NATIONAL
SENIOR CERTIFICATE
NASIONALE
SENIOR SERTIFIKAAT
GRADE/GRAAD 12
PHYSICAL SCIENCES: CHEMISTRY (P2)
FISIESE WETENSKAPPE: CHEMIE (V2)
NOVEMBER 2024
MARKING GUIDELINES/NASIENRIGLYNE
MARKS/PUNTE: 150
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Physical Sciences P2 Nov 2024 MG Afr & Eng.pdf
Physical Sciences · Grade 12 · November 2024 NSC MG · 2024. Question paper, 28 pages. Read online or download the PDF.
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Physical Sciences P2/Fisiese Wetenskappe V2 2 DBE/November 2024
NSC/NSS – Marking Guidelines/Nasienriglyne
QUESTION 1/VRAAG 1
1.1 C (2)
1.2 C (2)
1.3 B (2)
1.4 D (2)
1.5 A (2)
1.6 A (2)
1.7 B (2)
1.8 D (2)
1.9 B (2)
1.10 D (2)
[20]
QUESTION 2/VRAAG 2
2.1
2.1.1 D (1)
2.1.2 A (1)
2.1.3 E (1)
2.2
2.2.1 Marking criteria:
• Correct stem, i.e. hexane.
• Correct substituents (bromo and methyl) identified.
• IUPAC name completely correct including numbering, sequence, hyphens and
commas.
Nasienkriteria:
• Korrekte stam d.i. heksaan.
• Korrekte substituente (bromo en metiel) geïdentifiseer.
• IUPAC-naam heeltemal korrek insluitende nommering, volgorde, koppeltekens en
kommas.
3,3-dibromo-4,4-dimethylhexane/3,3-dibromo-4,4-dimetielheksaan (3)
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Physical Sciences P2/Fisiese Wetenskappe V2 3 DBE/November 2024
NSC/NSS – Marking Guidelines/Nasienriglyne
2.2.2 Marking criteria:
• Correct stem, i.e. pentyne.
• Substituent (dimethyl) correctly identified.
• IUPAC name completely correct including numbering, sequence, hyphens and
commas.
Nasienkriteria:
• Korrekte stam, d.i. pentyn.
• Substituente (dimetiel) korrek geïdentifiseer.
• IUPAC-naam heeltemal korrek insluitende nommering, volgorde, koppeltekens en
kommas.
4,4-dimethylpent-2-yne/4,4-dimethyl-2-pentyne
4,4-dimetielpent-2-yn/4,4-dimetiel-2-pentyn (3)
2.3
2.3.1 Marking criteria/Nasienkriteria
If any one of the underlined key phrases in the correct context is omitted, deduct
1 mark/Indien enige van die onderstreepte frases in die korrekte konteks uitgelaat is,
trek 1 punt af.
Compounds with the same molecular formula, but different functional
groups/homologous series.
Verbindings met dieselfde molekulêre formule, maar verskillende funksionele
groepe/homoloë reekse. (2)
2.3.2 A and/en C (1)
2.4
2.4.1 H2SO4/Sulphuric acid/Swaelsuur (1)
2.4.2 Esterification/Condensation/Verestering/Esterifikasie/Kondensasie (1)
2.4.3
Marking criteria:
O H • Functional group correct.
H H H
• Whole structural formula correct.
H C C O C C C H Nasienkriteria:
• Funksionele groep korrek.
H H H H
• Hele struktuurformule korrek.
(2)
2.4.4 Marking criteria: Nasienkriteria:
• Correct chain length and functional • Korrekte kettinglengte en funksionele
group, i.e Propanol. ✓ groep, d.i. Propanol.
• Everything else correct: IUPAC name • Alles verder reg: IUPAC-naam
completely correct including heeltemal korrek nommering
numbering. ingesluit.
Propan-1-ol/1-propanol
NOTE/AANTEKENING:
Propanol (2)
[18]
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Physical Sciences P2/Fisiese Wetenskappe V2 4 DBE/November 2024
NSC/NSS – Marking Guidelines/Nasienriglyne
QUESTION 3/VRAAG 3
3.1 Marking criteria/Nasienkriteria
If any one of the underlined key phrases in the correct context is omitted, deduct
1 mark./Indien enige van die onderstreepte frases in die korrekte konteks uitgelaat
is, trek 1 punt af.
The pressure exerted by a vapour at equilibrium with its liquid in a closed
system.
Die druk uitgeoefen deur 'n damp in ewewig met sy vloeistof in 'n geslote
sisteem. (2)
3.2
3.2.1 146 (kPa)
Accept/Aanvaar:
146 000 Pa (1)
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Physical Sciences P2/Fisiese Wetenskappe V2 5 DBE/November 2024
NSC/NSS – Marking Guidelines/Nasienriglyne
3.2.2 Marking criteria:
• Compare structures.
• Compare the strength of intermolecular forces.
• Compare the energy required to overcome intermolecular forces.
Nasienkriteria:
• Vergelyk strukture.
• Vergelyk die sterkte van intermolekulêre kragte.
• Vergelyk die energie benodig om intermolekulêre kragte te oorkom.
Accept/Aanvaar:
Abbreviation IMF in explanations./Afkorting IMK in verduidelikings.
Comparing compound C/2,2-dimethylpropane with compounds
A/pentane and B/2-methylbutane
• Structure:
Compound C is more branched than compounds A and B/Shorter chain
length/most compact most spherical/smallest surface area (over which
intermolecular forces act).
• Intermolecular forces:
Compound C has weaker/less intermolecular forces/Van der Waals
forces/London forces than A and B.
• Energy:
Lesser energy needed to overcome or break intermolecular forces/Van der
Waals force in compound C than A and B.
Vergelyk verbinding C/2,2-dimetielpropaan met verbindings A/pentaan en
B/2-metielbutaan
• Struktuur:
Verbinding C is meer vertak as verbindings A en B/Korter kettinglengte/meer
kompak/meer sferies/kleiner oppervlak (waaroor intermolekulêre kragte
werk).
• Intermolekulêre kragte:
Verbinding C het swakker/minder intermolekulêre kragte/Van der Waals-
kragte/London-kragte as vebindings A en B.
• Energie:
Minder energie benodig om intermolekulêre kragte/Van der Waals-kragte/
London-kragte van verbinding C te oorkom/breek as in verbinding A en B. (3)
3.3
3.3.1 E/butanal/butanaal (1)
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Physical Sciences P2/Fisiese Wetenskappe V2 6 DBE/November 2024
NSC/NSS – Marking Guidelines/Nasienriglyne
3.3.2 Marking criteria:
• Strongest intermolecular forces in compound D: Hydrogen bond.
• Strongest intermolecular forces in compound E: Dipole-dipole forces.
• Compare the strength of intermolecular forces.
• Compare the energy required to overcome intermolecular forces.
Nasienkriteria:
• Sterkste intermolekulêre kragte in verbinding D: Waterstofbinding.
• Sterkste intermolekulêre kragte in verbinding E: Dipool-dipoolkragte.
• Vergelyk die sterkte van die intermolekulêre kragte.
• Vergelyk die energie benodig om intermolekulêre kragte te oorkom.
Accept/Aanvaar:
Abbreviation IMF in explanations./Afkorting IMK in verduidelikings.
• Compound D/Propanoic acid has hydrogen bonding (dipole-dipole and
London forces) between molecules.
• Compound E/Butanal has dipole-dipole forces (and London forces) between
molecules.
• Intermolecular forces between molecules of compound D/propanoic acid are
stronger than intermolecular forces between molecules of compound
E/butanal.
• More energy is needed to overcome/break intermolecular forces between
molecules of compound D/propanoic acid than in compound E/butanal
OR
• Compound D/Propanoic acid has hydrogen bonding (dipole-dipole and
London forces) between molecules.
• Compound E/Butanal has dipole-dipole forces (and London forces) between
molecules.
• Intermolecular forces between molecules of compound E/butanal are
weaker than intermolecular forces between compound D/propanoic acid
• Lesser energy is needed to overcome/break intermolecular forces between
molecules of compound E/butanal than in compound D/propanoic acid
• Verbinding D/propanoësuur het watertofbinding (dipool-dipool en London-
kragte) tussen die molekules.
• Verbinding E/butanaal het dipool-dipoolkragte (en London-kragte) tussen
die molekules.
• Intermolekulêre kragte tussen die molekules van verbinding D/
propanoësuur is sterker as die intermolekulêre kragte tussen molekules van
verbinding E/butanaal.
• Meer energie word benodig om die intermolekulêre kragte tussen die
molekules van verbinding D/propanoësuur te oorkom/breek.
OF
• Verbinding D/propanoësuur het watertofbinding (dipool-dipool en London-
kragte) tussen die molekules.
• Verbinding E/butanaal het dipool-dipookragtel (en London-kragte) tussen
die molekules.
• Intermolekulere kragte tussen die molekules van verbinding E/ butanaal is
swakker as die intermolekulêre kragte tussen verbinding D/propanoësuur.
• Minder energie word benodig om die intermolekulêre kragte tussen die
molekules van verbinding D/butanaal te oorkom/breek. (4)
[11]
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Physical Sciences P2/Fisiese Wetenskappe V2 7 DBE/November 2024
NSC/NSS – Marking Guidelines/Nasienriglyne
QUESTION 4/VRAAG 4
4.1 Marking criteria/Nasienkriteria
If any one of the underlined key phrases in the correct context is omitted, deduct
1 mark./Indien enige van die onderstreepte frases in die korrekte konteks uitgelaat is,
trek 1 punt af.
The underlined phrases must be in the correct context./Die onderstreepte frases moet
in die korrekte konteks wees.
The chemical process/reaction in which longer chain hydrocarbon/alkane
molecules/are broken down to shorter (more useful) molecules.
Die chemiese proses/reaksie waarin langer kettingkoolwaterstof/alkaan-
molekule afgebreek word in korter (meer bruikbare) molekules. (2)
4.2 Primary/Primêre
The halogen/bromine/functional group (-X) is bonded to a C atom that is bonded
to one other C atom.
Die halogeen/broom/funksionele groep (-X) is gebind aan 'n C-atoom wat aan
een ander C-atoom gebind is/ 'n premêre C-atoom.
OR/OF
The functional group ( C ) is bonded to one other C atom.
Br/X
Die funksionele groep ( C ) is gebind aan een ander C-atoom.
Br/X
Accept/Aanvaar:
The Br/bromine (atom)/X/halogen is bonded to first /last/ terminal C-atom.
Die Br/broom (atoom)/X/halogeen is gebind/verbind aan die eerste/laaste
C-atoom. (2)
4.3
Marking criteria:
4.3.1 H H H H • Correct stem, i.e. 4 C atoms.
• Whole structural formula correct.
H C C C C H Nasienkriteria:
• Korrekte stam, d.w.s. 4 C-atome.
H H H H • Hele struktuur korrek.
• Hele struktuurformule korrek. (3)
POSITIVE MARKING FROM QUESTION 4.3.1
POSITIEWE NASIEN VAN VRAAG 4.3.1
4.3.2 C8H18 (1)
4.4
4.4.1 Br2/Bromine/Broom (1)
4.4.2 Substitution / Substitusie (1)
4.4.3 UV/(Sun)light/Heat/(Son)lig/Hitte (1)
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Physical Sciences P2/Fisiese Wetenskappe V2 8 DBE/November 2024
NSC/NSS – Marking Guidelines/Nasienriglyne
4.5 Dehydrohalogenation/Dehydrobromination
Dehidrohalogenering/Dehidrohalogenasie/Dehidrobrominering (1)
4.6
4.6.1 Marking criteria:
Reaction IV
• Functional group of alkene on first C atom.
• Whole structural formula of alkene correct.
• HBr.
• Functional group of haloalkane correct.
• Whole structural formula of haloalkane correct (halogen on second/first C-atom).
Nasienkriteria:
• Funksionele groep van alkeen op die eerste C-atoom.
• Hele struktuurformule van alkeen korrek.
• HBr.
• Funksionele groep van haloalkaan korrek. ✓
• Hele struktuurformule van haloalkaan korrek (halogeen op die tweede/eerste C-
atoom). ✓
IF/INDIEN
• Condensed, semi structural or molecular formula
Gekondenseerde, semi-struktuurformule of molekulêre formule: Max/Mak: 1⁄5
• Marking rule 6.3.10/Nasienreël 6.3.10
Note/Aantekening:
For extra product or reactant, deduct 1 mark.
Vir ekstra produk of reaktans, trek 1 punt af.
H H H H H H H H
H C C C C H + HBr H C C C C H
H H H H Br H
OR
H H H H H H H H
H C C C C H + HBr H C C C C H
H H H H H Br (5)
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Physical Sciences P2/Fisiese Wetenskappe V2 9 DBE/November 2024
NSC/NSS – Marking Guidelines/Nasienriglyne
4.6.2 Marking criteria:
• NaOH.
• Whole structural formula of alkene correct (functional group on second/
first C atom).
• NaBr + H2O
Nasienkriteria:
• NaOH.
• Hele struktuurformule van van alkeen korrek (funksionele groep op de tweede/
eerste C-atoom). ✓
• NaBr + H2O
IF/INDIEN
• Condensed, semi structural or molecular formula.
Gekondenseerde, semi-struktuurformule of molekulêre formule. Max/Maks: 1⁄5
• Marking rule 6.3.10/Nasienreël 6.3.10
Note/Aantekening:
For extra product or reactant, deduct 1 mark.
Vir ekstra produk of reaktans, trek 1 punt af.
H H H H H H H H
H C C C C H + NaOH H C C C C H
H H Br H H H
+ NaBr + H2O
OR
H H H H H H H H
H C C C C H + NaOH H C C C C H
H H H Br H H
+ NaBr + H2O
(3)
4.6.3 But-2-ene/2-butene/but-1-ene/1-butene/But-2-een/2-buteen/but-1-een/
1-buteen
Butene/Buteen: deduct 1 mark/trek een punt af. (2)
[22]
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Physical Sciences P2/Fisiese Wetenskappe V2 10 DBE/November 2024
NSC/NSS – Marking Guidelines/Nasienriglyne
QUESTION 5/VRAAG 5
5.1 NOTE/LET WEL
5.1.1 Give the mark for per unit time only if in context of reaction rate.
Gee die punt vir per eenheid tyd slegs indien in konteks met reaksietempo.
ANY ONE:
• Change in concentration of products/reactants per (unit) time.
• Change in amount/number of moles/volume/mass of products or reactants
per (unit) time.
• Amount/number of moles/volume/mass of products formed/reactants used
per (unit) time.
• Rate of change in concentration/amount/number of moles/volume/
mass. (2 or 0)
ENIGE EEN:
• Verandering in konsentrasie van produkte/reaktanse per (eenheid) tyd.
• Verandering in hoeveelheid/getal mol/volume/massa van produkte of
reaktanse per (eenheid) tyd.
• Hoeveelheid/getal mol/volume/massa van produkte gevorm/reaktanse
gebruik per (eenheid) tyd.
• Tempo van verandering in konsentrasie/ hoeveelheid/getal mol/
volume/massa. (2 of 0) (2)
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NSC/NSS – Marking Guidelines/Nasienriglyne
5.1.2 Marking criteria Nasienkriteria:
(a) Substitute 0,033 and 5 in rate (a) Vervang 0,033 en 5 in tempoformule
formula. V
(b) Vervang 24,5 in
V Vm
(b) Substitute 24,5 in (c) GEBRUIK molverhouding:
Vm
(c) USE mol ratio: n(Aℓ) : n(H2) = 2 : 3
n(Aℓ) : n(H2) = 2 : 3 m
m (d) Vervang 27 g in
(d) Substitute 27 g∙mol-1 in M
M (e) Trek m(Aℓ)t=5 van m(Aℓ)begin /
(e) Subtract m(Aℓ)t=5 from m(Aℓ)ini / n(Aℓ)t=5 van n(Aℓ)begin
n(Aℓ)t=5 from n(Aℓ)ini (f) Finale korrekte antwoord: 0,38 g
(f) Final correct answer: 0,38 g (0,379 g)
(0,379) Gebied: 0,365 – 0,42 g
Range: 0,365 – 0,42 g
ΔV(H2 )
Rate/Tempo =
Δt
ΔV(H2 )
0,033 =
5 (a)
V(H2) = 0,165 dm3
V
n(H2) =
Vm
0,165
=
24,5 (b)
= 6,74 x 10-3 mol (0,0067)
2
n(Aℓ) = 3 n(H2)
2
= 3 (6,74 x 10-3) (c)
= 4,49 x 10-3 mol (0,00449)
OPTION 1/OPSIE 1: OPTION 2/OPSIE 2:
m m
n (Aℓ) = n (Aℓ) =
M M
m(Al) 0,5
4,49 x 10-3 = =
27(d) 27
= 0,0185 mol
m(Aℓ) = 0,12 g (0,121)
∆n(Aℓ) = 0,0185 – 4,49 x 10-3 (e)
= 0,014 mol
∆m(Aℓ) = 0,5 – 0,12 (e) m
= 0,38 g (f) n (Aℓ) =
M
m(Al)
0,014 =
27 (d)
m(Aℓ) = 0,38 g (f)
(6)
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Physical Sciences P2/Fisiese Wetenskappe V2 12 DBE/November 2024
NSC/NSS – Marking Guidelines/Nasienriglyne
5.1.3 • The surface area/contact area/mass/size of aluminium decreases.
• Less particles exposed.
• Less effective collisions per unit time/second.
OR
Lower frequency of effective collisions.
• Reaction rate decreases./Lower reaction rate./Reaction slows down.
• Die reaksieoppervlak/kontakoppervlak/massa/grootte van aluminium neem
af.
• Minder deeltjies blootgestel.
• Minder effektiewe botsings per eenheid tyd/sekonde.
OF
Laer frekwensie van effektiewe botsings.
• Reaksietempo neem af./Laer reaksietempo./ Reaksie is stadiger . (4)
5.1.4 Marking criteria: Nasienkriteria:
• Curve B starts at the origin and ends • Kurwe B begin by oorsprong en eindig
at the same point as curve A. by dieselfde punt as kurwe A.
• Gradient of curve B steeper for the • Gradiënt van kurwe B steiler vir die
whole duration. volle duur.
Note: Aantekening:
Graph not labelled: Max. 1⁄2 Grafiek nie benoem nie: Maks. 1⁄2
Volume of/van H2 (dm3)
B A
0 Time/Tyd (min) (2)
5.1.5 Equal to./Gelyk aan. (1)
5.2
5.2.1 An increase in temperature./'n Toename in temperatuur. (1)
5.2.2 Curve Y has a peak/maximum at a higher kinetic energy./Peak shifted to the
right.
OR
The (average) kinetic energy (of the particles) increases./More particles with
higher kinetic energy./Larger area with higher kinetic energy.
Kurwe Y het 'n piek/maksimum by 'n hoër kinetiese energie./Piek het regs
geskuif.
OF
Die (gemiddelde) kinetiese energie van die deeltjies het toegeneem./Meer
deeltjies met ‘n hoer kinetiese energie./Groter oppervlak met hoër kinetiese
energie (1)
[17]
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Physical Sciences P2/Fisiese Wetenskappe V2 13 DBE/November 2024
NSC/NSS – Marking Guidelines/Nasienriglyne
QUESTION 6/VRAAG 6
6.1 (The dynamic equilibrium when) the rate of the forward reaction equals the rate
6.1.1 of the reverse reaction. (2 or 0)
(Die dinamiese ewewig wanneer) die tempo van die voorwaartse reaksie gelyk
is aan die tempo van die terugwaartse reaksie.
OR/OF
The stage in a chemical reaction when the concentrations of the reactants and
products remain constant.
Die stadium in 'n chemiese reaksie waar die konsentrasie van die reaktanse en
produkte konstant bly. (2)
6.1.2 X (1)
6.1.3 Decreased/Verlaag (1)
6.1.4 The concentrations of (all) the gases decreased./The reverse reaction was
favoured.
Die konsentrasies van die (al) die gasse verminder./Die terugwaartse reaksie is
bevoordeel.
Accept/Aanvaar:
All concentrations decreased./Al die kosentrasies het verminder. (1)
6.1.5 CO(g)/carbon monoxide/koolstofmonoksied. (1)
6.1.6 The concentration of Z (CO) decreased with a decrease in the concentration
of X (O2).
OR
The concentration of Z (CO) increased with an increase in the concentration
of X (O2).
OR
Z (CO) behaves like X (O2)/Follows the same trend as X (O2).
OR
Z (CO) and X(O2) are both reactants/ Y(CO2) is the product.
OR
The reverse reaction is favoured to increase the number of moles.
Die konsentrasie van Z (CO) neem af met 'n afname in die konsentrasie van
X (O2).
OF
Die konsentrasie van Z (CO) neem toe met 'n toename in die konsentrasie van
X (O2).
OF
Z (CO) tree dieselfde op as X (O2)/volg dieselfde neiging as X (O2).
OF
Z(CO) en X(O2) is beide reaktanse/ Y(CO2) is die produk.
OF
Die terugwaartse reaksie word bevoordeel om die hoeveelheid mol te verhoog. (1)
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NSC/NSS – Marking Guidelines/Nasienriglyne
6.1.7 Decreased/Verlaag (1)
6.1.8 • Concentration of products/Y/CO2 increases.
OR
Concentration of reactant/Z/X/CO/O2 decreases.
OR
The forward reaction is favoured.
• The forward reaction is exothermic.
• A decrease in temperature favours the exothermic reaction.
• Konsentrasie van produkte/Y/CO2 neem toe.
OF
Konsentrasie van reaktanse/Z/X/CO/O2 neem af.
OF
Die voorwaartse reaksie word bevoordeel.
• Die voorwaartse reaksie is eksotermies.
• Afname in temperatuur bevoordeel die eksotermiese reaksie. (3)
6.2 REACTANTS ARE USED/REAKTANSE WORD GEBRUIK
CALCULATIONS USING MOLES
BEREKENINGE WAT GETAL MOL GEBRUIK
Marking criteria:
(a) USING ratio: n(H2O) : n(CO) : n(H2) : n(CO2) = 1 : 1 : 1 : 1
(b) n(CO)eq = n(CO)initial – ∆n(CO), n(H2O)eqm = n(H2O)initial – ∆n(H2O),
n(CO2)eq = n(CO2)initial + ∆n(CO2) AND n(H2)eqm = n(H2)initial + ∆n(H2)
(c) Divide neq by the volume 2 dm3
(d) Correct Kc expression.
(e) Substitute Kc value 4.
(f) Substitute concentrations in Kc expression.
(g) Substitute numerical values of x in n(CO)initial – ∆n(CO)change
m
(h) Substitute of 28 in n =
M
(i) Final answer: 6,44 g
Range: 6,44 – 6,72 g
Nasienkriteria:
(a) GEBRUIK verhouding: n(H2O) : n(CO) : n(H2) : n(CO2) = 1 : 1 : 1 : 1
(b) n(CO)ewe = n(CO)begin – ∆n(CO), n(H2O)ewe = n(H2O)begin – ∆n(H2O),
n(CO2)ewe = n(CO2)begin + ∆n(CO2) EN n(H2)ewe = n(H2)begin + ∆n(H2)
(c) Deel newe deur 2 dm3
(d) Korrekte Kc-uitdrukking.
(e) Vervang Kc-waarde 4.
(f) Vervanging van konsentrasies in Kc-uitdrukking.
(g) Vervanging van nomeriese waarde van x in n(CO)begin – ∆n(CO)
m
(h) Vervanging van 28 in n =
M
(i) Finale answer: 6,44 g
Gebied: 6,44 – 6,72 g
IF/INDIEN:
No table/calculation giving table values – do not award marks for criteria (a) and (b)
Geen tabel/berekening waarin tabelwaardes gegee is – geen punt vir riglyn (a) en
(b).
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Physical Sciences P2/Fisiese Wetenskappe V2 15 DBE/November 2024
NSC/NSS – Marking Guidelines/Nasienriglyne
(x change in amount/
CO H2O CO2 H2
verandering in hoeveelheid.)
Initial amount (moles)
0,6 0,6 0,1 0, 1
Aanvanklike hoeveelheid (mol)
Change in amount (moles)
x x x x (a)
Verandering in hoeveelheid (mol)
Equilibrium amount (moles)
Ewewigshoeveelheid (mol) (b) 0,6 - x 0,6 - x 0,1 + x 0,1 + x
Equilibrium concentration (mol∙dm-3) 0,6 - x 0,6 - x 0,1 + x 0,1 + x
Ewewigskonsentrasie (mol∙dm-3) 2 2 2 2
(c)
[CO2 ][H2 ]
Kc = (d) No Kc expression, correct
[CO][H2 O]
substitution/Geen Kc-uitdrukking,
0,1 + x 0,1 + x korrekte substitusie: Max./Maks. 8⁄9
( )( )
2 2 Wrong Kc expression/Verkeerde Kc-
4 (e) = 0,6 - x 0,6 - x (f)
( )( ) uitdrukking: Max./Maks. 6⁄9
2 2
x = 0,37
n(CO)eq = 0,6 – 0,37 (g) 0,6 - x
[CO]eq =
= 0,23 mol 2
0,6 - 0,37 (g)
m =
n(CO)eq = 2
M
= 0,115 mol∙dm-3
m
0,23 = n = cV
28 (h)
m(CO)eq = 6,44 g (i) = (0,115)(2)
= 0,23 mol
m
n(CO)eq =
M
m
0,23 =
28 (h)
m(CO)eq = 6,44 g (i)
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NSC/NSS – Marking Guidelines/Nasienriglyne
(x equilibrium amount/
CO H2O CO2 H2
ewewigshoeveelheid.) (a)
Initial amount (moles)
0,6 0,6 0,1 0, 1
Aanvanklike hoeveelheid (mol)
Change in amount (moles)
-x + 0,6 -x + 0,6 -x + 0,6 -x + 0,6
Verandering in hoeveelheid (mol)
Equilibrium amount (moles)
Ewewigshoeveelheid (mol) (b) x x 0,7 - x 0,7 - x
Equilibrium concentration (mol∙dm-3) x x 07 - x 0,7 - x
Ewewigskonsentrasie (mol∙dm-3) 2 2 2 2
(c)
[CO2 ][H2 ]
Kc = (d) m
[CO][H2 O] n(CO)eq =
M
0,7 - x 0,7 - x m
( )( ) (g) 0,23 =
2 2 (f)
4 (e) = x x 28 (h)
( )( )
2 2 m(CO)eq = 6,44 g (i)
x = 0,23
CALCULATIONS USING CONCENTRATION
BEREKENINGE WAT KONSENTRASIE GEBRUIK
Marking criteria:
(a) USING RATIO: [H2O] : [CO] : [H2] : [CO2] = 1 : 1 : 1 : 1
(b) Calculate [CO]initial, [H2O]initial, [CO2]initial AND [H2]initial (divide initial moles by the
volume of 2 dm3)
(c) [CO]eq = [CO]initial - ∆[CO] and [H2O]eq = [H2O]initial - ∆ [H2O] and
[CO2]eq = [CO2]initial + ∆ [CO2] and [H2]eq = [H2]initial + ∆[H2]
(d) Correct Kc expression
(e) Substitute Kc = 4
(f) Substitute Kc expression
(g) Substitute numerical value of x in c(CO)initial - ∆c(CO)
m
(h) Substitute 28 in n =
M
(i) CORRECT final answer; x = 6,72 g.
Range: 6,44 – 6,72 g
Nasienkriteria:
(a) GEBRUIK verhouding: [H2O] : [CO] : [H2] : [CO2] = 1 : 1 : 1 : 1
(b) Bereken [CO]begin, [H2O]begin, [CO2]begin AND [H2]begin (divide initial moles by the
volume of 2 dm3)
(c) [CO]ewe = [CO]begin - ∆[CO] en [H2O]ewe = [H2O]begin - ∆ [H2O] en
[CO2]eq = [CO2]begin + ∆[CO2] and [H2]ewe = [H2]initial + ∆[H2]
(d) Korrekte Kc uitdrukking (formules in vierkanthakies).
(e) Vervang Kc = 4
(f) Vervanging van konsentrasies in Kc-uitdrukking.
(g) Vervanging van nomeriese waarde van x in c(CO)begin - ∆c(CO)
m
(h) Vervang 28 in n =
M
(i) Korrekte final answer; x = 6,72 g.
Gebied: 6,44 – 6,72 g
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NSC/NSS – Marking Guidelines/Nasienriglyne
(x change concentration/
CO H2O H2 CO2
ewewigskonsentrasie.)
Initial concentration (mol∙dm-3)
0,3 0,3 0,05 0,05 (b)
Aanvanklike konsentrasie (mol∙dm-3)
Change (mol∙dm-3) (a)
x x x x
Verandering (mol∙dm-3)
Equilibrium concentration (mol∙dm-3)
0,3 - x 0,3 - x 0,05 + x 0,05 + x
Ewewigskonsentrasie (mol∙dm-3)
(c)
[CO2 ][H2 ] (d)
Kc =
[CO][H2 O]
(e)
(0,05 + ×)(0,05 + ×) (f)
4 =
(0,3 - ×)(0,3 - ×)
x = 0,18 (0,183)
m
[CO] = 0,3 – 0,18 (g) n(CO) =
M
-3
= 0,12 mol∙dm m
0,24 =
n(CO)eq = cV 28 (h)
= (0,12)(2) m(CO)eqm = 6,72 g (i)
= 0,24 mol
(x equilibrium concentration/
CO H2O H2 CO2
ewewigkonsentrasie) (b)
Initial concentration (mol∙dm-3)
0,3 0,3 0,05 0,05
Aanvanklike konsentrasie (mol∙dm-3)
Change (mol∙dm-3) -x + 0,3 (a)
-x + 0,3 -x + 0,3 -x + 0,3
Verandering (mol∙dm-3)
Equilibrium concentration (mol∙dm-3)
x x 0,35 - x 0,35 - x
Ewewigskonsentrasie (mol∙dm-3)
(c)
[CO2 ][H2 ] (d)
Kc =
[CO][H2 O]
(e)
(0,35 - ×)(0,35 - ×) (f) m
4 = n(CO) =
(×)(×) M
m
x = 0,12 mol∙dm-3 0,24 =
28 (h)
n(CO)eq = cV
= (0,12)(2) (g) m(CO)eqm = 6,72 g (i)
= 0,24 mol
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Physical Sciences P2/Fisiese Wetenskappe V2 18 DBE/November 2024
NSC/NSS – Marking Guidelines/Nasienriglyne
PRODUCTS ARE USED/PRODUKTE WORD GEBRUIK
CALCULATIONS USING MOLES
BEREKENINGE WAT GETAL MOL GEBRUIK
Marking criteria:
(a) USING ratio: n(H2O) : n(CO) : n(H2) : n(CO2) = 1 : 1 : 1 : 1
(b) n(CO)eq = n(CO)initial + ∆n(CO), n(H2O)eqm = n(H2O)initial + ∆n(H2O),
n(CO2)eq = n(CO2)initial - ∆n(CO2) AND n(H2)eqm = n(H2)initial - ∆n(H2)
(c) Divide neq by the volume 2 dm3
(d) Correct Kc expression.
(e) Substitute Kc value 4.
(f) Substitute concentrations in Kc expression.
(g) Substitute numerical value of x in n(CO)initial + ∆n(CO)change
m
(h) Substitute of 28 in n =
M
(i) Finale answer: 6,44 g
Range: 6,44 – 6,72 g
Nasienkriteria:
(a) GEBRUIK verhouding: n(H2O) : n(CO) : n(H2) : n(CO2) = 1 : 1 : 1 : 1
(b) n(CO)ewe = n(CO)begin + ∆n(CO), n(H2O)ewe = n(H2O)begin + ∆n(H2O),
n(CO2)ewe = n(CO2)begin - ∆n(CO2) EN n(H2)ewe = n(H2)begin - ∆n(H2)
(c) Deel newe deur 2 dm3
(d) Korrekte Kc-uitdrukking.
(e) Vervang Kc-waarde 4.
(f) Vervanging van konsentrasies in Kc-uitdrukking.
(g) Vervanging van nomeriese waarde van x in n(CO)begin +∆n(CO)
m
(h) Vervanging van 28 in n =
M
(i) Finale answer: 6,44 g
Gebied: 6,44 – 6,72 g
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NSC/NSS – Marking Guidelines/Nasienriglyne
(x change in amount/
CO H2O CO2 H2
verandering in hoeveelheid.)
Initial amount (moles)
0,6 0,6 0,1 0, 1
Aanvanklike hoeveelheid (mol) (a)
Change in amount (moles)
x x x x
Verandering in hoeveelheid (mol)
Equilibrium amount (moles)
(b) 0,6 + x 0,6 + x 0,1 - x 0,1 - x
Ewewigshoeveelheid (mol)
Equilibrium concentration (mol∙dm-3) 0,6 + x 0,6 + x 0,1 - x 0,1 - x
Ewewigskonsentrasie (mol∙dm-3) 2 2 2 2
(c)
[CO2 ][H2 ]
Kc = (d)
[CO][H2 O]
0,1 - x 0,1 - x
( )( )
2 2
4 (e) = 0,6 + x 0,6 + x (f)
( )( ) m
2 2 n(CO)eq =
M
x = - 0,37
m
0,23 =
28 (h)
n(CO)eq = 0,6 + (– 0,37) (g)
m(CO)eq = 6,44 g (i)
= 0,23 mol
(x equilibrium amount /
CO H2O CO2 H2
ewewigshoeveelheid.)
Initial amount (moles)
0,6 0,6 0,1 0, 1
Aanvanklike hoeveelheid (mol)
Change in amount (moles)
-0,6 +x -0,6 +x -0,6 +x -0,6 +x (a)
Verandering in hoeveelheid (mol)
Equilibrium amount (moles)
(b) x x 0,7 - x 0,7 - x
Ewewigshoeveelheid (mol)
Equilibrium concentration x x 0,7 - x 0,7 - x
(mol∙dm-3)
Ewewigskonsentrasie (mol∙dm-3) 2 2 2 2
(c)
[CO2 ][H2 ]
Kc = (d)
[CO][H2 O]
0,7 - x 0,7 - x m
( )( ) n(CO)eq =
2 2 M
4 (e) = x x (f)
( )( ) (g) m
2 2 0,23 =
28 (h)
x = 0,23
m(CO)eq = 6,44 g (i)
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Physical Sciences P2/Fisiese Wetenskappe V2 20 DBE/November 2024
NSC/NSS – Marking Guidelines/Nasienriglyne
CALCULATIONS USING CONCENTRATION
BEREKENINGE WAT KONSENTRASIE GEBRUIK
Marking criteria:
(a) USING RATIO: [H2O] : [CO] : [H2] : [CO2] = 1 : 1 : 1 : 1
(b) Calculate [CO]initial, [H2O]initial, [CO2]initial AND [H2]initial (divide initial moles by the
volume of 2 dm3)
(c) [CO]eq = [CO]initial + ∆[CO] and [H2O]eq = [H2O]initial + ∆ [H2O] and
[CO2]eq = [CO2]initial - ∆ [CO2] and [H2]eq = [H2]initial - ∆[H2]
(d) Correct Kc expression
(e) Substitute Kc = 4
(f) Substitute Kc expression
(g) Substitute numerical value of x in c(CO)initial + ∆c(CO)
m
(h) Substitute 28 in n =
M
(i) CORRECT final answer; x = 6,72 g.
Range: 6,44 – 6,72 g
Nasienkriteria:
(a) GEBRUIK verhouding: [H2O] : [CO] : [H2] : [CO2] = 1 : 1 : 1 : 1
(b) Bereken [CO]begin, [H2O]begin, [CO2]begin AND [H2]begin (divide initial moles by the
volume of 2 dm3)
(c) [CO]ewe = [CO]begin + ∆[CO] en [H2O]ewe = [H2O]begin + ∆ [H2O] en
[CO2]ewe = [CO2]begin - ∆[CO2] and [H2]ewe = [H2]initial - ∆[H2]
(d) Korrekte Kc uitdrukking (formules in vierkanthakies).
(e) Vervang Kc = 4
(f) Vervanging van konsentrasies in Kc-uitdrukking.
(g) Vervanging van nomeriese waarde van x in c(CO)begin - ∆c(CO)
m
(h) Vervang 28 in n =
M
(i) Korrekte final answer; x = 6,72 g.
Gebied: 6,44 – 6,72 g
(x change in concentration/
CO H2O H2 CO2
verandering in konsentrasie.) (b)
Initial concentration (mol∙dm-3)
0,3 0,3 0,05 0,05
Aanvanklike konsentrasie (mol∙dm-3)
Change (mol∙dm-3) (a)
X x x x
Verandering (mol∙dm-3)
Equilibrium concentration (mol∙dm-3)
0,3 + x 0,3 + x 0,05 - x 0,05 - x
Ewewigskonsentrasie (mol∙dm-3)
(c)
[CO2 ][H2 ] (d)
Kc =
[CO][H2 O]
(e)
(0,05 - ×)(0,05 - ×) (f)
4 =
(0,3 + ×)(0,3 + ×)
x = - 0,18 (0,183)
m
[CO] = 0,3 +( – 0,18) (g) n(CO) =
M
= 0,12 mol∙dm-3
m
n(CO)eq = cV 0,24 =
28 (h)
= (0,12)(2)
= 0,24 mol m(CO)eq = 6,72 g (i)
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Physical Sciences P2/Fisiese Wetenskappe V2 21 DBE/November 2024
NSC/NSS – Marking Guidelines/Nasienriglyne
(x equilibrium concentration/
CO H2O H2 CO2
ewewigkonsentrasie)
Initial concentration (mol∙dm-3)
0,3 0,3 0,05 0,05 (b)
Aanvanklike konsentrasie (mol∙dm-3)
Change (mol∙dm-3) (a)
-0,3 +x -0,3 +x -0,3 +x -0,3 +x
Verandering (mol∙dm-3)
Equilibrium concentration (mol∙dm-3)
X x 0,35 - x 0,35 - x
Ewewigskonsentrasie (mol∙dm-3)
(c)
[CO2 ][H2 ]
Kc = (d)
[CO][H2 O]
(e) (0,35 - ×)(0,35 - ×) (f)
4 =
(×)(×) m
n(CO) =
x = 0,117 mol∙dm-3 M
m
0,233 =
28 (h)
n(CO)eq = cV
= (0,117)(2) (g) m(CO)eq = 6,53 g (i)
= 0,233 mol
(9)
[20]
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Physical Sciences P2/Fisiese Wetenskappe V2 22 DBE/November 2024
NSC/NSS – Marking Guidelines/Nasienriglyne
QUESTION 7/VRAAG 7
7.1 Weak bases dissociate/ionise incompletely/partially in water to form a low
concentration of hydroxide/OH─ ions
Swak basisse dissosieer/ioniseer onvolledig/gedeeltelik in water om 'n lae
konsentrasie hidroksied/OH─-ione te vorm. (2)
-
7.2 HCO3 (aq) (1)
7.3
7.3.1 26,55 (cm3) (1)
7.3.2 28,15 (cm3) (1)
7.4 • The titration’s equivalence point/colour change is in pH range less than 7./
Solution is acidic/ The reaction of strong acid and weak base has
equivalence point at pH less than 7.
Die titrasie se ekwivalente punte/kleurverandering is in pH gebied minder
as 7./ Oplossing is suur/ Die reaksie van 'n sterk suur met 'n swak basis het 'n
ekwivalente punt laer as pH 7.
• The end point of this titration is within the pH range in which methyl
orange/indicator changes colour./Methyl orange changes colour at a pH less
than 7.
Die endpunt van hierdie titrasie is binne die pH-gebied waarin
metieloranje/indicator kleur verander./ Metieloranje verander van kleur by ‘n
pH minder as 7.
(2)
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Physical Sciences P2/Fisiese Wetenskappe V2 23 DBE/November 2024
NSC/NSS – Marking Guidelines/Nasienriglyne
7.5 Marking criteria Nasienkriteria:
Va × ca na Va × ca na
(a) Any formula: = (a) Enige formule: =
Vb × cb nb Vb × cb nb
OR n = cV OF n = cV
(b) Substitute: 0,1 mol∙dm-3 & (b) Vervang: 0,1 mol∙dm-3 &
25 x 10-3 dm3 (25 cm3) 25 x 10-3 dm3 (25 cm3)
(c) Substitute average volume 20,1 x 10-3 (c) Vervang gemiddelde volume
dm3 (20,1 cm3) 20,1 x 10-3 dm3 (20,1 cm3)
(d) Use ratio: (d) Gebruik verhouding:
1 1
n(K2CO3) = 2n(HCℓ) n(K2CO3) = 2n(HCℓ)
(e) Final answer: 0,0625 mol∙dm-3 (e) Finale antwoord: 0,0625 mol∙dm-3
Range: 0,06 to 0,0625 mol∙dm-3 Gebied: 0,06 tot 0,0625 mol∙dm-3
Note: Aantekening:
If 20,05 or 20,15 is used: deduct 1 mark Indien 20,05 of 20,15 gebruik word: trek
een punt af
OPTION 1/OPSIE 1: OPTION 2/OPSIE 2:
ca Va na n(HCℓ) = cV (a)
= (a) = (0,1)(25 x 10-3) (b)
cb Vb nb = 2,5 x 10-3 mol
(b) 0,1 × 25 2 1
= (d) n(K2CO3) = n(HCℓ) (d)
cb × 20,1 1 2
(c) 2,5 x 10-3
[K2CO3] = 0,0622 mol∙dm-3 (0,06) (e) =
2
= 1,25 x 10-3 mol
n(K2CO3) = cV
1,25 x 10-3 = c(20,1 x 10-3) (c)
c (K2CO3) = 0,0622 mol∙dm-3 (0,06) (e) (5)
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Physical Sciences P2/Fisiese Wetenskappe V2 24 DBE/November 2024
NSC/NSS – Marking Guidelines/Nasienriglyne
7.6 POSITIVE MARKING FROM QUESTION 7.5/
POSITIEWE NASIEN VANAF VRAAG 7.5
Marking criteria Nasienkriteria:
m m m m
(a) Any formula: n = OR c = (a) Enige formule: n = OF c =
M MV M MV
OR n = cV OF n = cV
(b) Substitute: 600 cm3 OR 0,6 dm3 in (b) Vervang: 600 cm3 OF 0,6 dm3 in
n = cV n = cV
m m
(c) Substitute: 6,525 in formula n = OR (c) Vervang: 6,525 in formule n =
M M
m OF
c= m
MV c=
m MV
(d) Substitute: 138 & 18 in n = m
M (d) Vervang: 138 & 18 in n =
(e) Final answer: x = 2 M
(e) Finale antwoord: x = 2
OPTION 1/OPSIE 1:
m
c= (a)
MV
6,525 (c)
0,0622 =
M(0,6) (b)
M = 174,84 g∙mol-1
K2CO3∙xH2O = 174,84
2(39) + 12 + (3)(16) + x(18) (d) = 174,84
x = 2 (e)
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Physical Sciences P2/Fisiese Wetenskappe V2 25 DBE/November 2024
NSC/NSS – Marking Guidelines/Nasienriglyne
OPTION 2/OPSIE 2: OPTION 3/OPSIE 3:
(b)
n(K2CO3) in 600 cm3 = (0,0622)(0,6) n(HCℓ) = cV (a)
= 0,0373 mol = (0,1)(2,5 x 10-2)
= 2,5 x 10-3 mol
1
n(K2CO3) = n(HCℓ)
2
2,5 x 10-3
=
2
= 1,25 x 10-3 mol
n(K2CO3) in 20 cm3 = 1,25 x 10-3 mol
n(K2CO3) in 600 cm3
(b)
(1,250 × 10-2 ) (600)
=
20
= 0,0375 mol
m m
n(K2CO3∙xH2O) = (a) OR n(K2CO3) =
M M
6,525 (c) m
0,0373 = 0,0373 =
138+18x (d) 138
m = 5,147 g
x = 2 (e) (c) (d)
m(H2O) = 6,525 – 5,147 Both/
= 1,378 g Beide
m
n(H2O) =
M
1,378
=
18
= 0,0766 mol
n(K2CO3):n(H2O)
0,0373 : 0,0766
x = 2 (e) (5)
[17]
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Physical Sciences P2/Fisiese Wetenskappe V2 26 DBE/November 2024
NSC/NSS – Marking Guidelines/Nasienriglyne
QUESTION 8/VRAAG 8
8.1
8.1.1 The oxidation number of H changes from +1 to 0 AND the oxidation number
of Mg changes from 0 to +2.
Die oksidasiegetal van H verander van +1 na 0 EN Die oksidasiegetal van Mg
verander van 0 na +2.
OR/OF
Mg0 → Mg2+ Oxidation number increases./Oksidasiegetal neem toe.
H+ → H20 Oxidation number decreases./Oksidasiegetal neem af. (2)
8.1.2 H+/HCℓ (1)
-
8.1.3 Cu/copper is a weaker reducing agent than hydrogen/H2 (and will not
reduce H+/hydrogen ion to H2).
OR
-
Cu/copper is too weak a reducing agent to reduce H+/hydrogen ion (to H2).
-
Cu/koper is 'n swakker reduseermiddel as H2 (en sal nie H+/waterstofione na H2
te reduseer).
OF -
Cu/koper is te 'n swak reduseermiddel om H+/waterstofione (na H2) te reduseer. (2)
8.1.4 Yes/Ja
-
-
NO3 /Nitrate ion/Nitric acid is a stronger oxidising agent than Cu2+/copper (II)
ion (therefore Cu/copper will be oxidised to Cu2+ /copper (II) ion).
-
-
NO3 /Nitrate ioon/Salpetersuur is 'n sterker oksideermiddel as Cu2+/
koper(II)ioon (daarom sal Cu/koper geoksideer word na Cu2+/koper(II)ion). (3)
8.2 Marking criteria/Nasienkriteria:
8.2.1 • Reactants Products Balancing
Reaktanse Produkte Balansering
• Ignore/Ignoreer ⇌ and phases/en fases
• Marking rule 6.3.10/Nasienreël 6.3.10
Pb(s) + 2Fe3+(aq) Pb2+(aq) + 2Fe2+(aq) Bal.
OR/OF:
Pb + 2Fe3+ Pb2+ + 2Fe2+ Bal. (3)
8.2.2 Increases/Toeneem (1)
[12]
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Physical Sciences P2/Fisiese Wetenskappe V2 27 DBE/November 2024
NSC/NSS – Marking Guidelines/Nasienriglyne
QUESTION 9/VRAAG 9
Notes/Aantekeninge
• Accept any other correct formula from the data sheet./Aanvaar enige ander
korrekte formule vanaf gegewensblad.
• Any other formula using unconventional abbreviations, e.g. E°cell = E°OA - E°RA
followed by correct substitutions:/Enige ander formule wat onkonvensionele
afkortings gebruik, bv. E°sel = E°OM - E°RM gevolg deur korrekte vervangings: 3
4
9.1 OPTION 1/OPSIE 1
E cell = Ereduction − E oxidation
= -0,13 – (0,80)
= -0,93 V
∴ non-spontaneous/nie-spontaan
OPTION 2/OPSIE 2
Pb2+ + 2e- Pb E = -0,13 V
2Ag 2Ag+ + 2e- E = -0,80 V
Pb2+ + 2Ag Pb + 2Ag+ E = -0,93 V
∴ non-spontaneous/nie-spontaan (5)
9.2.1 ANY ONE: (2 or 0)
• A substance of which the (aqueous) solution contains ions.
• A substance that dissolves in water to give a solution that conducts
electricity.
• A substance that forms ions in water / when melted.
• A solution/substance that conducts electricity through the movement of
ions.
ENIGE EEN: (2 of 0)
• 'n Stof waarvan die oplossing in water ione bevat.
• ‘n Stof wat in water oplos om 'n oplossing te vorm wat elektrisiteit gelei.
• 'n Stof wat ione in water vorm/ wanneer dit gesmelt word.
• 'n Oplossing/stof wat elektrisiteit gelei deur die beweging van ione. (2)
Copyright reserved/Kopiereg voorbehou Please turn over/Blaai om asseblief
Physical Sciences P2/Fisiese Wetenskappe V2 28 DBE/November 2024
NSC/NSS – Marking Guidelines/Nasienriglyne
9.2.2 2Cℓ- Cℓ2 + 2e-
Note/Aantekening:
-
• Cℓ2 + 2e- ← 2Cℓ ( 2 )
2
-
2Cℓ ⇌ Cℓ2 + 2e- (1 )
2
Cℓ2 + 2e- ⇌ 2Cℓ- ( 0 )
2
-
2Cℓ ← Cℓ2 + 2e- (0 )
2
• Ignore if charge omitted on electron./Ignoreer indien lading weggelaat op elektron.
•
- -
If charge (-) omitted on Cℓ /Indien lading (-) weggelaat op Cℓ :
Example/Voorbeeld: 2Cℓ Cℓ2 + 2e- Max/Maks: 1
2 (2)
9.2.3 Hydroxide ions/OH-/Sodium hydroxide/NaOH
Hidroksiedione/Natriumhidroksied
Hydrogen/H2
Waterstof (2)
9.2.4 Water/H2O is a stronger oxidising agent (than Na+/sodium ion) and water/H2O
will be reduced.
Water/H2O is 'n sterker oksideermiddel (as Na+/natrium-ioon) en water/H2O sal
gereduseer word.
OR/OF
Na+/sodium ion is a weaker oxidising agent than water/H2O and water/H2O will
be reduced.
Na+/natrium-ioon is 'n swakker oksideermiddel as water/H2O en water/H2O sal
gereduseer word. (2)
[13]
TOTAL/TOTAAL: 150
Copyright reserved/Kopiereg voorbehou
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