFECT of the SHAPE of EACH MOLECULE on its polarity. (5) 2.4 A type of bond is formed between the nitrogen atom (N) in a molecule of ammonia (NH3) with the hydrogen ion (H+) as shown below. + H H H N + H+ → H N H H H 2.4.1 Write down the NAME of the bond formed between the nitrogen atom and the H+ ion. (1) 2.4.2 Give a reason why the oxygen atom (O) in the water molecule is able to form the type of bond mentioned in QUESTION 2.4.1 with the H+ ion. (2) [14] Copyright reserved Please turn over

Downloaded from hlayiso.com (EC/NOVEMBER 2016) PHYSICAL SCIENCES P2 7 QUESTION 3 (Start on a new page.) 3.1 Water has extra ordinary macroscopic properties, for example density of ice is different from that of liquid water. 3.1.1 Write down the NAME of intermolecular forces between water molecules responsible for the difference in the density of liquid water and ice. (1) 3.1.2 Explain how the difference in the density of ice and liquid water protects aquatic life at extremely low temperatures. (2) 3.1.3 Calculate the number of water molecules in 1 dm3 of water at 25 ºC. The density of water is 1 g/cm3 at 25 ºC. (4) 3.1.4 Explain why coastal areas experience moderate temperatures compared to inland areas. (2) 3.2 The graph of molecular size versus the boiling point is given below. The letters A, B and C represent the compounds CH4, C2H6 and C3H8 respectively. BOILING POINT (K) 273 223 C 173 B 123 A 73 MOLECULAR SIZE 3.2.1 Describe the trend in the boiling points of the compounds as shown by the graph. (2) 3.2.2 Explain the answer to QUESTION 3.2.1 by referring to MOLECULAR SIZE, TYPE and STRENGTH of INTERMOLECULAR FORCES. (3) 3.2.3 Which ONE of the compounds (A, B or C) has the HIGHEST melting point? (1) 3.3 Consider the molecules NH3 and PH3. NH3 has a smaller molecular mass and similar shape as PH3. The boiling point of NH3 is -33 ºC and that of PH3 is -87,4 ºC. Explain the difference in the boiling points by referring to the TYPE and STRENGTH of INTERMOLECULAR FORCES. (3) [18] Copyright reserved Please turn over

Downloaded from hlayiso.com 8 PHYSICAL SCIENCES P2 (EC/NOVEMBER 2016) QUESTION 4 (Start on a new page.) 4.1 A group learners conducted an investigation to verify the relationship between volume and temperature of a gas. They filled a syringe with hydrogen gas and placed the syringe in water baths at different temperatures. They recorded the results which they used to plot the graph below. Graph of Volume versus Temperature 120 0 Volume (cm3) 80 0 40 0 100 200 300 400 0 Temperature (K) 4.1.1 Name the quantity which is defined as a measure of the average kinetic energy of gas molecules. (1) 4.1.2 Use the information from the graph and: (a) Determine the volume (in cm3) of the gas when the temperature is 27 °C (2) (b) Write down the learners’ conclusion (2) 4.1.3 Write down TWO variables that must be kept constant during the investigation. (2) 4.1.4 Write down the NAME of an apparatus that was used to measure the values of the independent variable in this investigation. (1) 4.1.5 Explain why real gases deviate from ideal gas behaviour at low temperatures. (3) Copyright reserved Please turn over

Downloaded from hlayiso.com (EC/NOVEMBER 2016) PHYSICAL SCIENCES P2 9 4.2 2,04 g of a gas occupies a volume of 2 dm3 at 27 °C and 150 kPa. Calculate the molar mass of the gas. (6) 4.3 In the diagram below a syringe is filled with gas A while the other syringe contains gas B. The volume, temperature and mass of the contents of the syringes are the same. The pressure of gas A is twice that of gas B. A B How does the molar mass of gas B compare with the molar mass of gas A? Write only HIGHER, LOWER or THE SAME. Explain the answer. (3) [20] Copyright reserved Please turn over

Downloaded from hlayiso.com 10 PHYSICAL SCIENCES P2 (EC/NOVEMBER 2016) QUESTION 5 (Start on a new page.) 5.1 In order to determine the empirical and molecular formula of a compound, CxHy, a certain mass of the compound is burnt completely in excess oxygen to produce 47,1 g CO2 and 19,35 g H2O as the only products. 5.1.1 Define the term empirical formula. (2) 5.1.2 Use relevant calculations to determine the empirical formula of the compound. (8) 5.1.3 The molar mass of the compound is 28 g.mol-1. Determine by using calculations the values of x and y. (2) 5.2 A sample of IMPURE calcium carbonate (limestone) of unknown mass required a continuous supply of strong heat to decompose according to the following equation: CaCO3(s) Δ CaO(s) + CO2(g) After the completion of reaction, 11,76 g CaO was produced. The percentage purity of calcium carbonate is found to be 80%. 5.2.1 Calculate the mass of the impure calcium carbonate. (6) 5.2.2 Sketch a potential energy diagram for the above reaction. Clearly indicate the axes and indicate the following on the graph: (No values are required.)  ∆H  Reactants(R) and Products (P)  Activation energy (EA)  Activated complex (X) (5) [23] Copyright reserved Please turn over

Downloaded from hlayiso.com (EC/NOVEMBER 2016) PHYSICAL SCIENCES P2 11 QUESTION 6 (Start on a new page.) 6.1 The hydrogen sulphate ion (HSO4 ) can act as both an acid and a base. It reacts with water according to the balanced equation: HSO4 + H2O ⇋ SO42- + H3O+ Write down: 6.1.1 A term for the underlined phrase (1) 6.1.2 The FORMULAE of the TWO acids in the reaction (2) 6.2 A solution of potassium hydroxide (KOH) is prepared by dissolving 3,36 g crystals of KOH in 250 cm3 of solution. Calculate the concentration of the potassium hydroxide solution. (4) 6.3 25 cm3 of a potassium hydroxide solution of concentration 0,25 mol.dm -3 completely neutralises a dilute solution of sulphuric acid (H2SO4 ) in a flask. The incomplete equation below represents the reaction that takes place: 2KOH + H2SO4 → K2SO4 + Y 6.3.1 Write down the NAME the salt formed. (1) 6.3.2 Write down the FORMULA of compound Y. (1) 6.3.3 Calculate the mass of sulphuric acid in the flask. (5) [14] Copyright reserved Please turn over

Downloaded from hlayiso.com 12 PHYSICAL SCIENCES P2 (EC/NOVEMBER 2016) QUESTION 7 (Start on a new page.) 7.1 The following equation represents a redox reaction in which 8 grams of iron (III) oxide (Fe2O3) reacts with 3,8 grams of aluminium (Aℓ ). Fe2O3 + 2Aℓ → Aℓ 2O3 + 2Fe 7.1.1 Define the term reduction in terms of electron transfer. (2) 7.1.2 Write down the formula or symbol of the substance that is the reducing agent. Justify your answer by making use of oxidation numbers. (4) The reaction runs to completion. 7.1.3 Calculate the percentage yield if 4,76 g of Fe was formed. (7) 7.2 Butane (C4H10) gas reacts COMPLETELY with 4,48 dm3 of oxygen (O2) at STP according to the equation. 2C4H10(g) + 13O2(g) → 8CO2(g) + 10H2O(g) Calculate the number of molecules of butane reacting. (5) 7.3 Consider the following reaction: NO3─ + H2S → S + NO + H2O (in an acid medium) Balance the equation by using ion-electron method. (7) [25] Copyright reserved Please turn over

Downloaded from hlayiso.com (EC/NOVEMBER 2016) PHYSICAL SCIENCES P2 13 QUESTION 8 (Start on a new page.) The following diagrams show the most important steps during the recovery of gold from the ore. A Gold-ore A NaAu(CN)2 B Gold precipitation C Pure gold 8.1 8.1.1 Define the term ore. (2) 8.1.2 Write down the NAME of the type of mining used to recover gold. (1) The incompletely balanced reaction is taking place during process A: 4Au + NaCN + O2 + 2H2O → NaAu(CN)2 + 4NaOH 8.2 Is the reaction in process A a REDOX, ACID-BASE or PRECIPITATION reaction? (1) 8.3 Balance the above equation by inspection. (2) 8.4 Write down the FORMULA of the oxidising agent. (2) 8.5 Is the solution formed during process A ACIDIC, ALKALINE or NEUTRAL? Give a reason for your answer. (2) A transition element is added during process B to displace gold from NaAu(CN)2. 8.6 Write down the NAME or SYMBOL of the element. (1) 8.7 Why is it important to send gold into a hot furnace? (1) 8.8 Name TWO reasons why the gold mining industry is so important to the South African economy. (2) 8.9 Write TWO negative impacts that gold mining industry has on water in the environment. (2) [16] TOTAL: 150 Copyright reserved Please turn over

Downloaded from hlayiso.com 14 PHYSICAL SCIENCES P2 (EC/NOVEMBER 2016) NATIONAL SENIOR CERTIFICATE NASIONALE SENIOR SERTIFIKAAT DATA FOR PHYSICAL SCIENCES GRADE 11 PAPER 2 (CHEMISTRY) GEGEWENS VIR FISIESE WETENSKAPPE GRAAD 11 VRAESTEL 2 (CHEMIE) TABLE 1: PHYSICAL CONSTANTS/TABEL 1: FISIESE KONSTANTES NAAM/NAME SIMBOOL/SYMBOL WAARDE/VALUE Avogadro’s constant NA 6,02 x 1023 mol-1 Avogadro se konstante Molar gas constant R 8.31 J. K-1.mol-1 Molêre gaskonstante Standard pressure p 1,013 x 105 Pa Standaarddruk Molar gas volume at STP Vm 22,4 dm3∙mol-1 Molêre gasvolume teen STD Standard temperature Tθ 273 K Standaardtemperatuur TABLE 2: FORMULAE/TABEL 2: FORMULES p1V1 = p2V2 pV = nRT T1 T2 m N n = n = M NA V n m n = c = OF/ OR c = VM V MV Copyright reserved Please turn over

15 Downloaded from hlayiso.com PHYSICAL SCIENCES P2 (EC/NOVEMBER 2016) TABLE 3: THE PERIODIC TABLE OF ELEMENTS/TABEL 3: DIE PERIODIEKE TABEL 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 (I) (II) (III) (IV) (V) (VI) (VII) (VIII) KEY/ SLEUTEL Atoomgetal 1 Atomic number 2 2,1 H He 1 29 4 3 4 Elektronegatiwiteit Simbool 5 6 7 8 9 10 1,0 Li 1,5 Be Electronegativity 1,9 Cu Symbol 2,0 B 2,5 C 3,0 N 3,5 O 4,0 F Ne 7 9 63,5 11 12 14 16 19 20 11 12 13 14 15 16 17 18 0,9 Na 1,2 Mg Benaderde relatiewe atoommassa 1,5 Aℓ 1,8 Si 2,1 P 2,5 S 3,0 Cℓ Ar 23 24 Approximate relative atomic mass 27 28 31 32 35,5 40 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 0,8 K 1,0 Ca 1,3 Sc 1,5Ti 1,6 V 1,6 Cr 1,5 Mn 1,8 Fe 1,8 Co 1,8Ni 1,9 Cu 1,6 Zn 1,6 Ga 1,8 Ge 2,0 As 2,4 Se 2,8 Br Kr 39 40 45 48 51 52 55 56 59 59 63,5 65 70 73 75 79 80 84 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 0,8 Rb 1,0 Sr 1,2 Y 1,4Zr Nb 1,8 Mo 1,9 Tc 2,2 Ru 2,2 Rh 2,2 Pd 1,9 Ag 1,7 Cd 1,7 In 1,8 Sn 1,9 Sb 2,1 Te 2,5 I Xe 86 88 89 91 92 96 101 103 106 108 112 115 119 122 128 127 131 55 56 57 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86 0,7 Cs 0,9 Ba La 1,6Hf Ta W Re Os Ir Pt Au Hg 1,8 Tℓ 1,8 Pb 1,9 Bi 2,0 Po 2,5 At Rn 133 137 139 179 181 184 186 190 192 195 197 201 204 207 209 87 88 89 0,7 Fr 0,9 Ra Ac 58 59 60 61 62 63 64 65 66 67 68 69 70 71 226 Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu 140 141 144 150 152 157 159 163 165 167 169 173 175 90 91 92 93 94 95 96 97 98 99 100 101 102 103 Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No Lr 232 238 Copyright reserved Please turn over